• Title/Summary/Keyword: 포화곡선

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Studies on the Laboratory Test of Lime Requirement (실험실(實驗室)에서의 석회소요량(石灰所要量) 측정방법(測定方法)에 관(關)한 연구(硏究))

  • Park, C.S.;Lee, J.K.;Lee, Y.C.;Lee, J.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.1 no.1
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    • pp.117-123
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    • 1968
  • A simplest and best method to find out lime requirement for Korean soils is described. Twenty six top soil samples were collected from various localities and chemical characteristics were dertermined. Three different buffer curve methods were employed as the standard to find out the most reliable test for lime requirement. In addition, the lime requirement test by the Shoemaker's and Woodruff's as well as the O.R.D. kit method were compared with the most reliable buffer curve method. The results may be summarized as follows. 1. The regression equation of the most reliable lime requirement by buffer curve method, y, on percent base saturation of various soils, X, was y=9.69-0.106 X and the negative correlation coefficient r=-0.84 was statistically significant at 5% level. 2. Lime requirement test by the best, buffer curve, method was more well correlated with the sum of exchangeable hydrogen and exchangeable aluminum contents of the soil samples than the exchangeable hydrogen content only. 3. The ordinary buffer curve method for lime requirement is more reasonable than the lime requirement test by the buffer curve prepared after addition of 1 normal potassium chloride or calcium chloride solutions. 4. The lime requirement tests by the most reasonable buffer curve method, X, and by the Woodruff's, the Shoemaker's and O.R.D. kit were compared. The best method for laboratory lime requirement test was the Shoemaker's method and the O.R.D. kit method also was good enough for the field test and these two method are recommended as the unified method of lime requirement test in each soil testing laboratories throughout Korea.

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Properties of ultra-thin silicon oxynitride films using plasma-assisted oxynitridation method (플라즈마 처리 기법을 이용한 초박형 실리콘 옥시나이트라이드 박막의 특성)

  • Jung, Sung-Wook;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.260-260
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    • 2009
  • 초박형 절연막은 현재 다양한 전자소자의 제작과 향상을 위하여 활용되고 있으며, 일반적인 화학 기상 증착 방법으로는 균일도를 확보하기 어려운 문제점을 가지고 있다. 본 논문에서는 디스플레이의 구동소자로 활용되는 박막 트랜지스터의 특성 향상과 비휘발성 메모리 소자의 터널링 박막에 응용하기 위하여 초박형 실리콘 옥시나이트라이드 박막의 증착과 이의 특성을 분석하였다. 실리콘 옥시나이트라이드 박막은 실리콘 산화막에 질소가 주입되어 있는 형태로 실리콘 산화막과 실리콘 계면상에 존재하는 질소는 터널링 전류와 결함 형성을 감소시키며, bulk 내에 존재하는 질소는 단일 실리콘 산화막에 비해 더 두꺼운 박막을 커패시턴스의 감소없이 이용할 수 있는 장점이 있다. 플라즈마 처리 기법을 이용하였을 경우에는 초박형의 균일한 박막을 얻을 수 있으며, 본 연구에서는 이산화질소 플라즈마를 이용하여 활성화된 질소 및 산소 라디칼들이 실리콘 계면을 개질하여 초박형 실리콘 옥시나이트라이드 박막을 형성활 수 있다. 플라즈마 처리 시간과 RF power의 변화에 따라 형성된 실리콘 옥시나이트라이드 박막의 두께 및 광학적 특성은 엘립소미터를 통하여 분석하였으며, 전기적인 특성은 금속-절연막-실리콘의 MIS 구조를 형성하여 커패시턴스-전압 곡선과 전류-전압 곡선을 사용하여 평가하였다. 이산화질소 플라즈마 처리 방법을 사용한 실리콘 옥시나이트라이드 박막을 log-log 스케일로 시간과 박막 두께의 함수로 전환해보면 선형적인 증가를 나타내며, 이는 초기적으로 증착률이 높고 시간이 지남에 따라 두께 증가가 포화상태에 도달함을 확인할 수 있다. 실리콘 옥시나이트라이드 박막은 초기적으로 산소의 함유량이 많은 형태의 박막으로 구성되며, 시간의 증가에 따라서 질소의 함유량이 증가하여 굴절률이 높고 더욱 치밀한 형태의 박막이 형성되었으며, 이는 시간의 증가에 따라 플라즈마 챔버 내에 존재하는 활성종들은 실리콘 박막의 개질을 통한 실리콘 옥시나이트라이드 박막의 두께 증가에 기여하기 보다는 형성된 박막의 내부적인 성분 변화에 기여하게 된다. 이산화질소 플라즈마 처리 시간의 변화에 따라 형성된 박막의 정기적인 특성의 경우, 2.3 nm 이상의 실리콘 옥시나이트라이드 박막을 가진 MIS 구조에서 accumulation과 inversion의 특성이 명확하게 나타남을 확인할 수 있다. 아산화질소 플라즈마 처리 시간이 짧은 실리콘 옥시나이트라이드 박막의 경우 전압의 변화에 따라 공핍영역에서의 기울기가 현저히 감소하며 이는 플라즈마에 의한 계면 손상으로 계면결합 전하량이 증가에 기인한 것으로 판단된다. 또한, 전류-전압 곡선을 활용하여 측정한 터널링 메카니즘은 2.3 nm 이하의 두께를 가진 실리콘 옥시나이트라이드 박막은 직접 터널링이 주도하며, 2.7 nm 이상의 두께를 가진 실리콘 옥시나이트라이드 박막은 F-N 터널링이 주도하고 있음을 확인할 수 있다. 즉, 2.5 nm 두께를 경계로 하여 실리콘 옥시나이트라이드 박막의 터널링 메카니즘이 변화함을 확인할 수 있다. 결론적으로 2.3 nm 이상의 두께를 가진 실리콘 옥시나이트라이드 박막에서 전기적인 안정성을 확보할수 있어 박막트랜지스터의 절연막으로 활용이 가능하며 2.5 nm 두께를 경계로 터널링 메커니즘이 변화하는 특성을 이용하여 비휘발성 메모리 소자 제작시 전하 주입 및 기억 유지 특성을 확보를 위한 실리콘 옥시나이트라이드 터널링 박막을 효과적으로 선택하여 활용할 수 있다.

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Study on the Moisture Sorption Characteristics of Seasoned Dried Laver (조미 건조김의 흡습특성에 관한 연구)

  • 임종환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.4
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    • pp.476-483
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    • 1993
  • The moisture sorption characteristics of commercially produced seasoned dried layer (Porphyra yezoensis) was investigated by measuring sorption isotherms. The laver and two kinds of desiccant (silica gel and zeolite based desiccant) were used at temperatures of 30, 40 and 5$0^{\circ}C$ respectively using the method of saturated salt solution. Time to reach the equilibrium moisture content at each temperature and relative humidity varied from 4~6hr for the laver to 20~25hr for the silica gel and 43~46hr for the zeolite. The isotherms of the layer and the desiccants showed the characteristic sigmoidal curve. Monomolecular layer moisture content calculated using the BET equation at each temperature (30, 40, 5$0^{\circ}C$) were 5.26, 4.46 and 3.49% (d.b.) for the laver, 17.32, 15.24 and 12.89% (d.b.) for the silica gel, 16.89, 14.92 and 14.44% (d.b.) for the zeolite, respectively, Both desiccants showed higher values of the monomolecular layer moisture content than the laver. In all cases, the monomolerular layer moisture contents were decreased linearly as the temperature was increased in the experimental ranges. Water vapor transmission rate of the packaged material was also influenced by the temperature, which could be explained by the Arrhenius equation.

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Influence of Antecedent Rainfall in Stability Analysis of Unsaturated Soil Slope (불포화토 사면 안정해석에서 선행강우의 영향에 관한 연구)

  • Lee, Yeongsaeng;Yoon, Seunghyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.5
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    • pp.1073-1082
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    • 2015
  • The behavior of the unsaturated soil slope can be influenced by the various factors such as the hydraulic characteristics, the mechanical characteristics, the coefficient of conductivity, the stratifications, the rainfall conditions i.e. the rainfall intensity, the rainfall pattern, the duration time of the rainfall and the antecedent rainfall etc. It is known that the slope failure is influenced greatly by the antecedent rainfall rather than the rainfall condition at the failure time, so the antecedent rainfall is supposed to be a very important factor in slope stability analysis among these factors. To predict and to prevent the slope failure by the rainfall, the distribution of the matric suction by the antecedent rainfall must be considered first of all and the slope stability analysis should be carried out by considering the successive rainfall characteristics. In this research, 3 samples with different quantity (5%, 10%, 20%) of silts were prepared and the SWCC (Soil-water characteristic curve) tests were carried out and the associated parameters were analyzed. After analyzing the distribution of the matric suction and the change of the mechanical characteristics such as the stress and the strength when applying the antecedent rainfall for one month and the successive intensive rainfall for 12 hours, the slope stability analyses were carried out numerically. And the influence of the antecedent rainfall for one month and the SWCC on the stability of a slope were compared and analyzed.

Numerical Analysis of Infiltration in Permeable Pavement System considering Unsaturated Characteristics (불포화 특성을 고려한 투수성 포장 시스템의 침투성 수치해석)

  • Kim, Seungbae;Ahn, Jaehun;Teodosio, Bertrand;Shin, Hyunjun
    • Journal of the Society of Disaster Information
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    • v.11 no.3
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    • pp.318-328
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    • 2015
  • Effective urban flood reduction and restoration of natural water cycle at present include the application of permeable pavements. The application of permeable pavement addresses urban water cycle and disaster related events which gained attention internationally. However, few researches have been conducted to investigate unsaturated behavior and evaluate the water characteristics curves of these type of pavement materials most especially in the unsaturated state. In this study, first the saturated permeability and the soil-water characteristics curve of a pervious concrete are evaluated based on laboratory tests, and, based on experimental results, the infiltration of permeable pavement system is numerically modelled. In the soil-water characteristics curve of a pervious concrete, the volumetric water content drops very steeply after the air entry value with increasing matric suction. From the finite element analyses, the performance of the permeable pavement when compared to impermeable pavement, confirmed that the whole system effectively delayed and reduced runoff.

Study on the structure of the articulation jack and skin plate of the sharp curve section shield TBM in numerical analysis (수치해석을 통한 급곡선 구간 Shield TBM의 중절잭 및 스킨플레이트 구조에 관한 연구)

  • Kang, Sin-Hyun;Kim, Dong-Ho;Kim, Hun-Tae;Song, Seung-Woo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.3
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    • pp.421-435
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    • 2017
  • Recently, due to the saturation of ground structures and the overpopulation of pipeline facilities requires to development of underground structures as an alternative to ground structures. Thus, mechanized tunnel construction of the shield TBM method has been increasing in order to prevent vibration and noise problems in construction of the NATM tunnel for the urban infrastructure construction. Tunnel construction plan for the tunnel line should be formed in a sharp curve to avoid building foundation and underground structures and it is inevitable to develop a shield TBM technology that suits the sharp curve tunnel construction. Therefore, this study is about the structural stability technology of the articulation jack, shield jack and skin plate for the shield TBM thrust in case of the mechanized tunnel construction that is a straight and sharp curve line. The construction case study and shield TBM operation principle are examined and analyzed by the theoretical approach. The torque of the cutter head, the thrust of the articulation jack and the shield jack, the amount of over cutting for curve is important respectively in shield TBM construction of straight and sharp curve line. In addition, it is very important to secure the stability of the skin plate structure to ensure the safety of the inside worker. This study examines the general structure and construction of the equipment, experimental simulation was carried out through numerical analysis to examine the main factors and structural stability of the skin plate structure. The structural stability of the skin plate was evaluated and optimizes the shape by comparing the loads of the articulation jack by selecting the virtual soil to be applied in a straight and sharp curve line construction. Since the present structure and operation method of the shield TBM type in domestic constructions are very similar, this study will help to develop the localized shield TBM technology for the new equipment and the vulnerability and stability review.

Analysis of Landscape According to Land Use at Rural Area in Korea Using GIS Application (GIS기법을 이용한 농촌지역의 토지이용에 따른 경관유형 분석)

  • Hong, Seung-Gil;Seo, Myung-Chul;Jung, Pil-Kyun;Sonn, Yeon-Kyu;Park, Kwang-Lai;Kang, Kee-Kyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.1
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    • pp.1-7
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    • 2006
  • To designate rural landscape spatially, land use and topographic features for 383 of "Ri"s or "Dong", which is a basic administrative unit in Korea, were analyzed using GIS application. We have categorized rural landscape into three types such as agricultural, natural and urban landscape by land use. On the basis of spatial landscape pattern, rural area could be classified into 6 groups of Mountainous area (MA), Mountainous village area (MV), Developing mountainous village area (DM), Plain agricultural area (PA), Developing plain village area (DP) and Urbanized area (UA) according to the ratios of land for agricultural and urban use as the criteria. In MA, the ratio of upland area including orchard was slightly larger than that of paddy, while that of paddy was about 1.5 times larger than upland in other groups. Forested area was distributed more than two-thirds among natural landscape area in MA, MV and DM. In plain types (PA and DP), the ratio of irrigated paddy was extremely larger than partially irrigated paddy and the ratio of water body area among the natural landscape area was two times as large as that of forested area. The ratio of land for industrial and livestock facilities among urban landscape area were 20% or more in MV, DM and DP, and it means that these facilities are mainly distributed in the developing ru ral area where residents and industry are closely related each other. According to the relative ratio of sloped land of 6 categorized areas, the MA area have lots of land with E and F slopes and MV and DM have all grades of sloped land evenly distributed in relative to other types of rural landscape. It has been showed that PA, DP and UA occupied more than two-thirds of land with A or B slope. In case of the analysis of topological distribution in 6 types of rural landscape, there were overwhelmingly lager highland areas in MA. Conclusively, we have confirmed that 6 types of rural landscape classified by land use pattern in 3 categorized areas such as agricultural, natural and urban landscape area would be useful for the management of rural area. For development of sustainable agriculture and the preservation of rural amenity, proper management ways should be properly applied according to rural landscape patterns.

Magnetic Properties of Hard/Soft Nanocomposite Ferrite Synthesized by Self-Combustion Precursors (자전 연소 전구체로 합성한 나노 크기 경/연 복합페라이트의 자기 특성)

  • Oh, Young Woo;Ahn, Jong Gyeon
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.3
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    • pp.45-50
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    • 2015
  • The goal of this research is the create novel magnets with no rare-earth contents, with larger energy product by comparison with currently used ferrites. For this purpose we developed nano-sized hard-type/soft-type composite ferrite in which high remanent magnetization (Mr) and high coercivity (Hc). Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ composite ferrites were prepared by sol-gel combustion method by use of glicine-nitrate and citric acid. Nanocomposite ferrites were calcined at temperature range $700-900^{\circ}C$ for 1h. According to the X-ray diffraction patterns and FT-IR spectra, single phase of NiZn-ferrite and Ba-ferrite were detected and hard/soft nanocomposite ferrite was indicated to the coexistence of the magnetoplumbite-structural $BaFe_{12}O_{19}$ and spinel-structural $Ni_{0.5}Zn_{0.5}Fe_2O_4$ that agreed with the standard JCPDS 10-0325 data. The particle size of nanocomposite turn out to be less than 120 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite ferrite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that of the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite, and $(BH)_{max}$ is increased slightly.

A New Methodology for the Assessment of Liquefaction Potential Based on the Dynamic Characteristics of Soils (I) : A Proposal of Methodology (지반의 동적특성에 기초한 액상화 평가법(I) : 이론제안)

  • 최재순;홍우석;박인준;김수일
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.91-99
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    • 2002
  • In this study, a new methodology for the assessment of liquefaction potential is proposed. Since there is no data on the liquefaction damage in Korea, the dynamic behavior of fully saturated soils is characterized through laboratory dynamic tests. There are two experimental parameters related to the soil liquefaction resistance characteristics : the one is the index of disturbance determined by $G/G_{max}$ curve and the other is a plastic shear strain trajectory evaluated from stress-strain curve. The proposed methodology takes advantage of the site response analysis based on real earthquake records to determine the driving effect of earthquake. In the evaluation of liquefaction resistance characteristics, it is verified experimentally that the magnitude of cyclic shear stress has no influence on the critical value of plastic shear strain trajectory at which the initial liquefaction occurs. Cyclic triaxial tests under the conditions of various cyclic stress ratios and torsional shear tests are carried out far the purpose of verification. Through this study, the critical value at the initial liquefaction is found unique regardless of the cyclic stress ratio. It is also f3und that liquefaction resistance curve drawn with disturbance and plastic shear strain trajectory can simulate the behavior of fully saturated soils under dynamic loads.

Estimate of Characteristics and Manufacture of Blood Substitutes (혈액대용물질의 제조 및 특성 평가)

  • Kim, Gi-Beum;Park, Jai-Koan;Kim, Seong-Jong;Kim, Jong-Soo;You, Il-Soo;Kim, Min-Ho;Hong, Chul-Un;Kim, Jin-Shang;Kang, Hyung-Sub
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.626-632
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    • 2008
  • The purpose of this study was to enhance gas exchange by producing hemosome, a hemoglobin microencapsulated with phospholipid of egg, and perfluorocarbone(PFC) emulsion solution. In the experiment, stable emulsion solution with 437 nm of mean particle size could be produced by Flusol-DA sonication, and shortening of emulsion time could be attained with higher stability as well. $0.8{\mu}m$ sized hemosome could be produced by microencapsulation of hemoglobin with phospholipid extracted from egg yolk. The pattern of oxygen saturation curve of hemosome was S shape, which is similar to that found in normal blood, and $P_{50}$ was measured to be 24 mmHg. The oxygen saturation in the mixed solution of hemosome and blood in 1:4(V/V%) ratio was similar to that of normal blood, and the same result was found in the mixed solution of PFC emulsion and blood in 1:4(V/V%) ratio.