• Title/Summary/Keyword: 한국지지

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Thermal and Electrical Properties of Poly(vinylidenefluoride-hexafluoropropylene)-based Gel-Electrolytes (Poly(vinylidenefluoride-hexafluoropropylene)계 겔-전해질의 열적, 전기적 특성)

  • 김영완;최병구;안순호
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.382-388
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    • 2000
  • Polymer electrolyte films consisting of poly(vinylidenefluoride-hexafluoropropylene) (PVdF-HFP), LiClO$_3$ and a mixture of ethylene carbonate (EC) and ${\gamma}$-butyrolactone (GBL) were examined in order to obtain the best compromise between high ionic conductivity, homogeniety, dimensional and electrochemical stability. Measurements of ionic conductivity, differential scanning calorimetry and linear sweep voltammetry have been carried out for various compositions. The highest conductivity of 3.8$\times$10$^{-3}$ S$cm^{-1}$ / at 3$0^{\circ}C$ were obtained for a film of 30(PVdF-HFP)+7.8LiClO$_4$+62.2EC/GBL. From the DSC study, it has been found that the PVdF-HFP gels are stable up to 10$0^{\circ}C$, and the salt lowers the melting temperature of crystalline part of PVdF by interacting sensitively with polymer segments. When Lithium metal is in contact with the gel films, it tends to undergo corrosion and the reaction products accumulate resulting in the formation of a passive film on Li electrode. As the aging time progresses, the interfacial resistance increases continuously. Anodic stability is measured to extend up to about 4.5 V vs. Li.

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Rock Support Design of Bakun Tunnelling Project in Sarawak, Malaysia (바쿤 가배수로 터널의 최적지보설계)

  • 지왕률
    • Tunnel and Underground Space
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    • v.8 no.4
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    • pp.296-306
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    • 1998
  • Ongoing huge Bakun Hydropower project is including the construction of a 210 m height hydroelectric rockfill dam with an installed capacity of 2,520 MW and a power transmission system connecting to the existing networks between Sarawak and peninsula Malaysia. In order to allow the main dam construction during the dry season, the Ballui river will have to be detoured through 3 concrete lined diversion tunnels with an internal diameter of 12 m and a length of 1,400 m each. The geology of Bakun site belongs to the several thousand meters thick Belaga formation deposited from the late Cteteceous to the early Teriary in the Northwest Borneo geosyncline. The orientation of the bedding plane, strike at N55$^{\circ}$E to N70$^{\circ}$E and dip at 50$^{\circ}$SE to 70$^{\circ}$SE, is developed uniformly in Bakun sedimentary rocks. Rock mechanical characteristics of Bakun site have been classified into 4 rock mass types(RMT) depending on the degree of weathering and the occurrence of rock jointing with RMR. Graywacke(Sandstone) as well as Shale can take place together in the same rock mass type if their rock mass properties are similar. It was summarized the rock support type and support system design of underground diversion tunnels in view of rock mechanics.

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An Analysis Model of the Secondary Tunnel Lining Considering Ground-Primary Support-Secondary Lining Interaction (지반-1차지보재-2차라이닝의 상호작용을 고려한 터널 2차라이닝 해석모델)

  • 서성호;장석부;이상덕
    • Tunnel and Underground Space
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    • v.12 no.2
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    • pp.107-114
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    • 2002
  • It is the common practice to over design the reinforcement for the secondary tunnel lining due to the lack of rational insight into the ground loosening loads. and due to the conservative application of the empirical design methods. The main loads of the secondary lining are the ground Loosening loads and the ground water pressure, and the ground load is critical in the reinforcement design of the secondary lining in the case of drained tunnel. If the external load is absent around a tunnel, the reasons of the load far secondary tunnel lining are the deterioration of the primary supports such as shotcrete, steel rib, and rockbolts. Accordingly, the analysis method considering the ground-primary supports-secondary lining interaction should be required tar the rational design of the secondary tunnel lining. In this paper, the interaction was conceptually described by the simple mass-spring model and the load transfer from the ground and primary supports to the secondary lining is showed by the ground-primary supports-secondary lining reaction curves fur the theoretical solution of a circular tunnel. And also, the application of this proposed model to numerical analysis is verified in order to check the potential far the tunnel with the complex analysis conditions.

Investigation of Bordered Pit Ultrastructure in Tracheid of Korean Red Pine (Pinus densiflora) by Confocal Reflection Microscopy (공초점반사현미경을 이용한 소나무 유연벽공의 초미세구조 연구)

  • Kwon, Ohkyung
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.3
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    • pp.346-355
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    • 2014
  • Confocal reflection microscopy (CRM) was utilized to create 3-dimensional images of bordered pits and cell wall in the tracheid of Korean red pine (Pinus densiflora). Ultrastructures of torus, margo, and pit border were clearly observable in the CRM micrograph. Micrograph of cross-field pit revealed the connecting and supporting structure between tracheid and ray parenchyma cell. The CRM micrographs enabled to investigate detailed structures of tracheid cell wall such as S1, S2, S3 layers, transition layers between these layers, and microfibril (MF) orientation in S3 and S2 layers as well as complicated distribution of MF orientation around bordered pits. Not only concentric MF orientation of border thickening in the pit border was observed, but also changes in MF orientation from the cell wall to the border. From the experimental results, the CRM was thought to be a versatile microtechnique to investigate detailed structures of cell wall and bordered pit in the tracheid and cross-field pit between tracheid and ray parenchyma cell.

Evaluation of Wet Pressing Response of Recycled OCC with Roll Press Simulator (롤프레스를 적용한 골판지 고지지료의 압착탈수특성평가)

  • Sung, Yong-Joo;Jeong, Wong-Ki;Kim, Dong-Seop;Oh, Min-Taek;Hong, Hae-Un;Seo, Yong-Bum;Im, Chang-Kuk;Gwon, Wan-Oh;Kim, Jin-Doo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.85-90
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    • 2012
  • Wet pressing process has great influence not only on the paper properties but also on the efficiency of total manufacturing process including energy efficiency. The slow drainage propensity of old corrugated container(OCC) might require more complicated control of wet pressing process. In this study, the change in press efficiency and in structure of wet sheet by the various condition of laboratory roll press simulator were evaluated to provide background information about wet pressing of OCC. The higher pressure and the slower machine speed resulted in higher efficiency of wet pressing but the change trends of dryness depending on the wet press pressure and machine speed were shown differently according to OCC treatment. The effects of water contents of felt on the wet press efficiency and sheet structure were also investigated. The higher contents of water in felt resulted in less removal of water generally and the crushed structure of wet sheet were appeared especially at higher pressure.

Removal of Volatile Organic Compounds from Water Using PU/PDMS-PTFE Composite Membranes by Vapor Permeation Separation Process (PU/PDMS-PTFE 복합막을 이용한 증기투과공정에 의한 물로부터 휘발성 유기화합물 제거)

  • Rhim Ji Won;Cheon Se Won;Yun Tae Ihl;Shin Hyun Su;Kim Baek Ahm;Chung Rae Ick
    • Membrane Journal
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    • v.15 no.1
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    • pp.44-51
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    • 2005
  • Polyurethane-polysiloxanes (PU/PDMS) was synthesized using 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) to overcome the weakness to the organic chemicals. The composite membranes were prepared onto porous poly(tetrafluoroethylene) (PTFE) supports. In vapor permeation experiments, the flux increased with increasing operating temperatures and feed concentrations while the separation factors showed the opposite trend, so-called 'trade-off'. In this study, the effect of the flux on the operating temperatures was not severe since the content of the soft segments is fairly higher than that of the hard segments. The composite membrane type of PU/PDMS maintained high flux and separation factor as well when comparing with the dense type membranes.

Composite Membrane Preparation for Low Pressure Using Salting-Out Method and Its Application to Nanofiltration Process (염석법에 의한 저압용 역삼투막 제조 및 NF로의 적용)

  • Jeon, Yi Seul;Rhim, Ji Won
    • Membrane Journal
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    • v.25 no.5
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    • pp.440-446
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    • 2015
  • Nanofiltration composite membranes were prepared through the ion exchange polymers coating onto the porous microfiltration polyethylene (PE) membrane surfaces the salting-out and phase separated and pressurization (PSP) methods. The existence of coating on the surfaces was confirmed by the scanning electronic microscopy. The resulting membranes were characterized under the various conditions, such as the coating material, coating time, ionic strength etc., in terms of flux and rejection for NaCl 100 ppm solution. Under the same coating conditions of 10,000 ppm coating solution concentration and 3 atm coating pressure for both the coating materials of PEI and PSSA_MA, the flux 91.2 LMH and rejection 64.6% were obtained for PEI whereas 122.7 LMH and 38.1% were observed for PSSA_MA. From this study, it may be concluded that the composite membrane preparation is possible.

Solvent Resistance and Gas Permeation Property of PEI-PDMS Hollow Fiber Composite Membrane for Separation and Recovery of VOCs (VOCs의 분리 및 회수를 위한 PEI-PDMS 중공사 복합막의 내용매성 및 기체 투과 특성)

  • Kim, Se-Jong;Lee, Chung-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Rhim, Ji-Won;Choi, Whee-Moon
    • Membrane Journal
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    • v.22 no.1
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    • pp.54-61
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    • 2012
  • To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.

Stability Analysis of Floating Ring Bearing Supported Turbocharger (플로팅 링 베어링으로 지지된 터보차저 로터의 안정성 해석)

  • Lee, Donghyun;Kim, Youngcheol;Kim, Byungok
    • Tribology and Lubricants
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    • v.31 no.6
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    • pp.302-307
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    • 2015
  • The use of turbocharger in internal combustion engines has increased as it is a key components for improving system efficiency without increasing engine size. Because of increasing demand, many studies have evaluated rotordynamic performance so as to increase rotation speed. This paper presents a linear and nonlinear analysis model for a turbocharger rotor supported by a floating ring bearing. We constructed rotor model by using the finite element method and approximated bearings as being infinitely short. In the linear model, we considered fluid film force as stiffness and damping element. In nonlinear analysis, calculation of the fluid film force involved solving the time dependent Reynolds equation. We verified the developed model by comparing the results to those of previous research. The analysis results show that there are four unstable modes, which are rigid body modes combining ring and rotor motion. As the rotating speed increases, the logarithmic decrement shows that certain unstable modes goes into the stable area or the stable mode goes into the unstable area. These unstable modes appear as sub-synchronous vibrations in nonlinear analysis. In nonlinear analysis frequency jump phenomenon demonstrated in several experimental studies appears. The analysis results also showed that frequency jump phenomenon occurs when the vibration mode changes and the sequence of unstable mode matches the linear analysis result. However, the natural frequency predicted using linear analysis differs from those obtained using nonlinear analysis.

The Case Study of Rock Treatment Method for the Fractured Rock Foundation of Underground Roadway Structure (기반암의 파쇄대 특성을 고려한 지하차도 기초 보강사례)

  • Yoon, Ji-Nam;Yang, Sung-Don;Lee, Geun-Ha;Park, Sa-Won;Jung, Hun-Chul
    • Tunnel and Underground Space
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    • v.18 no.2
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    • pp.125-133
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    • 2008
  • The rock treatment methods for improving bearing capacity and reducing settlement of the underground roadway structure foundation on fractured rock was studied in this paper. Also, effective reinforcement scheme was evaluated by numerical analysis for the application to the practical construction. Various in-situ and laboratory tests were executed systematically at Yeongi-goon, Ohoongchungnam-do, Korea, for the purpose of defining the physical and mechanical properties of rock. Consequently the effective treatment methods insuring the bearing capacity of fractured rock were proposed. In addition, the adequate reinforcing depth of the comparatives measure, such as double rod, triple rod injection methods and micropile, were investigated from the case study. Finally, the most effective construction scheme with the consideration of safety and economical aspects were proposed by using numerical analysis(Plaxis ver. 8.2).