• Title/Summary/Keyword: 패기물

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모의 고준위 방사성 폐액의 침전여액으로부터 옥살산 제거

  • 김영환;김응호;유재형
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.283-288
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    • 1997
  • 고 준위 방사성 액체 패기물의 옥살산 침전 공정을 통하여 침전여액이 발생된다. 이 침전여액에는 옥살산과 같은 유기 물질이 함유되어 있으며 이 물질의 제거는 방사성 폐기물의 긍극적인 처리 처분에 대단히 중요하다 본 연구는 모의 침전여액을 제조하고 이로부터 옥살산 제거 연구가 두 가지 방법으로 수행되었다. 첫째 과산화수소를 이용한 제거 법으로서 침전여액 내 Ru$^{+4}$ 와 Fe$^{+3}$ 는 과산화수소를 자체 분해시키기 때문에 옥살산 제거를 방해함을 알 수 있었다 둘째는 NaOH를 용액 내 첨가하는 방법으로 pH증가에 따라 침전이 발생되면서 COD는 상당히 감소함을 보여주었다. 침전물은 $Na_2$C$_2$O$_4$로 확인되었고 pH9 이상에서 99%이상 감소함을 보여 주었다.다.

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Waste Treatment technique for the Resources of Marine Debris(I) - Recycling of marine debris for RDF - (수거된 해양패기물 자원화 기술 개발(I) - 해양패기물의 폐기물 연료화 -)

  • Keel Sang-In;Yun Jin-Han;Choi Yeon-Seok;Kang Chang-Gu;Yu Jeong-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.2
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    • pp.28-34
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    • 2002
  • The purpose of this study is the RDF process development for the disposal of marine debris, and physical properties of RDF was analyzed for the reliability as a industrial fuel. By the separation of lead from the waste rope and the pelletizing of burning material, marine debris changes to fuel resources. The resource recycling process is effective in the clean treatment of waste and the secure of substitute energy.

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Thermal Decomposition and Stabilization of the Lagoon Sludge Solid Waste after Dissolution with Water (라군 슬러지 물 용해 후 고체 패기물의 열분해 및 안정화)

  • Oh Jong-Hyeok;Hwang Doo-Seong;Lee Kue-Il;Choi Yun-Dong;Hwang Sung-Tae;Park Jin-Ho;Park So-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.3
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    • pp.249-256
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    • 2005
  • Thermal decomposition and stabilization characteristics of the solid cake after the dissolution of nitrate of the lagoon sludge was investigated. Most of the nitrates were dissolved in the water and removed to the filtrate, but small amount of nitrates, calcium carbonate and uranium were remained in the solid cake. The solid cake was thermally decomposed in the muffle furnace at $900^{\circ}C$ for 5 hours. Uranium, which is in the lagoon 1, was stabilized with $NaNO_3$ decomposition to $Na_{2}O{\cdot}2UO_3$ form. For the lagoon 2, it is confirmed that CaO, which was created by thermal decomposition of the $Ca(NO_3)_2$ and $CaCO_3$, was transferred to $Ca(OH)_2$ in the air with water. Because it is known that $Ca(OH)_2$ is stable material, further additives did not need to the stabilization of the thermal decomposition of the lagoons.

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Investigation on the Structural Changes of Calcium Silicate Hydrates in Nanosilica-incorporated Cement Pastes exposed to Heating using Nuclear Magnetic Resonance Spectroscopy (핵자기 공명을 활용한 가열에 따른 나노실리카 혼입 시멘트 페이스트 내 칼슘실리케이트 수화물 구조 변화 해석)

  • Suh, Heongwon;Li, Pei-Qi;Liu, Jun-Xing;Bae, Sungchul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.151-152
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    • 2020
  • When concrete is exposed to fire, the thermal decomposition of hydrates of Portland cement paste results in critical damage to the concrete structure of a building. Recently, nanosilica arose as the effective nano-additive which can enhance the thermal resistance of the cementitious materials. However, the mechanism of the enhancement was not elucidated specifically. In this study, we investigated the properties of calcium silicate hydrates(C-S-H)of the nanosilica incorporated cement paste after heating to different heating temperatures (200℃, 500℃, and 800℃) by 29Si nuclear magnetic resonance. The results showed that the polymerization of C-S-H of nanosilica incorporated samples was larger than ordinary cement paste after heating to 200℃, and C-S-H formed during heating process to 500℃ due to the pozzolanic reaction during heating process.

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PE 첨가에 의한 방사성폐수지 아스팔트고화체의 특성연구

  • 김태국;손종식;김길정;안섬진;정인하
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.385-390
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    • 1998
  • 방사성 페이온교환수지 아스팔트고화체를 처분장 등지에서 장기간 저장시 안전성 확보를 위하여 물리적 강도가 높고 고화체내에서 방사성핵종의 침출저항성 및 처리시 감용의 효과가 우수한 고화체 연구가 필요하게 되었다. 실험에 사용된 이온교환수지는 입상형 양이온 교환수지를 대상으로 하였으며 고화매질로서는 도로포장용으로 생산되는 직류아스팔트 60/70을 사용하였다. 고화보조제는 방사성 고체패기물 포장시 사용되어 폐기물로 발생되는 페폴리에틸렌(폐PE) 필름을 사용하였다. 실험결과 고화체의 형태안정성은 PE 함유량이 10 wt% 이상일 때 고화체 형태를 그대로 유지할 수 있으며 압축강도는 414 kPa(60 psi) 이상을 나타내었다. 최적의 운전조건은 이온교환수지, PE 함유량이 건조기준으로 각각 30~50 wt%, 10~25 wt% 이며, 고화온도는 170~20$0^{\circ}C$이다. 고화체의 침출특성은 확산 (diffusion) 으로 해석이 가능하며, 유효확산계수(De)는 Cs, Co의 경우 각각 1.621$\times$$10^{-7}$, 1.186$\times$$10^{-9}$ $\textrm{cm}^2$/day로 나타나고, Leachablity index는 각각 11.7, 13.8로 미국 원자력위원회 (NRC)가 요구하는 기준값 6보다 훨씬 높게 나타났다.

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A Study on Development of Eco-revegetation Measures Using Remnant Root-stock of Native Trees(III) (자생수목그루터기를 재활용한 에코녹화공법 개발연구(III))

  • 오구균;안영희;일본명;나경태
    • Korean Journal of Environment and Ecology
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    • v.18 no.1
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    • pp.7-17
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    • 2004
  • The objective of this study was to find eco-revegetation measures recycling remnant root-stock of native species which comes to be disused. The monitoring plot was established in Nov.2001 at Honam University's affliated farm that is located in Wolya-Myeon, Hampyeong-Gun, Jeollanam-Do. The plots were monitored 2 times each in Oct.2002 and Sep.2003. Sprout and survival rate of the root-stock including the effect of trunk length, antiseptic treatment, planting season and number of planted were surveyed. The results of the study were as follows Ten tree species including Zelkova serrata among twenty tree species showed outstanding sprout and survival rate (over 90 percent). The growth rate was better in the longer trunk length root-stocks (35cm) than shorter ones (10cm). There was a difference in the size of the root ball when digging the root-stocks. It showed better condition when the root ball sizes were 3 times wide and 5 times deep of the root-stocks or 5 times wide and 5 times deep. Antiseptic treatment on the cuts of the trunk of root-stocks makes a difference in the growth rate. The survival rate of the root-stock showed highest value (100%) when it was transplanted in late autumn (November). And the next best survival rate was reached when it was in early or late spring (March and May)

A Study on Profitability of Power Plant for Landfill Gas (매립가스 자원화를 위한 가스엔진 발전의 수익성에 관한 연구)

  • Kim, Oh-Woo;Lee, Jeong-Il
    • Korean Business Review
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    • v.19 no.2
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    • pp.69-94
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    • 2006
  • Landfill gas is a mixture of methane and carbon dioxide produced by the bacterial decomposition of organic wastes, and it is considered to produce bad smells and pollute the environment. Economic trials and the developments of landfill gas, as an alternative energy resource, become known at the recent years. Resource development of landfill gas, which is managed by Korea up to now, is for the most part generation using gas engine. Medium BTU and High BTU are considered for the power generation as well. I\10st income of generation using gas engine is selling charge through a power plant. Expecting to manage the power plant for up to 10 years, the analysis based on revenue and expenditure shows when the unit price is 65.2 Won and the operating rate reaches 90%, it is possible to be into the black in 2012 without considering additional financial expense. It was also analyzed that the profit at a unit price of 85 Won under the anticipated rising unit price by the operating rate of 71% is larger than at the operating rate of 90% under limited unit price of 65.2 Won. It means to manage the power plant at a unit price of 65.2 Won and the operating rate must be higher than 90% for economic logicality. If we assume that the operating rate is 90% and it increases the unit price, the unit price must be higher than 85 Won for the management of a power plant. Analysis of changing a unit price, however, might be expected to have a gradual rise of prices. If there is no price rising and additional income related to CDM(Clean Development Mechanism) and emission trading upon Kyoto protocol, the management of a power plant using gas engine will get financial difficulties because of many operating expenses. However, since landfill gas is considered as a worthy energy resource for the guarantee of sustainable development and for the equity between recent generation and future generation, the development of it must be accomplished by the government's additional supporting and efforts under the interest of all stakeholder who are involved.

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Development of the Environmentally Friendly Filling Material for the Underground Cavities using the Rock-dust and an Assessment on Filling and Material Characteristics (석분토를 이용한 지하공동의 친환경적 충전재 개발과 충전 및 재료특성 평가)

  • Ma Sang-Joon;Kim Dong-Min
    • Journal of the Korean Geotechnical Society
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    • v.21 no.9
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    • pp.35-44
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    • 2005
  • Recently, underground cavities such as limestone cavity and abandoned mine give rise to a lot of damage in SOC facilities. But there are many difficult problems such as delay of the working terms and enormous economic losses in finding a new method and changing construction design. In this study, a new filling material for underground cavities was developed using the stone-dust classified as industry waste polluting environment. As a result of test, filling material properties was that a compressive strength was $34{\~}60\;kgf/cm^2$, a change ratio in length was $0.268{\~}0.776\%$ and water absorption was $34.3{\~}46.9\%$. Also as a result of suspended mass test and pH test, it was confirmed that the developed filling material has a characteristic of non-separating in water and it was an environmentally friendly material.

Adiabatic Optical-fiber Tapers for Efficient Light Coupling between Silicon Waveguides and Optical Fibers (실리콘 도파로와 광섬유 사이의 효율적인 광 결합을 위한 아디아바틱 광섬유 테이퍼)

  • Son, Gyeongho;Choi, Jiwon;Jeong, Youngjae;Yu, Kyoungsik
    • Korean Journal of Optics and Photonics
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    • v.31 no.5
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    • pp.213-217
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    • 2020
  • In this study we report a wet-etching-based fabrication method for adiabatic optical-fiber tapers (OFTs), and describe their adiabaticity and HE11 mode evolution at a wavelength of 1550 nm. The profile of the fabricated system satisfies the adiabaticity properties well, and the far-field pattern from the etched OFT shows that the fundamental HE11 mode is maintained without a higher-order mode coupling throughout the tapers. In addition, the measured far-field pattern agrees well with the simulated result. The proposed adiabatic OFTs can be applied to a number of photonic applications, especially fiber-chip packages. Based on the fabricated adiabatic OFT structures, the optical transmission to the inversely tapered silicon waveguide shows large spatial-dimensional tolerances for 1 dB excess loss of ~60 ㎛ (silicon waveguide angle of 1°) and insertion loss of less than 0.4 dB (silicon waveguide angle of 4°), from the numerical simulation. The proposed adiabatic coupler shows the ultrabroadband coupling efficiency over the O- and C-bands.