• Title/Summary/Keyword: 형광 온도

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White electroluminescent device by ZnS:Mn, Cu, Cl phosphors

  • Kim Jong-Su;Park Jae-Hong;Kim Gwang-Cheol;Gwon Ae-Gyeong;Park Hong-Lee
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.05a
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    • pp.225-231
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    • 2006
  • .고상반응법 (solid state reaction)합성된 ZnS:Mn,Cu,Cl 형광체는 약 $20^{\sim}25{\mu}m$ 의 구형이고, Cubic/hexagonal 구조를 보였다. Electroluminescent device(ELD)는 실크 스크린된 형광층(ZnS:Mn,Cu,Cl)/유전체층 ($BaTiO_3$)으로 구성되었으며, 각층은 $30^{\sim}50{\mu}m,\;50^{\sim}60{\mu}m$ 정도로 도포 하였다. 100 V-400 Hz 의 구동조건에서, ELD 의 백색 발광은 450 nm, 480 nm 픽에서 각각 $Cl_s{\to}Cu^{+}\;_{Zn},\;Cl_s{\to}Cu^{2+}\;_{Zn}$ 전이에 의해 중첩된 청색, 녹색 밴드의 발광과, 580 nm 픽에서 Mn 의 $^{4}T_1{\to}^{6}A_1$ 전이에 의한 황색 밴드의 발광으로 이루어진다. Cu 농도의 증가에 따라 450 nm 의 발광 밴드의 휘도는 감소하며 580 nm 의 발광 밴드의 휘도가 증가하였고 발광 휘도가 향상되었다. 즉, 색온도가 높은 cold white(10000 K)에서 색온도가 낮은 Warm white(3000 K) 로 변한다. 이것은 450 nm 의 발광 밴드가 580 nm 의 발광 밴드에 흡수되는 에너지 전이 (Energy transfer) 현상에 기인한다. ZnS:Mn,Cu,Cl 의 Mn 1.5 wt %, Cu 2.5 wt.% 에서 최적 발광 휘도를 보이며, 100 V-400 Hz 에서 약 $12cd/cm^2$이였다.

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Effects of Activators and Heat Treatment on the Luminous Properties of $Zn_2SiO_4$ Phosphors (활성제 및 열처리효과가 $Zn_2SiO_4$ 형광체의 발광특성에 미치는 영향)

  • Park, Chan-Hyuk;Chung, Sung-Mook;Kim, Young-Jin;Song, Kuk-Hyun;Lee, Joon
    • Korean Journal of Crystallography
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    • v.13 no.2
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    • pp.63-68
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    • 2002
  • Zn/sub 2-x/Mn/sub x/SiO/sub 4/ phosphors for PDP were synthesized by solid state reaction method. The effects of firing temperature, ratio of hydrogen gas to nitrogen for heat treatment and concentration of activator and co-dopants on the luminous properties have been investigated. It was found that the phosphor fabricated at 1400℃ with x = 0.002 Mn concentration had a maximum brightness. Luminous properties of a phosphor were improved when Cr/sup 3+/ was added as a co-dopant rather than other co-dopants.

Impedance Properties of Solenoid Coil for Electrodeldss lamp (무전극 형광램프 안테나 코일의 임피던스 특성)

  • Kim, Kwang-Soo;Jo, Ju-Ung;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.525-528
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    • 2003
  • 유도결합형 플라즈마를 이용하는 무전극 형광램프는 소프트 페라이트를 이용하여 방전을 유도하며, 페라이트의 주파수나 온도 특성이 안정하면, 공심 솔레노이드코일을 사용하였을 때보다 램프저력이 더 효율적이 된다. 페라이트의 형상과 코일의 권선수는 코일의 임피던스, 인덕턴스, Q-factor에 직접적으로 영향을 주며, 감은 위치에 변화에 의해서도 그 값들이 변할 수 있다. 본 논문에서는 전구형 무전극 형광램프의 방전에 중요한 역할을 하는 안테나에 대한 실험 결과로서 Mn-Zn 페라이트를 이용한 솔레노이드 코일에 주파수와 코일의 권선수를 변화시켜 코일의 전기적 특성을 조사하였다. 임피던스 특성은 주파수가 증가함에 따라 증가하였으며, 코일의 권선수가 14회일 때, 기존 램프의 안테나와 비슷한 324[$\Omega$]을 나타내었으나, Q-factor는 코일의 권선수가 증가할 수 록 감소하였으며, 기존 램프의 안테나와 많은 차이를 나타내었다.

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Fine Size YAG:Tb Phosphor Particles Prepared by Spray Pyrolysis (분무 열분해 공정에 의해 합성된 미세 YAG:Tb 형광체)

  • Lee, Hyo Jin;Hong, Seung Kwon;Jung, Dae Soo;Kang, Yun Chan;Jung, Kyeong Youl
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.407-411
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    • 2005
  • YAG:Tb($Y_3Al_5O_{12}:Tb$) phosphor particles were prepared by spray pyrolysis from spray solution containing various types of flux materials. The effects of type of flux, organic material and post-treatment temperature on the characteristics of morphology, crystallinity and photoluminescence of YAG:Tb phosphor particles were investigated. Citric acid and ethylene glycol used as organic additive improved the photoluminescence intensity of the YAG:Tb phosphor particles without destruction of the morphology after post-treatment at high temperature. However, the spherical shape of the precursor particles obtained by spray pyrolysis from spray solution containing high amount of flux material disappeared after post-treatment at $1300^{\circ}C$. YAG:Tb phosphor particles prepared from spray solution containing lithium carbonate flux had fine size and regular morphology after post-treatment. Lithium carbonate used as flux material was also efficient in improvement of the photoluminescence intensity of the YAG:Tb phosphor particles. The optimum photoluminescence intensity of the YAG:Tb phosphor particles prepared from spray solution containing lithium carbonate flux was 189% of that of the phosphor particles prepared from spray solution without flux material.

Synthesis and Luminous Properties of Thin Film Phosphors (박막형 형광체 합성 및 발광 특성)

  • 김영진;정승묵;정영호;송국현;박광자
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.51-52
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    • 1999
  • 각기 녹색, 적색의 발광특성플 갖는 $ZnGa_20_4:Mn,{\;}CaTi0_3:Pr$을 rf 마그네트론 스퍼터링법으로 박막을 제조하였다. 박막증착변수가 성장특성 및 발광특성에 미치는 영향을 분석한 결과, 산소분압 및 기판온도조건에 따라서 결정화 및 발광특성이 크게 달라짐을 확인할수 있었다. 열처리후에는 진공분위기보다는 $N_2$가스분위기에서 열처리를 한 시편이 발광특성이 우수하 게 나타났으며, 기판의 종류에 따라서 박막의 성장기구와 발광특성이 다르며, 특히 결정질의 기판이 형광체 박막 합성에 적합함을 알 수 있었다.

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Electrical and optical characteristics of Cold Cathode Fluorescence Lamp (냉음극 형광램프의 전기적 및 광학적 특성)

  • Kim, Soo-Yong;Jung, Won-Chae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.502-505
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    • 2002
  • 본 논문에서는 냉음극 형광램프의 구조 및 동작원리를 파악하고 램프의 특성을 알아본다. 램프의 특성에 영향을 주는 요소인 관경, 관길이, 가스압, 전극등을 최적화 하여야 하고 CCFL(cold cathode fluorescent lamp) 의 휘도가 관선류, 주파수, 가스압력, 주위온도에 의한 영향에 따른 전기적 및 광학적인 특성을 분석하고자 한다.

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Optimization of Light Source Combination through the Illuminance and Color Temperature Simulation of Circadian Lighting Apparatus (감성조명용 조명기기의 조도 및 색온도 시뮬레이션을 통한 광원 조합의 최적화)

  • Park, Yang-Jae;Choi, Jong-Hyun;Jang, Myong-Gi
    • The Journal of the Korea Contents Association
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    • v.9 no.8
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    • pp.248-254
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    • 2009
  • The aim of this study is to optimize the light source combination which can maximize the capability of the illuminance and color temperature of circadian lighting apparatus. To achieve this goal, the circadian lighting apparatus was consisted of two different types of fluorescent lamps having different color temperature of 2000K and 8000K, respectively, and the capability of the illuminance and color temperature of circadian lighting apparatus was evaluated by optical simulation as the number of the respective lamps were varied. Considering the Kruithof's curve and exceptional cases, the ranges of illuminance and color temperature for the living activities were reclassified in 4 groups - gathering, studying, relaxing and sleeping - so that the target range of illuminance and color temperature of lighting apparatus was settled. As a result, in the case of adopting two fixtures in which four 2000K lamps and five 8000K lamps were consisted, respectively to one fixture, the highest illuminance was expected at 4000K and over 500lx of illuminance was calculated between 3000K and 6000K. Through the optimized combination of light sources, the range of illuminance and color temperature were calculated as $44{\sim}750lx$ and $2500{\sim}6500K$, respectively.

A study on the powder synthesis of the amorphous calcium carbonate precursor for phosphors by wet chemical method (습식법에 의한 형광체 제조용 비정질 탄산칼슘 전구체 분말의 합성에 관한 연구)

  • 최종건;김판채;이충효
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.302-308
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    • 2000
  • Stable amorphous calcium carbonate were synthesized from the serial work for the synthetic conditions such as concentration of solution, reaction temperature, aging time and pH of mother liquor. By using this as a precusor, calcite, aragonite and vaterite crystal particles were obtained in the water from adequate crystallization conditions. Furthermore, characterization for flourescence were performed by using crystals which were crystallized from the Sn dopped amorphous calcium carbonate. Calcite showed the most intensive emission and the center of emission wavelength was 464 nm with pure blue color. Calcite is expected to be used as phosphor for flourescent lamp because the maximum emission intensity was obtained from the excitation with 255 nm wavelength.

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Growth of $ZnGa_2O_4:Mn^{2+}$ Thin Film Phosphors by RF Magnetron Sputtering (박막 형광체 $ZnGa_2O_4:Mn^{2+}$의 RF Magnetron Sputtering법을 이용한 생장)

  • Kim J.S.;Lee S.H.;Park J.H.;Park H.W.;Choi J.C.;Park H.L.
    • Journal of the Korean Vacuum Society
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    • v.15 no.4
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    • pp.404-409
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    • 2006
  • Thin-film $ZnGa_2O_4 : Mn^{2+}$ phosphors of spinel structure were grown on quartz substrate by RF magnetron sputtering method at room temperature. As an increase of post-annealing temperatures, crystallinity, surface roughness and stoichiometry of thin films were varied. At the post-annealing temperatures of $500^{\circ}C$ and $600^{\circ}C$, the luminescence intensity was poor due to the poor crystallinity. The smallest surface roughness was observed at the sample post-annealed at $700^{\circ}C$ leading to low external extraction efficiency, and poor luminescence intensity. The highest luminescence intensity was shown at the sample post-annealed at $800^{\circ}C$. It was because both the surface roughness and crystallnity were optimized. On the other hand, at $900^{\circ}C$, the luminescence intensity was poor due to the violation of stoichiometry.

Photochemical Index Analysis on the Influence of LED Illumination Color Temperature on Donarium Cherry (도시야간조명의 LED 색온도별 겹벚나무의 광화학적 생리지표 해석)

  • Kim, Ji-Su;Yoo, Sung-Yung;Kim, Hway-Suh;Kim, Tae-Wan
    • Korean Journal of Environmental Biology
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    • v.36 no.2
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    • pp.117-123
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    • 2018
  • In this study, the efficiency of photosynthetic electron transfer according to LED color temperature was verified in order to find a way to efficiently grow trees under night illumination. The experiment was carried out with White treatment, Warmwhite treatment, and non-treatment with donarium cherry. The study uses to a method for analyzing and evaluating the color temperature of an LED light source by photochemical analysis. We found that all treatments 115 DAT of maximum fluorescence amount(P) had the lowest. In the treatment using white light and the Warm-white light, the T amount of florescence of the late stage during the transition of the J-I level was increased, and the photosystem I electron transfer efficiency was decreased. Therefore, the electron transport efficiency of $RE1_O/CS$ and RE1o/RC were reduced. Especially, compared to Warmwhite, the light intensity increased greatly in the white-light treatment, The $PI_{TOTALABS}$ of 7 DAT was the highest value, but it was decreased to the lowest value on 115 DAT. This study has shown that the white treatment was low in electron transfer efficiency and soundness. Warmwhite-light treatments showed lower stress.