• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.585-585
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• 2013

유도 결합 플라즈마는 비교적 간단한 방전 구조와 고밀도 플라즈마 생성에 유리하기 때문에 산업 플라즈마 공정 장비로 널리 사용되고 있으며, 안테나에 의한 전력 전달 특성 및 방전 특성이 공정 결과에 큰 영향을 주게 된다. 이러한 유도 결합 플라즈마는 변압기 모델을 통하여 전력 전달 특성을 해석할 수 있으며, 안테나의 감은 수가 증가할수록 플라즈마로의 전력 전달 효율 및 플라즈마 밀도 상승이 기대된다. 반면에, 안테나 양단 또는 챔버 벽면과의 원치 않는 용량성 결합에 의하여, 실제로 안테나 감은 수가 증가함에 따라서 플라즈마로의 전력 전달 효율 및 방전 특성이 향상되지 않을 수도 있다. 본 연구는 이러한 안테나 감은 수 효과에 의한 전력 전달 효율 및 플라즈마 변수 변화에 대한 내용을 다루고 있으며, 플라즈마 변수 진단을 통하여 방전 특성을 연구하였다. 용량성결합을 최소화하기 위하여, 평형 전력 안테나를 사용하여 실험을 진행하였으며, 평형 전력이 인가되지 않은 안테나 구조에서의 안테나 감은 수에 따른 방전 특성과 결과를 비교하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2006.05a
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• pp.588-593
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• 2006

자연하천은 일반적으로 만곡수로나 사행수로 형태를 보이고 있으며, 직선수로에서와 달리 원심력에 기인한 이차류 영향을 받게 된다. 이차류에 의해서 수면에서는 만곡부 바깥쪽으로, 하상에서는 만곡부 안쪽으로의 흐름특성을 보이게 된다. 만곡부 안쪽으로 가해지는 하상 전단응력에 기인하여 하상에서의 입자가 만곡부 안쪽으로 이송되며, 결과적으로 만곡부 안쪽에는 점사주가, 바깥쪽에는 소(pool)가 생성된다. 또한 지형경사의 생성으로 입자에 가해지는 중력효과도 변화된다. 따라서 이와 같은 자연하천의 흐름과 하상변동을 수치모의 하기 위해서는 만곡부 이차류 특성을 고려한 모형이 필요하다. 본 연구에서는 수심 적분된 흐름방정식과 하상토 보존방정식 (Exner equation)을 이용한 하상변동을 위한 비연계 수치모형을 위해서 하상토 보존방정식의 유한요소 알고리즘을 개발하였다. 하상토 보존방정식은 흐름 특성에 따른 평형 유사량의 공간변화율을 이용하여 일정 기간 동안의 하상 변화량을 계산한다. 이 때 이차류에 의한 하상 전단응력의 편각 및 지형경사 변화에 따른 실제 입자의 이송방향을 보정하여 평형 유사량이 계산된다. 이러한 보정식을 적용시키기 위해서는 유속성분의 공간변화량 및 지형경사의 공간성분이 필요하다. 유한요소법은 연속성 변수를 이산화시켜 근사해를 구하는 수치기법의 일종이기 때문에, 요소망이 불규칙적으로 구성되었을 경우 임의의 절점에서 연속성을 지닌 변수의 공간변화율을 계산하는데 어려움이 있다. 따라서 본 연구에서는 평형 유사량 계산 시에 절점이 아닌 요소 내부에서 평형 유사량을 계산하는, 하상토 보존방정식의 새로운 유한요소 알고리즘을 개발하고, 새로운 알고리즘을 적용시킨 수치모형의 검증을 행하였다. 경계조건 알고리즘의 검증으로 위해서 Soni 등 (1980)이 행한 상류 유입 유사량에 따른 하상변동을 수치 모의하고 실험치와 비교하였으며, Sutmuller와 Glerum (1980)이 수행한 만곡수로에서의 하상변동을 모의하고 실험과 비교하였다. 새로운 알고리즘을 적용시킨 하상토 보존방정식의 유한요소 수치모형의 결과는 매우 안정적이며, 실험과 매우 유사한 결과를 얻을 수 있었다. 본 수치모델은 현재 균일한 입자의 하상토만을 고려하므로, 입자분급이나 하상 장갑화 현상 등은 무시한다.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.755-761
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• 2009

To a first approximation, phase behavior of a system becomes increasingly skew in proportion to the boiling point difference of system-forming constituents. Therefore, phase behavior data of a system of a large boiling point difference are to be experimentally measured for thorough understanding of the thermodynamic characteristics of such system. In this work, isobaric vapor-liquid equilibrium of a mixture consisting of toluene and cresol, which shows a large boiling point difference of nearly $100^{\circ}C$ and is consequently expected to be considerably nonideal, was measured by using a recirculating equilibrium cell at various subatmospheric pressures ranging from 10 kPa to 60 kPa. The measured VLE data were correlated with NRTL and UNIQUAC models in a satisfactory manner and the accompanying thermodynamic consistency test represented soundness of the measurements. In addition, the excess molar volume of the mixture was also measured with a vibrating densitometer and correlated with a Redlich-Kister polynomial. A negative excess volume prevailed over the whole concentration range, which indicates a favorable attraction between toluene and cresol isomers and results in an extensive miscibility.

• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.460-467
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• 2006

Adsorption experiments for $H_2$, $CO_2$, CO, and their binary mixtures on zeolite 5A were performed by static volumetric method. Experimental data were obtained at temperatures of 293.15, 303.15 and 313.15 K and at pressures to 25 atm. The parameters obtained from single component adsorption isotherm. Multicomponent adsorption equilibria could be predicted and compared with experimental data. Langmuir isotherm, Langmuir-Freundlich isotherm and Dual-Site Langmuir isotherm be used to predict the experimental results for binary adsorption equilibria of $CO_2/CO$ and $H_2/CO_2$ on zeolite 5A. Dual-Site Langmuir isotherm showed the best agreement with the experimental results.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.893-900
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• 1997

In this study, vapor-liquid equilibria of a binary system, which consists of glycerol and water, are measured using a vaporrecirculating modified Othmer still at various subatmospheric pressures. The constituent components of the binary system considered in this study exhibit a large difference in the boiling temperatures. Since it is generally observed that the properties of a mixture greatly differ from those of the pure components, the phase equilibrium characteristics of a mixture can not be predicted from the properties of the pure components. Furthermore, an abrupt increase in the boiling temperature occurs as the concentration of the higher boiling component exceeds a certain value. Therefore, it is essential to acquire realistic phase equilibrium data of the mixture for industrial applications. Using the UNIQUAC model, the experimental vapor-liquid equilibrium data are correlated with good accuracy. The thermodynamic consistency test is also performed to ensure soundness of the data.

• Applied Chemistry for Engineering
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• v.21 no.3
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• pp.295-300
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• 2010

A binary system of 1-propanol and bromochloromethane which exhibits an azeotropic point and a considerable nonideal phase behavior probably due to the large boiling point difference is not amenable in the actual chemical processes such as the distillation tower and absorber. Therefore, experimental data of phase behavior data of this mixture are indispensable in understanding the inherent thermodynamic characteristics for an efficient application of the system in the industrial processes. In this work, the isobaric vapor-liquid equilibrium of a binary mixture consisting of 1-propanol and bromochloromethane was measured by using a recirculating equilibrium cell at various pressures ranging from 30 to 70 kPa. The measured VLE data were correlated in a satisfactory manner by using the UNIQUAC and NRTL models along with the thermodynamic consistency test based on Gibbs/Duhem equation. In addition, the excess molar volume of the mixture was also measured by using a vibrating densitometer and correlated with a Redlich-Kister polynomial.

• The Journal of Engineering Geology
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• v.17 no.3
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• pp.381-391
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• 2007

A series of talus slope stability analyses were carried out using 2D FEM and 3D limit equilibrium methods for this study. The FEM analyses on Phase 2 were performed to delineate failure depths based on stress distributions for each slope. The results revealed that the failure surface exist in the colluvium layer of about 3-10 m thickness. Three dimensional models, derived from the FEM analyses and geological field survey, were made for the use in a 3D limit equilibrium analysis. The result shows that all the talus slopes are stable under dry condition, but unstable under saturated condition due to heavy rain.

• Korean Journal of Food Science and Technology
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• v.40 no.1
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• pp.111-114
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• 2008

Adsorption isotherm with the most fundamental information related to chromatography process is obtained experimentally. The adsorption isotherm of 2-deoxyuridine (dUrd) and 2-deoxycytidine (dCyd) with ${\mu}$-Bondapak $C_{18}$, static method was adopted in RP-HPLC. The concentrations of mobile and stationary phases were measured with different initial concentrations of dUrd and dCyd, 1, 3, 5, 7, 10 mg/mL, respectively. The adsorption isotherm data were applied by Freundlich, Langmuir, Sips, and Radke-Prausnitz model equations. As a result of the regression analysis, standard error between adsorption isotherm of dUrd and Radke-Prausnitz equation was very low, and adsorption isotherm of dCyd was in an agreement with Sips equation very well.

• Journal of the Korean Chemical Society
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• v.62 no.4
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• pp.279-287
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• 2018

In this study, we analyzed the explanations and examples of Brønsted-Lowry model in Chemistry I and Chemistry II textbooks of the 2009 revised curriculum. In particular, the definition of the Brønsted-Lowry model, the examples, and the content of experiments were analyzed by the process perspective of chemical equilibrium, emergent process. The analyzed textbooks were 4 kinds of Chemistry I textbooks and 4 kinds of Chemistry II textbooks in 2009 revision curriculum. As a result, Chemical I textbooks did not adequately show the chemical equilibrium viewpoint when explaining the Brønsted-Lowry model. In the Chemistry II textbooks, the examples of Brønsted-Lowry model were not present emergent process viewpoint, and those were described as sequential viewpoint of Arrhenius model. In addition, examples of experiments to demonstrate the Brønsted-Lowry model of Chemistry II textbooks were insufficient. The experimental examples related to the definition of acid bases were at the level of classification by the color change of indicators. The experimental examples for explaining the strength of acid and base were to compare current intensity or amount of hydrogen gas generated from the reaction with metal. In addition, all textbooks presented the state of aqueous solution when describing the Brønsted-Lowry model, causing problems with differentiation from the Arrhenius model. Therefore, it is necessary to develop examples of experiments to help students understand Brønsted-Lowry model by presenting acid and base reaction in the non-aqueous solution state.

• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.477-482
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• 2015

This study examined the adsorption characteristics of heavy metal ions ($Cr^{6+}$, $As^{3+}$) in an aqueous solution using recycled aggregate (RA) and recycled aggregate (RA)/steel slag (SS) composites. The RA and SS are favorable for the absorbent because it contains about 91% and 86.9%, respectively, which are some of the major adsorbent ingredients (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$) for heavy metal. Kinetic equilibrium of $Cr^{6+}$ and $As^{3+}$ in RA and RA/SS composites reached within 180 min and 360 min, respectively. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Freundlich model and showed the affinity order of $As^{3+}$ > $Cr^{6+}$. The results of $As^{3+}$ also showed that the adsorption capacity slightly increased with increasing pH from 6 to 10. Meanwhile, the adsorption capacity of $Cr^{6+}$ was slightly decreased. From these results, it was concluded that the RA and RA/SS composites can be successfully used for removing the heavy metals ($Cr^{6+}$ and $As^{3+}$) from aqueous solutions.