• The Journal of Engineering Geology
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• v.16 no.1 s.47
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• pp.15-21
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• 2006

Sandy soils obtained from the field were examined by the way of particle analyses. The hydraulic conductivity values of the disturbed soil samples were measured by the falling head method. Then the correlations between the hydraulic conductivity and particle distribution were defined. The soil which was a product of the weathering of the granitic rocks belonged to sand and loamy sand area in a sand-silt-clay triangular diagram. The measurements of hydraulic conductivity were $1.15X10^{-5}\sim7.31X10^{-4}cm/sec$ which is the range of sand and silt. It was clearly observed that the hydraulic conductivity measurements of the sandy soils showed stronger correlations with the particle variances rather than the mean grain sizes. The larger the variances, the smaller the hydraulic conductivity measurements. The sandy soil which was a product of weathered granite and whose mean grain size was $0.38\sim1.97mm$ showed regression curves of $y=6.0E-5x^{-1.4}$ in a correlations between hydraulic conductivity and particle variances. Accordingly, it is clearly concluded that making estimates with-out any consideration about particle variances can produce serious errors.

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.1
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• pp.79-89
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• 2005

Forest soils were analyzed on their biological and physicochemical properties for the ecological restoration of burnt forest soil using organic wastes and proper microorganisms. Three kinds of soil samples were collected from undamaged soil(US), naturally restoring soil(NS) and artificially restoring soil(AS). All soil samples were sandy soil and acidic soil, ranged pH 5.34~5.78. Moisture content was higher in the soil of NS region. And the others were similar. Total organic matter and soluble sugar were higher at the surface, generally. Heterotrophic soil microbes were abundant at the surface soil of NS and subsoil of AS. Dehydrogenase, cellulase and phosphatase activities were higher at the NS soil. Especially, Dehydrogenase activity as primary index of soil microbial process showed high correlationship with moisture content(r=0.90, P < 0.05).

• Journal of Korean Society of Environmental Engineers
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• v.34 no.2
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• pp.136-142
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• 2012

Various factors affecting on the bioassay were investigated. Experiments with a low mixture ratio (cell to toxicant solution) of 0.5 : 9.5 (v/v) produced observable bioluminescence intensity for assay. Both sodium lactate and potassium nitrate stimulate bioluminescence activity; 2.6~4.0 times of control. Distilled water and MSM, which gave non significant effects on the bioluminescence activity, were determined as proper diluent or extract solutions. A wide range of toxic responses of metals and organics were observed. In general, organics were much less sensitive than metals. Samples collected from eleven sites showed the bioluminescence activity ranging from 29 to 111% of the control. Significant correlation between toxicity and total metal contents was not observed, but the toxicity of two groups, sorted based on the contaminated arsenic concentration in soils, was 44% and 20%, showing considerable differences.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.362-365
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• 2004

토양오염의 확산과정중의 서로 다른 지질적 기반위에 놓인 토양에 대한 침투특성과 4단계 이상의 장력을 적용하여 침투율을 산정하였다. 장력과 침투율과는 지수함수로 비선형 회귀시켜서 산정하였으며, 단지 몇단계의 장력만으로 구하여진 값보다 더 많은 불포화대수리특성과 신뢰성있는 포화수리전도도를 제공할 수 있을 것이다. 구하여진 침투율은 토양분석결과를 비교했을 경우 점토함량이 적은 시료에서 적게나오는 경향이 있고, sand가 많은 토양의 경우 높게 산정되었다.

• The Korean Journal of Pesticide Science
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• v.9 no.4
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• pp.316-329
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• 2005

Mobility of pesticides can be occurred by run-off and leachate or soil erosion. It is one of the most important factors for environmental contamination, particularly in steep sloped-land as Gangwon alpine region. In this study, the mobility of seven pesticides in different slopes and soil textures was investigated by simulated rainfall under controlled conditions. Simulated rainfall subjected to 60 mm $hr^{-1}$ was treated using rainfall simulator after 12 hr of pesticide treatment. Amounts of the pesticides were measured in run-off and leachate samples. The soil samples collected after rainfall from upper and lower parts and three different depths of sloped-plot were also analyzed. At result, all pesticides from the un-off samples collected from Taebaek(silty clay loam) and Heongseong(sandy loam) soils were detected maximum 96% within 60 minutes after first collection except carbendazim and cypermethrin which have the lowest water solubilities. From the leachate samples, a similar pattern was shown as run-off samples but amount of pesticides was lower than those of run-off samples. In soil samples, the order of the amount of pesticide residues was $0{\sim}5$ > $5{\sim}10$ > $10{\sim}15$ cm of soil depth and no pattern was shown in upper and lower, and different slopes. Comparing to mobility of pesticides in water and soil samples, pesticides in soil samples were higher than those of water samples in Taebaek soil. However, the results using Heongseong soils were in contrast to those of Taebaek soil. These results revealed that mobility of pesticides can be dependant mainly on soil textures and physicochemical properties of pesticides. Therefore, it can be suggested that selection of pesticides should be considered for soil texture and properties of pesticide in the alpine and sloped-land.

• Journal of Soil and Groundwater Environment
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• v.6 no.4
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• pp.13-23
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• 2001

In this study, the characteristics of pH variations and contaminant distribution in soil are investigated during electrokinetic treatment for the purpose of restoring contaminated soil with heavy metal. For these objects, laboratory test for the kaolin contaminated by lead was performed. During electrokinetic treatment, lead was transported from anode to cathode. And 75% of lead removed within 80% region of the specimen. Most lead, however, that transported from anode to cathode precipitated in the vicinity of cathode compartment, thus the amount of lead removed by electroosmosis was little. Electrokinetic treatment satisfied regulation criteria of Korean Soil Environment Conservation Law within almost region of the specimen. But enhancement methods can be regarded as inevitable requisite for the cathode region.

• Analytical Science and Technology
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• v.37 no.3
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• pp.174-188
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• 2024

This review summarized research trends regarding sample collection methods, pretreatment method, and types of analysis devices for microplastics (MPs) in soil and groundwater matrices. Soil sampling considers the selection of sampling location, depth, and volume. The typically sampling depth is within 15 cm (topsoil), and about 1 kg of mixed each sample. Among spot sampling and continuous flow sampling, groundwater sampling mainly used a continuous flow sampling, with collection rates 2 to 6 L/min in the range of 300~1,000 L, and followed by immediate on-situ filtration. Pretreatment method, applied to soil and groundwater, consist of organic digestion and density separation. In the organic digestion method, H₂O₂ is recommended among H₂O₂, acidic, alkaline, and enzymatic method. NaCl is primarily used as a reagent in density separation. However, depending on the density of MPs, other regents can be selectively used like ZnCl₂, ZnBr₂, and etc. Representative analysis device includes Fourier Transform Infrared (FTIR) and Raman spectroscopy for non-destructive analysis and Pyrolysis Gas Chromatography Mass Spectrometry (Py-GC/MS) for destructive analysis. µ-FTIR and Raman can count MPs of larger than 10 and 1 ㎛, and analyze MPs materials. However, it is need to sufficiently remove interference, like organic matter, in spectroscopic analysis using essential pretreatment method. Py-GC/MS is being continuously researched because it doesn't require complex pretreatment method and allows quantitative analysis of specific materials.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.229-235
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• 2007

관개나 수분수지 규명을 위한 기본적인 자료는 토양수분 함량이다. 그러나, 포장상태에서의 토양수분 함량은 직접 측정하는 것이 쉽지 않기 때문에 많은 경우 건조기를 이용한 중량수분 함량측정 방법을 이용하거나 토양수분 포텐셜 측정용인 텐시오미터를 이용한 토양수분의 에너지 특성을 관개에 활용하는 것이 현실이었다. 중량수분 함량은 시료를 채취해서 건조하기 때문에 시료채취 당시의 토양수분 함량을 아는 것이 어렵고, 토양수분 포텐셜은 에너지를 측정하는 것이기 때문에 이 역시 토양의 수분함량을 얻는 것이 불가능 하다. 따라서, 최근에 이런 측정상의 어려움을 극복하기 위해 여러 나라에서 포장에서의 토양수분 함량을 직접 측정하는 다양한 센서를 개발하고 있고 있다. 그 중 몇 가지는 현재 우리나라에 공급되고 있는데, 가격 등의 문제로 별로 알려져 있지는 않다. 센서는 현장에서 수분함량을 파악할 수 있는 장점이 있기 때문에 관개에 직접 적용이 가능하며 자동화시설이나 수분수지 모형 산정에도 활용할 수 있다. 본 시험은 우리나라에 소개되어 있는 몇 가지의 토양수분 측정용 센서를 현장에서 코어를 이용해 측정한 용적수분 함량과 비교하여 센서의 정확도나 이용 가능성을 검정하고자 하였다. 코어를 이용해 실측한 토양 용적수분 함량과 비교하고자 7종의 센서를 선택해 실험에 이용하였다. 가격이 비싼 것으로 알려진 TDR 형태의 센서가 2종이었으며, 나머지 5종은 FDR 형태의 센서였다. TDR 센서는 Soilmoisture사에서 제작한 MiniTrase와 Imko 사의 Trime이고, FDR은 Sentek사에서 개발한 EasyAG, EnviroSCAN과 Delta-T사에서 제작한 PR-1과 WET-2 및 Decagon사에서 제작한 $ECH_2O$ 센서였다. 실헙방법은 본량사양토인 포장에서 건조한 상태인 시험구와 물이 포화된 시험구를 만들어 놓고, 그곳에서 센서 종류별로, 측정 깊이별로 토양의 용적수분 함량을 측정하고, 센서로 측정한 위치 바로 옆에서 코어를 이용해 토양시료를 채취하고 이를 건조기에 건조해 용적수분 함량을 측정하였다. 비교결과 TDR인 MiniTrase가 결정계수$(r^2)$가 0.964이고 표준오차(SE)가 0.01로 좋은 결과를 보여줬고 WET-2가 $r^2$와 SE가 0.932와 0.013이였으며 EasyAG는 0.877과 0.0211, EnviroSCAN은 0.803과 0.0259의 값을 보였다. 일반적으로 토양수분 함량 측정오차가 1% 미만인 센서가 정확한 수분함량 해석을 유도할 것이지만 위의 센서 중 MiniTrase를 비롯한 4개의 센서 정도가 토양의 수분 함량을 측정하는데 유용할 것이라는 결론을 얻었다.

• Nuclear industry
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• v.15 no.2 s.144
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• pp.22-28
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• 1995

1994년도에 각 원전주변의 환경시료를 채취하여 방사능을 조사한 결과, 인공방사성핵종은 육상토양시료에서 Cs-137이 최대 31.9Bq/kg-dry, 해저토에서 최대 4.24Bq/kg-dry로 나타났으며, 일부 해양생물시료중 검출된 Co-58, Co-60, Mn-54 및 Ag-110m은 170Bq/kg 이내로 허용치 대비 0.08$\%$ 이내로 안전한 것으로 평가된다.

• Korean Journal of Soil Science and Fertilizer
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• v.42 no.5
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• pp.399-407
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• 2009

Laser induced breakdown spectroscopy(LIBS) is an simple analysis method for directly quantifying many kinds of soil micro-elements on site using a small size of laser without pre-treatment at any property of materials(solid, liquid and gas). The purpose of this study were to find an optimum condition of the LIBS measurement including wavelengths for quantifying soil elements, to relate spectral properties to the concentration of soil elements using LIBS as a simultaneous un-breakdown quantitative analysis technology, which can be applied for the safety assessment of agricultural products and precision agriculture, and to compare the results with a standardized chemical analysis method. Soil samples classified as fine-silty, mixed, thermic Typic Hapludalf(Memphis series) from grassland and uplands in Tennessee, USA were collected, crushed, and prepared for further analysis or LIBS measurement. The samples were measured using LIBS ranged from 200 to 600 nm(0.03 nm interval) with a Nd:YAG laser at 532 nm, with a beam energy of 25 mJ per pulse, a pulse width of 5 ns, and a repetition rate of 10 Hz. The optimum wavelength(${\lambda}nm$) of LIBS for estimating soil and plant elements were 308.2 nm for Al, 428.3 nm for Ca, 247.8 nm for T-C, 438.3 nm for Fe, 766.5 nm for K, 85.2 nm for Mg, 330.2 nm for Na, 213.6 nm for P, 180.7 nm for S, 288.2 nm for Si, and 351.9 nm for Ti, respectively. Coefficients of determination($r^2$) of calibration curve using standard reference soil samples for each element from LIBS measurement were ranged from 0.863 to 0.977. In comparison with ICP-AES(Inductively coupled plasma atomic emission spectroscopy) measurement, measurement error in terms of relative standard error were calculated. Silicon dioxide(SiO2) concentration estimated from two methods showed good agreement with -3.5% of relative standard error. The relative standard errors for the other elements were high. It implies that the prediction accuracy is low which might be caused by matrix effect such as particle size and constituent of soils. It is necessary to enhance the measurement and prediction accuracy of LIBS by improving pretreatment process, standard reference soil samples, and measurement method for a reliable quantification method.