• Title/Summary/Keyword: 혼합기 분포

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A study on the hydration of sludge from limestone washing process in a steel making factory (제철소 석회석수세슬러지의 수화반응 특성에 관한 연구)

  • Ahn, Ji-Whan;Kim, Ka-Yeoun;Kim, Hwan
    • Resources Recycling
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    • v.3 no.3
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    • pp.32-49
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    • 1994
  • Hydration process is one of the basic carbonation system. Limestone sludge produced in Pohang Iron & Steel Co., Ltd. We tested for identify of hydration characteristics. The result obtained in this study can be summarized as follows; 1. The classify of limestone sludge is type of ground calcium carbonate(-3mm+325mesh)and the major mineral of calcite, and further more high grade(CaO 51%), fine powder(15~22$\mu\textrm{m}$). 2. Limestone sludge mixed two process sludge, first one is washing process sludge and the other one is wet collect kiln dust. The composition rate is about 8:2. Wet collect kiln dust is major mineral of calcite, too. But the sludge is assumed to one by quick lime, slaked lime and unreacted natural limestone. So, the ideal process is dividing of the washing process sludge and wet collect kiln dust. 3. We manufactured of slaked lime from limestone sludge. To investigate the effect of hydration reactor, the experiments was done with various reactor type as magnetic stirrer, shaking incubator and ultrasonic vibration reactor, respectively. Generally, ultrasonic vibration reactor is excellent hydration for limestone sludge and produced very fine slaked lime powder with ideal distribution. 4. The optimum condition is 10% pulp density, when the manufacture of fine slaked lime powder by ultrasonic vibration reactor. And hydration times to compare the results of the study with ultrasonic vibration reactor of generalized most short time(5~10 min). 5. Finally, the dispersive characteristics of slaked lime powder measured 1~5 $\mu\textrm{m}$ from limestone sludge were compared with those of natural limestone ones(10~20$\mu\textrm{m}$), in order to check applicability of slaked lime with hydration process from limestone sludge.

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Identification of New, Old and Mixed Brown Rice using Freshness and an Electronic Eye (신선도와 전자눈을 이용한 현미 신곡, 구곡 및 혼합곡의 판별)

  • Hong, Jee-Hwa;Park, Young-Jun;Kim, Hyun-Tae;Oh, Sang Kyun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.63 no.2
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    • pp.98-105
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    • 2018
  • The sale of brown rice batches composed of rice produced in different years is prohibited in Korea. Thus, new methods for the identification of the year of production are critical for maintaining the distribution of high quality brown rice. Here, we describe the exploitation of an enzyme that can be used to discriminate between freshly harvested and one-year-old brown rice. The degree of enzyme activity was visualized through freshness test with Guaiacol, Oxydol, and p-phenylenediamine reagents. With electronic eye equipment, we selected 29 color codes for identifying new brown rice and old brown rice. The discrimination power of selected color codes showed a minimum of 0.263 to a maximum of 0.922 and an average value of 0.62. The accuracy with which new brown rice and old brown rice could be identified was 100% in principal component analysis (PCA) and discriminant function analysis (DFA). The DFA analysis had greater discriminatory power than did the PCA analysis. A verification test using new brown rice, old brown rice, or a mixture of the two was then performed to validate our method. The accuracy of identification of new and old brown rice was 100% in both cases, whereas mixed brown rice samples were correctly classified at a rate of 96.9%. Additionally, in order to test whether the discriminant constructed in winter can be applied to samples collected in summer, new and old brown rice stored for 8 months were collected and tested. Both new and old brown rice collected in summer were classified as old brown rice and showed 50% identification accuracy. We were able to attribute these observations to changes in enzyme content over time, and therefore we conclude, it will be necessary to develop discriminants that are specific to distinct storage periods in the near future.

Rate of Sediment Accumulation and Geochemical Characteristics of Muddy Sediment in the Central Yellow Sea (황해 중앙부 해역 니질 퇴적물의 지화학적 특성 및 퇴적률)

  • 윤정수;김여상
    • The Korean Journal of Quaternary Research
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    • v.16 no.1
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    • pp.1-16
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    • 2002
  • A total of 4 muddy sediment samples collected from the Central Yellow Sea were analyzed for chemical composition. The results are compared with the previously published Huanghe, Changjiang and Keum River geochemical data in order to understand provenance and sedimentation of fine-grained mud, and the sediment accumulation rates estimated. The sandy sediment facies is distributed in the eastern area, a patch of fine-grained mud exists in the western central prat, and the sandy mud and clay sedimentary facies shot. north to south zonal distribution in the central region. The content of calcium carbonate ranges from 2.8 to 10.5%, and its distributional trends to be more concentrated on the western muddy sediments near toward the China side rather than on the eastern sandy sediments. The accumulation rates obtained using Pb-210 geochronologies for the muddy sediments in the Central Yellow Sea showed ranges from 0.21 to 0.68 cm/yr or 0.176 to 0.714 g/$\textrm{cm}^2$. yr. The sedimentation rate from core CY96010 located in the eastern near side of Shandong Peninsula which is affected by the Huanghe River shows 0.68 cm/yr or 0.714 g/$\textrm{cm}^2$ . yr. The sediment cores CY96008 and CY96002 in the Central Yellow Sea, the estimated of sediment accumulation rates shows 0.21~0.23cm1yr or 0.176~0.220 9/$\textrm{cm}^2$.Vr respectively, which are much lower than above samples. These indicate that the muddy sediments in central area of the Yellow Sea may have received influence of the sediment discharge from the Huanghe River. The concentrations of Ca, Na, Sr, Ho, La, Tb, Ta and Ca/Ti ratio of the muddy sediments in the Central Yellow Sea are higher than those of the Changjiang sediments and lower than those of the Huanghe sediments. However, these element values showed similar concentration patterns than those of the Huanghe sediment. The element contents such as Fe, Ti, Nl, Co, Cr, Cu, Pb, Sc, Ce, Nd, Sm, Eu, Cd and Dy in the study area are higher than those of the Huanghe sediments and lower than the Changjiang River sediments, but these values showed close to resemblance content trends those of the Changjiang sediment. The concentration of Mn, K and Sr in sediments of the study area are similar to those of the Keum River and eastern Yellow Sea sediment. They are rich in Zn, Rb, Cd, U, Cs and Li than those of the other comparison legions. Therefore, the terrigenous materials sources of the muddy sediment in the Central Yellow Sea comes mainly from Huanghe River in the past and present, and also have party derived from the Changjiang and Keum River, while the biological deposit in this area are carried by the Yellow Sea Warm Current.

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Comparison of Color Quality, Winter Color, and Spring Green-up among Major Turfgrasses Grown under Three Different Soil Systems (세 종류 잔디지반 구조에서 주요 초종의 엽색품질, 동절기 색상 및 이른 봄 녹화 특성비교)

  • Kim, Kyoung-Nam
    • Horticultural Science & Technology
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    • v.31 no.3
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    • pp.259-268
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    • 2013
  • This study was carried out to evaluate the visual turfgrass's color quality, winter color, and spring green-up under three different soil systems and to make a practical use for sports turf design and construction. Several turfgrasses were evaluated in multi-layer, USGA and mono-layer systems. Turfgrass entries in the study comprised of 3 cultivars from Korean lawngrass (Zoysia japonica Steud.) of typical warm-season grass (WSG) and 3 blends and 3 mixtures from Kentucky bluegrass (KB, Poa pratensis L.), perennial ryegrass (PR, Lolium perenne L.), and tall fescue (TF, Festuca arundinacea Schreb.) of cool-season grass (CSG). Significant differences were observed in the turfgrass's color quality, winter color, and spring green-up in the study. Seasonal variation of visual turf color greatly occurred according to soil systems and turfgrasses. Multi-layer and USGA systems were highly associated with better visual color ratings, as compared with mono-layer system. Regardless of soil system, visual turf color in all entries was better from spring to fall than in winter. Great color differences were observed during a period of early December to early spring. CSG produced a better color quality over WSG in any soil system. Overall color ratings for CSG were KB > PR > Mixtures > TF. As for a winter color, its ranking was USGA > multi-layer > mono-layer system. No difference was found in winter among cultivars of Korean lawngrass, being completely brown, but great differences among CSG. Rated best for winter color was PR, followed by CSG mixtures, KB and finally TF in order. It was generally conceded that fast green-up in spring was greatly related with multi-layer over mono-layer system and also CSG over WSG. Among CSG, TF had a fastest green-up. PR was also fast in green-up, but poor in color uniformity. KB, however, was the slowest due to shallow rooting system, when compared with other CSGs. These results demonstrate color differences were greatly variable according to soil systems and also among turfgrass species. A precise decision should be made in selecting turfgrass species and soil system. Multi-layer and USGA systems were considered as the suitable one for turfgrass color quality, winter color and spring green-up. It is a great necessity to combine proper soil system, right turfgrass species, and appropriate mixing rates by a concept-oriented approach, when establishing garden, parks, soccer field, and golf courses and so on.

Paleoecological Aspect using Palynology since 4,000 Year B. P. in the Lowland of Western Central Korea (화분분석에 의한 한국 중서부 저지대의 4,000년전 이후 고환경)

  • 이상헌;전희영;윤혜수
    • The Korean Journal of Quaternary Research
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    • v.13 no.1
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    • pp.1-23
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    • 1999
  • A palynological investigation of the Annyeong-ri, Hwasung-gun Gyeonggi-do, in where Yung-Nung and Gun-Nung are located, was carried out for the first time. From the pollen analysis, two pollen zones are established: Pollen Zone I : Ainus-Quercus-Pinus and Pollen Zone Ⅱ : Pinus. Pollen Zone I is characterized by Mixed coniferous and deciduous broadleaved vegetation during about 3,500 yr. B.P.-2,000 yr. B.P., while after 2,000 yr. B.P. Pollen Zone Ⅱ appears to be Coniferous vegetation and Evergreen broadleaved vegetation. The former reflects there was a lowland fluvio-lacustrine environment before fully lacustrine one which represents the latter. Pollen analysis indicates the vegetation before 2,000 yr. B.P. was controled by environmental factor such as climate conditions, whereas after that time vegetation was strongly effected by human's impact. It is concluded that pollen analysis is useful to find out the relationship between vegetation history and man's interference. In addition freshwater algae play to tell the lake environments.

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Feature of Spray Transport and Atomization from Two-Phase Swirling Jet with Air-to-Liquid Mass Ratio (공기액체질량비에 따른 이류체 선회형 분사의 분무거동 및 미립화 특성)

  • Lee, Sam-Goo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.2
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    • pp.39-45
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    • 2004
  • Experiments were performed in a two-phase swirling spray facility that has been described elsewhere. Measurements of spray transport and drop size distribution are analyzed over wide ranges of air to liquid mass flow ratios, utilizing four different internal mixing pneumatic nozzles. The spatial distributions of mean velocities. fluctuating velocities, and velocity-diameter correlation were quantitatively analyzed. Also, the exponential correlation curves were obtained with ALR along the spray centerline, which indicated an approximately identical formulation regardless of ALR. It indicated that the atomization characteristics were remarkably superior in the case of 30o of swirl angle with higher ALR. Among other things. nozzle configuration is one of the significant parameters affecting spray phenomena from an internal mixing nozzle. Turbulence intensities are increasingly degenerated with an increase of nozzle configuration, allowing a rapid increment of drop size distribution.

Effect of Oxidation of Bond Coat on Failure of Thermal Barrier Coating (Bond Coat의 산화가 Thermal Barrier Coating의 파괴에 미치는 영향)

  • 최동구;최함메;강병성;최원경;최시경;김재철;박영규;김길무
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.88-94
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    • 1997
  • The oxidation behavior of the NiCrAlY bond coat and thermal fatigue failure in the plasma-sprayed thermal barrier coating system, ZrO2.8wt%Y2O3 top coat/Ni-26Cr-5Al-0.5Y bond coat/Hastelloy X superalloy substrate, in commercial use for finned segment of gas turbine burner were investigated. The main oxides formed in the bond coat were NiO, Cr2O3, and Al2O3. It divided the oxide distribution at this interface into two types whether an Al2O3 thin layer existed beneath ZrO2/bond coat interface before operation at high temperature or not. While a continuous layer of NiO was formed mainly in the region where the Al2O3 thin layer was present, the absence of it resulted in the formation of mixture of Cr2O3 and Al2O3 beneath NiO layer. Analyses on the fracture surface of specimen spalled by thermal cycling showed that spalling occurred mainly along the ceram-ic coat near ZrO2/bond coat oxide layer interface, but slightly in the oxide layer region.

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Synthesis and Surface Properties of Fluorinated Polyurethanes (불소화된 폴리우레탄의 합성과 표면특성)

  • Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.33-40
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    • 2001
  • Fluorinated polyurethane elastomers were synthesized by two step polyaddition of a perfluorinated polyether diol(trade name of Fomblin $ZDOL^{\circledR}$) and diisocyanates such as 4,4'-diphenyl methane diisocyanate(MDI) and toluene 2,4-diisocyanate(TDI). In order to control the Fomblin moiety of the soft segment in the synthesized elastomers to 10~50%, polyether type polyols such as polypropylene glycol(PPG) and polytetramethylene glycol(PTMG) were mixed during the polymerization reaction. Ethylene diamine or 1,4-butane diol was used as chain extenders. The structure and average molecular weight of the produced polyurethanes were confirmed by using FT-IR, $^1H-NMR$, DSC, and GPC. The surface properties were analyzed by using X-ray photoelectron spectroscopy(XPS) and contact angle meter. From the results of the surface analysis it was concluded that the fluorine groups were localized on the surface rather than the inside of the polyurethane films.

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도공층의 공극 구조와 인쇄후 잉크의 잔류거동에 관한 연구

  • 김병수;최창활;정성욱
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.04a
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    • pp.76-76
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    • 2001
  • 종이가 가지는 공극 특성은 종이의 광학적 특성에 지대한 영향을 미칠 뿐만 아니라 인쇄용 지로서 사용될 때 잉크의 다공성 기질로서 잉크의 잔류 특성에도 큰 영향을 미친다. 특히 다공성 기지의 표변에 유동성이 뛰어난 물질이 가해 질 때, 이들의 유동 특성은 기질이 지 니고 있는 공극율과 공극의 분포에 따라 큰 차이를 나타내는 것으로 알려져 있다. 이러한 공극성은 백상지의 경우 사용된 펄프의 혼합 비율과 충전제의 사용량 그리고 펄프의 고해 정도에 따라 종이의 공극울이 달라진다. 종이의 공극성이 광학적 특성과 밀접한 연관성을 지니는 것은 종이의 광산란 계수를 결정하기 때문이다. 잘 알려진 바와 같이 종이의 광산란 계수는 빛의 산란과 관계되어 백색도와 백감도에 영향을 미친다. 그러나 도공지가 인쇄 용 지로 사용 될 경우, 도공지 표면에 도피되는 영크층은 도공지가 가지고 있는 구조적 특성을 변화시킬 수 있는 제3의 요인으로 간주 될 수 있다. 결국, 인쇄가 완료된 종이의 경우 원지층, 도공층 그리고 잉크층으로 구성된다. 따라서 다양 한 공극 구조를 가지는 기질위에 잉크가 도피될 경우 기질의 공극 특성에 따라 잉크 조성분 의 침투 거동에도 많은 차이가 있을 것으로 예측된다. 잉크의 구성 요소를 살펴보면 잉크의 색상을 결정하는 안료, 단일의 각 안료 입자를 도포하여 인쇄판으로부터 종이까지 운송시키 는 기능과 인쇄기에서 잉크의 유동성을 유지하고 종이 또는 기타 피인쇄체에 전이된 후에는 건조막을 형성하는 비히클 그리고 각종 기능성 첨가제로 구성되어 있다. 동일한 성분으로 구성된 잉크를 사용하여 각각 공극성이 다른 피인쇄체 위에 인쇄 될 경우 이들 조성분의 이 동과 표면 잔류 특성에 변화가 있을 것으로 생각된다. 즉 공극성이 풍부한 기질에 도피된 잉크는 반대의 경우와 비교하여 보다 많은 조성분이 종이의 공극 속으로 침투하게 될 것이 다. 이 과정에서 특히 미세한 안료 입자의 경우 피인쇄체의 표면 공극을 채우고, 비히클의 경우 미세한 공극속으로 침투되어 경화됨으로써 피인쇄체가 지니고 있는 공극량을 감소시커 게 될 것이다. 그리고 피인쇄체의 각종 형태의 공극으로 침투된 잉크의 양에 반비례적으로 피인쇄체의 표변에 잉크가 잔류하게 될 것이다. 따라서 본 연구에서는 여러가지 안료를 사용하여 각각 다른 공극 특성을 지니는 도공지를 제조한 후 이들이 가지는 공극 특성과 잉크의 잔류 거동에 대해 고찰해 보고자 하였다.

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Discussion on the Mechanical Alloying Process of Ni-20Cr alloy (Ni-20 Cr계 분말의 기계적 합금화 과정에 대한 고찰)

  • Yoo, Myoung Ki;Choi, Ju
    • Analytical Science and Technology
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    • v.6 no.2
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    • pp.197-205
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    • 1993
  • Blends of elemental Ni and 20 weight % Cr powder were milled for different period in a laboratory attritor. Powder size distribution, microstructure and X-ray diffraction characteristics were investigated as a function of processing period. Saturated magnetization, Ms and coercive force, Hc we also measured and compared with plasma melted ingot to confirm the mechanically alloyed states. Mechanical alloying occurred as a consequence of the partition of powders and the increase of interfacial area driving diffusing of Cr into Ni. However, magnetic properties of chemically homogeneous solid solution like melted ingot has not been observed even though steady state of submicron grain size has been achieved after milling over 15 hrs. Further mechanical alloying period gave refinement of grain size, which resulted in the increase of alloyed layer. It is concluded that homogenization should be controlled by the increase of interfacial area between constitutive powders caused by plastic particle deformation and by the diffusion of Cr within the alloyed phase into Ni-rich phase through lattice defects.

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