• Title/Summary/Keyword: 팽창형

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A Study on Glasses and Glass-Ceramics as Sealing Materials for Flat-Plate Solid Oxide Fuel Cell Components (평판형 고체산화물 연료전기 구성층의 봉착을 위한 유리 및 결정화 유리질 봉착재의 제조에 관한 연구)

  • 이경호
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.151-162
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    • 1998
  • ZnO-BaO-$SiO_2-Al_2O_3$계 유리 및 결정화 유리 시편들을 제조하여 평판형 고체산화물 연료전지 봉착재로의 이용가능성을 조사하였다 구성층과 일치되는 열팽창 계수 및 화학적 안정성을 봉착재로의 적용에 있어 판단 기준으로 정하였다 실험된 다양한 조성의 유리 및 결정화 유리 시편들중 7.79ZnO-58.52BaO-$28.69SiO_2-5Al_2O_3$(ZBS3-A5) 결정화 유리의 측정된 열팽창 계수값은 $11.02\times10^{-6/^{\circ}C}$로써 YSZ 및 LSC의 평균 열팽창 계수 값과의 차이가 $0.07\timestimes10^{-6/^{\circ}C}$로 매우 작아 봉착시 열응력 발생의 최소화를 기대할수 있었다 이런 ZBS3-A5+LSC 접합 couple의 경우는 ZnCr2O4 의 dis-crete한 입자가 결정화 유리 부위에 형성되었고 역시 시간의 증가에 따라 이러한 입자의 성장은 없었다 특히 ZBS3-A5 구성 성분인 Ba, Zn, Sil 그리고 Al의 YSZ 및 LSC로의 확산은 없어 봉착후에 YSZ 및 LSC의 전기적 특성에 악영향을 미치지 않으리라 판단되었다.

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Mechanical Properties of Early Strength Mortar with Ground Granulated Blast Furnace Slag and Expansive Additive (고로슬래그미분말 및 팽창재를 혼입한 조강형 모르타르의 역학적 특성)

  • Koo, Kyung-Mo;Choi, Jae-Won;You, Byeong-Know;Cha, Wan-Ho;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.177-184
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    • 2021
  • In this study, the effects of ground granulated blast furnace slag(GGBFS) and expansive additive(EA) on early strength mortar were examined for the purpose of reducing carbon and improving cement performance. As a result, ealry strength Portland cement(EPC) tended to decrease in flow compared to ordinary Portland cement(OPC), but binder with EPC and GGBFS was possible to obtain higher liquidity than OPC. EPC showed higher compressive strength and shrinkage than OPC. The compressive strength of specimen with EPC and GGBFS was reduced proportionally to the replacement ratio of GGBFS. The replacement ratio of GGBFS above the compressive strength equivalent to OPC was higher under low temperature conditions. The use of GGBFS resulted in high shrinkage compared to OPC, and this characteristic was even greater under low temperature conditions. The shrinkage of specimen with EA was decreased in early ages, but was higher than the OPC in long-term ages.

An Experimental Study on the Durability of Concrete adding MgO-Type Expansive Agent (MgO를 혼합한 콘크리트의 내구특성 평가에 관한 실험적 연구)

  • Kim, Tae-Sang;Jang, Bong-Seok;Jung, Sang-Hwa;Kim, Joo-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.397-400
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    • 2008
  • MgO powder-mixed concrete, expanded at the lower temperature around $850{\sim}1000$ degree celcius, might have long-term expansibility, which could remunerate for the contraction of concrete with delayed expansion, and through the process, the crack resistance of mass concrete might be improved. Currently used expandable concrete additive has three different types : CSA, CaO and MgO. In this study, therefore, such tests as carbonation, chloride diffusivity, freezing-thawing resistance and sulfate resistance after 56 days' curing were implemented and compared the results with the concrete with no MgO mixed to evaluate the durability of 5% MgO-mixed concrete after longer period of time. The degree of hydration for the MgO-mixed cement paste was analyzed after 1 day, 3 days, 7 days, 28 days, and 56 days using SEM, XRD, DSC.

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Analysis of Crack characteristic on Concrete Cover for Subway Box Structure Due to Reinforcement Corrosion (철근부식으로 인한 지하철 박스구조물의 콘크리트 피복층 균열특성 분석)

  • Choi, Jung-Youl;Shin, Dong-Sub;Chung, Jee-Seung
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.6
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    • pp.727-732
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    • 2022
  • Applying the calculated cross-sectional reduction due to the corroded rebar investigated in the field to the numerical analysis model, the damage pattern and delamination of concrete in the field showed a tendency relatively similar to the numerical analysis results. It was analyzed that when the expansion pressure due to corrosion of the reinforcing bar is greater than the tensile stress of the concrete, cracks are generated and the concrete cover can be fracture. As a result of this study, the correlation between the corrosion rate of reinforcing bars and the crack occurrence of the concrete cover of the subway box structure was verified based on the numerical analysis and field test results. To prevent rebar corrosion, the corrosion rate can be reduced by applying rust prevention to the reinforcing bar and changing the material. In the case of exposed to a corrosive environment, the tensile strength of the concrete is improved by adjusting the concrete compressive strength to secure durability against the expansion pressure caused by the corroded rebar.

Analysis of Weathering Sensitivity by Swelling of Domestic Highway Sites (국내 고속도로현장의 스웰링에 의한 풍화민감도 분석)

  • Jang, Seokmyung;Han, Heuisoo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.3
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    • pp.15-22
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    • 2022
  • This study aims to observe the swelling representative rocks in Korea and to suggest improvements in the use of test methods and prior analysis in relation to the weathering of rocks. The swelling test and analysis were performed on the drilling cores obtained for the ground investigation at the domestic highway construction site. For the method of determining the absorption expansion index of rocks, the method proposed in "Standard Methods for Sample Collection and Specimen Preparation" of ISRM and Korean Rock Engineers Standard Rock Test Method was used. The specimen for the measurement of the expansion displacement was cylindrical with a height of 10 cm and a diameter of 5 cm. The existing swelling analysis method evaluates the sensitivity to weathering by using the maximum expansion displacement, but since the classification by bedrock grade is unclear, it is reasonable to use the rate of change of the expansion displacement according to the immersion time. It is necessary to conduct an experiment to distinguish between weathering and fault deterioration. In addition, long-term weathering prediction technology for each cancer type is needed through the expansion displacement analysis of the chemical weathering stage.

Sulphate Effects on Lime and Chemical Additives Stabilized Soils (생석회와 화학 첨가제 혼합토에 대한 황산염의 영향)

  • 민덕기;황광모;정진형
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.31-38
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    • 2003
  • It has been recently reported that the presence of sulphate causes abnormal volume changes in lime-stabilized soils. Volume changes in lime-stabilized soils can take place due to sulphate compounds such as ettringite. Sulphate compounds caused a variety of serious geotechnical hazards such as swelling pressure and damages to light structures and pavements. This paper discusses the influence of sulphate on the soil specimens treated with quicklime and chemical additives. The physical and mechanical characteristics were studied by means of laboratory tests. The results showed that the presence of sulphate treated soil reduced the shear strength of the lime treated soils and increased the swelling properties. SEM and XRD results indicated that the presence of sulphate producted needle-like crystals such as ettringite. Moreover, the role of needle-like crystals in specimen was probably related to the swelling properties.

Influence of Water-Binder Ratio and Expansion Admixture on Mechanical Properties of Strain-Hardening Cement-Based Composite with Hybrid Steel and Polyethylene Fibers (강섬유와 폴리에틸렌 섬유를 함께 혼입한 SHCC의 물결합재비와 팽창재 치환유무에 따른 역학적 특성)

  • Kim, Sung-Ho;Lee, Young-Oh;Kim, Hee-Jong;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.233-240
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    • 2012
  • Hybrid SHCC is being researched actively for its excellent performance in controlling macro and micro cracks using macro and micro fibers, respectively. However, a significant autogenous shrinkage of SHCC is expected since it possesses high unit cement volume in its mix proportion, resulting in autogenous shrinkage cracks. Therefore, this study was performed to evaluate mechanical property of shrinkage-reducing type hybrid SHCC mixed together with steel fiber and PE fiber with excellent micro/macro crack controlling performance. In order to evaluate mechanical property of shrinkage-reducing type hybrid SHCC, replacement ratios of 0% and 10% of expansive admixture and water to binder ratios of 0.45, 0.3, and 0.2 were considered as variables. Then, shrinkage, compressive, flexural, and direct tensile tests were performed. The test results showed that mix proportion with W/B 0.3 significantly improved mechanical performance by using 10% replacement of expansive admixture.

Rotor Leading Edge Thickness Effect on Supersonic Impulse Turbine Performance (초음속 충동형 터빈의 로터 앞전 두께가 성능 변화에 미치는 영향)

  • Lee, Hang-Gi;Jung, Eun-Hwan;Park, Pyun-Gu;Kim, Jin-Han
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.4
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    • pp.41-47
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    • 2011
  • Turbopump, which is a part of 75 ton open cycle liquid rocket engine has a super sonic impulse turbine. This paper investigated the leading edge thickness effect on the turbine performance experimently. Two rotors were tested with the different leading edge thickness. The ratios (rotor thickness to Pitch) are 1.9 and 1.4 times to 30 ton turbine rotor. As a result, a rotor with 1.4 times ratio had a 1.5% higher efficiency gain than a rotor with 1.9 times ratio. The pressure ratio with the maximum efficiency on the same rotational speed was increased to the full expansion ratio of nozzle.

Thrust modulation performance analysis of pintle-nozzle motor (핀틀 노즐형 로켓 모타의 추력 조절 성능에 관한 연구)

  • Kim, Joung-Keun;Park, Jong-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.4
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    • pp.392-398
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    • 2009
  • Theoretical thrust equations for the diverse nozzle expansion condition were derived. By using the obtained thrust equations, parametric studies were carried out to estimate the effect of pressure exponent, minimum operation pressure, ambient pressure and extinguishment pressure on thrust modulation performance in pintle-nozzle solid rocket motors. Analysis results showed that thrust turndown ratio can be easily attained by small nozzle-throat area variation at high pressure exponent, low minimum operation pressure, high ambient pressure and high extinguishment pressure condition. At those conditions, the highest chamber pressure to obtain the intended thrust turndown ratio can be minimized.