• Journal of the Mineralogical Society of Korea
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• v.15 no.4
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• pp.305-314
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• 2002

The dehydration of hexadecyltrimethylammonium (HDTMA)-exchanged montmorillonite has been studied using X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The dehydration in HDTMA-montmorillonite seems to influence the swelling behavior of the organo-clay during heating. The basal d(001) spacing vs temperature curve of the HDTMA-montmorillonite has one broad swelling edge with a shoulder on the low-temperature side. We believe that the shoulder at $100^{\circ}C$ for the HDTMA-montmorillonite is due to interlayer swelling induced by the initial rearrangement of surfactants, and the second edge at $200^{\circ}C$ is caused by interlayer swelling resulting from the secondary vertical reorientation of alkyl chains. It seems that the dehydration of organo-clay induces a reorientation of the alkyl chains by transition to more vertical position relative to the silicate sheets, allowing instantly greater d-spacing.

• Journal of the Korean Society for Railway
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• v.13 no.2
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• pp.147-151
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• 2010

Since the kinetic energy is dissipated through plastic deformation energy generated in expanding process of the tube by a die. In order to successfully absorb the kinetic energy there should be no buckling in the expansion tube during expanding process. The buckling instability of the expansion tubes is affected by the initial boundary conditions, tube thickness and length. In this study, the effects of the tube thickness except length and initial boundary condition on the buckling instability are studied using a finite element method. In addition, Analysis procedure for nonlinear post-buckling analysis of expansion tube is established. There are three kinds of finite element analysis procedures for buckling analysis of expansion tube, quasi-static analysis, linear buckling analysis and nonlinear post-buckling analysis. The effect of the geometry imperfections defined as linear superimposition of buckling modes is considered in the nonlinear post-buckling analysis. The results of finite element analysis indicate that the buckling load increase with increase of thickness of tube and geometry imperfection. Finial buckling shapes are changed with respect to the geometry imperfection.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.223-231
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• 1998

Existing cast in place piles made by grouting cement mortar have many problems that cracks by autogeneous and drying shrinkage bring about the deterioration of force for piles, segregations by the submersion of ground water occur and also, high cement contents lead to rise the manufacturing cost. Therefore, this study is intended to investigate the mechanical properties of high performance mortar, incorporating expansive additives and fly ash. for cast in place piles. According to the experimental results, as the contents of expansive additives increase in mortar mixture, fluidity decrease and air contents shows inverse tendency. Setting time is delayed. Although compressive strength at 7days shows a decline tendency. compressive strength at 28days and 91days increase slightly with 5% of expansive additives. As fly ash increase in mortar mixture, high fluidity is shown, air contents increase and setting time is delayed at fresh state, and additives are, the larger length change is, whereas shrinkage decrease with the increase of fly ash.

• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1090-1097
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• 1998

Lidocaine compounds have widely been used as local anesthetics. Regarding the molecular mechanism for anesthesia by lidocaine, it is proposed that lidocaine molecules penetrate to the hydrophobic region of cell membrane and expand the membrane volume, producing a change in protein conformation that blocks sodium permeability or lidocaine molecules directly adsorb into lidocaine receptor in the protein channel without expanding the cell membrane. But these proposals have never been proven experimentally. In this study, the expansion of cell membrane by lidocaine compounds was investigated by employing lipid monolayer at the air/water interface as the mimetic system of cell membrane. It was found that oil-soluble lidocaine contracted the area/molecule of lipid in the monolayer of phosphatidyl choline, sphingomyelin, DS-PL95E and lipoid, but expanded the monolayer of phosphatidyl ethanolamine only in a certain range of mixing ratios. On the contrary, water-soluble lidocaine-HCl salt expanded the monolayers of all lipids used in this study.

• Elastomers and Composites
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• v.42 no.4
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• pp.201-208
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• 2007

In this study, the thermal shrinkage and expansion stresses of filled NR and SBR vulcanizates were measured to investigate the dimensional stability at an elevated temperature. When a rubber sample was held at constant pre-strain, a thermal stress developed upon heating due to the entropic consideration. The peak shrinkage stress of carbon black or silica filled NR decreased with increasing filler content. In SBR compounds, however, the peak shrinkage stress of SBR with 30 phr filler content was higher than that of unfilled compounds. The expansion stress of carbon black filled NR was changed little, but that of filled SBR increased with increasing the filler content. The peak expansion stress of silica filled NR and SBR vulcanizates increased with increasing silica content.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.2
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• pp.299-305
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• 2016

The High Temperature Superconducting power cables (HTS power cables) become increasingly longer to commercialize the HTS power cable system. Accordingly, demands on refrigerators of large cooling capacity per a unit system have been increased. In Korea, it is currently imported from abroad with the high price due to insufficient domestic technologies. In order to commercialize the HTS power cables, it is necessary to develop the refrigerators with large cooling capacity. The Brayton refrigerators are composed of recuperative heat exchangers, compressors and cryogenic turbo expanders. The most directly considering the efficiency of the Brayton refrigerator, it depends on performance of the cryogenic turbo expander. Rotating at high speed in cryogenic temperature, the cryogenic turbo expanders lower temperature by expanding high pressure of a helium or neon gas. In this paper, the reverse Brayton cycle is designed and the cryogenic turbo expander is designed in accordance with the thermodynamic cycle.

• Journal of the Korean Society of Propulsion Engineers
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• v.4 no.3
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• pp.11-18
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• 2000

When supersonic underexpanded jets are exhausted from the nozzle, complex shock cell configurations such as barrel shock, expansion fan, Mach disc, and exhaust-gas jet boundary are appeared repetitively. The shock cell is smeared by turbulence dissipation and disappeared in long distance from the nozzle. When underexpanded jet is suddenly impinged on a flat plate, it forms very complex flow structure. In this paper, we solve compressible Wavier-Stokes equation adapting finite volume method to obtain jet impingement flow structure and compare calculated data with experimental ones. It is shown that numerical simulation data are in good agreement with experimental one in a short distance between nozzle exit and flat plate and little influence of underexpanded ratio is appeared in jet impingement now distribution.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4A
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• pp.787-794
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• 2006

Generally, high performance concrete has characteristics such as low water-cementitious material ratio, lots of unit binder powder, thus the heat of hydration, autogenous shrinkage are tend to be increased. This study is to investigated the effect of the expansive additive and shrinkage reducing agent on the shrinkage properties of high performance concrete as a study to develop the reduction technology of the concrete shrinkage. Test results showed that the expansive additive and shrinkage reducing agent were effective the reduction of shrinkage of high performance concrete. Especially, the using method in combination with expansive additive and shrinkage reducing agent was more effective than the separately using method of that. Also, it analyzed that the combination of expansive additive of 5% and shrinkage reducing agent of 1% was the most suitable mixture, considering to the fluidity, strength and shrinkage properties.

• Korean Journal of Agricultural Science
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• v.24 no.2
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• pp.194-206
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• 1997

This paper was performed to evaluate the properties of no-coarse lightweight concrete using perlite and expanded polystyrene bead on fine aggregate. The results were shown that w/c and unit weight was affected by absorption ratio and unit weight of using aggregate itself. The compressive strength of no-coarse lightweight concrete was showed $187kgf/cm^2$ by using natural sand, $170kgf/cm^2$ by using perlite. Tensile and bending strength were showed the same tendency of compressive strength, but when expanded polystyrene bead concrete dose not have strength nearly. The pulse velocity and static modulus of elasticity of no-coarse lightweight concrete were smaller than that of normal cement concrete. And stress-strain curves were shown that was increased with increase of stress, and when the stress-strain curve using expanded polystyrene bead was repeated at short intervals increase and decrease irregularly.

• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.851-863
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• 2002

Corrosion products of reinforcement in concrete induce pressure to the adjacent concrete due to the expansion of steel. This expansion causes tensile stresses around the reinforcing bar and eventually induces cracking through the concrete cover The cracking of concrete cover will adversely affect the safety as well as the service life of concrete structures. The purpose of the this study is to examine the critical corrosion amount which causes the cracking of concrete cover. To this end, a comprehensive experimental and theoretical study has been conducted. Major test variables include concrete strength and cover thickness. The strains at the surface of concrete cover have been measured according to the amount of steel corrosion. The corrosion products which penetrate into the pores and cracks around the steel bar have been considered in the calculation of expansive pressure due to steel corrosion. The present study indicates that the critical amount of corrosion, which causes the initiation of cracking, increases with an increase of compressive strength. A realistic relation between the expansive pressure and average strain of corrosion product layer in the corrosion region has been derived and the representative stiffness of corrosion layer was determined. A concept of pressure-free strain of corrosion product layer was introduced to explain the relation between the expansive pressure and corrosion strain. The proposed theory agrees well with experimental data and may be a good base for the realistic durability design of concrete structures.