• Clean Technology
• /
• v.21 no.4
• /
• pp.271-277
• /
• 2015

A photocatalyst which mixed by the commercialized P25-TiO₂ and a synthesized Ag_xO was used in an appropriate weight ratio to effectively produce hydrogen gas in this study. The Ag_xOs were synthesized with the conventional sol-gel method, and tetramethylammonium hydroxides were added at the synthesis process in order to stabilize the solutions, and then the solutions were heat-treated at the temperatures of -5, 25, and 50 ℃, resulted to obtain the three types of silver oxides. Physicochemical properties of the synthesized Ag_xOs were identified through X-ray diffraction analysis (XRD), scanning emission microscopy (SEM), ultraviolet-visible spectroscopy, and X-ray photoelectron spectroscopy (XPS). In the photolysis results of water/methanol (weight ratio 1:1) solution, the mixture of P25-TiO₂/Ag_xO exhibited a significantly higher hydrogen gases evolution, compared to that of pure P25-TiO₂. Additionally, the addition of H₂O₂ as an supplement oxidant and in Ag_xO synthesized at 50 ℃ improved the hydrogen production efficiency. In particular, the emitted hydrogen gases reached to 13,000 μmol during 8 hours when a mixed catalyst, Ag_xO of 0.1 g and P25-TiO₂ of 0.9 g, were used.

• Membrane Journal
• /
• v.22 no.5
• /
• pp.359-368
• /
• 2012

For hybrid water treatment of high turbidity water, we used the hybrid module that was composed of photocatalyst packing between tubular membrane outside and module inside. Photocatalyst was PP (polypropylene) bead coated with $TiO_2$ powder by CVD (chemical vapor deposition) process. Water back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling for modified solution was prepared with humic acid and kaolin. Resistance of membrane fouling ($R_f$) decreased as humic acid concentration changed from 10 mg/L to 2 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L, which was the same with the previous results. Then, treatment efficiencies of turbidity and humic acid were above 98.9% and 88.7%, respectively. As results of treatment portions of UF, UF + $TiO_2$, and UF + $TiO_2$ + UV processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of humic acid by adsorption and photo-oxidation were 2.5% and 12.3%, respectively. Compared with the previous results, treatment portions of humic acid by adsorption and photo-oxidation were different depending on membrane material and pore size. As simplified the process, the membrane fouling resistance after 180 minutes' operation ($R_{f,180}$) increased and the final permeate flux decreased a little.

• Environmental and Resource Economics Review
• /
• v.19 no.3
• /
• pp.597-632
• /
• 2010

There is general agreement that global warming is occurring and that the main contributor to this probably is the buildup of green house gasses, GHG, in the atmosphere. Two main contributors are the utilization of fossil fuels and the deforestation of many regions of the world. The burning of fossil fuels increases atmospheric carbon while the burning of fuel-wood reducing fossil fuel consumption along with its forest source maintain an atmospheric carbon level. The standing timber in the forests is a carbon sink, as are wood buildings and structures, and fossil fuel in the ground. This paper is designed to examine a number of current issues related to mitigating the global warming problem through forestry. For this purpose, we develop a modeling approach by integrating timber market, fossil fuel market and carbon cycling model. We use discrete time optimal control theory to identify optimal time paths, the laws of motion, and stationary stats solutions of endogenous variables in the model. On the basis of these results, we identify the optimal amounts of subsidies to be provided or taxes to be imposed by the regulatory agency to mitigate atmospheric carbon accumulation. We also present a numerical example to help illustrate the characteristics of variables in the model when the social cost for atmospheric carbon incrementally shifts upward. A surprising result is that the social cost function for atmospheric carbon has a very smaller impact on the optimal rotation period than previous literature suggested.

• KIPS Transactions on Software and Data Engineering
• /
• v.2 no.8
• /
• pp.579-588
• /
• 2013

This paper proposes an effective watermarking approach for copyright protection of fire video images. The proposed watermarking approach efficiently utilizes the inherent characteristics of fire data with respect to color and texture by using a gray level co-occurrence matrix (GLCM) and fuzzy c-means (FCM) clustering. GLCM is used to generate a texture feature dataset by computing energy and homogeneity properties for each candidate fire image block. FCM is used to segment color of the fire image and to select fire texture blocks for embedding watermarks. Each selected block is then decomposed into a one-level wavelet structure with four subbands [LL, LH, HL, HH] using a discrete wavelet transform (DWT), and LH subband coefficients with a gain factor are selected for embedding watermark, where the visibility of the image does not affect. Experimental results show that the proposed watermarking approach achieves about 48 dB of high peak-signal-to-noise ratio (PSNR) and 1.6 to 2.0 of low M-singular value decomposition (M-SVD) values. In addition, the proposed approach outperforms conventional image watermarking approach in terms of normalized correlation (NC) values against several image processing attacks including noise addition, filtering, cropping, and JPEG compression.

• Clean Technology
• /
• v.22 no.2
• /
• pp.96-105
• /
• 2016

VOCs emissions from industries cause the air pollution and odor. In the industrial facilities, the existing odor treatment techniques have limits and problems. In this study, the optimum essential oil and metal oxide selected by screening test. lavender oil, cypress oil and TiO₂ were determined by deodorant materials and those were blended by 5%, 45%, 10%, respectively. In addition, the result of batch type experiments depending on the dilution rate, injection, rate, temperature showed that the optimum condition of deodorant is 6 mL of injection rate, and 200 times of dilution rate and the removal efficiency increased in proportion with temperature. In addition, the activation energy was calculated from the rate equation, which appeared in the 3-4 times lower than conventional deodorants.

• Clean Technology
• /
• v.22 no.2
• /
• pp.114-121
• /
• 2016

In this studies, SCR reaction activity and SO₂ durability enhancement study on manufacturing conditions of the V/TiO₂ catalyst was carried out for the removal of nitrogen oxides generated in the combustion furnace. The catalysts are characterized by XPS, Raman, H₂-TPR and SO₂-TPD. When the vanadium was contained of 2 wt%, it showed excellent SO₂ durability and catalytic activity. and When the tungsten is added as a promotor, the enhancement of reducing ability at a low temperature and reduction of SO₂ adsorption capacity improved the reaction activity and SO₂ durability. V/W/TiO₂ are prepared by the lower pH of vanadium solution, vanadium was highly dispersed on the surface and inhibited the formation of crystalline V₂O₅. in addition, it was confirmed that this catalyst can be used as excellent resistance to high concentration of CO in the combustion furnace.

• Clean Technology
• /
• v.14 no.3
• /
• pp.204-210
• /
• 2008

A series of $V_{2}O_{5}-TiO_2$ xerogel catalysts were prepared by nonhydrolytic sol-gel method and analysed by various characterization techniques. These catalysts showed much higher surface areas and total pore volumes than conventional V$V_{2}O_{5}-TiO_2$ xerogel and impregnated $V_{2}O_{5}/TiO_2$ catalysts. It was found that the textural property of $V_{2}O_{5}-TiO_2$ material varies with the method and conditions of synthesis. Surface vanadates and $TiO_2$ anatase phase are the crucial factors to obtain high catalytic activities. The selective oxidation of hydrogen sulfide in the presence of excess water and ammonia was studied over these catalysts. Xerogel catalysts prepared by non-hydrolytic sol-gel method showed very high conversion of $H_{2}S$ without harmful emission of $SO_2$. The highest catalytic activity shown by these $V_{2}O_{5}-TiO_2$ catalysts may be due to their high surface area and good dispersion of vanadia species in the titania matrix.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.4
• /
• pp.232-236
• /
• 1999

A solar cell based on dye-sensitized photoelectric conversion was studied by electrochemical and spec-trofluorometric methods for the purposes of enhancing its efficiency and stability of $TiO_2$ solar cells. Nanocrystalline $TiO_2$ was used to prepare photoelectrodes, and photosensitizing dyes such as malachite green oxalate, basic blue3, rhodamine B, and bromocresol purple were chosen as sensitizers. Electrochemical oxidation potentials and absorption and emission wavelengths of dyes were used to determine energy levels of the dyes. By comparing excited energy levels of the dyes with the conduction band edge potential $(E_{c,s})\;of\;TiO_2$ calculated by using the flat-band potential $(E_{fb})\;of\;TiO_2$, properties of a dye required to fabricate a high efficient photosensitizing solar cell with high short-circuit current $(J_{sc})$ were suggested. Enhanced stability of photocurrent was obtained by coating a $TiO_2|ITO$ electrode with Polypyrrole that Possibly Prevented the recombination between the conduction band electrons and oxidized dyes and suppressed the direct electrode redox reactions of dyes on ITO.

• The KIPS Transactions:PartB
• /
• v.12B no.7 s.103
• /
• pp.729-736
• /
• 2005

In this paper. the proposed method for the digital watermarking is based on the multiresolution wavelet transform. The 1-level Discrete Wavelet Transform(DWT) coefficients of a $2N_{wx}{\times}2N_{wy}$ binary logo image used as a watermarks. The LL band and middle frequency band of the host image that the 3-level DWT has been performed are divided into $N_{wx}{\times}N_{wy}$ size and we use large coefficients at the divided blocks to make threshold. we set the thresholds that completely insert the watermark in each frequency of the host image. The thresholds in each frequency of the host image differ each other. The watermarks where is the same positions are added to the larger coefficients than threshold in the blocks at LL band and middle frequency band in order to prevent the quality deterioration of the host image. The watermarks are inserted in LL band and middle frequency band of the host image. In order to be invisibility of the watermark, the Human Visual System(HVS) is applied to the watermark. We prove the proper embedding method by experiment. We rapidly detect the watermark using this watermarking method. And because the small size watermarks are inserted by HVS, the results confirm the superiority of the proposed method on invisibility and robustness.

• The KIPS Transactions:PartB
• /
• v.10B no.3
• /
• pp.257-264
• /
• 2003

In the context of a dynamic trading environment, the ultimate goal of the financial forecasting system is to optimize a specific trading objective. This paper proposes a two-phase (extraction and filtering) stock trading system that aims at maximizing the rates of returns. Extraction of stocks is performed by searching specific time-series patterns described by a combination of values of technical indicators. In the filtering phase, several rules are applied to the extracted sets of stocks to select stocks to be actually traded. The filtering rules are automatically induced from past data. From a large database of daily stock prices, the values of technical indicators are calculated. They are used to make the extraction patterns, and the distributions of the discretization intervals of the values are calculated for both positive and negative data sets. We assumed that the values in the intervals of distinctive distribution may contribute to the prediction of future trend of stocks, so the rules for filtering stocks are automatically induced from the data in those intervals. We show the rates of returns when using our trading system outperform the market average. These results mean rule induction method using distributional differences is useful.