• Title/Summary/Keyword: 혼합확산

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Electrochemical Deposition Characteristics of Ca2+ on Cu Wire Electrode in CaCl2 Molten Salt (CaCl2 용융염에서 Ca2+의 Cu 전극에 대한 전기화학적 증착 특성평가)

  • Hwang, Dong Wook;Lee, Jong Hyeon;Jeong, Sang Mun
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.175-183
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    • 2022
  • With the expansion of the automobile market, the demand for Nd as an essential rare earth material for automobile motors is rapidly increasing. Research on the calcio-thermic reduction process between Nd2O3 and calcium-based alloys has been extensively studied in order to manufacture Nd. In this study, Ca-Cu, as a reducing for Nd2O3, was prepared by electrolysis in CaCl2 molten salt. Cu wire and graphite were employed as a working electrode and a counter electrode for electrolysis reaction, respectively. The reference electrode was manufactured by putting Ag wire in a mixture of AgCl and CaCl2 at a ratio of 1:99 mol%. The cyclic voltammetry results showed that the deposition of Ca2+ on the surface of working electrode was observed from a potential of -1.8 V, and the reduction potential of Ca2+ decreased as the reaction temperature increased. The diffusion coefficient of Ca2+ calculated by the chronoamperometry experiment was found to be 5.4(±6.8)×10-6 cm2/s. In addition, Ca-Cu liquid alloy was prepared by applying a constant potential to Cu electrodes. The element ratio of Ca-Cu alloy formed by applying a potential of -2.0 V was found to Ca:Cu=1:4.

Characteristics of Tide-induced Flow and its Effect on Pollutant Patterns Near the Ocean Outfall of Wastewater Treatment Plants in Jeju Island in Late Spring (제주도 하수처리장 해양방류구 인근해역의 늦은 봄철 조류 특성과 조석잔차류에 의한 오염물질의 분포 특성)

  • KIM, JUN-TECK;HONG, JI-SEOK;MOON, JAE-HONG;KIM, SANG-HYUN;KIM, TAE-HOON;KIM, SOO-KANG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.2
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    • pp.63-81
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    • 2021
  • In this study, we investigated the tide-induced flow patterns near the ocean outfall of the Jeju and Bomok Wastewater Treatment Plants (WTP) in Jeju Island by using measurements of Acoustic Doppler Current Meter (ADCP) and a numerical experiment with inserting passive tracer into a regional ocean model. In late spring of 2018, the ADCP measurements showed that tidal currents dominate the flow patterns as compared to the non-tidal components in the outfall regions. According to harmonic analysis, the dominant type of tides is mixed of diurnal and semi-diurnal but predominantly semidiurnal, showing stronger oscillations in the Jeju WTP than those in the Bomok WTP. The tidal currents oscillate parallel to the isobath in both regions, but the rotating direction is different each other: an anti-clockwise direction in the Jeju WTP and a clockwise in the Bomok WTP. Of particular interest is the finding that the residual current mainly flows toward the coastline across the isobath, especially at the outfall of the Bomok WTP. Our model successfully captures the features of tidal currents observed near the outfall in both regions and indicates possibly high persistent pollutant accumulation along the coasts of Bomok.

The Transformation of Norms and Social Problems: Focusing on the COVID-19 Pandemic (규범의 전환과 사회문제: 코로나를 중심으로)

  • Lee, Jangju
    • Korean Journal of Culture and Social Issue
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    • v.28 no.3
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    • pp.513-527
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    • 2022
  • This study was conducted to examining the socio-cultural impact of the COVID-19 pandemic that swept the world around 2020, and the transformation of norms and social problems due to COVID-19. For this, the characteristics of changes in the socio-cultural norms of the 14th century European Black Death, a representative example of the pandemic, were derived, and based on this, the COVID-19 pandemic was analyzed. The Black Death served as an opportunity to change social norms based on the existing religious authority and the power of the feudal system to the Enlightenment. The population declination and labor shortage also promoted commercialization and mechanization. Printing, which spread during this period, led to the popularization of knowledge, which raised the level of thinking and led to epochal scientific development. This became the foundation of the Industrial Revolution. Like the recent Black Death, COVID-19 has triggered changes in social norms. The technological environment of metaverse, a mixture of virtual and reality, has changed the norm of a consistent identity into free and open identities exerting various potentials through alternate characters. In addition, meme, which are about people being friendly to those with the same worldview as him on the metaverse, weakened the sense of isolation in non-face-to-face situations. Artificial intelligence (AI), which developed during the COVID-19 pandemic, has entered the stage of being used for creative activities beyond the function of assisting humans. Discussions were held on what new social problems would be created by the social norms changed due to the COVID-19 pandemic.

A Transient Separation Behavior of PDMS/PSF Hollow Fiber Membrane Modules for Ethanol-Water Mixtures (PDMS/PSF 중공사 분리막의 시간 의존적 에탄올-물 분리 거동 연구)

  • Muhammad Junaid, Ammar;Arepalli, Devipriyanka;Kim, Min-Zy;Ha, Seong Yong;Cho, Churl Hee
    • Membrane Journal
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    • v.32 no.2
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    • pp.163-171
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    • 2022
  • Many studies on pervaporation (PV) for the separation of dilute alcohols as an alternative to conventional energy-intensive technique of distillation have been conducted earlier. The pervaporation transition behavior of ethanol-water mixtures through the PDMS/PSF membrane is important, in order to understand the mechanism of diffusion process. Therefore, in the present work, transient PV behavior for 50 wt% EtOH/H2O mixture at 50℃ was investigated by using 1194 cm2 PDMS/PSF hollow fiber membrane modules. The overall total flux and the separation factor of all the membrane modules increased initially and then gradually decreased with respect to PV time. The initial increase can be attributed to fact that membrane fibers were dry and it took time to dissolve into the membrane surface, but the subsequent decrease is due to the depletion of ethanol concentration in the feed. Therefore, it was confirmed that the ethanol permeation through a PDMS membrane is governed by the solution-diffusion mechanism.

Injection Characteristics Evaluation of Conductive Grout Material According to Carbon Fiber Mixing Ratio (탄소섬유 배합비에 따른 전도성 그라우트 재료의 주입특성평가)

  • Hyojun Choi;Wanjei Cho;Hyungseok Heo;Teawan Bang;Chanyoung Yune
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.1
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    • pp.15-23
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    • 2023
  • The grouting method is a method of construction for the purpose of waterproofing and reinforcing soft ground. When grout is injected into the ground, there are various types of penetration and diffusion of grout depending on the shape of the ground, the size of soil, the porosity, and the presence or absence of groundwater. the current situation. Therefore, in this study, to investigate the penetration performance of the grouting to conductive material, laboratory tests were performed on the addition of the conductive material. In the injection test, 0%, 3%, and 5% of the mixed water were added as conductive materials to the grout, and the original ground condition was composed of various types of ground composed of gravel and silica sand. Conductive grout is injected by pressure into the model ground using a dedicated injection device, and the injection time (t), pressure (p), flow rate (v) and injection amount (q) are measured, and the hardened body injected in the model ground is collected. Penetration performance was evaluated. In the results of the grout injection experiment, the amount of conductive material used and the grout injection rate showed an inverse relationship, and it was confirmed that the penetration pattern was changed according to the size of the soil particles in the model ground. The grout containing the conductive material has relatively good penetration into the ground and excellent strength and durability of the hardened body, so it was judged that it could be used as an additive for measuring the penetration range of the grout.

Separation of Antioxidants and Glucose from Grape Skin Extract Using Polyethylene Glycol and Sodium Citrate (폴리에틸렌글리콜과 구연산 나트륨을 이용하여 포도껍질 추출물에서 항산화물질과 포도당 분리)

  • Eun Min Shin;Yeong Eun Joo;Su Min Jung;Jaechan Suh;Chang-Joon Kim
    • Clean Technology
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    • v.29 no.2
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    • pp.109-117
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    • 2023
  • The purpose of this study is to develop a method for separating antioxidants and sugars from grape skin extract. The extract was first mixed with a variety of organic solvents to investigate whether the separation was feasible. When employing acetone, ethanol, dimethylsulfoxide, or dimethylformamide, the organic solvent-extract combination formed a single phase. However, when benzene, ethyl acetate, or n-hexane was added to the extract, the mixture separated into an organic and an aqueous phase and the pigments remained in the aqueous phase. On the other hand, when polyethylene glycol-2,000 (PEG-2000) and sodium citrate were added to the extract, the mixture was separated into three layers, with the majority of the flavonoids migrating to the top layer and 53% of the extract's glucose migrating to the bottom layer. The top layer had significant antioxidant activity, whereas the bottom layer showed no antioxidant activity. The glucose recovery in the bottom layer increased as the molecular weight of PEG increased and the highest recovery (67%) was observed when PEG-8,000 was added. The highest flavonoid separation was observed with PEG-2,000, followed by PEG-8,000 and PEG-400. The flavonoid separation when PEG-2,000 was added resulted in a flavonoid recovery of 48% and 0.2% from the top and bottom layers, respectively. Examining the effect of the separated solution using the agar disc diffusion method on yeast cell growth confirmed that the addition of the extract, the top, and the bottom layer did not inhibit cell growth.

Characteristics of Water Level and Velocity Changes due to the Propagation of Bore (단파의 전파에 따른 수위 및 유속변화의 특성에 관한 연구)

  • Lee, Kwang Ho;Kim, Do Sam;Yeh, Harry
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5B
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    • pp.575-589
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    • 2008
  • In the present work, we investigate the hydrodynamic behavior of a turbulent bore, such as tsunami bore and tidal bore, generated by the removal of a gate with water impounded on one side. The bore generation system is similar to that used in a general dam-break problem. In order to the numerical simulation of the formation and propagation of a bore, we consider the incompressible flows of two immiscible fluids, liquid and gas, governed by the Navier-Stokes equations. The interface tracking between two fluids is achieved by the volume-of-fluid (VOF) technique and the M-type cubic interpolated propagation (MCIP) scheme is used to solve the Navier-Stokes equations. The MCIP method is a low diffusive and stable scheme and is generally extended the original one-dimensional CIP to higher dimensions, using a fractional step technique. Further, large eddy simulation (LES) closure scheme, a cost-effective approach to turbulence simulation, is used to predict the evolution of quantities associated with turbulence. In order to verify the applicability of the developed numerical model to the bore simulation, laboratory experiments are performed in a wave tank. Comparisons are made between the numerical results by the present model and the experimental data and good agreement is achieved.

Analysis of Damage Impact Range according to the NG/NH3 Mixing Ratio when applying Ammonia as Fuel for a Combined Cycle Power Plant using an ALOHA Program (ALOHA 프로그램을 활용한 복합화력발전소 내 암모니아 연료 적용 시 NG/NH3 혼소율에 따른 피해영향범위 분석)

  • Yoo Jeong Choi;Hee Kyung Park;Min Chul Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.73-84
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    • 2024
  • In this study, a quantitative risk impact assessment is performed using an ALOHA program to identify the risks when applying ammonia as fuel for combined cycle power plants as one of the solutions of climate change. The worst and the alternative accident scenarios are established for the Sejong combined cycle power plant and the effective ranges are calculated in terms of flammability, thermal radiation, overpressure and toxicity. The analysis results show that the toxic risk is the most critical and the effective distance is highly proportional to the mixing ratio of natural gas and ammonia by showing the Pearson's correlation coefficient over 98% as 0.991, 0.987 and 0.989 for the Level Of Concern(LOC)-1, LOC-2 and LOC-3, respectively. In addition, the coefficients of linearity for LOC-1, LOC-2 and LOC-3 are calculated to 133, 70 and 29, respectively so it can be confirmed that the effective distance increases as the criterion decreases.

A Study on the Work Adaptation of Re-Employed Industrial Accident Workers (재취업 산재근로자의 직장 적응 결정요인 분석)

  • Kye-Won Choi;Young-Min Lee
    • Journal of Industrial Convergence
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    • v.22 no.3
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    • pp.1-12
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    • 2024
  • The purpose of this study is to categorize the adaptation of re-employed injured workers to the workplace and to explore the determinants that affect their adaptation to the workplace. In order to categorize the group of re-employed injured workers to adapt to the workplace, a latent profile analysis was conducted on 522 injured workers. As a result of the analysis, the workplace adaptation group was classified into three types: environmental dominant adaptation type (group 1), work-oriented adaptation type (group 2), and 'environmental adaptation type (group 3). In addition, as a result of conducting a mixed regression analysis to analyze the factors influencing their adaptation to the workplace after industrial accident, it was found that the work-oriented adaptation and environmental adaptation adaptation type were lower than the environmental dominant adaptation type. In addition, it was confirmed that educational background and self-esteem are factors that have an important influence on the adaptation of injured workers to the workplace. Based on the results of this study, it was suggested that the system needs to be supplemented in two aspects: customized support for individuals in the pre-reemployment stage and the employment environment after re-employment in order to increase the adaptation of injured workers to work. Specifically, there are consideration of the development and spread of rehabilitation programs and the expansion of the scope of subsidies that were paid only to the original business owners. Through this study, it is expected that more targeted policy measures can be prepared for re-employed injured workers.

The Physiochemical Characteristics of Seawater and Sediment of Marine Shellfish Farm in Jindong Bay (진동만 패류양식해역의 환경특성)

  • Jeong, Woo-Geon;Cho, Sang-Man
    • The Korean Journal of Malacology
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    • v.19 no.2
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    • pp.161-169
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    • 2003
  • Seawater and sediment quality analysed was calculated to examinate the present environmental characteristics and pollution load was also calculated to evaluate the effect of farming area on the coastal environment. The measurements for seawater quality demonstrate the coastal environment has relatively eutrophicated with significantly decreased DO (0.2-8.5 mg/l) and elevated COD (9.6-31.2 mg/l) in summer. It was also evident that the water quality in Jindong Bay has been influenced by residues tide from Masan Bay with high metal concentration in August of 2002. Annual total pollution load (land and farm-driven) was estimated at 37,316 ton (SS) /yr: 9,809 ton/yr (26.3%) of land-driven load, 23,576 ton/yr (63.2%) of coastal sedimentation and 3,932 ton/yr (10.5%) of feces of cultural organisms. When all ark shell seedling farms are permitted species conversion to ascidian farm, the pollution load would increase by 196%, which may be another source for accelerating the eutrophication of the environment in Jindong Bay.

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