• Title/Summary/Keyword: 팽창성

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Flame Retardancy and Foaming Properties of the NBR/Ground Tire Rubber Foams Containing Expandable Graphite (팽창 흑연을 포함한 NBR/GTR 발포체의 난연 및 발포특성)

  • Moon Sung-Chul;Choi Jae-Kon;Jo Byung-Wook
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.412-425
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    • 2004
  • The influence of expandable graphite (EG) on flame retardancy and foaming properties of the NBR/GTR foams was studied. The foaming properties were similar to those of NBR/GTR foams without EG when the EG contents were 10$\~$30 phr. The LOI values were increased with the EG content. For cone-calorimeter test, the data showed the trend similar to that from experiment. When the composition ratios of the compounds of NBR/GTR were 100$\~$0/80$\~$20 (w/w), and the EG contents were 10$\~$30 phr, we obtained high flame retardancy foams with low heat release rate (HRR), total heat release (THR), effective heat of combustion (EHC) and carbon monoxide yield (COY). The smoke density is similar to CO yield values obtained by the cone-calorimeter test. TGA analysis also showed the results approximately similar to those from the LOI and cone-calorimeter experiments.

Waterproofing performance evaluation according to the number of layer for shield TBM segment hydrophilic rubber waterstop (쉴드 TBM 세그먼트 지수재의 배열수 변화에 따른 방수성능 평가)

  • Ham, Soo-Kwon;Jung, Hoon;Kim, Beom-Ju;Jeong, Kyeong-han;Lee, Seok-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.1
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    • pp.47-58
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    • 2020
  • The interest in the use of shield TBM (Tunnel Boring Machine) on the tunnel excavation has been increased rapidly in Korea. The shield TBM tunnel is generally designed as non-drainage tunnel. Consequently, if water leakage through the segment joints happens, big problems on the usage and stability of tunnel can be occurred. In this study, the variation of waterproof capacity of hydrophilic rubber waterstop by the construction error and excessive displacement of segment was studied. In particular, the waterproof capacity of each of single and double layer arrangements of hydrophilic rubber waterstop was examined to verify the efficiency of the double layer arrangement. The test results show that the single layer and double layer hydrophilic rubber waterstop showed the same waterproof performance. hydrophilic rubber waterstop has favorable on the offset, however unfavorable on the gap.

실린더 후부 유동장 모사를 위한 난류 모형 비교

  • 김성훈;정명균
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.10a
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    • pp.38-38
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    • 1998
  • 원기둥을 지나는 초음속 유동장은 재순환, 재접합, 유동 박리, 팽창파동이 발생하는 복잡한 유동장이며, 비행체의 성능개선을 위해서 이해되어야 한다. 난류 에너지를 지배하는 방정식에는 압축성 유동장의 경우 압력 팽창항, 팽창 소산항, Favre 속도에 의한 영향 등의 수정항이 첨가되어야 한다는 연구 결과가 나오고 있다 본 연구에서는 밀도변화에 따른 영향이 적은 것으로 알려진 k-$\omega$ 보형에 압축성에 대한 수정항을 첨가하여 유동장을 모사하여 비교하였다. 수정항의 첨가로 인하여 나온 결과를 얻을 것으로 예측되었으나 k-$\omega$ 모형에 수정을 가한 경우 수정하지 않을 경우에 비해 좋지 않은 예측을 하는 결과가 나왔다. 이는 압축성 난류 유동을 위한 수정항의 사용이 기지부 근처의 유동을 모사하기에는 부적합함을 보이며, 압축성 난류 유동에 대해서 보다 근본적인 이해가 필요함을 보여주고 있다

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The Ground Resistance Reduction Effect of o Conductive Expansion Ground Resistance Reducing Material (도전성 팽창 접지저감재의 접지저항 저감 효과)

  • Kim, Jong-Wook;Kim, Kyung-Chul;Choi, Jong-Kee;Kang, Min-Gyu;Baek, Nam-Woong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.2
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    • pp.155-161
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    • 2008
  • The grounding systems provide a low resistance path for fault or normal currents into the earth. The material for reducing ground resistance is buried around the grounding electrode to increase its effective size of the electrode and thus to obtain low ground resistance. Increasing the contacting area with the grounding electrode is effective for lowering the ground resistance in soils. Using this idea the conductive expansion ground resistance reducing material was developed. In this paper experimental data has shown that the ground resistance reduction method using proposed material is superior to using a typically available commercial ground resistance reducing material.

Effect of a Hydrothermal Reaction on the Expandibility, Layer Charge, and CEC of Smectite Clay (스멕타이트 점토의 팽창도, 층전하, 양이온 교환능에 대한 열수반응의 영향)

  • Lee, Jae-Owan;Cho, Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.3
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    • pp.173-179
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    • 2010
  • In a HLW repository, the buffer is exposed to an elevated temperature due to a radioactive decay and geochemical conditions for a long time and such a hydrothermal condition may cause a significant loss of its barrier function. This study carried out hydrothermal tests with a domestic smectite clay to investigate the changes in the expandibility, layer charge, and cation exchange capacity of the smectite. When the temperature and potassium concentration in solution was increased for the hydrothermal treatments, the expandibility decreased, the layer charge negatively increased, and the CEC also decreased.

Reforming of Expanded Graphite for Improving Fire Resistance of Fireproof Sealant (방화용 실란트의 내화성 향상을 위한 첨가제로서 팽창흑연의 개질)

  • Hong, In Kwon;Lee, Won Jae;Lim, Hyun Seok;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.437-441
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    • 2017
  • This study was carried out to investigate the volumetric expansion ratio and hardness of expanded graphite after coating with various resins which were used as an additive of fireproof sealant. The coating thickness of the resin, which represents the coating rate, was dependent of the drying speed of the resin and the viscosity of the resin. Therefore the coating thickness was shown as follows: polyvinyl acetate > acrylic resin > urethane resin > water soluble latex. Furthermore, the volumetric expansion ratio was as follows: urethane resin > water soluble latex > acrylic resin > polyinyl acetate and the hardness was as follows: polyvinyl acetate resin > acrylic resin > water soluble latex > urethane resin. This showed that the volume of expansion was reduced by expansion, which was not covered by coating, but significantly increased by increasing hardness and allowed it to be used as a refractory addition. According to the response surface methodology, the optimized addition amount and stirring speed of acrylic resin were 37.6 wt% and 441.4 rpm, respectively.

Evaluation of Crack Resistant Performance in Cement Mortar with Steel Fiber and CSA Expansion Admixture (CSA 팽창재를 혼입한 강섬유 보강 모르타르의 균열 저항성능 평가)

  • Ahn, Jung-Kil;Park, Ki-Tae;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.125-132
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    • 2014
  • Steel fiber is a effective composite for crack resistance and improve structural performance under tensile loading. This study presents an evaluation of crack resistance and structural performance in cement mortar with steel fiber and expansion agent through internal chemical prestressing. For this work, cement mortar samples with 10% replacement of cement binder with CSA (Calcium-Sulfo-Aluminate) expansion agent and 1% volume ratio of steel fiber are prepared. Including basic mechanical properties, initial cracking load and fracture energy are evaluated in cement mortar beam with notch. Initial cracking load and fracture energy in cement mortar with CSA and steel fiber increase by 1.75 and 1.41~1.53 times compared with those in cement mortar with steel fiber. With optimum mix design for steel fiber and CSA expansive agent, the composite with chemical prestressing can be applied to various members and effectively improve crack resistance to external loading.

Utilization of Electric Arc furnace Slag md Converter Slag after Aging for Concrete Aggregate (콘크리트용 골재로서 에이징처리한 제강슬래그외 활용)

  • 문한영;유정훈
    • Journal of the Korea Concrete Institute
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    • v.14 no.4
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    • pp.597-607
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    • 2002
  • Electric arc furnace and converter slag are produced by about 6 millions tons in Korea at 2000 year. But compared with blast furnace slag, those are utilized only in unvalued material like landfill and road construction. There are unstable materials, like free CaO, in electric arc furnace and converter slag at steel-manufacturing process. This might cause volume expansion in concrete, if electric arc furnace and converter slag aggregates were used in concrete. This expansion may reach to crack or collapse of concrete. It is therefore settled by standard specification for concrete that electric arc furnace and converter slag aggregates have not to use in concrete. First of all, volume stability and stabilized process should be solved in electric arc furnace and converter slag aggregate to use in concrete. In this study, 6 types of aging are evaluated for effects of stabilization to reduce the expansion of electric arc furnace and converter slag. h converter slag aggregate, these types of aging are not good for volume stability for concrete aggregate, and even if converter slag aggregate is treated with aging, concrete with it has some problems that strength is reduced with curing days. But in electric arc furnace slag aggregate treated with hotwater and steam aging, the expansion of electric arc furnace slag aggregate is reduced about two times than that of converter slag aggregate, and electric arc furnace slag aggregate concrete has good results in strength compared with control concrete using crushed stone.

A Study on the Chloride Migration Properties of High Durable Marine Concrete Using the Expansion Production Admixture (팽창재를 혼입한 고내구성 해양콘크리트의 염화물 확산특성에 관한 연구)

  • Kim, Kyoung-Min;Ryu, Dong-Woo;Park, Sang-Joon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.697-700
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    • 2008
  • Recently, high strength, flowability, and durability of concrete were required according to increase of large scale and high rise structure. However, cracks occurred easily on the high performance concrete. In this reason, using expansion agent for reducing shrinkage cracks were increased, but it did not consider on durability of high performance concrete. Accordingly, this study1 investigated the resistance of shrinkage and damage form salt by mixing CSA expansion agent on the blast-furnace slag cement and mixed cement for the low heat of hydration by three components. The cases that 8% of expansion agent was mixed and the proportion was OPC were expanded till 43.7 times compared with control concrete. For the resistance to the damage of salt, it was improved when mixing ratio was incresed and the maximum size of coarse aggregate growed bigger. In this study, the resistance to the damage of salt of the cases that 8% of expansion agent was mixed was improved about 16% compared with control concrete.

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Study on expandability and X-ray coherent scattering domain size of bentonite from Gampo and Yonil area, Korea (감포와 연일 지역 벤토나이트의 팽창성 및 X-선 부합성 산란영역 크기에 관한 연구)

  • 강일모;박석찬;문희수;유장한
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.1-8
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    • 2003
  • This study was performed to measure expandabilities and coherent scattering domain sizes (CSDs) of bentonite samples from Campo and Yonil area, Korea, using X-ray powder diffraction (XRD), and to compare their experimental data with those of international standard bentonite samples (SAz-1, STx-1, and SWy-2). Most of Gampo and Yonil bentonite samples comprised randomly interstratified illite-smectite (R0 I-S), and their expandabilities ranged over 77-100%S$_{XRD}$ from the saddle/001 method. The interstratification deformed 001 peaks of EG-solvated samples (Mering's first principle), which prohibited us from adopting these peaks to measure CSDs using BWA (Bertaut-Warren-Averbach) method. CSDs of the bentonite samples with R0 I-S could be measured through dehydration at 30$0^{\circ}C$ after K-saturation, where the deformation originated from the interstratification could be removed effectively. Campo and Yonil bentonite samples showed that their mean CSDs ranged over 3.8-5.4 interlayers, and that their CSDs distributions were similar to those of Gonzales (STx-1) and Wyoming (SWy-2) bentonite samples.