• Title/Summary/Keyword: 폴리메틸 메타크릴레이트

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Study on Quality Criteria for Transparent Soundproof Panels(2) - Sound Insulation Characteristics and Evaluation of Weatherability (투명방음판의 품질기준 설정에 관한 연구(2) - 음향 특성 및 내후성 평가)

  • Chang, Taesun;Kim, Chulhwan;Hwang, Cheolho
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.11
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    • pp.1099-1105
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    • 2012
  • Transparent noise barrier panels have the advantages of transmitting light to nearby residents and allowing drivers to orientate themselves by providing views of the surrounding area. To develop guidelines on quality criteria for transparent soundproof panels, their sound transmission loss and weatherability were experimentally investigated. In Korea, the sound transmission loss of noise barrier panels should be more than 25 dB at 500 Hz and 30 dB at 1000 Hz. The transmission loss tests of transparent panels were performed in accordance with KS F 2808. Typically, plastic materials suffer from color changes when exposed to ultraviolet(UV) light over extended periods. Therefore, weathering of plastics is one of the most important properties for outdoor applications. Protection against UV radiation and weathering is usually accomplished by using UV stabilizer additives or coatings. Transparent materials for soundproof panels were examined through accelerated weathering tests and their weathering resistances were evaluated from changes in yellowness index.

A study on Creep of Plate PMMA in Thermal-Nanoindentation Process for Hyperfine pit structure Fabrication (극미세 점 구조체 제작을 위한 열간나노압입 공정에서의 평판형 PMMA의 크립현상에 관한 연구)

  • Lee, E.K.;Jung, Y.N.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.273-276
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    • 2008
  • Thermoplastic resin takes place stress relaxation and creep according to temperature and time. In room temperature, time dependent deformation (TDD) of polymer was carried out at previous study. In this study, it evaluates time dependent deformation to relate temperature. Nanoscale indents can be used as cells for molecular electronics and drug delivery, slots for integration into nanodevices, and defects for tailoring the structure and properties. Therefore, it is important to control pattern depth for change of indent depth by creep when using Nanoindenter. For evaluating TDD at high temperature, it is occurred thermal-nanoindentation test by changing hold time at maximum load. Temperature is putted at $90^{\circ}C$, hold time at maximum loads are putted at 1, 10, 50, 100, 200, 300 and 500s.

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Characteristics of PMMA Sheet with Phosphorous Flame Retardant Additives (인계 첨가제를 이용한 PMMA판재의 난연성 물성 특성)

  • Kim, Yong-Ryeol;Lim, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.224-230
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    • 2012
  • In this paper, flame-resisting PMMA(polymethyl methacrylate) sheet was manufactured and its characteristics were tested. PMMA was synthesized by bulk polymerization of a monomer methyl methacrylate with addition of phosphorous flame retardant, triethyl phosphate and ethylene glycol dimethacrylate as a cross linking agent. PMMA sheet was manufactured by using the cell molding method, which does not alter or affect the existing property of PMMA. Then the characteristics of PMMA sheet were tested for the TEP content, the content and curing time of EGDMA. As TEP content increases, the length of carbonization lessens and the amount of char production increases. As a result, it strengthened the effect of flame retardants. But the hardness of the sheet decreased as TEP content increased. However, hardness increased when EGDMA was added up to 3 wt% while curing time was decreased from 3 hours to 2 hours. There was no change of hardness when more than 3 wt% of EGDMA was used.

Effects of the Surface Modification on the Dispersion of Carbon Nanotube (탄소나노튜브의 분산성에 미치는 표면개질의 영향)

  • Kim, Sung-Su;Kim, Hyung-Joong;Yoo, Youngjae;Lee, Sung-Goo;Choi, Kil-Yeong;Lee, Jae Heung
    • Journal of Adhesion and Interface
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    • v.4 no.4
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    • pp.22-27
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    • 2003
  • Chemical modification of carbon nanotube (CNT) was carried out using $HNO_3$ and $H_2SO_4$ and characterized by analyzing the CNT before and after the modification using FT-IR and titration. Aggregation behaviors were investigated using a real-time video microscope after the chemically modified CNT(mCNT) had been dispersed in organic solvents such as toluene, dimethylformamide (DMF) and N-methylpyrrolidone (NMP) by ultrasonication. The mCNT showed better dispersion in polar sovents of DMF and NMP than the rCNT. CNT/ poly(methylmethacrylate) (PMMA) films were prepared from solution DMF/PMMA solutions. The films containing mCNT also revealed the improved dispersion.

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Evaluation of Image Uniformity and Radiolucency for Computed Tomography Phantom Made of 3-Dimensional Printing of Fused Deposition Modeling Technology by Using Acrylonitrile Butadiene Styrene Resin (아크릴로나이트릴·뷰타다이엔·스타이렌 수지와 용융적층조형 방식의 3차원 프린팅 기술로 제작된 전산화단층영상장치 팬톰에서 영상 균일성 및 X선 투과성 평가)

  • Seoung, Youl-Hun
    • Journal of radiological science and technology
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    • v.39 no.3
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    • pp.337-344
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    • 2016
  • The purpose of this study was to evaluate the radiolucency for the phantom output to the 3D printing technology. The 3D printing technology was applied for FDM (fused deposition modeling) method and was used the material of ABS (acrylonitrile butadiene styrene) resin. The phantom was designed in cylindrical uniformity. An image uniformity was measured by a cross-sectional images of the 3D printed phantom obtained from the CT equipment. The evaluation of radiolucency was measured exposure dose by the inserted ion-chamber from the 3D printed phantom. As a results, the average of uniformity in the cross-sectional CT image was 2.70 HU and the correlation of radiolucency between PMMA CT phantom and 3D printed ABS phantom is found to have a high correlation to 0.976. In the future, this results will be expected to be used as the basis for the phantom production of the radiation quality control by used 3D printing technology.

Mechanical Properties of Monodisperse Polymer Particles and Electroless Ni Plated Monodisperse Polymer Particles (단분산 가교고분자 미립자 및 그의 무전해 니켈도금체의 기계적 물성 연구)

  • Kim Dong-Ok;Jin Jeong-Hee;Shon Won-IL;Oh Seok-Heon
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.332-337
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    • 2006
  • Monodisperse polymer particles were prepared via one-step seeded polymerization using PMMA seed particles and HDDA (or EGDMA) as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer or monomer mixture to the seed polymer particles (swelling ratio), 2) the ratio of EGDMA in absorbed monomer mixture, 3) the dosage of initiator, and 4) electro less Ni plating on the variation of mechanical properties of monodisperse polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement, were investigated by using MCT (micro compression test). It was observed that monomer swelling ratio influenced only breaking strength, but EGDMA ratio in monomer mixture, dosage of initiator and electroless Ni plating affected both K-values and breaking strength.

Study for Mechanical Properties of Electroless (Ni/Au) Plated Monodisperse Polymer Particles (무전해 (니켈/금) 도금 처리된 단분산 가교고분자 미립자의 기계적 물성 연구)

  • Kim, Dong-Ok;Jin, Jeong-Hee;Shon, Won-Il;Oh, Seok-Heon
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.410-416
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    • 2007
  • Monodisperse polymer particles were prepared via one- step seeded polymerization using PMMA as seed particles, and HDDA, triEGDMA or EGDMA as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer to the seed polymer particles (swelling ratio), 2) the characteristics of crosslinking monomer, 3) electroless Ni plating, and 4) electroless Au Plating on the variation of mechanical properties of polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement were investigated by using MCT (micro compression test). It was observed that swelling ratio of polymer particles influenced only on breaking strength of polymer Particles, while electroless plating did on recovery rate, K-values ($K_{10}\;and\;K_{20}$) and breaking strength of electroless plated polymer particles. However, breaking displacement and K-values ($K_{30}{\sim}K_{50}$) were more or less insensitive to electroless plating.

Manufacture and Properties of PMMA Grafted Starch/Carbon Black/NBR Composites (PMMA 그래프트 전분/카본블랙/NBR 복합체의 제조와 물성)

  • Kim, Min-Su;Cho, Ur Ryong
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.764-769
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    • 2013
  • Starch was grafted by poly(methyl methacrylate) through the emulsion polymerization method. Modified starch/(acrylonitrile-butadiene rubber) (NBR) compounds were prepared by a latex blend method. The morphology, thermal properties and mechanical properties of the modified starch/carbon black/NBR composites were investigated with the change of starch concentration. The mechanical properties of the composites were improved by the addition of modified starch. But, when the concentration of modified starch was higher than 40 phr, the mechanical properties were deteriorated due to the poor dispersion of modified starch. At the same ratio of starch to carbon black, the composite showed a synergistic reinforcing effect by the good dispersion and high cross-linking density. In addition, the tensile strength, storage modulus, hardness, swelling and other properties were the best.

Effect of BLU Ingredient on Electrical and Optical Properties of Light Diffusing Film used for TFT-LCD TV (백라이트 유니트 구성요소가 TFT-LCD TV용 광확산필름의 전기, 광학적 특성에 미치는 영향)

  • Ahn, Cheol-Heung;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.397-402
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    • 2006
  • We have investigated the effect of each ingredient in the light diffusing film (LDF) which was used as backlight unit (BLU) of TFT-LCD TV on physical, electrical, thermal and optical properties of LDF. In anti-blocking layer, the excellent anti-blocking ability was obtained when 0.5~1.5 wt% of acrylic bead was added, and good decay-time and water-stability were shown when 0.8 wt% of tertiary ammonium salt was added. Optimal results for adhesion strength, curing rates and flexibility on the surface of PET film have been obtained in the light diffusing layer by using acrylic polyol as a binder resin, and by addition of 30~35 wt% non-yellowing type HDI crosslinker. In addition, the highest normal luminance value was obtained by addition of 250 wt% poly-dispersive polystyrene ($20{\mu}m$ PS) and polymethylmethacrylate ($20{\mu}m$ PMMA) beads into the binder resin (100 wt%). The higher normal luminance could be got for PMMA beads than PS beads because of the transmittance difference.

Preparation of Fibrous Adsorbent Modified with Iminodiacetic Acid and Its Co2+, Fe2+, and Pb2+ Adsorption Characteristics (이미노디아세트산을 함유한 섬유상 흡착제 제조 및 코발트, 철, 납 이온 흡착특성)

  • Yang, Hyun-Soo;Choi, Jun-Kyu;Nho, Young Chang
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.477-485
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    • 1999
  • The grafting of 2,3-epoxypropylmethacrylate (GMA) onto polypropylene fabric was carried out by the $\gamma$-ray preirradiation grafting technique. Subsequently, the GMA-grafted polypropylene fabric was reacted with iminodiacetic acid (IDA) in different mixed solvents to prepare the fibrous metal adsorbent. The grafting extent was found to be dependent on the reaction time, temperature, preirradiation dose and dose rate. The effects of various mixed solvents on the IDA amination onto GMA-grafted polypropylene fabric were investigated. Compared with other mixed solvents, the extent of amination was highest in the dimethylsulfoxide (DMSO)/water, but the reaction did not occur in the water. The adsorption characteristics of various metal ions by the prepared adsorbent were examined when it was immersed in the 100 ppm metal ion solution. The amount of adsorption followed the order:$Pb^{2+}>Co^{2+}>Fe^{2+}$.

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