• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.3
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• pp.175-182
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• 2009

The spent cationic exchange resins and anionic exchange resins were separated from mixed spent exchange resins by a fluidized bed gravimetric separator. The separated resins were identified by an elemental analysis and thermogravimetric analysis. The each test sample was prepared by diluting the slurry made by wet ball milling the cationic exchange resins and the anionic exchange resins separated as a spherical granular form for 24 hours. The resulting test samples showed a slurry form of less than $75{\mu}m$ of particle size and 25,000ppm of $COD_{cr}$. The decomposition conditions of each test samples from a thermal power plant were obtained with a lab-scale(reactor volume : 220mL) supercritical water oxidation(SCWO) facility. Then pilot plant(reactor volume : 24 L) tests were performed with the test samples from a thermal power plant and a nuclear power plant successively. Based on the optimal decomposition conditions and the operation experiences by lab-scale facility and the pilot plant, a commercial plant(capacity : 150kg/h) can be installed in a nuclear power plant was designed.

• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.10-17
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• 2013

Heavy oil residue upgrading process was being used in conventional refinery process. Recently, as the importance of non conventional energy development is growing up, the commercial projects of heavy oil upgrading are getting more active than before. For having competitive business model in the resource competition, non conventional energy development should be considered as an important business strategy. In developing oil sands, extra heavy oil, and shale gas, canadian oil sands and extra heavy oil have great importance in substitution of conventional oil consumption. In oil sands development, the bitumen, which is extracted from oil sands, has great value after upgrading or refining process. Similar process is being used current conventional refinery process. The bitumen is highly viscous hydrocarbon. This bitumen includes impurities which can not be treated in conventional refinery process. As this reason, specified process is needed in bitumen or extra heavy oil upgrading process. Moreover, there will be additional specified facilities in the process of production, transportation and marketing. In oil sands, there are various kinds of commercial upgrading process. Extraction, dilution, coking and cracking method were being used commercially.

• Clean Technology
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• v.6 no.2
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• pp.121-127
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• 2000

There are several kinds of hazardous materials in incinerator flue gas, such as particulate matter, acid gas, heavy metal, dioxin, etc. The activated carbon adsorption is considered as one of the methods removing dioxin from flue gas. Without any additional equipment and facilities, the activated carbon was mixed with lime and sprayed in the semi-drying reactor of an incinerator and filtered in the bag filter, and its efficiency of removing hazardous organic material was investigated. 1,2-dichlorobenzene (o-DCB) was used as a precursor material of dioxin and the effects of the activated carbon amount, the operating temperature of the reactor, and the atomizer r.p.m were measured and analyzed. Experimental results showed that the optimum outlet temperature of the reactor was $145^{\circ}C$ considering the performance of the bag filter, and the adsorption performance improved with the increase of the atomizer r.p.m. Also the performance of removing o-DCB in the bag filter is higher than of the semi-drying reactor.

• Plant Journal
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• v.9 no.3
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• pp.38-42
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• 2013

Submarine gas fields have focused because of the increasing fuel cost, the environmental regulations, and the safety & NIMBY problems. LNG-FPSO which is available for acid gas removal, recovery of the condensate & LPG and Liquefaction in topside process is one of high technology offshore structures. On the other hands, it is necessary to verify the pre-treatment efficiency by the ship motion and to apply to the design for LNG-FPSO. This study is to develop the pre-treatment technology for LNG-FPSO as taking account to the process efficiency by ship motion effects and the area optimization. Based on the simulation results, it founds that hybrid process shows the low circulate rate, the low heat duty and the small size of column dimensions compared to typical amine process. It will be verified the process efficiency in the various conditions by sea states as performing the 6-DOF motion test and CFD simulation.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.05a
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• pp.108-108
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• 1998

일반적으로 탄소강은 수용액 중에 노출될 경우 전면부식에 의한 손상을 받는다. 그러나 부식방지를 위하여 부식억제제를 적용할 경우, 탄소강의 부식거동은 현저한 변화를 겪게된다. 이러한 부식거동의 변화는 첨가되는 부식억제제의 종류에 따라 분 류할 수가 있는데, 양극부식억제제, 음극부식억제제 그리고 이들의 혼합부식억제제로 분류할 수가 있다. 현장에 적용된 부식억제제 시스템 중에는 자동차용 부동액과 가스히터용 열전달 매체액이 있다. 이러한 부식억제제가 적용된 시스댐은 정확한 부식억제능의 평가에 의한 그 교체 시기의 결정이 매우 중요하다. 교체 시기가 빠를 경우, 유지비용이 과다하게 소요되는 문제가 있으며, 교체시기가 늦을 경우 설비의 부식을 초래하는 문제 가 있다. 따라서 부식억제제의 정확한 성능 평가법은 매우 중요하며, 이에 대한 다양 한 연구가 진행 중이다. 부식억제제가 함유된 용액의 부식억제성능을 평가하는 방법에는 대표적으로 무게 감량법을 이용하고 있다. 이 방법은 다종의 금속이 적용된 자동차용 부동액을 실제 사용조건과 유사한 실험 조건에서 단기간, 가혹조건에서의 무게 감량에 의해 부식억 제능을 평가하는 방법이다. 그러나 이러한 방법은 특히 국부부식이 진행될 경우 부 식억제능을 정량화 하는데 어려움이 있다. 한편 전기화학적 측정방법으로는 분극곡선법을 이용한 $E_P$(공식개시전위), $E_R$(재부동태 화전위)의 측정법이 있다. 또한 부식억제피막의 안정성을 측정하기 위한 방법으로 인 위적인 양극전류 인가에 의한 피막의 파괴후에 피막이 복원가능 여부 및 그 속도 측 정에 의해 부식억제제의 건전성을 확인할 수가 었다. 본 연구에서는 가스히터의 주구성 재료인 A210 Gr Al의 탄소강을 사용하여, 사용기간이 5년 이상되어 부식억제 기능을 거의 상실한 것으로 여겨지는 열전달 매체액 과 신규 부식억제제가 적용된 시스템 등 객관적으로 확인된 부식억제제 시스랩에 대 하여 다양한 평가 방법을 동원 비교분석하고자 하였다. 실험은 KSM 2142에 의한 무게감량법, 분극곡선 측정에 의한 $E_P$(공식개시전위), $E_R$(재부동태화전위) 측정, 시간에 따른 자연전위 변화 측정 빛 이때의 부식속도(선형분극법), 인위적인 피막 파괴 전,후 의 전위 변화 및 부식속도 측정법에 의한 국부부식 발달 저지능 등을 평가하여 각 실험결과를 비교분석하여 보았다.

• Proceedings of the KSCN Conference
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• 2003.11a
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• pp.1081-1082
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• 2003

교육인적자원부에서는 학교급식의 안전성 확보를 위하여 1999년에 특별정책 연구를 실시하여 학교급식 HACCP 일반모델을 개발 보급하고 2001년부터는 규모가 큰 학교에서 조리실이 설치된 모든 급식학교로 점진적으로 적용을 확대하였다. 그럼에도 불구하고 학교급식에서 식중독 사고는 증가 추세에 있으므로 학교급식에서의 HACCP 시스템을 재진단하고 수행도가 낮은 중점관리점의 문제점을 짚어내는 것이 필요하다. 따라서 본 연구에서는 대전지역의 초, 중, 고등학교 영양사 153명을 대상으로 위생관리 직무 수행도와 HACCP의 일부 CCP (중점관리점)수행도, HACCP에 대한 인지도, 급식시설현황 등에 대하여 조사하고 변인간의 관련성을 분석하였다. 조사 대상자는 초등학교 영양사 56.5%, 중학교 영양사 25.5%, 고등학교 영양사 17.6%이었으며 4년제 대학 졸업자가 51.0%로 가장 많았고 연령은 30-34세가 36.6%, 35-40세가 21.6%로 30대가 대부분이었다. 근무경력은 평균 5.8년이었으며 영양사 1인당 담당하는 평균 학생수는 1,163명, 조리종사원 1인당 배식 아동수는 평균 124명이었다. 배식방법은 교실배식이 56.2%, 식당배식 34.6%, 교실과 식당의 혼합형태가 9.2%로 교실배식이 차지하는 비율이 많았고 직영급식이 90.2%로 대부분을 차지하였다. 위생관리 영역의 수행도는 개인위생관리 부문이 가장 높았고 기기설비 위생관리, 저장관리, 교차오염관리, 시간관리, 온도관리 순으로 나타났으며, 특히 온도관리 수행도는 낮은 것으로 나타났다. 식당배식을 실시하는 학교의 온도관리 수행도가 다른 그룹에 비해 높았고 직영급식의 시간관리수행도가 위탁급식 보다 높았다. 영양사의 연령과 근무경력이 증가할수록 모든 위생관리영역에서 수행도가 높아지는 경향을 보였다. CCP별 수행정도 평가에서는 ‘운반 및 배식과정(CCP7)’이 가장 높은 수행도를 나타냈고 그 다음으로는 ‘검수’, ‘식품취급 및 조리과정’, ‘식품접촉 표면 세척 및 소독과정’, ‘식단의 구성’, ‘생채소 및 과일의 소독’, ‘잠재적으로 위험한 식단의 관리’ 순으로 나타났다. ‘운반 및 배식과정의 수행도’는 식당배식이 유의적으로 높은 점수를 보였고 CCP8(식품접촉표면의 세척 및 소독)를 제외한 모든 영역에서 직영급식이 위탁급식에 비해 높은 유의성을 나타내었다. 또한 근무경력과 연령이 많을수록 모든 CCP영역에서 높은 수행도를 보였다. CCP1과 CCP2의 수행도가 낮은 주된 이유로 ‘CCP1과 CCP2의 관리기준이 이해하기 어렵다’이었다. 학교 급식관리 영양사의 HACCP시스템에 대한 지식 및 이해 정도를 조사한 결과 HACCP 인지도 점수의 평균은 총 100점 만점에 전체 평균 점수는 74.9점이었다 CCP별 점수분포는 CCP7의 인지도 점수가 가장 높았고 CCP6, CCP1, CCP5, CCP3, CCP8, CCP2의 순으로 절차 낮아졌다. 정규직의 HACCP인지도 점수가 위탁직 보다 높았으며 근무경력에서도 경력이 3년 미만인 경우가 가장 낮고 8년 이상인 경우가 가장 높은 점수를 보였다. 급식시설면은 보온보냉시설을 갖춘 학교가 온도관리 부문에서 갖추지 않은 학교보다 높은 수행도를 나타냈고, 전처리실과 손 소독기가 있는 학교는 교차오염관리 부문에서 높은 수행도를 보였다.

• Journal of the Korean Institute of Gas
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• v.25 no.5
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• pp.1-10
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• 2021

Semiconductor Photo Resist (PR) automation equipment uses a mixture of several flammable substances, and when it leaks during the process, it can lead to various accidents, therefore, risk assessment is necessary. This study analyzed the frequency of leakage of Acetone and PGMEA used in PR automation equipment and the frequency at which such leakage could lead to a fire accident through the frequency analysis method, and evaluated the need for additional risk reduction measures in the current facility. Based on the process leak data and ignition probability data of IOGP, leak frequency analysis and ignition probability were derived, and the frequency of actual fire accidents was analyzed by combining them. The frequency of material leakage in semiconductor PR process is 7.30E-03/year, and fire accidents can occur by acetone that exists above the flash point when the material is leaked, the frequency was calculated at the level of 1.24E-05/year. According to the UK HSE, for a major accident occurring with a frequency of 1.24E-05/year, it is defined as "Broadly Acceptable", a level that does not require additional measures for risk reduction when it causes 7 or less deaths, and due to the process operated by two people, no additional risk reduction are required.

• Environmental and Resource Economics Review
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• v.28 no.2
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• pp.201-229
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• 2019

This paper estimates the effects of generation mix changes in the $7^{th}$ and $8^{th}$ Basic Plan for Long-term Power Supply and Demand from two aspects: economic efficiency through electricity prices and environmental performance through $CO_2$ and air pollutants(NOx, SOx, PM) emissions. Particularly, we examined additional generation mix conversion paths that take into account the trade-off between economic efficiency and environmental performance through scenario analysis. According to our results, the conversion from the $7^{th}$ plan to the $8^{th}$ plan should increase the electricity prices in the mid- and long-term, while reducing GHG and air pollutants emissions at the same time. The alternative generation mix that combines $7^{th}$ and $8^{th}$ plans shows that there exists a path to mitigate the trade-off between economic and environmental in the long-term. It will be next to impossible to derive a optimal generation mix that simultaneously considers the core values, such as supply stability, environmental performance, economic efficiency, energy safety and energy security, when establishing the power supply and demand plan. However, by exploring the effects of various generation mix paths and suggesting near-optimal paths, people can best choose their direction after weighhing all the paths when deciding on a forward-looking generation mix in the long term.

• Resources Recycling
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• v.31 no.6
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• pp.60-65
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• 2022

This study presents the carburization process for recycling sludge, which was formed during silicon wafer machining. The sludge used in the carburization process is a mixture of silicon and silicon carbide (SiC) with iron as an impurity, which originates from the machine. Additionally, the sludge contains cutting oil, a fluid with high viscosity. Therefore, the sludge was dried before carburization to remove organic matter. The dried sludge was washed by acid cleaning to remove the iron impurity and subsequently carburized by heat treatment under vacuum to form the SiC powder. The ratio of silicon to SiC in the sludge was varied depending on the sources and thus carbon content was adjusted by the ratio. With increasing SiC content, the carbon content required for SiC formation increased. It was demonstrated that substoichiometric SiC_x (x<1) was easily formed when the carbon content was insufficient. Therefore, excess carbon is required to obtain a pure SiC phase. Moreover, size reduction by high-energy milling had a beneficial effect on the suppression of SiC_x, forming the pure SiC phase.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.226-233
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• 2023

In this study, the basic physical properties and microstructure of concrete interlocking blocks with amount of different CO₂ gas injection were analyzed according to determine the applicability of In-situ carbonation technology to construction secondary products. The amount of carbon dioxide gas injection was selected as 0, 0.1, 0.3, 0.5, 0.7 wt.% compared to cement amount. A lab-scale press equipment was designed to apply developed carbonation technology to real construction site. And mixer for stable CO₂ gas injection was designed. Using the designed devices, CO₂ gas injected samples were created and physical property of samples were performed. As a result of the physical property test, as the CO₂ injection amount increased to 0.3 %, it showed higher strength behavior compared to the original mix. And more than 0.5 % samples showed lower strength behavior than original sample, but they satisfied the standard of concrete interlocking block. This results were determined that CO₂ injection contributed to the creation of hydrates such as C-S-H. Therefore, the possibility of applying carbonation technology, which injects CO₂ during mixing, to various secondary construction products was confirmed.