• Title/Summary/Keyword: 한국의 이산

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Facilitated Transport Separation of Carbon Dioxide Using Aminated Polyetherimide Membranes (아민화된 폴리이서이미드 막을 이용한 이산화탄소의 촉진수송분리)

  • Kwon, Se Hwan;Rhim, Ji Won
    • Membrane Journal
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    • v.25 no.3
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    • pp.248-255
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    • 2015
  • Aminated polyetherimide membrane synthesized in the laboratory according to amine ratio was used for measurement of gas permeability, diffusivity, and solubility about carbon dioxide, nitrogen, methane, oxygen, and sulfur dioxide with Time-lag method at room temperature. Generally, gas permeability is totally decreased because the more amination rate reacted to the main chain of amine groups, the more intermolecular space became narrow. However, gas permeability of sulfur dioxide was increased due to combination of sulfur dioxide and amine groups have acid and base properties respectively. Diffusivity and solubility of dry gas are totally decreased excluding sulfur dioxide as increasing amination rate. In case of sulfur dioxide, however, diffusivity as well as solubility was increased as increasing amination rate. Selectivity of carbon dioxide/nitrogen showed 60 when amination rate was 3. In case of humid gas, gas permeability of carbon dioxide was 70 barrer when relative humidity showed 100, and selectivity with nitrogen approximately showed 18.

Control of Generation of Chlorine Dioxide Gas Using Polymer Hydrogels Containing Acetic Acid (아세트산이 탑재된 고분자 수화젤을 이용한 이산화염소 기체의 발생 제어)

  • Lee, Dong-Han;Lee, Ook
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.553-556
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    • 2013
  • Chlorine dioxide gas has an excellent ability for sterilization and deodorization, and is harmless to humans. However, it is very unstable and explosive as it is highly concentrated, thus its use in the air clean fields has been limited. Therefore, there is need to control chlorine dioxide gas at a low concentration for a long time. Chlorine dioxide gas could be produced slowly and sustainedly since the release of acetic acid from the polymer hydrogels delayed the reaction between acetic acid and sodium chlorite. In addition, as the amount of both acetic acid sodium chlorite loaded within the hydrogel and on the membrane increased, respectively, the generation amount of chlorine dioxide gas increased. The result shows that the use of polymer hydrogels has the potential to control the generation of chlorine dioxide gas.

Chipped Titanium Scraps as Raw Materials for Cutting Tools (타이타늄 밀링/터닝 스크랩의 절삭공구 소재화)

  • Kwon, Hanjung;Lim, Jae-Won
    • Resources Recycling
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    • v.30 no.2
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    • pp.61-67
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    • 2021
  • Scraps are a byproduct of the machining process used for transforming titanium ingots into useful mechanical parts. Scraps take two forms, namely, bulky scraps, which are produced by cutting, and chipped scraps, which are produced by milling. Bulky scraps are comparatively easier to recycle because of their small surface area and less oxygen content; as a result, they pose only a small risk of explosion. In contrast, chipped scraps pose a higher risk of explosion, because of which, their recycling is complicated, resulting in most such scraps being discarded. With the aim of avoiding this waste, we proposed a novel process for converting chipped scraps into stable carbide materials. Methods typically applied to reduce particle size and impair the formation of solid solution type phase in the carbide materials were used to improve the mechanical properties of carbides prepared from chipped scraps. Our novel recycling process reduced carbide production costs and improved carbide quality.

Experiment on Reduction of Pollutants in Titanium Dioxide Photocatalytic Ventilation System (이산화티탄 광촉매 환기장치의 오염물질 저감 실험)

  • Song, Yong Woo
    • Land and Housing Review
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    • v.13 no.2
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    • pp.117-123
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    • 2022
  • In this study, titanium dioxide photocatalyst was applied to the ventilation system to reduce particulate matter and nitrogen oxides (NOx), which are representative indoor harmful substances. A reaction device capable of installing an ultraviolet lamp was designed and manufactured so that the pollutant decomposition effect of the titanium dioxide photocatalyst identified through previous studies could be applied indoors. The reaction device was used on the indoor ventilation system and applied to the Mock-Up test. As a result of the Mock-up test, the NOx reduction performance according to the change in air volume once per hour and five times per hour was confirmed. As a result, it was confirmed that as the number of ventilation increases, the NOx reduction time decreases proportionally, and the reduction performance increases.

Changes of Peach (Prunus persica L. Batsch) Quality during Storage after Treatment with Aqueous Chlorine Dioxide (이산화염소수를 처리한 복숭아의 저장 중 품질 변화)

  • Lee, Kyung-Haeng;Choi, Ji-Hye;Ra, So-Jung;Min, Hye-In;Park, Yong-I
    • The Korean Journal of Food And Nutrition
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    • v.27 no.5
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    • pp.881-887
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    • 2014
  • To prolong the shelf-life of domestic peaches, samples were treated with 30 ppm of aqueous chlorine dioxide ($ClO_2$) for 0~15 minute, after which the spoilage rate, changes in physico-chemical and sensory properties of treated samples were investigated. The control showed spoilage at day 4, and then 31.25% of control showed spoilage at day 8. However, samples treated with aqueous $ClO_2$ had no spoilage at day 4. On day 6, only 6.25% of samples treated with aqueous $ClO_2$ for 5 min showed spoilage. After 8 days, no spoilage was observed for samples treated with aqueous $ClO_2$ for 10 and 15 min. The weight change of the control was higher than that of aqueous $ClO_2$ treated samples for 8 days of storage. There were no differences in pH of samples among the treatments, but they were increased by storage time. Although there were no initial differences in the firmness of samples among the treatments, firmness of the control sample was decreased faster than those of the aqueous $ClO_2$ treated samples for 8 days of storage. No significant changes in lightness, redness and yellowness of the samples by aqueous $ClO_2$ treatment were observed during storage. The sensory parameters including taste, flavor, color, texture and overall acceptance at the initial period were not different among treatments. However, all scores of the control were decreased faster than those of aqueous $ClO_2$ treated samples during storage.

Studies on the Contents of Naturally Occurring of Sulfite in Foods (식품중 천연유래 이산화황 함유량에 관한 연구)

  • Kim, Hee-Yun;Lee, Young-Ja;Hong, Ki-Hyoung;Kwon, Yong-Kwan;Ko, Hyun-Sook;Lee, Young-Kyong;Lee, Chul-Won
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.544-549
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    • 2000
  • This study was performed to compare optimum analytical method for the contents of naturally occurring sulfur dioxide in foods and to investigate the contents of sulfur dioxide in foods in order to provide a fundamental data when distinguish between added and naturally occurring sulfur dioxide. The determination of the contents of sulfur dioxide in foods from the 20 kinds, 180 cases of samples has been analyzed by the optimized Monier-Williams method, modified Rankine method and Acid Distillation/Ion Chromatography. As a result of the study, the contents of naturally occurring sulfur dioxide in foods by the optimized Monier-Williams method showed from 1.02 to 43.87 ppm and highly content of 43.87, 15.37, 11.50, 11.21 and 10.60ppm were observed in garlic, platicodon, green onion, cabbage and onion, the others were less than 10.00ppm. The sulfur dioxide contents in green onion and garlic by modified Rankine method were showed to be 2.87 and 6.14ppm, respectively, the others were detected less than 2.50ppm. The contents of sulfur dioxide by Acid Distillation/Ion Chromatography showed 15.43, 9.82, 5.74, 5.37, 2.14 and 0.49ppm in garlic, cabbage, green onion, onion, potato and apple, respectively and the others were not detected. And the contents of sulfur dioxide in green onion, onion, cabbage and garlic showed higher levels of sulfur dioxide in these foods than the others because of the naturally occurring sulfur containing compounds. The optimized Monier-Williams method, which is the of official analytical method of Korean Food Code, was suitable for monitoring of sulfur dioxide of most foods. Acid Distillation/Ion Chromatography was thought to be adequate for sulfur containing foods such as green onion, onion and cabbage. In order to distinguish between added and naturally occurring sulfur dioxide, it is though to be need of the fundamental data for the contents of sulfur dioxide in sulfite-free foods and continue the investigation for it.

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Sensitivity of NOx Removal on Recycled TiO2 in Cement Mortar (재생 이산화티탄을 혼입한 모르타르의 NOx 저감률 민감도 분석)

  • Rhee, Inkyu;Kim, Jin-Hee;Kim, Jong-Ho;Roh, Young-Sook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.388-395
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    • 2016
  • This paper explores the photocatalytic sensitivity of cement mortar incorporated with recycled $TiO_2$ from waste water sludge. Basically, $TiO_2$ cluster sank down slowly to the bottom of cement mortar specimen before setting and hardening process. This leads the mismatch of $TiO_2$ concentration on the top and the bottom faces of a specimen. This poorly dispersed $TiO_2$-cement mortar naturally exhibits poor NOx removal efficiency especially on the top of cementitious structure. In architectural engineering application such as building or housing structures, one can simply filp over from the bottom so that more $TiO_2$ concentrated surface can be placed outward into the air. However, in highway pavement case, this could not be applicable due to in-situ installation of concrete pavement. Hence, the dispersion of $TiO_2$ cluster inside the cementitous material is getting important issue onto road construction application. To elaborate this issue, according to our results, silica fume, high-ranged water reducer, viscosity agent, blast furnace slag were not enhanced much of dispersion characteristics of $TiO_2$ cluster. The combination of foaming agent and accelerator of hardening with viscosity agent and small grain size of fine aggregate may help the dispersion of $TiO_2$ inside cementitious materials. Even though the enhanced dispersion were applied to the specimen, NOx removal efficiency doest not change much for the top surface of the specimen. This concurrently affected by the presence of tiny air voids and the dispersion of $TiO_2$ in that these voids could easily adsorbed NOx gas with the aid of large surface area.

A Unit Root Test via a Discrete Cosine Transform (이산코사인변환을 이용한 단위근 검정)

  • Lee, Go-Un;Yeo, In-Kwon
    • The Korean Journal of Applied Statistics
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    • v.24 no.1
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    • pp.35-43
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    • 2011
  • In this paper, we introduce a unit root test via discrete cosine transform in the AR(1) process. We first investigate the statistical properties of DCT coefficients under the stationary AR(1) process and the random walk process in order to verify the validity of the proposed method. A bootstrapping approach is proposed to induce the distribution of the test statistic under the unit root. We performed simulation studies for comparing the powers of the Dickey-Fuller test and the proposed test.

The Application of Discrete Time Optimal Control Theory to Natural Resource Problems (이산시간 적정제어이론의 응용사례에 관한 연구)

  • Kim, Jin Hyung;Lee, Dug Man
    • Environmental and Resource Economics Review
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    • v.12 no.1
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    • pp.157-175
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    • 2003
  • 본 연구는 이산시간 적정제어이론을 사용하여 동태적 경제 문제의 최적해를 구하기 위해 사용되는 두 가지 형태의 극대원리를 분석하고 있다. 이산시간 적정제어이론에 관한 선행연구들은 상태방정식이 차분방정식의 형태를 띠는 경우에 적용할 수 있는 극대원리를 제안하고 있다. 그러나 본 연구는 상태방정식이 차분방정식이 아닌 일반방정식의 형태를 띠는 경우에 적용할 수 있는 극대원리를 개발하였다. 그리고 본 연구를 통해 개발된 극대원리와 선행연구들이 제안한 극대원리와의 차이는 공동상태 변수의 운동법칙에 있음을 보여주고 있다. 특히 본 연구는 Bellman의 최적원리를 이용하여 본 연구에서 개발된 극대원리는 선행연구들이 제안한 극대원리를 포함하는 일반적인 극대원리임을 설명하고 있다. 마지막으로 본 연구는 목재공급모형인 TSM2000에 포함된 경제변수의 동태적 최적화를 구하는 과정을 통해 본 연구에서 개발된 극대원리가 경제 문제에 적용되는 사례를 보여 주고 있다.

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