• Title/Summary/Keyword: 토양의 화학적 특성

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Characterization and Feasibility Study of the Soil Washing Process Applying to the Soil Having High Uranium Concentration in Korea (우라늄 함량이 높은 국내 토양에 대한 토양학적 특성 규명 및 토양세척법의 적용성 평가)

  • Chang, See-Un;Lee, Min-Hee
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.8-19
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    • 2008
  • The physicochemical properties of soils having high uranium content, located around Duckpyungri in Korea, were investigated and the lab scale soil washing experiments to remove uranium from the soil were preformed with several washing solutions and on various washing conditions. SPLP (Synthetic Precipitation Leaching Procedure), TCLP (Toxicity Characteristic Leaching Procedure), and SEP (Sequential Extraction Procedure) for the soil were conducted and the uranium concentration of the extracted solution in SPLP was higher than Drinking Water Limit of USEPA (30 ${\mu}g$/L), suggesting that the continuous dissolution of uranium from soil by the weak acid rain may generate the environmental pollution around the research area. For the soil washing experiments, the uranium removal efficiency of pH 1 solution for S2 soil was about 80 %, but dramatically decreased as pH of solution was > 2, suggesting that strong acidic solutions are available to remove uranium from the soil. For solutions with 0.1M of HCl and 0.05 M of ${H_2}{SO_4}$, their removal efficiencies at 1 : 1 of soil vs. washing solution ratio were higher than 70%, but the removal efficiencies of acetic acid, and EDTA were below 30%. At 1 : 3 of soil vs. solution, the uranium removal efficiencies of 0.1M HCl, 0.05 M ${H_2}{SO_4}$, and 0.5M citric acid solution increased to 88%, 100%, and 61% respectively. On appropriate washing conditions for S2 soil such as 1 : 3 ratio for the soil vs. solution ratio, 30 minute for washing time, and 2 times continuous washing, TOC (Total Organic Contents) and CEC (Cation Exchange Capacity) for S2 soil were measured before/after soil washing and their XRD (X-Ray Diffraction) and XRF (X-Ray Fluorescence) results were also compared to investigate the change of soil properties after soil washing. TOC and CEC decreased by 55% and 66%, compared to those initial values of S2 soil, suggesting that the soil reclaimant may need to improve the washed soils for the cultivated plants. Results of XRF and XRD showed that the structural change of soil after soil washing was insignificant and the washed soil will be partially used for the further purpose.

Quantification of Soil Properties using Visible-NearInfrared Reflectance Spectroscopy (가시·근적외 분광 스펙트럼을 이용한 토양 이화학성 추정)

  • Choe, Eunyoung;Hong, S. Young;Kim, Yi-Hyun;Song, Kwan-Cheol;Zhang, Yong-Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.6
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    • pp.522-528
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    • 2009
  • This study focused on establishing prediction models using visible-near infrared spectrum to simultaneously detect multiple components of soils and enhancing the performance quality by suitably transformed input spectra and classification of soil spectral types for prediction model input. The continuum-removed spectra showed significant result for all cases in terms of soil properties and classified or bulk predictions. The prediction model using classified soil spectra at an absorption peak area around 500nm and 950nm efficiently indicating soil color showed slightly better performance. Especially, Ca and CEC were well estimated by the classified prediction model at $R^{2}$ > 0.8. For organic carbon, both classified and bulk prediction model had a good performance with $R^{2}$ > 0.8 and RPD> 2. This prediction model may be applied in global soil mapping, soil classification, and remote sensing data analysis.

Adsorptive Removal Properties of Heavy Metal Ions By Soils from the Upper Banbyun Stream (반변천 상류 주변 토양의 중금속 이온 흡착제거 특성)

  • Kim, Younjung;Hwang, Haeyeon;Kim, Yunhoi;Ryu, Sanghoon;Baek, Seungcheol;Seo, Eulwon
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.2
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    • pp.5-9
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    • 2007
  • This study carried out to investigate the removal capacity of heavy metals such as Cu (II), Zn (II) and Cd (II) dissolved in aqueous solution in the soils collected from Hyeon-Dong (HD), San-seong (SS), Keum-chon (KC) and Keum-Hac (KH) located in the upper Banbyun stream. The pH of all the soils was weak alkali such as 8.8 9.2. According to the analysis of chemical composition of the soils, the amount of $SiO_2$, $AlO_2$ and CaO were similar in all tested soils. However, the amount of $K_2O$, $FeO_3$ and MgO were different from each soil. The XRD measurement with these soils showed that quartz and feldspar were presented in all tested soils, and the distribution of kaoline, illite, montmorillonite, vermiculite and calcite were different from each soil. The results of the removal capacity of heavy metals indicated that all the soils had more than 98% of the removal efficiency of Cu (II), Zn (II) and Cd (II), and among the heavy metals, Cu (II) was removed the most effectively. These results suggested that the soils collected from the upper Banbyun stream have the high removal capacity of heavy metals, and these soils could be used for the banking a river around the abandoned mine area, containing the higher concentrations of heavy metals than the usual stream.

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Evaluation of Air Pollution Effects in Seoul City on Forest Soil at Mt. Namsan by Assay of Denitrifying and Sulfur-Reducing Bacteria (탈질균(脫窒菌) 및 황산환원균(黃酸還元菌) 정량(定量)을 통(通)한 서울의 대기오염(大氣汚染)이 남산(南山)의 토양(土壤)에 미치는 영향(影響) 평가(評價))

  • Park, Hyun
    • Journal of Korean Society of Forest Science
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    • v.86 no.1
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    • pp.98-104
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    • 1997
  • Soil pollution intensity at Mt. Namsan in Seoul city which was expected to show significant soil contamination due to long-term air pollution was evaluated by comparing soil chemical properties at Mt. Kyebangsan in Hongcheon area as a control, and the bacteria participating in nitrogen or sulfur mineralization were assayed simultaneously in order to evaluate the validity of N and/or S mineralization bacteria as an index of soil contamination. The soil of Mt. Namsan showed 10 times higher concentration of hydrogen ion compared to that of Mt. Kyebangsan, which indicated that the soil had relatively been acidified seriously. Especially, large amount of canons were thought to be leached out from the soil, while the amount of extractable Al was getting larger and larger, which result in serious problems in soil ecosystem of the mountain. I could infer from soil chemical properties of the four study sites that the major reason of soil acidification was SOx deposition. However, the sulfur-reducing bacteria were not significantly different between the two regions, which indicated that the microbial dynamics of the soil ecosystem was not controlled by simple factor, but by multiple factors. By the way, the dynamics of bacteria participating in denitrification process was different between the two regions, which was more active at Mt. Kyebangsan than at Mt. Namsan. Thus, the microbial assay for nitrogen mineralization is desirable to be examined as a tool for evaluating soil health or microbial activity in soil ecosystem.

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Chemical Properties in the Soils of Reclaimed and Natural Tidelands of Southwest Coastal Area of Korea (III) - Distribution of Nitrogens Fractions - (우리나라 서남해안 간척지 및 간석지 토양의 화학적 특성 (III) -질소의 형태별 함량 분포-)

  • Cho, Jae-Young;Koo, Ja-Woong;Son, Jae-Gwon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.3
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    • pp.3-8
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    • 2006
  • The fractions of nitrogen were investigated in the soils of reclaimed and natural tidelands of southwest coastal area of Korea. The content of total-N varied to ranged form 619 to 5,534 mg/kg dry weight with a mean value of 1,857 mg/kg. The order of different fractions of nitrogen was as follows: Acid non-extractable-N > uncounted-N > acid extractable-N > ammonia-N > nitrate-N. The content of ammonia-N, acid extractable-N, and acid non-extractable-N showed highly negative correlations with pH. The content of acid extractable-N and ammonia-N showed highly positive correlation with clay content.

Chemical Properties of Soil in the Proposed Horticultural Complexes of Saemangeum Reclaimed Tideland (새만금 전작.원예단지 후보지구 토양의 화학적 특성)

  • Son, Jae-Gwon;Choi, Jin-Kyu;Cho, Jae-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.4
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    • pp.67-73
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    • 2009
  • Chemical properties of soil in the proposed horticultural complexes of Saemangeun reclaimed tideland were studied for sustainable development of the newly reclaimed land resources. The soil texture of Gwanghwal, Gyehwa, Mangyeong and Okgu complex area were sandy loam. The pH and ESP (exchangeable sodium percentage) were 7.42 to 7.82 and 61.05 to 73.62 %, respectively. Compared to general agricultural land in Korea, the soil organic matter and other plant nutrients were low. The concentrations of heavy metals in the soil were found to be acceptable except several sites where they doesn't meet the warning standard of agricultural land contamination. Continuous monitoring and interception of external pollutants are suggested for water-soil-plant system conservation.

Chemical Characteristics of Golf Course Soils in Kyonggi Province (경기도 골프장의 코스별 토양의 화학적 특성)

  • 이인숙
    • Asian Journal of Turfgrass Science
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    • v.8 no.1
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    • pp.25-28
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    • 1994
  • Chemical characteristics of soils were investigated in three golf courses of Kwanak, Gold and Korea Country Club with different open year. The soil samples were collected in tee, fairway and rough. There were ranges of 4.80~5.55 in pH, 3.68~5.39% inorganic matter, 0.10~0.25% in total nitrogen, 5.63~45.64ppm in available phosphorus, 0.80~1.7lme /l00g in exchangeable Ca, 0.09~0 42me /l00g in exchangeable Mg, 0.03~0.O9me /l00g in exchangeable Na, and 0.06~0.l4me /l00g in exchangeable K. The pH was significant with golf club(P<0.05) and positively correlated with exchangeable Ca and exchangeable Mg(P<0.0l).

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Distribution of Soil Fertility in Paddy Fields as Affected by Cultivation Methods and Topographical Regions (경작지대 및 재배방법에 따른 논토양의 비옥도 분포)

  • Kim, Dong-Jin;Kang, Da-Seul;Ahn, Byung-Koo;Lee, Jin-Ho
    • Korean Journal of Organic Agriculture
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    • v.23 no.3
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    • pp.595-604
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    • 2015
  • Soil chemical properties in paddy fields were found to be varied depending upon different cultivation methods such as environmentally-friendly, conventional, and two-crop farming systems and different topographical regions, namely plain, middle mountainous, and reclaimed land regions. Overall soil pH was found to be in optimal range (pH 5.5~6.5) for rice cultivation, except with conventional cultivation fields of the reclaimed lands in Jeonnam province. Electrical conductivity (EC) was relatively higher in the two-crop cultivation fields than in others. However, the concentrations of available phosphate as $P_2O_5$ were exceptionally higher in the two-crop farming fields, thus in submerged paddy condition the phosphate could be released into streams and rivers. Soil organic matter (SOM) contents were mostly in optimal range ($25{\sim}30g\;kg^{-1}$) for paddy field in Jeonbuk province, but in Jeonnam province they were slightly higher values of the range. The concentrations of available silicate ($SiO_2$) were mostly depended on the cultivation methods and the region, but some of paddy fields contained extremely high $SiO_2$ concentration. Statistical relationships among the soil chemical properties showed as follows: Correlations between EC values and exchangeable cation concentrations, between SOM contents and CEC values, and between available $SiO_2$ concentrations and pH, EC, exchangeable cations, and CEC values were positively significant, whereas total nitrogen concentrations were significantly negatively correlated with the concentrations of exchangeable K and Mg. These results might be very useful to establish benchmark paddy fields contained with certain levels of soil fertility.

Monitoring for Change of Soil Characteristics by repeated Organic Supply of Comport and Green Manures in Newly reclaimed Organic Upland Field (신규 개간 유기농경지에서 가축분 퇴비와 녹비작물 연용에 따른 밭 토양의 이화학적 특성 변화 모니터링)

  • Ok, Jung-Hun;Cho, Jung-Lai;Lee, Byung-Mo;An, Nan-Hee;Shin, Jae-Hoon
    • Korean Journal of Organic Agriculture
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    • v.23 no.4
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    • pp.813-827
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    • 2015
  • This study was conducted to evaluate the effect of organic inputs on soil properties in a newly reclaimed organic soils. The soil of the experiment site was very low in soil fertility and the physico-chemical properties were poor. Several organic input treatments with different source of nutrient were placed, including compost in combination with green manures for organic agricultural practices, chemical fertilizers for conventional agricultural practices, and control without fertilizer. The experiment was conducted with continuous cropping system during 3 years. The chemical properties concentration in compost+green manure treatment was increased continually compare to control and chemical fertilizer treatment, and closed to the recommended rate of fertilizer. The organic matter value for compost+green manure treatment was increased from 0.86~0.96% to 2.00~2.29% by continuous nutrient supply of compost and green manure. However, further investigation on increasing of organic matter value for 3 years is necessary to monitor carefully during the long-term because it will help to clarify the all mechanisms of organic matter on organic input application way. The available phosphate value for compost+green manure treatment was generally increased from 21.9~27.1 mg/kg to 182.0~394.1 mg/kg. In case of exchange cation, the concentration for compost+green manure treatment was increased during 2 years within the range to the recommended rate of fertilizer, however, it is expected to cause a rather over supply for 3 years.