• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.18 no.1
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• pp.80-90
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• 2008

This study was carried out to investigate the correlation of urinary NMF concentration in workers exposed to DMF and concentration of DMF in the workplace. Samples were collected in workers exposed to high dose solvent in the synthetic leather factory by using silicagel tubes for 5-15 minutes, and were analyzed by GC. Geometric mean concentrations of DMF in the workplaces were 4.67 ppm in normal operation and 63.95 ppm in high exposure operation. The concentration of case uppers and machine cleaning process were more than 100 ppm in short time. The correlation of urinary NMF in workers and DMF in workplace was statistically significant in normal operation and high exposure operation. Correlation coefficient are 0.215(p<0.05) and 0.263(p<0.05). The result implied that STEL of DMF should be established in normal operation processes as well as high exposure operation processes.

• Journal of the Korean Applied Science and Technology
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• v.32 no.4
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• pp.623-630
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• 2015

Prepared polyurethane resin for buffalo leather coating on surface was synthesized with addition reaction glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on buffalo leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had demonstrated reduce properties. On the contrary, elongation and flexibility properties had highly increased. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

• Journal of the Korean Applied Science and Technology
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• v.32 no.1
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• pp.100-107
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• 2015

Prepared polyurethane resin for vegetable leather coating on surface was synthesized with glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on vegetable leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had highly stronger in intensity and longer durability. On the contrary, demonstrated reduce properties of elongation and flexibility. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.264-271
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• 2013

In this study, we have synthesized waterborne polyurethane dispersion(WPU) and analyzed mechanical properties of WPU film and leather coatings in different content of monoammonium phosphate. According to the measured data by DSC, sample WPU-AM3 which included high content of monoammonium phosphate showed the highest Tm at $382^{\circ}C$. All samples had good solvent resistance. In tensile tests, WPU-AM3($2.130kg_f/mm^2$) had the lowest physical properties. Also abrasion resistance properteis and elongation properties were investigated, WPU-AM3 had lowest physical properties with 52.07 mg.loss for abraison and 615 % of elongation.

• The Research Journal of the Costume Culture
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• v.9 no.1
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• pp.33-43
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• 2001

In this study, both kinds of materials, that is, leather and woolen fabrics, which have similar thickness, have been adopted. To determine proper length of ease, not only sleeve cap height but also sleeve width has been adjusted mainly based on 5cm length of the ease, which follows maximum sleeve cap height, and then different length of ease, for example, 4cm, 3cm, 2cm and 1cm of ease, have been made. As a result, eighteen kinds in total of sleeves have been made: In other words, each nine kinds of both leather and woolen fabrics have different ease lengths. In addition, each sleeve has been inspected visually and functionally. Following conclusion has been gotten based on outcome of the study: 1. Proper ease length for manufacture of leather garment is said to be 1∼2 cm. As a result, ease length with higher sleeve cap height shall be 1∼2cm, while the length with lower sleeve cap height shall be 1cm or less. 2. Wider sleeve width has better function. Considering relations with sleeve cap height, sleeve width shall exceed +4cm of bicep line. 3. to satisfy a variety of those conditions while manufacturing leather garment, sleeve cap height, which is used for the manufacture of full dress and street wear garment, To lessen the ease length, body A.H shall be relatively loose under the arms, or pad shall be supplemented on the shoulder, so that the difference had better be lessened to solve such problems.

• Journal of the Korean Applied Science and Technology
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• v.27 no.2
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• pp.188-195
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• 2010

In this study, we experimented that how to synthesis waterborne urethane-acrylic hybrid resin for leather coatings. First of all, We had analyzed data by FT-IR, SEM and TGA for the machanical properties. By TGA analysis polymers showed heat distortion temperature. and by FT-IR measurement we confirmed that synthesis of urethane and acrylic. In the experiment, solvent resistance, polyurethane and acrylic grades 4-5 showed both a high. Tensile strength measured in the waterborne polyurethane > Acrylic emulsion showed strength in the order. Films were obtained by coating the water born resin on leveled surfaces and allowing them to dry at room temperature for 72hrs. After demolding, the films were kept in a desiccator to avoid moisture contant at $25^{\circ}C$ for 45hrs before the measurements. In this result, the mechanical propersies of waterborne polyurethane-acrylic hybrid resin showed that how effect to resin in leather coating between polyurethane content and acrylic content. Therefore, acrylic emulsion had most high solvent resistance glade and waterborne polyurethane had good result in abrasion test and tensile strength.

• Journal of the Korean Society of Clothing and Textiles
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• v.5 no.2
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• pp.35-40
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• 1981

This study aims at finding appropriate adhesive conditions with special regard the material of 'fusible padding cloth inter ling' was frequently used for leather. As for leather material, pig suede, sheep suede were selected and drum dyed, cow split, napa have also been used. Mixed spinning non-woven fabric (polyester $50\%$, nylon $50\%$) were used as for padding cloth. Experimental appearance has been observed under the following adhesive conditions: Temperature of press were devided four levers; $120^{\circ}C$, $130^{\circ}C$, $140^{\circ}C$, $150^{\circ}C$, respectively. Adhesive time has been limited 5, 10, 15 second each. And the pressure has been conditioned as $0.2kg/cm^2$ continuously. After all this experiment, it was discovered that the material which had long contact with low temperature conditions has similar adhesive power to material that has short contact with high temperature conditions. There is a great difference according to the leather's dying process, the finishing method of the cloth, and the part of leather surface. The best condition for suede are $140^{\circ}C$, $150^{\circ}C$, at 10 seconds. and for D/D, NAPA, $130^{\circ}C$, at 10 seconds. Although the conditions of $150^{\circ}C$, at 15 seconds was possible for split, the process time can be shortened according to the increase of temperature.

• Journal of the Korean Society of Industry Convergence
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• v.11 no.3
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• pp.107-111
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• 2008

Usually, flow mediation earth and settling pond etc. of processing plant to handle water or wastewater. Mediation is the wastewater that flowed past settling pond than material of heavy particles, water weight colloid particles that big solids are removed but are suspensibility material settlement exclusion impossible. So, we need flocculation and coagulation action to remove materials from this colloid state. Flocculation and coagulation by addition of chemical agents forms floc settle size. That is, shorten the sedimentation time and quality of processing water because promoting sedimentation doing to do fines or suspended solids and colloid can materials large size and also, flocculation to annex efficiency of filtration augment. Therefore, I executed this research to prove that COD efficiency for wastewater by using inorganic coagulant.

• Textile Coloration and Finishing
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• v.18 no.6 s.91
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• pp.31-36
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• 2006

Study has been made for producing anionic surfactant using waste fleshing scraps from the leather making process through refining, esterification, sulfonation and blending processes. As a most optimum lard oil refining method, refining was carried out for 4 hours under temperature of $120^{\circ}C$ and approximately 200 mbar vacuum, which gave a recovery of more than 80% lard oil. Refined lard oil obtained thus was undergone methlyl-esterification, then sulfonated to make a degreasing agent. By methyl-esterification using lard oil, more than 85% of fatty acid and $12{\sim}13%$ of glycerine were extracted from the oil. Sulfonation of the extracted fatty acid ester lard oil has shown most optimum at $15{\sim}20%$ chlorosulfonic acid content, and the content of bonding sulfate at this time was higher than 3.5%. Finally the followed anionic surfactant having degreasing force of 80% and higher could be made by blending process.

• Conservation Science in Museum
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• v.6
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• pp.39-46
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• 2005

The National Museum of Korea has a collection of various materials. In particular, items made from organic materials such as wood, paper, and leather are vulnerable to the influence of insects and germs, requiring fumigation as well as pesticides and bactericides. The influence of pesticides and bactericides on the change in dyed paper was examined by applying the oddy test used to confirm the toxicity of various materials used in museums. Results revealed that the products of B and H companies had the least influence on the change in dyed paper. On the other hand, the result of the examination of cochineal and curcuma dyed paper revealed a significant change in the control group compared to the one exposed together with dyed paper, probably because of humidity rather than the sample.