• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.6
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• pp.2306-2310
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• 2010

Corrosion is a complex series of oxidation/reduction reactions between at the water-metal surfaces and materials in which the water is stored or transported. With respect to the corrosion potential of drinking water, the primary concerns include the potential presence of toxic metals, such as lead and copper; deterioration and damage to the household plumbing, and aesthetic problems such as stained laundry, and bitter taste. This study was performed to evaluate the effects of corrosion inhibitors on corrosion rates, Fe and Cu release concentration in water distribution pipes. Decrease of corrosion rates were strongly related to phosphate corrosion inhibitors. Considering that typical corrosion processes consists of a series of electrochemical reaction at the metal surface in contact with water, corrosion rates were positively correlated with Fe release.

• Journal of the Korean Chemical Society
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• v.34 no.2
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• pp.197-202
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• 1990

Polyethylene glycol (PEG) grafted poly γ-benzyl L-glutamate (PBLG) were prepared from esterification or substitution reaction of PBLG with PEG having hydroxyl group at one end or primary amino groups at both ends. The viscosity of these polymer solution was decreased with decrease of polymer concentration. But in more dilute solution the viscosity was increased with decrease of polymer concentration. PEG-grafted PBLG polymers showed smaller water contact angles than PBLG homopolymer, and the water contact angles of the surface of PEG-grafted PBLG polymers were largely dropped by reacting with aminoethanol, resulting in hydrogel surfaces.

• Fire Science and Engineering
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• v.12 no.4
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• pp.13-19
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• 1998

We investigated the weight loss according to temperature using Thermal Gravimetric Analysis(TGA) in order to find the thermal hazard of carbon black(Hi-Black 10, Hi-Black 50L) dusts, and the properties of dust explosion in variation of the surface functional groups and specific surface area of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of carbon black dust. The explosion pressure of both carbon black increased as the specific surface area increased. The results indicated that Hi-Block 50L of which specific surface area was larger three to four times than that of Hi-Black 10 was much easier of dust explosion.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.276-276
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• 2011

진공증착법으로 ITO (indium-tin-oxide) 기판 위에 $AgGaSe_2$ 박막을 성장시켜 그 구조와 광학적 특성을 조사하였다. X-선 회절 분석에 의하여 살창상수는 a=5.97 ${\AA}$와 c=10.88 ${\AA}$이고, 황동광(chalcopyrite) 구조를 하고 있었으며, 그 성장 방향은 (112)방향으로 선택 성장됨을 알 수 있었다. 증착된 박막과 200~400$^{\circ}C$로 열처리한 박막의 실온에서 측정한 광학적인 에너지 띠 간격은 2.02 eV에서 2.28 eV까지 변하였다. 또한 열린회로로 구성되어 있는 시료의 표면에 광 펄스를 주입하여 표면에서 형성된 전하들의 거동을 광유기 방전 특성(PIDC) 방법을 이용하여 조사하였다. 초기전위 V0로 형성된 시료의 양단을 주행하는 운반자 농도, 전류밀도 및 전기장 효과를 관찰하여 운반자의 주행시간, 이동도 그리고 전하운반자 농도를 계산한 결과는 각각 42 ${\mu}s$~81 ${\mu}s$, $1.9{\times}10^{-1}\;cm^2/Vs$~$5.7{\times}10^{-2}\;cm^2/Vs$ 그리고 약 $6.0{\times}10^{17}/cm^3$~$2.0{\times}10^{18}/cm^3$이었으며, p-형 전도를 나타내었다. 원자 힘 현미경 실험으로 제곱평균제곱근 거칠기와 입계크기를 조사하였으며, X-선 광전자 분광실험으로 원소들의 결합상태를 관찰하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.76-76
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• 2018

LCD 디스플레이 크기는 점차 대형화를 이루면서, 현재 LCD 디스플레이 크기는 3,000*3,320mm 크기까지 증가하여 개발이 활발이 이루어지고 있다. 디스플레이의 크기가 증가함에 따라 제조 장비의 크기도 증가되어야 하므로, LCD 디스플레이 CVD 공정에 사용되는 4,200*3,300mm 크기의 대형 Aluminium Vacuum Chamber 에 피막두께 $15{\mu}m$ 이상을 구현함과 동시에 두께 균일도가 우수하며 염수분무시험으로 168시간 이상의 내식성 확보가 가능한 양극산화조건 개발을 위하여 양극산화 피막의 각종 특성 평가를 실시하였다. 양극산화 피막 두께 측정은 와전류(Eddy Current)의 원리를 이용한 비파괴식 두께 측정법(ISO 2360, ASTM D 7091)을 적용하였으며, 염수분무시험 방법은 (KS D 9502)을 적용하였으며, HCl bubble stream 시험 방법은 HCl 5% 농도를 투명 아크릴 튜브에 채운후 bubble stream 을 종점으로 하여 평가를 실시하였으며, 열충격을 이용한 도금밀착성(KS D 0254), 도장접착력(ASTM D 3359) 등을 이용하여 전해조건 및 전해액 농도에 따른 피막 특성 비교평가를 실시하여 최적의 대형 Aluminium Vacuum Chamber 양극산화 전해 조건을 개발하여 4,200*3,300mm 크기의 대형 Aluminium Vacuum Chamber 제조를 목적으로 하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.84.1-84.1
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• 2018

현재 사용되고 있는 화석 연료는 고갈되고 있으며 지구온난화와 같은 환경오염을 일으키는 주원인으로 이를 대체하는 에너지원으로서 수소가 주목받고 있다. 그러나 수소는 상온 및 대기압에서 4 %의 낮은 LEL (lower explosive limit)을 가지므로 높은 인화성과 폭발성을 가진다. 또한 무색, 무취한 성질을 가지고 있어 사람에 의해 검출되지 않는다. 그러므로 상온에서의 수소 농도를 정량화하고 검출하기 위한 방법이 필요하다. 수소를 검출하기 위한 수소센서에는 저항, 촉매, 광학, 일함수 등을 이용한 센서들이 있으며 그 중 저항을 이용한 귀금속 기반 수소센서가 널리 알려져 있다. 팔라듐(Pd), 백금 (Pt)와 같은 귀금속 기반 수소센서는 높은 수소 용해도 및 확산으로 인해 수소에 우수한 선택성을 가진다. 특히 Pd는 흡착에 대한 친화성이 매우 우수하다. 팔라듐에 수소가 노출되면, 수소가 Pd 격자로 확산되어 Pd-hydride를 형성시켜 부피가 팽창되고 저항이 변한다. 이러한 특성을 바탕으로 팔라듐의 저항 변화를 기반으로 한 수소센서의 개발이 진행되고 있다. 본 연구에서는 물리기상증착 (PVD)을 이용하여 다양한 다공성 나노 Pd 박막을 가지는 수소센서를 제작하였으며, 수소 농도에 따른 실온에서의 수소 검출 특성을 관찰하였다. 제작된 다공성 나노 Pd 박막의 특성은 SEM, TEM 및 XRD를 통하여 확인하였다. 다공성 나노 Pd 박막이 수소에 노출 되었을 때 전자 산란 및 접촉 면적의 증가에 따른 저항의 변화를 확인하였다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.2 no.2
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• pp.77-82
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• 1992

When a crystal is grown by FZ process, the melt zone is located at between the solid of upper and lower side and is kept by the solid-liquid interface tension. On the surface of the melt zone, a surface tension gradient is occured by the difference of temperature and solute concentration, it is the driving force of marangoni flow. The crystal even in the steady state growth can become imperfect for the dislocation distribution and the solute concentration in the peripheral region of the crystal are higher than those in the inner part and the probability of the formation of the defects such as voids, bubble penetration, secondary phase creation and crack is high near the solid-liquid interface. This is because the solid -liquid interface becomes irregular because of the local variation of temperature in that region due to marangoni convection.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.2
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• pp.63-70
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• 2010

A construction process of hydrogen peroxide supply system was investigated to use hydrogen peroxide as an oxidizer of bi-propellant liquid rocket engine. To use hydrogen peroxide as a rocket propellant, it has to be in high concentration over 90%. It is very important to make the supply system free of pollutants, because highly concentrated hydrogen peroxide has a characteristic of hypersensitive reaction to pollutants such as dust and oil sludge. We suggested the cleaning and passivation process of main components to minimize pollutants of the supply system. In conclusion, we verified stability of the constructed supply system by leak test and hot test.

• Applied Chemistry for Engineering
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• v.27 no.2
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• pp.185-189
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• 2016

Among many kinds of bioaffinity sensors, the avidin-biotin system has been widely used in a variety of biological applications due to the specific and high affinity interaction of the system. In this work, gold nanorods with high surface area were explored as electrodes in order to amplify the signal response from the avidin-biotin interaction which can be further utilized for avidin-biotin biosensors. Electrochemical performance of electrodes modified with nanorods and functionalized with avidin in response to interactions with biotin at various concentrations using $[Fe(CN)_6]^{3-/4-}$ couple as the redox probe were investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). A very low biotin concentration of less than 1 ng/mL could be detected using the electrodes modified with nanorods.

• Journal of ILASS-Korea
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• v.26 no.4
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• pp.212-218
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• 2021

The present study aims to develop the Surface Plasmon Resonance (SPR) imaging system facilitating the real-time measurement of the concentration of evaporating binary mixture droplet (BMD). We introduce the theoretical background of the SPR imaging technique and its methodology for concentration measurement. The SPR imaging system established in the present study consists of a LED light source, a polarizer, a lens, and a band pass filter for the collimated light of a 589 nm wavelength, and a CCD camera. Based on the Fresnel multiple-layer reflection theory, SPR imaging can capture the change of refractive index of evaporating BMD. For example, the present study exhibits the visualization process of ethylene glycol (EG)-water (W) BMD and measures real-time concentration change. Since the water component is more volatile than the ethylene glycol component, the refractive index of EG-W BMD varies with its mixture composition during BMD evaporation. We successfully measured the ethylene glycol concentration within the evaporating BMD by using SPR imaging.