• Title/Summary/Keyword: 한국 제4기학회

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Electrochemical Characteristics of Fine Soils in the Application of Electrokinetic Remediation (동전기력 복원공정 적용에 따른 세립토양의 전기화학적 특성 변화)

  • 고석오
    • Journal of Soil and Groundwater Environment
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    • v.7 no.3
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    • pp.85-94
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    • 2002
  • Overall objective of this study was to evaluate the electrochemical characteristics of fine soils during the electrokinetic(EK) remediation. Zeta potential of kaolinite as a function of solution pH and surfactant concentration was investigated to make a relationship with electroosmotic flow direction and rate. During the EK experiments, pH of pore solution, electroosmotic permeability($k_e$), electric conductivity($\delta_e$) and voltage distribution was measured, respectively, The point of zero charge(PZC) of kaolinite was estimated to be about 4.2 and the zeta potential of kaolinite above PZC was more negative as solution pH increased. Sorption of surfactants on the kaolinite altered the zeta potential of kaolinite. resulting from the variation of electrochemical characteristics of kaolinite surface. hs the EK experiment progressed, low pH was predominant over most of the kaolinite specimen and thus resulted in very low mass and charge flow. The $k_e$ and $\delta_e$ was also affected by the variation of voltage drop across the EK column with time. Results from this study implied that zeta potential of kaolinite affected by the pH variation of pore solution and voltage distribution in soil column played important role in the determination of mass and charge flow during EK process. It was also suggested that pH adjustment or addition of suitable sorbates could alter the electrochemical characteristics of soil surface and thus maintain high mass and charge flow rate with time.

Expression and Role of Trypsin-Like Enzyme Involved in Hatching of Preimplantation Mouse Embryos (생쥐 배아의 부화에 관여하는 Trypsin 유사 효소의 발현과 역할)

  • Kim, Soo-Kyung;Kang, Hee-Kyoo;Jun, Jin-Hyun;Choi, Kyoo-Wan;Kim, Moon-Kyoo
    • Development and Reproduction
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    • v.5 no.1
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    • pp.17-21
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    • 2001
  • This study was conducted to investigate the expression pattern of Trypsin-like enzyme and the effect of a trypsin inhibitor(benzimidine) on hatching process during in-vitro culture of mouse preimplantation embryos. The Trypsin-like enzyme was identified by rhodamine-conjugated Trypsin substrate probe. The expression of trypsin-like enzyme was firstly detected at the late morula stage, and the enzyme was uniformly localized in the trophectoderm of late blastocysts. Especially, intense fluorescence was observed in the blebbing area of hatching blastocysts. Bisbenzamidine, contained in culture media, did not alter embryonic development from 4-cell stage to the expanded blastocyst but decrease the hatching rate in ImM concentration (15.8% vs 89.7%, p<0.02). In the treatment of bisbenzimidine (5mM) for 12 hours according to the embryonic stage of mouse, the hatching rate of control (83.0%) and treatment in late blastocysts (8.7%) were significantly (p<0.01) different. From these results, we suggested that the hatching enzyme having trypsin-like activity was localized from the late morula stage, and the hatching process by this enzyme was activated in the late blastocyst stage of mouse embryos.

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Antioxidative Activity of the n-Hexane Fractions from Spatholobus suberectus (SS), Scutellsria barbata (SB), Psoralea corylifolia (PC), Curcuma zedoaria (CZ), Schisandra chinensis (SC), and Corydalis turtschaninovii (CT) (계혈등, 반지련, 보골지, 봉출, 오미자, 현호색 헥산 분획층의 항산화활성)

  • Choi, Eun-Jeong;Kim, Se-Hun;Shim, Sang-Hee;Chung, Hyun-Jung;Bang, Woo-Suk
    • Korean Journal of Food Science and Technology
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    • v.44 no.4
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    • pp.493-497
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    • 2012
  • The objective of this study was carried out in order to evaluate the antioxidative activities of n-hexane fractions from medicinal herbs. Certain parts from 6 species of edible and medicinal herbs were extracted with methanol. Radical scavenging activity of the n-hexane fractions against DPPH and ABTS radicals were observed to be high in Psoralea corylifolia, and Scutellsria barbata; it also significantly increased (p<0.05). For a comparison of the effect of various concentration of fractions, as the concentration of treatment increased, the antioxidative effects on radical scavenging activity also oncreased; yet it was not significant. The antioxidative effect of medicinal plants was dependent on the concentration but was not significant. Therefore, these results indicate that edible wild plants, such as Psoralea corylifolia, and Scutellsria barbata may be useful as potential antioxidant sources for improving the human antioxidant defense system against disease.

Development of Oxy-fuel Combustor for the Underwater SMV(Sub-Merged Vaporizer) (수중연소식 천연가스기화기(SMV)용 순산소 연소기 개발)

  • Sohn, Whaseung;Kim, Hoyeon;Jeong, Youngsik
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.253-254
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    • 2014
  • 지구온난화 문제는 한국가의 문제가 아니라 인류의 문제로 대두되어 많은 이에대한 많은 연구가 이루어 지고 있다. 지구온난화의 주 대상물질인 화석연료로부터 연소시 발생하는 이산화탄소를 감축하기위한 많은 규제와 노력이 요구된다. CCS(Carbon Capture & Storage)란 화석연료로 부터 연소시 대기 중으로 배출되는 온실가스($CO_2$)를 포집하여 재생 또는 지중, 해양에 저장하는 기술로서 국가녹색성장 핵심기술중의 하나로 분류되며, $CO_2$ 회수방안, 저장, 처리관련 연구를 비롯하여 국내외 적으로 활발한 연구가 이루어 지고 있다. 또한 순산소 연소기술을 통한 $CO_2$ 회수, 처리기술은 연료의 산화제를 공기대신 순도 95% 이상의 고농도 산소를 이용하여 순산소연소를 하며, 이때 발생하는 배가스의 대부분은 $CO_2$와 수증기로 구성되어 있다. 발생된 배가스의 약 70~80%를 다시 연소실로 재순환시켜 연소기의 열적 특성에 적절한 연소가 가능하도록 최적화함과 동시에 배가스의 $CO_2$ 농도를 80% 이상으로 농축시켜 회수를 용이하게 하며, 동시에 공해물질은 NOx 발생량을 10ppM 이하로 줄일 수 있는 기술이다. 천연가스를 생산하는 LNG기지에서 연소에 의한 이산화탄소를 발생시키는 기기로는 수중연소식기화기(SMV ; Submerged Combustion Vaporizer)를 들 수 있다. SMV는 버너를 이용하여 $-162^{\circ}C$ LNG를 $10^{\circ}C$의 LN로 기화시키는 설비로서 특히 동절기에 작동시키며 $CO_2$를 배출시키는 연소기다. 본 연구에서는 수중연소식 SMV에 순산소 연소방식을 적용하여 천연가스와 산소를 연소시키므로서 발생되는 $CO_2$를 LNG냉열을 이용 액체화 시켜 회수하는 연구를 수행하고 있다. 내용중에 수중연 소식 SMV에 대한 순산소 연소기를 개발하는 연구를 수행하였으며, 실제 SMV의 1/10크기, 열량기준 1/900로 모형을 제작하여 실험하였다. 연소기 노즐 은 직경 0.6mm, 배가스가 수조내에서 48개의 노즐을 제작하였다. 실험결과 일정량 이상의 $CO_2$ EGR율이 일정 값 이상이 되면 화염의 길이가 공기/NG 화염 길이와 큰 차이가 없었으며 $CO_2$ EGR율이 100%이상에서는 $CO_2$ EGR율 증가에 따른 화염길이 변화는 크게 나타나지 않았다. CO 배출 농도는 공기/NG 연소의 경우보다 높게 나타났으며, ${\lambda}$가 1.4보다 높은 조건에서는 측정되지 않았다. NOx의 배출 농도는 약 1~8ppm으로 나타났다.

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The Effect of C-4 Substituent of 2-phenylimino-1,3-thiazolines on the Antifungal Activity Against Rice Blast (2-페닐이미노-1,3-티아졸린 유도체의 C-4 치환체가 벼도열병에 대한 항균활성에 미치는 영향)

  • Lim, Jung-Sup;Han, Min-Soo;Nam, Kee-Dal;Choi, Kyung-Ja;Hahn, Hoh-Gyu
    • The Korean Journal of Pesticide Science
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    • v.13 no.2
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    • pp.63-69
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    • 2009
  • New morpholinylcarbonylmethyl-2-phenylimino-1,3-thiazolines 2(X=O) and piperidinylcarbonylmethyl-2-phenylimino-1,3-thiazolines 3(X=C) to which morpholinyl or piperidinyl functional group were introduced at C-4 side chain of the 2-phenylimino-1,3-thiazoline scaffold were synthesized to investigate the effect of NH hydrogen of 2-phenylimino-1,3-thiazoline-4-acetanilide derivatives on the antifungal property against rice blast. Synthesized 30 compounds were screened against 6 kinds of typical plant fungi. Treatment of ketene dimer with chlorine followed by the reaction of morphorine or piperidine without isolation of the intermediate acetoacetylchloride gave $\gamma$-chloro-$\beta$-keto derivatives. These were reacted with thioureas to give morpholinylcarbonylmethyl-2-phenylimino-1,3-thiazolines and piperidinylcarbonylmethyl-2-phenylimino-1,3-thiazolines respectively in good yield (27-98%). The compound 3j, in which two fluorine atoms are substituted at ortho and para position of phenyl group of 2-phenylimino moiety and piperidinyl group is substituted at C-4, showed the highest antifungal activity (100 ppm, 90%). This result suggested that the substituent at C-4 of the 2-phenylimino-1,3-thiazolines may play a supplementary role to show the antifungal activity against rice blast.

Incineration Process of Double Base Propellant for Demilitarization (더블 베이스 추진제의 비군사화 소각공정)

  • Lee, Si-Hwang;Baek, Seung-Won;Moon, Il;Park, Jung-Su;Oh, Min
    • Clean Technology
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    • v.22 no.3
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    • pp.190-195
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    • 2016
  • The thermal decomposition of waste energetic materials such as TNT, RDX and composition B in a commercial rotary kiln has previously been carried out. As part of the demilitarization process, the thermal decomposition of homogeneous double base propellant (DB) used in M8 and consisting predominantly of nitrocellulose and nitroglycerine is examined with respect to a number of operating conditions. A single condensed phase reaction with 4 species and 365 gas phase reactions and 59 species are considered. Simulation results show the sensitivity of the thermal decomposition of DB with temperature and velocity. At relatively low velocity with constant inlet hot air temperature, temperature in the rotary kiln was found to be highest, 953 K and 1300 K for cases 3 and 6 respectively. Illustrating that optimum operating temperature can be achieved by controlling the inlet velocity without additional cooling systems.

Study on the Current Horizontal Stress Characteristics of the Tertiary Rock Formations in the Pohang Basin by Integrated Analysis with In-situ Rock Stress Measurement and Borehole Scanning Data Set (현장 초기응력 측정과 시추공 이미지 스캐닝 자료의 통합 분석을 통한 포항분지 제 3기 지층 내 수평응력 분포 특성 연구)

  • Bae, SeongHo;Jeon, Seokwon;Kim, Jangsoon;Park, Kwongyu
    • Tunnel and Underground Space
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    • v.26 no.4
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    • pp.304-315
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    • 2016
  • In this study, the current horizontal stress characteristics of the Tertiary rock formations in the Pohang Basin are investigated on the basis of the in-situ rock stress measurements at depths from 75 m to 716 m of the 3 test boreholes in the Doumsan area, Pohang. The deep hydraulic fracturing stress measurement results indicated that the horizontal stress components in the test site appear far lower than the average ones by the linear fit for the data set measured from the other domestic sites. But, borehole scanning revealed clearly that lots of small and large scale borehole failures occurred due to the low strength characteristics of the existing rocks. To obtain more accurate and overall information on the horizontal stress direction, the integrated analysis combining the hydraulic fracturing stress measurement and borehole scanning data set were additionally carried out. The analysis results showed that in the upper sedimentary and the lower volcanic rock formation, the dominant orientations of the current maximum horizontal stress components were appeared in the range of $80^{\circ}{\sim}100^{\circ}$ (N80E~N80W) and $120^{\circ}{\sim}140^{\circ}$ (N60W~N40W), respectively. From this study result it was found that the maximum horizontal stress directions have a tendency to rotate in a clockwise direction as the rock formation changes with depth in the test site.

Interfacial and Mechanical Properties of MGF Reinforced p-DCPD Composites with Surface Treatments (MGF 표면처리에 따른 p-DCPD 복합재료의 계면 및 기계적 특성 연구)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Ha, Jung-Chan;Park, Joung-Man
    • Composites Research
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    • v.29 no.5
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    • pp.282-287
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    • 2016
  • p-DCPD (poly dicyclopentadiene) is the resin that the versatile mechanical properties can be changeable via the control of inner monomer and catalysts. In this work, to improve the strength of composites, surface treated MGF (milled glass fiber) was used as an reinforcement in p-DCPD by molybdenum (Mo) catalyst matrix. The optimum concentration of surface treatment was obtained and the cohesion of MGF themselves increased with concentration. In case of 0.2 wt% silane concentration, the maximized mechanical properties of MGF/p-DCPD composite exhibited because of minimized MGF cohesion. When butyl silane showing minimizing cohesion was used as the optimized alkyl length, high tensile and flexure strength exhibited due to the steric hindrance effect among MGFs. Mechanical and their fractured surfaces of MGF/p-DCPD composites was compared for 4 different chemical functional groups. Norbornene functional groups containing similar chemical structure to DCPD matrix exhibited higher interfacial adhesion between MGFs and DCPD matrix.

Risk Factors Influencing Stroke : using data from the 7th(2016-2018) Korea National Health and Nutrition Examination Survey (뇌졸중에 영향을 미치는 위험요인 : 국민건강영양조사 제7기(2016-2018) 자료를 활용하여)

  • Chung, Myung Sill;Seomun, GyeongAe
    • Journal of Digital Convergence
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    • v.18 no.9
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    • pp.277-283
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    • 2020
  • The purpose of this study was to identify the risk factors influencing stroke. The research method was used two-stage stratified cluster sampling using data from the National Health and Nutrition Survey (2016-2018). This study subjects performed a complex sample logistic regression analysis on adults aged 19 or older. Risk factors affecting stroke were shown as follows: in age groups, odds ratio were conformed when people are in their 70s, the rate is 8.861 times higher; when they are in their subjective health conditions, the odds ratio are 4.501 times higher in the bad groups; odds ratio was 3.158 times higher in the group diagnosed with hypertension and 1.598 times higher in the group diagnosed with diabetes. The result of this study found that chronic diseases such as high blood pressure and diabetes and the management of senior citizens are important because stroke is dangerous and can be managed through prevention.

New Discovery of Aira-Tn Ash(AT) in Korea (아이라Tn화산재 (AT)의 신발견)

  • Seonbok Yi;Tsutomu Soda;Fusao Arai
    • Journal of the Korean Geographical Society
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    • v.33 no.3
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    • pp.447-454
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    • 1998
  • As a widespread tephra erupted 24 to 25 KA, Aira-Tn Ash, or AT, provides an invaluable datum for stratigraphic study of late Pleistocene in Northeast Asia. AT can be identified from their tonal characteristic and morphology (the so­called bubble-wail feature), as well as typical refractive index. First reported in 1983, its presence was confirmed from many palaeolithic deposits distributed throughout Korea. It forces us to reconsider the age of prominent Pleistocene deposits. At the famous archaeological site of Chon-gok-ni, presence of AT lends a firm support that sedimentation and deposition of lithic assemblage were in fact a late Upper Pleistocene event, thus, throwing a new question at archaeologists to explain why such archaic-looking tools were continued to be made. Discovery of AT at Chongdongjin is more surprising, since the coastal terrace has been regarded by many as an early Lower Pleistocene eustatic feature. It implies strongly that we need to devise a new scheme for Quaternary stratigraphy. In the absence of reliable datum and marker for Quaternary research, efforts must be given to search for and identify AT and other widespread tephras.

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