• Title/Summary/Keyword: 투명성 소재

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폴리머-ZnO 양자점 나노 복합체에 그래핀층을 삽입한 UV 광탐지기의 광전류 향상

  • Yang, Hui-Yeon;Kim, Tae-Hwan;Lee, Jeong-Min;Park, Won-Il
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.428-428
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    • 2012
  • ZnO 나노 구조는 화학적으로 안정하고 큰 엑시톤 에너지를 가지는 성질 때문에 청색 영역에서 작동하는 광전소자의 제작에 대단히 유용하다. ZnO 나노 구조중에서 ZnO 나노 입자는 UV 광탐지기 소자가 작동하는 영역에서 광반응이 매우 민감하여 연구가 많이 진행되고 있다[1]. 그래핀은 높은 전도도, 투명도 및 화학적, 열적 안정성이 뛰어난 독특한 물리적 특성을 가지고 있기 때문에 차세대 전자소자와 광전소자의 우수한 소재로 각광 받고 있다[2,3]. 본 연구에서는 UV 광탐지기에서 뛰어난 특성을 보이는 ZnO 양자점을 포함된 poly-N-vinylcarbazole (PVK) 층에 전기적 특성이 뛰어난 그래핀 층을 삽입하여 UV 광탐지기의 광전류를 향상 시키는 연구를 하였다. PVK 표면에 ZnO 양자점이 붙어서 형성되어 있는 모습과 그래핀 층에 PVK와 ZnO QD가 붙어있는 것을 투사 전자 현미경을 통하여 관찰 하였다. 전류-접압 측정을 하여 암전류와 광전류의 차이가 많이 나는 것을 알 수 있었다. 그래핀 층을 삽입한 광탐지기 소자에서 광전류가 향상되는 것을 알 수 있었다.

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Suppressed Sheet Resistance of Ag Nanostructure Films by O2 Plasma Treatment (O2 플라즈마 처리를 통한 Ag 나노구조체 필름의 면저항 저감)

  • Kim, Wonkyung;Roh, Jong Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.37-41
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    • 2019
  • Sheet resistance reduction in the Ag nanowire (NW) coated films is accomplished with slight improvement of optical properties for the application of transparent conducting electrodes by using $O_2$ plasma treatment. The sheet resistance was optimized after 30 seconds $O_2$ plasma treatment, showing the 27 % of maximum decrease of sheet resistance. It is found that the $O_2$ plasma treatment get rid of the residual organic materials at the junction of Ag NWs. However, the Ag NWs may be also snapped by the excessive $O_2$ plasma treatment can showing the collapses of Ag NWs networks. Furthermore, the optical properties such as optical transmittance and haze were monotonically improved with the $O_2$ plasma treatment time until 90 seconds.

A Survey on the Consumer Packaging Preferences for Mini Pot Flower Plants on Domestic Market in Korea (소형 분화류의 포장재 및 포장용기에 대한 소비자의 기호도 조사)

  • Lee, Sun Yup;Woo, Hyun Jeong;Lee, Youn Suk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.1
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    • pp.47-53
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    • 2017
  • In this study we surveyed the preferences of consumer packaging for mini pot flower plants to improve the flower market application in Korea. The surveys were consisted of the consumers residing in Seoul metropolitan (221), Gyeonsang (70), Jeonla (29), Chungceong (19), Gangwon (7), other provinces (3). A total of 349 eligible respondents (male 173, female 176) were surveyed with a self-administered questionnaire asking on the general characteristics for residents, packaging material, packaging design, type of flower pot, degree of transparency, convenience, consumer's demand for packaging development, a significant point when purchasing the flower pot product. The collected date was analyzed using a chi-square (${\chi}^2$) statistical test in SPSS program. Most residents prefer for mini pot flower plants packed with packaging characteristics of plastic material (56.4%), packaging design of separated type (76.2%), angled type (62.5%), and transparency (48.6%). The other question results showed that major consumer's demand for mini pot flower plants is maintaining the freshness quality and stability structure for them. Transparency of packaging can also affect directly the preferences for purchasing the mini pot flower plants. The packaging structure with a proper shape design may protect the fresh mini pot flower plants from shock or any other damage during distribution. The results of this study help to provide consumer's demand for packaging development and to give the greatest advantages in terms of production and marketability of mini pot flower plants.

Analysis of Research Trend and Development Direction on Domestic and International Noise Barriers (국내외 방음벽 관련 연구동향 분석 및 개발 방향)

  • Ahn, Hosang;Kim, Ilho;Park, Jong-Bin;Lee, Ju Haeng;Kim, Gwang Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.12
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    • pp.847-854
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    • 2012
  • The demand for noise barriers and necessity for the installation are highly growing because residential areas have become diverse and locational priority is changed to consider how to approach highway easily. However, public annoyance to the noise generated from highway is continued despite lots of noise barrier are installed. Moreover, there are growing concerns to maintain noise barriers to be free from losing transparency, dust stack, and shock fracture. To resolve these issues, it is suggested to develop new polymer materials and conceptually new noise barrier. In this study, as a first step to develop a new noise barrier to overcome current technological challenges as well as economic issues, recent research trends have been analyzed and found the direction for the future research in terms of material, supplementary function, and patterning.

Zn-Sn-O비정질 산화물 반도체 박막의 Ga 첨가 영향

  • Kim, Hye-Ri;Song, Pung-Geun;Kim, Dong-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.61.2-61.2
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    • 2011
  • 넓은 밴드갭을 가지고 있어 가시광에서 투명하며 높은 이동도를 가진 산화물 반도체는 기존의 Si 기반 TFT 소자를 대체할 차세대 디스플레이의 핵심 소재기술로 관심이 높아지고 있다. 그러나 대표적인 산화물 반도체인 In-Ga-Zn-O (IGZO)에 포함된 인듐의 수요 증가에 따른 가격 급등 문제로 이를 대체할 수 있는 새로운 산화물 반도체 재료에 대한 연구의 필요성이 대두되고 있다. 이에 비교적 저가의 물질로 구성된 Zn-Sn-O계 산화물 소재에 대한 연구가 진행된 바 있으나, 높은 수준의 캐리어 농도를 가지고 있어 TFT 채널용 반도체소재로 적용되기 위해서는 이를 $10^{17}\;cm^{-3}$ 이하로 조절할 수 있는 기술개발이 요구된다. 본 연구는 마그네트론 스퍼터링법을 이용하여 증착된 Ga-Zn-Sn-O (GZTO) 박막의 갈륨 첨가에 따른 특성변화를 조사하였다. GZO ($Ga_2O_3$ 5wt%)와 $SnO_2$ 타켓의 인가 파워를 고정한 상태에서 $Ga_2O_3$ 타켓의 인가 파워를 0~100W로 조절하여 박막 내 Ga 함량을 증가시켰다. 제조된 모든 GZTO 박막은 Ga함량에 관계없이 비정질 구조를 가지며 가시광 영역에서 약 78%의 우수한 투과율을 나타낸다. Ga 함량에 따라 박막의 구조적, 광학적 특성은 크게 변하지 않지만 전기적 특성은 뚜렷한 변화를 나타냈다. $Ga_2O_3$ 파워가 증가할수록 박막 내 캐리어 농도와 이동도의 감소로 비저항이 크게 증가하는데 특히 캐리어 농도는 $Ga_2O_3$ 파워가 0에서 100W로 증가할 때 $2{\times}10^{18}$에서 $8{\times}10^{14}\;cm^{-3}$으로 감소하였다. 이는 Ga-O의 화학적 결합 에너지가 다른 원소들(Zn 또는 In)에 비해 커서 박막 내 산소공공의 감소가 야기되었기 때문이다. 이러한 전기물성의 변화를 이해하기 위해 XPS 분석을 수행하였다. 제조된 GZTO 박막은 $Ga_2O_3$ 파워가 증가함에 따라 O 1s peak에서 산소공공과 관련된 530.8 eV peak의 intensity가 감소한다. 따라서 Ga을 첨가에 따른 캐리어 농도의 감소는 산소공공의 발생억제로 기인한 것으로 판단되며, 본 연구결과는 ZTO계 비정질 산화물 반도체의 활용가능성을 제시하였다.

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A Study on Weatherability with Particle Size and Orientation of Aluminum in Pre-painted Basecoat for Automotive (자동차용 선도장 베이스코트에서 알루미늄 입자 크기와 배향에 따른 내후성 연구)

  • Lee, Jae Woo;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.167-171
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    • 2013
  • Weatherability was examined according to aluminum particle size and its orientation used in PCM(Paint Coated Metal). Substrate delamination was checked by different UV transmission rate with QUV$^{(R)}$ (Q-LAB) equipment that can make accelerated UV irradiation. Film was prepared using three different types of conflake aluminum pastes under a PCM coating process and clearcoat was sprayed. UV transmission test results showed low transmission rate when EKART #790 having the smallest particle size and horizontal orientation was used. From the gloss retention results, gloss retention was highest in EKART #790 and followed by #770, #750.

Research Trend of Biomass-Derived Engineering Plastics (바이오매스 기반 엔지니어링 플라스틱 연구 동향)

  • Jeon, Hyeonyeol;Koo, Jun Mo;Park, Seul-A;Kim, Seon-Mi;Jegal, Jonggeon;Cha, Hyun Gil;Oh, Dongyeop X.;Hwang, Sung Yeon;Park, Jeyoung
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.115-124
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    • 2020
  • Sustainable plastics can be mainly categorized into (1) biodegradable plastics decomposed into water and carbon dioxide after use, and (2) biomass-derived plastics possessing the carbon neutrality by utilizing raw materials converted from atmospheric carbon dioxide to biomass. Recently, biomass-derived engineering plastics (EP) and natural nanofiber-reinforced nanocomposites are emerging as a new direction of the industry. In addition to the eco-friendliness of natural resources, these materials are competitive over petroleum-based plastics in the high value-added plastics market. Polyesters and polycarbonates synthesized from isosorbide and 2,5-furandicarboxylic acid, which are representative biomass-derived monomers, are at the forefront of industrialization due to their higher transparency, mechanical properties, thermal stability, and gas barrier properties. Moreover, isosorbide has potential to be applied to super EP material with continuous service temperature over 150 ℃. In situ polymerization utilizing surface hydrophilicity and multi-functionality of natural nanofibers such as nanocellulose and nanochitin achieves remarkable improvements of mechanical properties with the minimal dose of nanofillers. Biomass-derived tough-plastics covered in this review are expected to replace petroleum-based plastics by satisfying the carbon neutrality required by the environment, the high functionality by the consumer, and the accessibility by the industry.

Fabrication of LiDAR-detectable Plate-type Black Materials and Application in Hydrophilic Paints (라이다 센서에 인지되는 판상형 검은색 소재의 제조 및 친수성 도료로의 응용)

  • Jiwon Kim;Minki Sa;Chan-Gyo Kim;Ha-Yeong Kim;Yeon-Ryong Chu;Suk Jekal;Chang-Min Yoon
    • Journal of Adhesion and Interface
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    • v.24 no.3
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    • pp.95-99
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    • 2023
  • In this study, LiDAR-detectable black materials are synthesized by coating and reduction of titanium dioxide onto plate-type natural mica, which evaluated practical LiDAR verification. In detail, black TiO2@Mica materials are fabricated by utilizing a sol-gel reaction to coat titanium dioxide onto natural mica, followed by reduction using sodium tetrahydridoborate. Subsequently, Black TiO2@Mica materials are dispersed in hydrophilic transparent varnish and sprayed onto the glass substrate to assess applicability as paints. As a result, Black TiO2@Mica-based paints exhibit true blackness (L*=12.1) and a higher NIR reflectance (30.2 R%). In addition, it was confirmed that as-synthesized Black TiO2@Mica materials are successfully recognized by a LiDAR sensor. This phenomenon is attributed to Fresnel's reflection law, in which light reflection occurs at the interface between natural mica and titanium dioxide with different refractive indices. In this regard, the findings of the study are expected to contribute to the potential utilization of LiDAR-detectable materials in various fields such as autonomous vehicles, robotics, and drones.

Characteristics of green colored opal glass with contents of iron oxide for LED light diffuser (LED diffuser용 green color 유백유리에 있어서 산화철 함량에 따른 특성)

  • Ku, Hyun-Woo;Lim, Tae-Young;Yoo, Seol;Hwang, Jonghee;Kim, Jin-Ho;Lee, Mi-Jai;Shin, Dong Wook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.3
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    • pp.120-126
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    • 2014
  • Translucent green colored opal glass was fabricated to substitute polycarbonate diffuser of LED lighting in order to solve the durability problem. Batch materials of green colored opal glass with the composition of calcium phosphate for opacifier and iron oxide for colorant were made and melted at $1550^{\circ}C$. As the results, translucent green colored opal glass was obtaind, which had excellent optical properties compare with nomal color glass for the diffuser of LED lighting, with no dazzling from direct light by high haze value over 90 % and low parallel transmittance value about 1 %. Therefore, it is concluded that this translucent green colored opal glass can be used for the glass diffuser materials of LED lighting with high heat resistance and high durability to substitute polycarbonate diffuser.

Change of Anti-reflective Optical Property by Nano-structural Control of Alumina Layer through Hydro-thermal Process (수열합성 공정을 통한 알루미나 코팅층의 나노구조 조절에 의한 반사방지 특성의 변화)

  • Lee, Yun-Yi;Son, Dae-Hee;Lee, Seung-Ho;Lee, Gun-Dae;Hong, Seong-Soo;Park, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.564-569
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    • 2010
  • Highly anti-reflective optical property has been focussed in the field of thin film and display because of increasing demands to the high transparency and clearness of optical component. In this study, to obtain anti-reflective property, the formation of aluminium oxide with nanoscaled flowerlike frame structure was introduced as oxide material monolayer on the substrate by hydrothermal synthesis through sol-gel method. The properties of coating layer were measured by the means of UV-Vis spectroscopy, FT-IR spectroscopy, XRD, and FE-SEM. The morphology of coating layer in alumina-sol coated samples was controlled by hydrothermal temperature and time with aid of ultrasound. It was found that high transparency and anti-reflective optical properties were obtained the formation of flowerlike nanoframe structure.