• Title/Summary/Keyword: 토양 입단

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Synthesis of Columnar Na-P Zeolite by Hydrothermal Process from Natural Zeolite of Korea (천연 Zeollte로부터 열수합성에 의한 주상 Na-P Zeolite합성)

  • Zhang, Yong-Seon;Jung, Pil-Kyun;Kim, Sang-Hyo
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.6
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    • pp.357-366
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    • 2003
  • This study was conducted to develop n convenient and efficient granular type absorbent with high CEC from powdery zeolite, which is a waste produced while crushing the natural zeolite of Korea to get a particular particle size. The change of mineralogical characteristics during hydrothermal alternation of natural zeolite to Na-P zeolite in alkaline solution at various reaction times was determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), and total elemental analysis. The columnar aggregate of Na-P Zeolite was produced by calcinating the natural zeolite-charcoal extrudates of about 3 mm diameter. In 24 hours reaction, clinoptillonite, mordenite and feldspar in natural zeolite were disappeared by 3 N NaOH treatment, while Na-P Zeolite with spherical granular structure was newly detected by XRD. As increasing reaction time, Si/Al ratio in remaining solution was deceased. The CEC of the synthesized material increased more than 2 times compared with that of natural zeolite, although the diameter of Na-P zeolite were rather increased.

Granulation of Natural Zeolite Powder Using Portland Cement (포트랜드 시멘트를 이용한 천연 지올라이트 미분의 입단화)

  • Kim, Su-Jung;Zhang, Yong-Seon;Ok, Yong-Sik;Oh, Sang-Eun;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.259-266
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    • 2007
  • Enormous amount of zeolite by-products as a fine powder have been produced while manufacturing commercial zeolite products. Granulation of the zeolite by-products is necessary in order for them to be recycled as soil conditioners or absorbent for various environmental contaminants due to the limitations inherent from their physical properties. We granulated the zeolite powders using Portland cement as a cementing agent and characterized the physical and chemical properties of the granulated zeolite product. The experimental natural zeolite had a Si/Al ratio of 4.8 and CEC of 68.1 $cmol_c\;kg^{-1}$. The X-ray diffractometry (XRD) revealed that clinoptilolite and mordenite were the major minerals of natural zeolite. Smectite, feldspar and quartz also existed as secondary minerals. Optimum conditions of granulated zeolite production occurred when natural zeolite was mixed with Portland cement at a 4:1 ratio and granulated using the extruder, left to harden for one month at $25^{\circ}C$ and treated at $400^{\circ}C$ for 3 hours. The wide spectra of XRD revealed that the granulated zeolite had amorphous oxide minerals. The alkali- or thermal-treated natural zeolite exhibited pH-dependent charge properties. The major minerals of the granulated zeolite were clinoptilolite, mordenite and tobermorite. The buffering capacity and charge density of the granulated zeolite were greater than those of natural zeolite.

Effect of Different Soil Managements on Physical Properties and Microbial Activities in Citrus Orchard Soil (초생재배가 감귤원 토양의 물리성과 미생물 활성에 미치는 영향)

  • Joa , Jae-Ho;Lee , Jong-Hee;Won , Hung-Yon;Han , Seung-Gap;Lim , Han-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.5
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    • pp.279-284
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    • 2008
  • This study was performed to investigate effect of different soil managements on physical properties and microbial activities in volcanic ash citrus orchard soil. Experiment plots had managed to control weeds on soil for 4 years with clean cultivation (CCM) used with herbicide, natural sod cultivation (NSCM), kentucky blue grass sod cultivation (KBG). Soil samples were taken on October, in both 1998 and 2000 from 3 experimental plots. In NSCM, Soil hardness was lower at 11.8 mm than in CCM. And water stable Aggregation coefficient(>0.5 mm) was high at 26.7% compared with CCM. Soil bulk density and porosity showed no significant among the treatments. Soil acid phosphatase was high in sod cultivation plots and the amount of microbial biomass C was about twice higher at $525.4mg\;kg^{-1}$ in KBG than in CCM. Conclusionally, Sod cultivation improved soil physical properties such as aggregation, hardness and increased microbial activities compared with clean cultivation in citrus orchard soil. Soil total PLFA, acid phosphatase, and microbial biomass C contents were investigated on May in nonvolcanic ash citrus soil. Soil samples were collected at 5 sites each; convention cultivation grown with herbicide, natural sod cultivation grown with 1/2 chemicals, organic cultivation. That sites have been managed for 5 years over. PLFA contents were two times higher at $112.2n\;mol\;g^{-1}$ in organic cultivation than in convention cultivation. According to the PLFA indicator, Gram negative bacteria and actinomycetes in organic cultivation were high compared with convention cultivation, which were at 15.1%, 6.6%, respectively. Soil microbial biomass C contents was about twice higher in organic cultivation than in convention cultivation. Soil acid phosphatase was high at 17.6% in organic cultivation compared with convention cultivation.

Characteristics and Genesis of Terrace Soils in Yeongnam Area -II. Physico-Chemical Properties (영남지역(嶺南地域)에 분포(分布)된 단구지토양(段丘地土壤)의 특성(特性)과 생성연구(生成硏究) -제(第) 2 보(報): 물리화학적(物理化學的) 특성(特性))

  • Jung, Y.T.;Kim, I.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.289-296
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    • 1985
  • To clarify the soil characteristics and genesis of the clayey terrace soils distributed in Yeongcheon (inland region) and Yeongil (coastal region), 9 typifying pedons including a recent local deposits were studied. The physico-chemical properties found were summarized as follows; 1. The contents of available water of the terrace soils were ranged from 12.0 to 20.3%. They were increased with increaseing clay content up to 35%, and then decreased at clay content of 35 to 55%, but were maintained about 12 to 13% when the clay content exceeds 55%. 2. The amount of water stable aggregates in the surface soils were ranged from 55.0 to 81.1%, and were low in cultivated upland where water erosion were accelerated while high in the paddy where the double cropping were practiced. The index of aggregate in cultivated upland were higher in the surface soils but the paddy soils were higher in subsoils. 3. The colloidal reactions checked by the differences between pH in $0.01N-Na_2SO_4$ and $H_2O$ indicate exchangeable acidity to exchangeable neutrality, which means a sort of Red-yellow soil forming process had been prevailed during genesis of the terrace soils. 4. Cation exchange capacity of the clayey terrace soils were averaged about 15.8-20.2me/100g of fine earth and 35.6-52.6me/100g of clay. The rates of base saturation were 32.7 to 57.6% and the rates decreased with increasing the elevations of terraces. 5. The activities of free iron oxides were 0.061 to 0.739 and the values decreased with increasing elevation while the crystallinity index of iron oxides positively correlated with elevations the values ranged from 0.067 to 0.537.

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The Effect of Anaerobic Fermentation Treatment of Rice or Wheat bran on the Physical and Chemical property of Plastic Film House Soil (쌀겨와 밀기울의 토양 혐기발효 처리가 시설 재배지 토양의 물리 화학성에 미치는 영향)

  • Kim, Hong-Lim;Sohn, Bo-Kyun;Jung, Kang-Ho;Kang, Youn-Ku
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.366-371
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    • 2006
  • This study was done to assess the physical and chemical properties after anaerobic fermentation treatment which use rice bran or wheat bran in plastic film house soil. The results which investigates the change of soil physical property after treatment 150 days showed a dramatic difference. The physical properties of control soil were the bulk density $1.46Mg\;m^{-3}$, hardness $2.30Kg\;cm^{-3}$, hydraulic conductivity $4.8cm\;hr^{-1}$, water stable aggregate(>0.5mm) 6.7%. Of the soil which treatment the rice bran in comparison to control soil, bulk density and hardness was diminished 12% and 58%, respectively. hydraulic conductivity and water stable aggregate(>0.5mm) were increased 4.5 and 5.2 fold, respectively. And, in the soil which treatment the wheat bran, bulk density and hardness was diminished 14% and 67%, respectively. Hydraulic conductivity and water stable aggregate(>0.5mm) were increased 6.3 and 6.5 fold, respectively. $NO_3-N$ contents of the soil which treated the rice bran or wheat bran after treatment 20 days were diminished 98% in comparison to control soil. The decrease of $NO_3-N$ contents in the soil was investigated with the fact that it is caused by with increase of the soil-microbial biomass. EC of the soil which treated the rice bran were $1.48dS\;m^{-1}$ which was diminished 58% in comparison to control soil. That of soil which treated the wheat bran was increased $3.65dS\;m^{-1}$ in the early stage because of acetic and butyric acid. But it was reduced as under $2.0dS\;m^{-1}$ after treatment 30 days. As the conclusion the anaerobic fermentation treatment with rice or wheat bran was effective to the improvement of soil physical and salt accumulation of the plastic film house soil.

Effect of municipal sewage sludge application on the change of physico-chemical properties and contents of heavy metals in soils (도시하수(都市下水)Sludge의 시용(施用)이 토양이화학성(土壤理化學性) 및 중금속(重金屬) 이동 (移動)에 미치는 영향(影響))

  • Choi, Jyung;Chang, Sang-Moon;Lee, Dong-Hoon;Choi, Choong-Ryeol;Park, Seon-Do
    • Korean Journal of Environmental Agriculture
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    • v.17 no.2
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    • pp.170-173
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    • 1998
  • This study was conducted to investigate the effect of municipal sludge application on the change of physico-chemical properties and contents of heavy metals in soils. The application of the sludge resulted in increasing the content of total nitrogen, available phosphate,exchangeable K, Ca, Mg, and the soil porosity and permeability but soil hardness was reduce. It is clear that application of municipal sewage sludge would not due to increase in the heavy metals content in soil because of the lower concentration of heavy metal in the sludge. Totally it is evident that municipal sewage sludge application should play an important role in improving soil physico-chemical properties.

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Case study of good soil management in plastic film-house cultivation (시설하우스 재배농가의 우수토양관리 사례연구)

  • Hyun, Byung-Keun;Kim, Lee-Yul;Kim, Moo-Sung;Cho, Hyun-Jun
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.2
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    • pp.98-104
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    • 2001
  • Cultivation area of the plastic film-house has been continuously increased with the increase of consumers' income. Intensive land use without fallowing or crop rotation caused severe problem such as salt accumulation in soils and in turn retarded growth and low productivity. This study was carried out to solve them derived from longterm intensive farming practices. Seven farmers who are practicing plastic film-house cultivation were recommended for case study by municipal government and selected for their excellency of cultivation and soil management. The cultivation periods of these systems were in the range of 5 to 40 years in the regions mainly located in alluvial soil cultivated with cucumber, tomato and red pepper. The soils texture of the excellent farmers' fields were silt loam or sandy loam, ranged from 7 to 15 percents of clay contents. Soil bulk density, depth of plowing layer and soil aggregates contents of the farmers' soils were 0.89, 23.1 cm, 61.6% whereas those in neighboring soils were 1.10, 17.8 cm, 54.2 %, respectively. And pH, OM and $NO_3-N$ of the farmers' soils also were better than those of neighboring soils. There was no difference in population densities of nematode between the good farmers' and neighboring soils, but actinomyces and Fusarium densities of recommended farmers' soils were better than neighboring soils. The major farming practices by the good farmers were characterized by deep plowing with flooding, amendment of crude organic matter, and reduction of chemical fertilizer application before transplanting, and also drip irrigation and liquid manure application after planting. They also conducted solar sterilization with or without flooding, removal of plastic films during rainy days and culturing rice or corn as rotation crops to avoid the problems mentioned above.

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Effect of Inorganic Cementing Agents on Soil Aggregate Formation in Reclaimed Tidelands (무기 결합재의 처리가 간척지 토양의 입단형성에 끼치는 영향)

  • Son, Jae-Gwon;Choi, Jin-Kyu;Cho, Jae-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.4
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    • pp.43-47
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    • 2009
  • Soil aggregation is an important part of influencing the soil behaviors in reducing rainfall-runoff and soil erosion, aeration, infiltration, and root penetration. Some inorganic materials such as clay minerals, Fe and Al oxides/hydroxides, and calcium carbonate can act as cementing agents within macroaggregates. The objective of this study was to determine the effects of different cementing agents (Fe, Mn, and Al) on soil aggregate formation in reclaimed tidelands. Water stable aggregate ratio and MWD (mean weight diameter) were higher in iron dioxides treatment than two other treatments. This result indicates significant correlation between soil aggregate formation and iron dioxides.

Soil Aggregate Distribution in Reclaimed Tidelands and Tidelands of Southwest Coastal Area of Korea (우리나라 서남해안 간척지 및 간석지 토양의 입단분포)

  • Son, Jae-Gwon;Koo, Ja-Woong;Choi, Jin-Kyu;Cho, Jae-Young;Song, Jae-Do;Kim, Young-Ju
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.219-224
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    • 2005
  • A aggregate size distribution is an important in successful crop production in reclaimed tidelands. The aggregate size distribution for this study were determined of 0.1mm, 0.5mm, 1.0mm, and 2.0mm by wet sieving method. Agricultural activity, period of reclamation showed significant effects on aggregate size distribution in reclaimed tidelands. The percentage of <2mm aggregates for SMG, GHD, and SM reclaimed tidelands were ranged 8.9, 36.7, and 38.0%, respectively. The percentage of >0.1mm aggregates for SMG, GHD, and SM reclaimed tidelands were ranged 9.0, 26.0, and 48.9%, respectively.

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Changes in the Soil Physical Properties of Vineyard Converted from Paddy Field (논에서 전환한 포도원의 토양물리적 특성변화)

  • Yun, Eul-Soo;Jung, Ki-Youl;Park, Ki-Do;Ko, Jee-Yeon;Lee, Jae-Saeng;Park, Sung-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.3
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    • pp.145-151
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    • 2009
  • This study was conducted to develop rational soil management and enhance the productivity of lands converted from paddy soils. Specifically, the changes in the soil physical properties brought about by the change in land usage from paddy soil were evaluated. This was carried out from 1999 to 2001 at 50 site in large-scale converted paddy fields of Kimcheon, Youngcheon, Gyeongsan and Milyang in the Youngnam region, categorized according to soil texture and drainage class. The ridge height of converted paddy soils was higher in coarse-textured and poorly-drained soils than in fine-textured and well-drained soils. The gray color of the surface soil was of lesser degree in converted soils than paddy soils and more notable in welldrained soils. The porosity ratio and the formation of aggregate structure were higher, and the appearance of soil mottling was deeper in converted paddy fields than in paddy soils. The glaying layer "g" of surface soil degraded with time. The porosity and amount of water stable aggregate was found to increase with time after conversion. The penetration resistance of the converted paddy soil was lower and deeper with time after conversion. The soil aeration of the converted paddy soil was lower in sandy loam than in loamy soil. Furthermore, soil aeration was influenced by ridge height and drainage class in poorly-drained soils.