• Title/Summary/Keyword: 표면물성

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Processing and Characterization of Polyamide 610/Carbon Fiber/Carbon Nanotube Composites through In-Situ Interfacial Polymerization (계면중합법을 이용한 폴리아마이드 610/탄소섬유/탄소나노튜브 복합재 제조 및 물성 평가)

  • Cho, Beom-Gon;Hwang, Sang-Ha;Park, Young-Bin
    • Composites Research
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    • v.33 no.6
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    • pp.415-420
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    • 2020
  • The interfacial properties in carbon fiber composites, which control the overall mechanical properties of the composites, are very important. Effective interface enhancement work is conducted on the modification of the carbon fiber surface with carbon nanotubes (CNTs). Nonetheless, most surface modifications methods do have their own drawbacks such as high temperatures with a range of 600~1000℃, which should be implemented for CNT growth on carbon fibers that can cause carbon fiber damages affecting deterioration of composites properties. This study includes the use of in-situ interfacial polymerization of polyamide 610/CNT to fabricate the carbon fiber composites. The process is very fast and continuous and can disperse CNTs with random orientation in the interface resulting in enhanced interfacial properties. Scanning electron microscopy was conducted to investigate the CNT dispersion and composites morphology, and the thermal stability of the composites was analyzed via thermogravimetric analysis. In addition, fiber pull-out tests were used to assess interfacial strength between fiber and matrix.

Recent Developments in Natural Fiber Reinforced Composites (천연섬유보강 복합재료의 최근 연구 개발)

  • Mirza, Foisal Ahmed;Afsar, Ali Md.;Kim, Byung-Sun;Song, Jong-Il
    • Composites Research
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    • v.22 no.4
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    • pp.41-49
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    • 2009
  • Natural fiber reinforced composites are emerging as low-cost, lightweight, recyclable, and eco-friendly materials. These are biodegradable and non-abrasive. Due to eco-friendly and biodegradable characteristics of natural fibers, they are being considered as potential candidates to replace the conventional fibers. The chemical, mechanical, and physical properties of natural fibers have distinct features depending upon the cellulose content of the fibers which varies from fiber to fiber. The mechanical properties of composites are influenced mainly by the adhesion between matrix and fibers. Several chemical and physical modification methods of fiber surface were incorporated to improve the tiber-matrix adhesion resulting in the enhancement of mechanical properties of the composites. This paper outlines the works reported on natural tiber reinforced composites with special reference to the type of fibers, polymer matrix, processing techniques, treatment of fibers, and fiber-matrix interface.

Effect of Water-Containing Conditions on Concrete Substrates on Defects of Polyurethane-based Waterproofing Materials (콘크리트 바탕면의 함수조건이 폴리 우레탄계 방수재 하자에 미치는 영향)

  • Lee, Gun-Cheol;Kim, Jae-Yeob;Kim, Young-Min;Hong, Sung-Rok;Kim, Young-Sam;Shin, Hong-Chol
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.1
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    • pp.1-9
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    • 2023
  • This study is to analyze the cause of the defects in polyurethane waterproofing, a material commonly used on the roof of buildings, and to determine if it has a relation with the curing conditions of humidity and temperature and the moisture content of the base structure. As a result, it was confirmed that the waterproofing coating did not adhere when the moisture content of the base plate was 10% or more. When the temperature and humidity conditions were 20℃ and 80%RH, none of the properties deteriorate but when the temperature was 40℃, 60%RH, air bubbles were formed on the surface, and at 40℃ and 80%RH, the basic properties of the dry coating film were less than the KS F 3211 performance standard.

Surface properties on ion beam irradiated polycarbonate (이온주입에 의한 폴리카보네이트의 표면특성 조사)

  • Lee, Jae-Hyung;Yang, Dae-Jeong;Kil, Jae-Kyun;Kim, Bo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.31-35
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    • 2003
  • 폴리카보네이트는 내열성과 투명성이 우수한데 비해 내후성이 좋지 않아 황변 및 물성이 저하되고, 내찰상성이 약하여 긁히기 쉬운데다 이물질에 의해 오염되기 쉬워 투명성이 저하되는 문제점이 있다. 이러한 단점을 극복하고, 사용하는 용도에 따라 요구되는 다양한 기능성을 부여하기 위하여 폴리카보네이트 표면에 기능성층을 형성시킴으로써 그 목적을 달성하고자 한다. 본 논문에서는 이온 주입기술을 이용하여, 폴리카보네이트 표면의 전기전도도 특성을 향상시키고, 피부암 및 백내장 등을 유발하는 유해한 자외선 (UV-A, UV-B)을 차단하려 한다. 표면전기전도도의 향상은 이물질로부터 오염되는 정도를 낮추며, 정전기를 방지할 수 있다. PC(Polycarbonate) 표면에 $N^+,\;Ar^+,\;Kr^+,\;Xe^+$ 이온을 에너지 20keV에서 50keV을 사용하여, 주입량 $5{\times}10^{15}\;{\sim}\7{\times}10^{16}\cm^2$ 로 조사하였다. 이온 주입된 PC의 표면을 두 접점 방법의 표면 저항 측정으로 표면전기전도도 특성을 알아보았고, 자외선차단 특성은 UV-Vis 로 분석하였다. 이들 전기적 광학적 특성간의 상관관계를 관찰하고, 이러한 특성을 나타내는 화학적 기능그룹들의 변화를 보기 위해 FTIR 분석법으로 관찰하였다. 이온조사량의 증가에 따라 표면저항은 $10^7{\Omega}/sq$까지 감소하여 표면전기특성을 증가시키며, 자외선 차단 특성은 UV-A를 95%까지 차단하여 인체에 유해한 자외선 차단에 유용함을 확인하였다. 이러한 특성은 PC 표면에 카본 네트워크 형성과 $\pi$전자들의 운동량을 증가시키는 구조로 고분자 사슬들의 결합구조 변형에 의한 것으로 생각된다.블을 가지고 파서를 설계하였다. 파서의 출력으로 AST가 생성되면 번역기는 AST를 탐색하면서 의미적으로 동등한 MSIL 코드를 생성하도록 시스템을 컴파일러 기법을 이용하여 모듈별로 구성하였다.적용하였다.n rate compared with conventional face recognition algorithms. 아니라 실내에서도 발생하고 있었다. 정량한 8개 화합물 각각과 총 휘발성 유기화합물의 스피어만 상관계수는 벤젠을 제외하고는 모두 유의하였다. 이중 톨루엔과 크실렌은 총 휘발성 유기화합물과 좋은 상관성 (톨루엔 0.76, 크실렌, 0.87)을 나타내었다. 이 연구는 톨루엔과 크실렌이 총 휘발성 유기화합물의 좋은 지표를 사용될 있고, 톨루엔, 에틸벤젠, 크실렌 등 많은 휘발성 유기화합물의 발생원은 실외뿐 아니라 실내에도 있음을 나타내고 있다.>10)의 $[^{18}F]F_2$를 얻었다. 결론: $^{18}O(p,n)^{18}F$ 핵반응을 이용하여 친전자성 방사성동위원소 $[^{18}F]F_2$를 생산하였다. 표적 챔버는 알루미늄으로 제작하였으며 본 연구에서 연구된 $[^{18}F]F_2$가스는 친핵성 치환반응으로 방사성동위원소를 도입하기 어려운 다양한 방사성의 약품개발에 유용하게 이용될 수 있을 것이다.었으나 움직임 보정 후 영상을 이용하여 비교한 경우, 결합능 변화가 선조체 영역에서 국한되어 나타나며 그 유의성이 움직임 보정 전에 비하여 낮음을 알 수 있었다. 결론: 뇌활성화 과제 수행시에 동반되는 피험자의 머리 움직임에 의하여 도파민 유리가 과대평가되었으며 이는 이 연구에서 제안한 영상정합을 이용한 움직임 보정기법에 의해서 개선되었다. 답이 없는 문제, 문제 만들기, 일반화가 가능한 문제 등으

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Effect of Liner Component Coatings by Oxidized Starch on Properties of Corrugated Board (라이너지의 산화전분 코팅이 골판지의 물성에 미치는 영향)

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.4 no.2
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    • pp.3-11
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    • 1998
  • Coating was carried out on liner components of B flute, single-wall corrugated board(SK180/S120/K200) to examine the effect of liner component coatings by oxidized starch on the properties of corrugated board. Both bursting strength and edgewise compression strength(ECS) of corrugated board were improved by coating of its liner components with oxidized starch. Bursting strength of corrugated board rapidly increased with an initial increase of coating weight, but as the coating weight further increased, there was no increase in bursting strength. The results showed 30.3% improvement for $2.32g/m^2$ coating on outside liner component, 36.8% improvement for $4.84g/m^2$ coating on inside liner component and 39.9% improvement for $7.16g/m^2$ coating on both liner components in bursting strength of corrugated board. Regardless of treated liner components, ECS of corrugated board was improved by coating of oxidized starch, and especially greater improvement was accomplished when corrugated board was coated on inside liner component or both liner components at low level of coating weight - 11.3% improvement for $1.58g/m^2$ coating on Inside liner component and 11.9% improvement for $2.99g/m^2$ coating on both liner components.

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Thermal stability of surface modified Ni-Cr-alloys in molten FLiNaK salt (표면처리된 Ni-Cr계 합금의 FLiNaK 용융염 하에서의 고온 안정성)

  • Kwang, Hyun Cho;Bang, Hyun;Lee, Tae Suk;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.5
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    • pp.227-232
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    • 2012
  • Inconel 617 and Hastelloy X are the most promising candidate materials for the heat exchanger of next generation nuclear reactor. Surface coating and its effects on high temperature properties for the Inconel 617 and Hastelloy X under molten FLiNaK (LiF-NaF-KF) salt environment have been investigated. For TiAlN and $Al_2O_3$ overlay coatings, the two different PVD (physical vapor deposition) methods of an arc discharge and a sputtering were applied, respectively. A study for the thermal stability of the surface modified Ni-Cr alloy substrates has been conducted. To evaluate the corrosion mechanism of Ni-Cr alloys in the molten salt, a ruptured Inconel pipe used for the molten salt transportation has been analyzed. The thermal properties of morphological and structural properties each sample were characterized before and after heat-treatment at $600^{\circ}C$ in molten FLiNaK salt. The results showed that the TiAlN and $Al_2O_3$ overlay coated specimens had the enhanced high temperature stability.

A study on the Manufacture and Application of UV-Cured Anti-stain Coating Compounds for PVC Tile (PVC 바닥상재용 광경화형 내오염 코팅액의 제조 및 응용에 관한 연구)

  • Yoon, Hyun-Jung;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1741-1746
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    • 2010
  • This study is on development of UV-cured anti-stain coating compounds which have more improved anti-stain function to prevent a surface of PVC tile from stain. To make an anti-stain coating composition, water soluble antistatic agent made from ammonium(IV) salt, antistatic agents for acrylic and polyurethane were used. Their contents varied from 5 to 20wt% against quantities of resin in coating composition. After coating PVC tiles using bar-coating method that can adjust a thickness, we estimated surface properties of coated layer such as anti-stain, electric resistance, adhesive power, thickness of coating, and so on. Results showed that a coating composition added 15wt% of water soluble antistatic agent and coated with No.12 bar-coater had the optimum surface property in electric resistance($3.24{\times}10^9{\Omega}/cm^2$), anti-stain(ink Test, Dust Test) and adhesive power. We could also find electric resistance and anti-stain effect were improved as antistatic agent content increased. However, excessive addition of antistatic agents(over 20wt%) caused the migration.

Interpretation of Physical Weathering and Deterioration Mechanism for Thermal Altered Pelitic Rocks: Ulju Cheonjeon-ri Petroglyph (열변질 이질암의 물리적 풍화작용과 손상메커니즘 해석: 울주 천전리 각석)

  • Chan Hee Lee;Yu Gun Chun
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.629-646
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    • 2023
  • Host rock of Cheonjeon-ri petroglyph is shale belonging to the Daegu Formation of Cretaceous Gyeongsang Supergroup. The rocks were hornfelsified by thermal alteration, and shows high density and hardness. The petroglyph forms weathered zone with certain depth, and has difference in mineral and chemical composition from the unweathered zone. As the physical deterioration evaluations, most of cracks on the surface appear parallel to the bedding, and are concentrated in the upper part with relatively low density. Breakout parts are occurred in the upper and lower parts of the petroglyph, accounting for 6.0% of the total area and occurs to have been created by the wedging action of cracks crossing. The first exfoliation parts occupying the surface were 23.8% of the total area, the second exfoliations covered with 9.3%, and the exfoliation parts with three or more times were calculated as 3.4%. It is interpreted that this is not due to natural weathering, and the thermal shock caused by the cremation custom here in the past. As the ultrasonic properties, the petroglyph indicates highly strength in the horizontal direction parallel to bedding, and the area with little physical damage recorded mean of 4,684 m/s, but the area with severe cracks and exfoliations showed difference from 2,597 to 3,382 m/s on average. Physical deterioration to the Cheonjeon-ri petroglyph occurred to influence by repeated weathering, which caused the rock surface to become more severe than the inside and the binding force of minerals to weaken. Therefore, it can be understood that when greater stress occurs in the weathered zone than in the unweathered zone, the relatively weathered surface loses its support and exfoliation occurs.

Measurement of Tensile Properties for Thin Aluminium Film by Using White Light Interferometer (백색광간섭계를 이용한 알루미늄 박막의 인장 물성 측정)

  • Kim, Sang-Kyo;Oh, Chung-Seog;Lee, Hak-Joo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.471-478
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    • 2010
  • Thin films play an important role in many technological applications including microelectronic devices, magnetic storage media, MEMS and surface coatings. It is well known that a thin film's material properties can be very different from the corresponding bulk properties and thus there has been a strong need for the development of a reliable test method to measure the mechanical properties of a thin film. We have developed an alternative and convenient test method to overcome the limitations of previous membrane deflection experiment and uniaxial tensile test by adopting a white light interferometer having sub-nanometer out-of-plane displacement resolution. The freestanding aluminium specimens are tested to verity the effectiveness of the test method developed and get the tensile properties. The specimens are 0.5 rum wide, $1{\mu}m$ thick and fabricated through MEMS processes including sputtering. 1 to 5 specimens are fabricated on Si dies. The membrane deflection experiments are carried out by using a homemade tester consisted of a motor-driven loading tip, a load cell, and 6 DOF alignment stages. The test system is compact enough to set it up beneath a commercial white light interferometric microscope. The white light fringes are utilized to align a specimen with the tester. The Young's modulus and yield point stress of the aluminium film are 62 GPa and 247 MPa, respectively.

Thermal and Mechanical Properties of OG POSS Filled DGEBA/DDM (OG POSS의 첨가가 DGEBA/DDM의 열적, 기계적 물성에 미치는 영향)

  • Choi, Chunghyeon;Kim, YunHo;Kumar, Sarath Kumar Sathish;Kim, Chun-Gon
    • Composites Research
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    • v.30 no.6
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    • pp.379-383
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    • 2017
  • A study on the low Earth orbit (LEO) space environment have been conducted as a use of composites have increased. Among the LEO environmental factors, atomic oxygen is one of the most critical factors because atomic oxygen can react and erode a surface of polymer-based composite materials. POSS (Polyhedral Oligomeric Silsesquioxane) materials have been widely studied as an atomic oxygen-resistant nanomaterial. In this study, nanocomposites, which are composed of OG (Octaglycidyldimethylsilyl) POSS nanomaterials and DGEBA/DDM epoxy, were fabricated to find out its thermal and mechanical properties. FT-IR results showed that the nanocomposites were fully cured and contained OG POSS enough. Thermogravimetric analysis and differential scanning calorimetry were performed to measure the thermal properties of the nanocomposites. The initial mass loss temperature and char yield were increased through the filling of OG POSS. As the content of OG POSS increased, glass transition temperature tended to increase to 5 wt.% of OG POSS, but the temperature decreased significantly at 10 wt.% of OG POSS. The tensile test results showed that the content of OG POSS did not affect tensile strength and tensile stiffness.