• Title/Summary/Keyword: 토양부식성

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Chemical Properties and Spectroscopic Characteristics of Humic Fractions Isolated from Commercial Organic Fertilizers (국산(國産) 유기질비료(有機質肥料)의 부식조성(腐植組成) 및 분광학적(分光學的) 특성(特性))

  • Kim, Jeong-Je;Yang, Jae-E;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.1
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    • pp.44-52
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    • 1996
  • Humic substances of 17 organic fertilizers available on the market were the objects of study. The list of ingredients for formulation of them comprised fish meal. bone meal, oil-cakes, brewer's grains, peat, sawdust, wood bark, zeolite, soil conditioner, live-stock droppings, amino acid fermentation byproduct, chaff, limestone and others. Humic and fulvic acids were isolated from those substances and given chemical and spectroscopic analyses. Nutritional values of the organic fertilizers showed big diversity. Humification of organic matter was incomplete for some of the fertilizers as indicated by a high C/N ratio. Extractable humic acid percentage was higher, in general, than that of fulvic acid. Also the relative content of humin increased with advanced humification. Total acidity was closely related to phenolic hydroxyl groups. Relationships between carboxyl and hydroxyl groups. and carboxyl and alcoholic hydroxyl groups were very significant. Ultraviolet and visible light absorption spectra of humic and fulvic acids were substantially similar. The types of humic acids were B. P, and Rp. Two humic acids of the 17 samples belonged to B type. 3 to P type and all the rest to Rp type.

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Performance Assessment for Radionuclides Transport from HLW Repository (고준위방사성폐기물 처분장으로부터 핵종이동 평가)

  • 김성기;강철형;이연명;황용수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.41-46
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    • 2001
  • 요오드나 세순 같은 핵종들은 고용해도 핵 종들로서 사용 후 핵연료 내 피복관 이나 연료 결정 경계면에 위치하고 있다가 고준위 방사성폐기물 처분 후 지하수가 용기를 부식시키고 용기 내부로 침투하면 고용해도를 가지고 유출된 후 공학적, 천연 방벽을 통해 최종적으로 유출되게 된다. 본 연구에서는 한국원자력연구소에서 개발한 MASCOT-K글 이용하여 고용해도 핵 종들이 조화 유출과 고용해도 유출할 경우 유출 량을 평가 분석해 보았다. 평가 결과 요오드와 같은 고용해도 핵 종인 경우 전체 핵 종 재고량의 최대 10%만이 고용해도 유출을 하지만 그 영향은 조차 유출에 비해 훨씬 중요한 것으로 판명되었다. 이러한 결과를 바탕으로 현재 국내 고 준위 처분 환경에서 보수적인 시나리오로 주목받고 있는 우물 굴착 시나리오를 대상으로 우물까지의 거리 등 입력 자료의 불확실성을 평가해 보았다. 36,000 톤의 사용 후 핵연료를 처분 대상으로 했을 때 성능 평가 결과는 현재 처분 개념이 안전함을 입증한다.

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가스배관 결함평가 현황

  • O, Gyu-Hwan;Yeom, Gyu-Jeong;Kim, U-Sik
    • Journal of the KSME
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    • v.54 no.1
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    • pp.38-42
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    • 2014
  • 운영 중인 가스배관에는 매우 낮은 빈도이긴 하지만 부식, 기계적 손상, 내압, 토양하중, 차량하중, 지반침하, 열하중, 균열 등이 생길 수 있다. 안정적인 가스공급과 안전한 배관 운영을 위해서는 손상배관에 대한 건전성 평가가 필요하다. 평가 방법은 국내외 규격을 적용하거나 배관 운영회사에서 독자적인 건전성 평가방안을 적용하면 된다. 결함평가 방안은 고압 가스배관뿐만 아니라, 중저압 가스배관, 압력용기, 원자력 배관, 화학플랜트 배관 등에 필요한 사항이다.

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A Study on the Characteristics of Humic Materials Extracted from Decomposing Plant Residues -IV. Amino Acids in the Hydrolysates of Humic Acids Extracted from Straw of Wheat and Rye (식물성(植物性) 유기물질(有機物質)의 부숙과정중(腐熟過程中) 부후물질특성(腐朽物質特性)에 관(關)한 연구(硏究) -IV. 밀짚과 호밀짚의 부식산(腐植酸)의 산가수분해용액중(酸加水分解溶液中) Amino 산(酸)의 함량(含量))

  • Kim, Jeong-Je;Lee, Wi-Young;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.4
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    • pp.416-421
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    • 1988
  • Humic acids were extracted from straw of wheat and rye at three different stages of decomposition. Contents and distribution of amino acids in the hydrolysates of humic acids were examined and the results obtained can be summarized as the following: 1. Contents and distribution of amino acids in the hydrolysates of humic acids differ from plant to plant and from one stage of decomposition to another. 2. Neutral amino acids as a group take the largest portion of the total amino acids in humic acid hydrolysates followed by the acidic and the basic. 3. The total amount of amino acids in decomposed wheat straw at the 90 days of humification was greater than that in the case of rye straw. 4. Contents of amino acids other than arginine, histidine and tyrosine were increased in the case of wheat straw, while only the contents of lysine, phenylalanine, tyrosine and methionine were observed to increase in the case of rye straw. 5. Exceptionally high contents of phenylalanine and tyrosine were measured in the hydrolysate from rye straw taken at the end of experimental period. 6. No amount of arginine was detected in any hydrolysate of humic acids from decomposed plant residues.

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Absorption Spectra and Functional Group Contents of Peat and Humus Fractions in Korea (한국산(韓國産) 이탄(泥炭)과 토양부식물(土壤腐植物) 획분(劃分)의 흡수(吸收)스펙트럼 및 관능기(官能基)의 함량(含量))

  • Lim, Sun-Uk;Moon, Moo-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.4
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    • pp.347-352
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    • 1983
  • To characterize humus fractions in soil, visible, ultraviolet and infrared absorption spectra of humic acids in alkaline solutions and hymatomelanic acids in ethanol solutions extracted by Stevenson's method from paddy rice soils, peats, and volcanic ash soils were analyzed. The spectra patterns of both fractions in visible and ultraviolet ranges did not have any peak and the absorbance decreased as the wavelength increased. Visible and ultraviolet spectra of the solutions from all the peats, volcanic ash soils and paddy rice soil were very similar each other but absorbances were slowly declined in the order of volcanic ash soils, peats and mineral paddy soils. The infrared spectra of the two solutions appeared in a typical pattern, showing a few broad peaks. The main absorption bands were in the regions of $3400cm^{-1}$ (hydrogen bonded OH), near $2900cm^{-1}$ (aliphatic CH), $1720cm^{-1}$ (C=O of COOH, C=O of carbonyl), $1625cm^{-1}$ (aromatic C-C conjugated with C=O and/or COO-), $1400-1450cm^{-1}$ (CH stretch), $1200-1250cm^{-1}$ (CaO stretch of phenolic OH or OH-deformation of COOH) and $1050cm^{-1}$. The hymatomelanic acid fractions, however, had spectra that were characterized especially by very distinct absorption at $2900cm^{-1}$ and $1720cm^{-1}$, for aliphatic CH and carbonyl stretching vibration respectively in addition to the weaker bands for COO- or aromatic CH vibration at $1625cm^{-1}$, as compared to humic acid. No differences were noted in the general patterns of the spectograms of both fractions extracted. Analyses of the functional groups revealed little differences between peats and paddy soils, although total acidity and the content of carboxyl groups were decreased in the order of volcanic ash soils, peats and mineral paddy soils.

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Studies on Establishment of Application Method of Organic Matter in Rice-Barley Cropping System (벼-보리 작부지대(作付地帶) 유기물연용시용법(有機物連用施用法) 연구(硏究))

  • Han, Gyu-Heung;Mazda, Naodo;Roh, Tae-Hong
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.4
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    • pp.333-337
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    • 1986
  • The fertilizer experiment was conducted to establish a pattern of a continuous application of organic matter in rice-barley cropping system. Fine textured gray lowland soil was used to grow the crops. The amount of nitrogen absorption and the yield of the crops were the highest in barnyard manure 1,000kg/10a. A correlation among the content of humus and nitrogen, the amount of nitrogen absorption, and the yield was significant while it was not significant among the the nitrogen content of the soil fertility, the total nitrogen, and the yield of crops. The result of this research suggests that revelation of available nitrogen after the decomposition of the organic matter depending on climate and regions should be studied for the organic matter application in due season.

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Extraction of PCBs by Subcritical Water Extraction (Subcritical Water Extraction에 의한 PCBs 추출)

  • Kwak, Dong Hwan;Moon, Ji Yong;Lee, Sung In;Jeong, Gi Ho
    • Analytical Science and Technology
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    • v.13 no.4
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    • pp.511-519
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    • 2000
  • Water in the supercritical state ($T{\geq}374^{\circ}C$, $p{\geq}221$ atm) is a good solvent for nonorganic pollutants, but it is extremely corrosive. Subcritical Water Extraction (SWE) is a very fast and an efficient method to extract nonpolar environmental pollutants adsorbed on the sediments and soils. Many nonpolar organic compounds are sufficiently soluble to be extracted to the water under subcritical conditions. Complete extraction of PCBs from the sediments and soils takes only a few minutes by applying SWE with the subcritical water at 50 atm and at $260^{\circ}C$.

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Edge Vegetation Structure in Kaya Mountain National Park (가야산 국립공원의 주연부식생구조)

  • 오구균;진태호;양민영
    • Korean Journal of Environment and Ecology
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    • v.3 no.1
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    • pp.51-69
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    • 1989
  • To investigate edge vegetation structure and edge species in Kaya Mountain National Park, field survey was executed from July to August, 1989 and the result are as follows. Cantilevered and advancing types of edge vegetation were observed on site, The relative importance values of major species were changed along distance from edge to forest interior and were seemed to be affected by aspect, soil moisture and present tree layer vegetation. Especially, light-oriented species were observed as a codominant species under pine tree canopy due to selective allelopathy effect and thin canopy. Ecological indices according to the distance from edge to forest interior did not show regular pattern, but edge depth was estimated as 15-20m, approximately, Dominant species of edge seemed to be affected by soil moisture rather than altitude and aspect, but floristic similarities seemed to be affected by altitude. Frequency classes of edge species were different by aspect, altitude and physiogra-phical location. Lespedeza maximowiczii, Weigela subsessilis and Fraxinus rhynchophylla showed high frequency class in all environment conditions.

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Characteristic of organic/inorganic composite formed grounding resistance lowering agents (유/무기 복합재료형 접지저감제의 특성)

  • Kim, Jang-Wook;Chung, Chul-Hee;Cho, Dae-Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.05a
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    • pp.74-80
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    • 2004
  • Among inorganic materials, it is grounding resistance lower agent of new form that use being strata style clay and makes using water soluble polymer by main material to organic substance. Water soluble polymer chains are dispertion in water because water soluble polymer reacts with water if is done and these discrete polymer chains are inserted to floor of being strata style clay with water. This material that moisture content is very excellent and rate of expansion, electrical conductivity that measure after supplies water of 300wt % as well as is excellent. Can prevent corrosion or electrolytic corrosion of grounding bar securing very environmentally, chemically and pollution of soil. When applied to general grounding rod worker $7{\sim}8$ times ground resistance reduction effect of not application.

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Development of humic acid extraction method in soil and sediment using ultrasonic for 14C dating (초음파를 이용한 14C 연대측정 토양시료의 부식산 추출법 개발)

  • Park, Jiyoun;Hong, Wan;Park, Junghun
    • Analytical Science and Technology
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    • v.22 no.2
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    • pp.136-140
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    • 2009
  • To improve the carbon recovery yield of chemical pretreatment in soil and sediment for $^{14}C$ age dating using AMS (Accelerator Mass Spectrometry), we have developed ultrasonic method in chemical pretreatment to replace with stirring method which has been generally used in each step of humic acid extraction for soil and sediment samples. Extraction conditions such as ultrasonic power, temperature and reaction time have been optimized. Six times higher carbon recovery yield could be obtained from low carbon content samples using ultrasonic method. We also compared the dating results by AMS obtained using ultrasonic method with the ages of samples treated by the stirring method. It was found that this new method could be applied to the pretreatment process of low carbon content samples for AMS age dating without effects on the dated ages, and with highly improved carbon recovery yields.