• Title/Summary/Keyword: 폐기물 고화

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The Corrosion Properties of Zr-Cr-NM Alloy Metallic Waste Form for Long-term Disposal (Zr-Cr-NM 금속폐기물고화체 합금의 장기처분을 위한 부식특성)

  • Han, Seungyoub;Jang, Seon Ah;Eun, Hee-Chul;Choi, Jung-Hoon;Lee, Ki Rak;Park, Hwan Seo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.2
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    • pp.125-133
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    • 2017
  • KAERI is conducting research on spent cladding hulls and additive metals to generate a solidification host matrix for the noble metal fission product waste in anode sludge from the electro-refining process to minimize the volume of waste that needs to be disposed of. In this study, alloy compositions Zr-17Cr, Zr-22Cr, and Zr-27Cr were prepared with or without eight noble metals representing fuel waste using induction melting. The microstructures of the resulting alloys were characterized and electrochemical corrosion tests were conducted to evaluate their corrosion characteristics. All the compositions had better corrosion characteristics than other Zr-based alloys that were evaluated for comparison. Analysis of the leach solution after the corrosion test of the Zr-22Cr-8NM specimen indicated that the noble metals were not leached during corrosion under 500 mV imposed voltage, which simulates a highly oxidizing disposal environment. The results of this study confirm that Zr-Cr based compositions will likely serve as chemically stable waste forms.

Solidification of municipal solid waste incineration fly ash by hauyne clinker (Hauyne 클링커에 의한 생활폐기물 소각 비산재의 고화 특성)

  • Han, Gi-Chun;You, Kwang-Suk;Um, Nam-Il;Cho, Kye-Hong;Cho, Hee-Chan;Ahn, Ji-Whan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.355-359
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    • 2005
  • 본 연구에서는 OPC 및 hauyne 클링커의 비산재에 대한 고화특성을 검토하였다. 비산재에 대해 OPC 및 OPC에 hauyne 클링커를 20%까지 대체하였을 때의 압축강도, 길이변화율, 중금속 용출량 등을 조사하였다. 결과로서, hauyne 클링커의 첨가량에 따라 고화체의 압축 강도가 증가하였다. hauyne 클링커의 첨가량은 10%내외가 적합하였으며, 그 이상에서는 길이변화율이 증가하며 팽창하였다. 고화체의 중금속 용출시험결과 모든 배합조건에서 환경기준치이하의 값을 나타내었다.

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Shear Strength Characteristics of Dredged Soil with Oyster Shell Binder (굴패각 고화재를 혼합한 준설토의 전단특성)

  • Lee, Sangjin;Yoon, Gillim;Lee, Yoongyu;Lee, Kidong;Kang, Ingyu;Kim, Hongtaek;Baek, Seungcheol
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.1
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    • pp.27-32
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    • 2007
  • Trafficability for construction equipments in soft ground should be secured by improving the surface course. For this situation, the ground improvement technique has been used with stiffening agent, but the improvement cement has been mostly used so far. However, oyster shell has been developed and used as the stiffening agent to expand the chance of recycling oyster shell, which is regarded as solid waste. In this research, it was confirmed mechanical characteristics of oyster shell as stiffening agent by analyzing the strength characteristic such as mixing rates, water contents, and curing days of that to the dredging soil.

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Identification of Uranium Species Released from the Waste Glass in Contact with Bentonite

  • Kim Seung-Soo;Chun Kwan-Sik;Kang Chul-Hyung;Han Phil-Su;Choi Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.3
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    • pp.177-181
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    • 2005
  • Yellowish uranium compounds were enriched at the interface between a Ca-bentonite block and a waste glass, containing about $20\%$ uranium oxide, in contact with the block due to the dissolution of uranium by a synthetic granitic groundwater in Ar atmosphere. The uranium compound formed for 6 years leach time was identified as a beta-uranophane $[Ca(UO_2)_2(SiO_{3}OH)_{2}5H_{2}O]$ using XRD, IR and mass spectrometer. The solubility of the beta-uranophane was measured to be about $10^{-6}\;mole/L$ in de-mineralized water at $80^{\circ}C$.

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The Effect of Freeze and Thaw for the Stabilized Soil Bottom Liners in the Landfill (폐기물 매립지 바닥층의 고화토 포설시 동결/융해 현상에 관한 연구)

  • Lee, Song;Lee, Jai-Young;Kim, Heung-Suck
    • Journal of the Korean Geotechnical Society
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    • v.16 no.1
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    • pp.179-189
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    • 2000
  • The purpose of this research is to complement the existing researches on landfill bottom liners behavior during the periods of freeze and thaw. Landfill-related researches have been typically focused on small-scale soil samples that are often compacted under conditions different from those used in the field. Although these tests have been invaluable in clarifying the problem of freeze and thaw, extending the results of such experimental studies to prototype landfills are questionable. In this investigation, the author utilized a large scale laboratory simulation allowing inclusion of the field depth of the cover systems, layered soil profiles, rainfall simulation, a cold climate and boundary conditions similar to those encountered in the landfill. The soil materials were stabilized soils (mixed clays, cements, and minerals) instead of clays. The bottom liners are made up of drainage layer (30 cm), stabilized layer (75 cm), and leach collection layer (60 cm). The stabilized layers are made up of supporting layer (45 cm) and low permeable layer (30 cm) - consisting of $P_A\; and\; P_B$ layer. As a results, depths of penetration increased by about 2~5 more centimeters at rainfall simulated designs than those at no rainfall simulated designs (that is design 3, design 5 and design 7) - it increased by about 20mm/day in the bottom liners and frost heaves also increased it by a few millimeters. Also, a few cracks appeared partly. According to these results, we can surmise that the compacted stabilized soil is more reliable than the compacted clay liners for construction of the landfill liners.

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Design, Manufacturing, and Performance estimation of a Disposal Canister for the Ceramic Waste from Pyroprocessing (파이로 공정 세라믹 폐기물을 위한 처분용기의 설계, 제작 방안, 그리고 기능 평가)

  • Lee, Minsoo;Choi, Heui-Joo;Lee, Jong-Youl;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.209-218
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    • 2012
  • A pyroprocess is currently being developed by KAERI to cope with a highly accumulated spent nuclear fuel in Korea. The pyroprocess produces a certain amount of high-level radioactive waste (HLW), which is solidified by a ceramic binder. The produced ceramic waste will be confined in a secure disposal canister and then placed in a deep geologic formation so as not to contaminate human environment. In this paper, the development of a disposal canister was overviewed by discussing mainly its design premises, constitution, manufacturing methods, corrosion resistance in a deep geologic environment, radiation shielding, and structural stability. The disposal canister should be safe from thermal, chemical, mechanical, and biological invasions for a very long time so as not to release any kind of radionuclides.