• Title/Summary/Keyword: 토양의 화학적 특성

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Geochemical and Environmental Isotope Study on the Groundwater from the Youngcheon Area, Gyeongbuk Province (경북 영천지역 지하수의 지구화학 및 환경동위원소 연구)

  • Kim, Geon-Young;Koh, Yong-Kwon;Bae, Dae-Seok;Won, Chong-Ho;Jung, Do-Hwan;Choi, Byoung-Young
    • Journal of Soil and Groundwater Environment
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    • v.12 no.4
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    • pp.35-53
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    • 2007
  • Geochemical and isotope studies on the groundwater system of the Youngcheon area were carried out. Most groundwaters belong to Ca-$HCO_3$ and Ca-$SO_4$ types and some groundwaters belong to Na-$HCO_3$ type. Geochemical characteristics of these groundwaters were mainly affected by their basement rocks around the boreholes. High $SO_4$ content of groundwater is the result of reaction with sulfate or sulfide minerals in the host rock. Ca was originated from the carbonate minerals in the sedimentary rock. After the groundwater was saturated with calcite, the Na-$HCO_3$ type groundwaters were evolved by the reaction with plagioclase for a relatively long residence time. This explanation was supported by low tritium contents of Na-$HCO_3$ type groundwaters. ${\delt}a^{18}O$ and ${\delta}D$ data indicate that the groundwaters are of meteoric water origin and there was no difference between the various types of waters. Grondwaters from the boreholes BH-1, BH-9 and BH-12 showed the geochemical and isotopic characteristics of deep groundwater. Most borehole groundwaters except them did not show the systematic geochemical variations with sampling depth indicating that the shallow and deep groundwaters were mixed with each other throughout the study area. The results of water quality analysis indicate that the study area is highly contaminated by the introduction of agricultural sewage.

안정동위원소를 이용한 제주 한림 지역 지하수 환경 및 오염 특성

  • 정성욱;우남칠;이광식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.417-420
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    • 2004
  • 이 연구는 안정동위원소를 이용하여 제주도 한림 지역의 지하수 환경 및 오염 특성을 규명하고자 시행되었다. 이를 위해 2002년 8월, 11월과 2003년 4월, 8월 네 차례에 걸쳐 39개 지점에서 지하수 및 용천수 시료를 채취하였다. 연구지역은 농촌지역의 대표적 오염특성인 질산성 질소의 오염이 심각하게 나타났으며, 고도 100m 내외에서 급증하는 특성을 보인다. 특히, 집중 강수가 있었던 8월에는 이러한 현상이 심화되었다. 질소 동위원소를 이용한 오염원 추정 결과, 대부분 화학비료의 영향으로 나타났으며, 이는 토지 이용 특성과 일치한다. 강수의 산소ㆍ수소 동위원소 조성은 '우량효과'를 반영하였으며, 지하수 시료들의 경우 함양에서 배출까지 순환이 매우 빠른 지하수 환경을 나타낸다.

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Isolation of Exopolysaccharide-Producing Bacillus polymyxa KS-1 and Some Properties of Exopolysaccharide (다당류를 생산하는 Bacillus polymyxa KS-1의 분리 및 생산 다당류의 특성)

  • 권기석;주현규;오태광
    • Microbiology and Biotechnology Letters
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    • v.20 no.1
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    • pp.34-39
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    • 1992
  • For the screening of new-functional and specific exopolysaccharide, a bacterium strain was isolated from soil through the two steps of screening. The isolated bacterium was identified as Bacillus polymyxa KS-1 according to the criteria of morphological, physiological, and chemical taxonomic analyses. The exopolysaccharide was composed of glucose:galactose: mannose and galactosamine in an approximate molar ratio of 1.00:0.36:1.02:1.10. The produced exopolysaccharide by Bacillus polymyxa KS-1 was found to be revealed new acidic polysaccharide which did not contain pentose, ketose, starch, and uronic acid.

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Compositions and pollution characteristics of total suspended particles (TSP) at 1100 Site of Mt. Halla (한라산 1100 고지 총부유분진(TSP)의 조성 및 오염 특성)

  • Kim, Won-Hyung;Kang, Chang-Hee;Jung, Duk-Sang;Go, Hui-Jeong;Lee, Won
    • Analytical Science and Technology
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    • v.21 no.4
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    • pp.304-315
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    • 2008
  • The total suspended particles (TSP) collected at the 1100 site of Mt. Halla have shown higher compositions for the anthropogenic components followed by marine and soil originated ones. The concentrations of the soil originated nss-$Ca^{2+}$, Al, Fe, Ca components have been increased in spring, and the anthropogenic $NH{_4}^+$, $K^+$, nss-$SO{_4}^{2-}$ components showed high concentrations in June. Meanwhile, the concentration of $NO{_3}^-$ as same as nss-$Ca^{2+}$ was higher in spring. It's likely due to the influence of its long-range transport from China. Compared to the non-Asian Dust periods, the concentrations of nss-$Ca^{2+}$, Al, Ca, and Fe have been increased 7.2~9.5 times in Asian Dust storm periods, and those of nss-$SO{_4}^{2-}$ and $NO{_3}^-$ were 1.3 and 3.8 times, respectively. From the factor analysis, the TSP compositions were influenced mainly by anthropogenic emission sources, followed by oceanic and soil sources. The backward trajectory analysis has shown that the concentrations of the anthropogenic and soil components were increased when the air parcels had been moved into Jeju island via China in a northwesterly wind.

Behaviour of the soil residues of the herbicide quinclorac in the micro-ecosystem (pot) (Micro-ecosystem(pot)중 제초제 quinclorac 토양잔류물의 행적)

  • Ahn, Ki-Chang;Kyung, Kee-Sung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.2 no.3
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    • pp.96-106
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    • 1998
  • Rice plants were grown for 42 days in the specially made micro-ecosystem(pot) containing two different soils treated with fresh and 60-day-aged residues of [$^{14}C$]quinclorac, respectively, to elucidate the behaviour of the herbicide quinclorac residues in the soils. Amounts of $^{14}CO_{2}$ evolved from two soils treated with different residues with and without vegetation were all less than 2.2% of the total $^{14}C$, indicating that there was little microbial degradation of quinclorac in soil. $^{14}C$-Radioactivity absorbed and translocated into rice plants from soil A and B containing fresh quinclorac residues was 8.4 and 24.2%, respectively, of the originally applied $^{14}C$, while 5.5 and 17.7%, in aged residue soils. These results indicate that larger amounts of $^{14}C$ were absorbed by rice plants from soil B with less organic matter and clay than soil A, and the uptake of [$^{14}C$]quinclorac and its degradation products decreased with aging in soil. After 42 days of rice growing, 84.5 and 61.8% of the $^{14}C$ applied freshly to soil A and B, respectively, remained in soil, whereas, in the case of aged soils, 86.3 and 67.7% of the $^{14}C$ applied did. Meanwhile, without vegetation, more than 98.3% of the $^{14}C$ applied, in both fresh and aged residues, remained in soil, suggesting that quinclorac was relatively persistent chemically and microbiologically. Most of the non-extractable soil-bound residues of [$^{14}C$]quinclorac were incorporated into the organic matter and largely distributed in the fulvic acid portion.

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Effect of Mixed Liquid Fertilization on Growth Responses of Cherry Tomatoes and Soil Chemical Properties (생초미생물혼합액비의 시용이 방울토마토의 생육반응과 토양화학성에 미치는 영향)

  • Park, Ji-Suk;Lee, Min-Jin;Lee, Seo-Youn;Kim, Jong-Sung;Lee, Tae-Kyu;Ro, Hee-Myong;Kim, Sang-Jun;Jeon, Seung-Woo;Seo, Sang-Gug;Kim, Kil-Yong;Lee, Geon-Hyoung;Jeong, Byung-Gon
    • Horticultural Science & Technology
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    • v.33 no.2
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    • pp.268-275
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    • 2015
  • We evaluated the effect of mixed liquid fertilizer (MLF) on growth responses of plants and soil chemical properties. To do so, a pot experiment with cherry tomatoes (Lycopersicon esculentum var. cerasiforme) using loam soil was conducted for 81 days in a temperature-controlled glasshouse, and four N fertilization treatments were laid out in a completely randomized design with three replicates: control (C), chemical fertilizer treatment (CF), and two rates (MLF-0.5 and MLF-1.0) of MLF treatment. Soils were periodically sampled and analyzed for pH, EC, total N, inorganic N and total C, and growth characteristics of cherry tomatoes were measured. During the experimental periods, the pH of MLF soils was higher than that of CF soils. Soil total-N content increased right after CF-application and ultimately decreased to the level of the control (C) soil, while MLF-application slightly increased the level of soil total-N and this level remained unchanged throughout the experiment. The levels of soil inorganic N content increased after application of CF or MLF, but the initial increase disappeared in 56 days after transplanting (DAT). The dry weight of shoots and roots increased in CF or MLF plants, while the number of fruit increased only in MLF plants. Whereas soluble solid contents were higher in MLF plants than in the other (C and CF) plants, the titratable acidity was not different among treatments. However, no consistent effect of N treatments on major elements of the organs of cherry tomatoes was found. The amounts of N taken up by plants were 0.91 g for CF, 0.61 g for MLF-1.0, 0.43 g for MLF-0.5, and 0.25 g for control treatments, resulting in greater N efficiency for CF than for MLF.

Properties of the Variation of Fe and Mn in the Vicinity of Soil Affected by Forest Fire for the Development of Technics that Reduces Forest Fire-induced 2nd Damage from Gangwon Provinces, Korea (2차산불피해저감기술개발을 위한 강원도 산불지토양 중 Fe-Mn원소의 분포특성)

  • 오근창;양동윤;김주영;남욱현;윤정한
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.285-297
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    • 2002
  • This study was carried out to prove the factor properties of the soil affected by a forest fire through the physical and chemical analysis and the data from the conclusion of those analysis are applied to the development of technics that reduces a forest fire-induced 2nd damage. The forest fire was in December 2000 at Gangreung city and Donghae city, Gangwon provinces, Korea. Soil samples were collected at upper layers (0-5 cm) and bottom layers (5-40 cm) in November 2001 from the burned and control sites. Values of pH in burned soils of the upper layers affected by forest fire are higher than those in control soils. Both the fragments of fire-burned plant and differences of geological properties are resulted in a class of soil. Contents of organic matters in burned soils are higher than those in control soils, exceptionally the contents of organic matters in burned soils that contain coaly shale are lower than those in control soils. Weathering indices in burned soils are higher than those in control soils and it concerned with loss of soil. Iron ions Fe(Fe$^{2+}$ or Fe$^{3+}$) are easily extracted from the burned soils by rainfall, but Mn ions are straightly exist in the burned soils by physiochemical adsorption of colloid. Through the sequential extraction in the burned soils and control soils, we are certificate the extraction of Fe ions and the disturbance of Mn ions from the burned soils. As a consequence of factor analysis in burned soil and control soil, we are certificate that the influence of forest fire results in a disturbance of positive correlation factors.

Assessing Effects of Farming Activities on the Water Quality in a Small Agricultural Watershed (충남 고성천 유역의 하천 수질 평가를 이용한 유역단위 질소와 인 수지 분석)

  • Kim, Min-Kyeong;Roh, Kee-An;Park, Seong-Jin;Choi, Chul-Mann;Ko, Byong-Gu;Yun, Sun-Gang;Lee, Jong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.32-37
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    • 2009
  • This study was conducted to assess the impact of agricultural land use on the water quality in mountain village farmlands. Two soil types, paddy and upland soil were analysed for their chemical properties. Although, pH and organic matter contents were not significantly different to each other, concentrations of available P and exchangeable K and Ca were much higher in upland soil compared with those in paddy soil. The results of water quality analysis indicated that, in Goseong-cheon watershed, the nutrients contents were much higher in downstream area than in upstream area. Particularly, the elevation of $COD_{Mn}$ and T-P were significant during rainy season. When paddy fields coexist with upland fields, SS, T-N, and T-P concentrations in paddy fields were lower than those of upland fields. This may indicate that paddy fields possess an water-purifying ability by absorbing nutrients. This effect may reduce excessive nutrients discharged into the neighboring streams which may cause eutrophication problem. The difference between inflow and outflow of nitrogen and phosphorus during the cultivation period were measured as -98.9 kg $ha^{-1}$ and -29.7 kg $ha^{-1}$, which means that nutrient outflow was higher than inflow. This may suggest that much nutrient was discharged during the crop harvest period.

Application of Laser-Induced Breakdown Spectroscopy (LIBS) for In-situ Detection of Heavy Metals in Soil (토양내 중금속 실시간 탐지를 위한 레이저 유도붕괴 분광법의 활용에 대한 소개)

  • Ko, Eun-Joung;Hamm, Se-Yeong;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.563-574
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    • 2007
  • Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.