• Title/Summary/Keyword: 탈수 효율

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Characteristic of Water Pervaporation Using Hydrophilic Composite Membrane Containing Functional Nano Sized NaA zeolites (기능성 나노 제올라이트가 분산된 친수성 복합막 제조 및 탈수 투과증발 특성 연구)

  • Oh, Duckkyu;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.98-105
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    • 2013
  • The NaA zeolite particles were dispersed in a poly(vinyl alcohol) (PVA) matrix to prepare a composite membrane. The nano sized zeolite particles of NaA were synthesized in the laboratory and the mean size was approximately 60 nm. Pervaporation characteristics such as a permeation flux and a separation factor were investigated using the membrane as a function of the feed concentration from 0.01 to 0.05 mole fraction and the weight % of NaA particles between 0 wt% and 5 wt% in the membrane. Also, the micro sized particles of $5{\mu}m$ were dispersed in the membrane for a comparison purpose. When the ethanol concentration in the feed solution was 0.01 mole fraction, the flux of water significantly increased from $600g/m^2/hr$ to $2000g/m^2/hr$ as the content of the nano NaA particles in the membrane increased from 0 wt% to 5 wt%, while the NaA particles improved the separation factor from 1.5 to 7.9. When the flux of water through the membrane containing nano sized particles was roughly 15% increased compared to the micro sized particles, whereas the separation factor of water was found to be approximately 5% increased. It can be said that the role of the nano sized NaA particles is quite important since both the flux and the separation factor are strongly affected.

Fractionation of KOCC by Froth-Flotation(IV)- (부상부유처리에 의한 국산 골판지 고지의 분급(IV))

  • 여성국;윤혜정;류정용;김용환;신종호;송봉근;서영범
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.40-40
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    • 2000
  • 우리나라의 제지산업은 천연펄프 자급능력이 20% 내외로서 낮은 실정이며 주원료의 7 70% 이상을 수입펄프와 고지에 의존하는 원료수급의 불균형이 심화된 상태이다 .. 1999년도 제지통계에 의하면 골판지 원지로 사용되는 라이너지와 골심지의 연간 생산량이 각각 169만 톤과 88만톤을 점유하여 국내 전체 지류생산량 887만톤의 약 29%를 점하고 있다. 이처럼 국내 제지산업에서 큰 비중을 차지하는 골판지 원지는 주로 국내에서 발생되는 고지를 원료 로 하여 생산되고 있어 환경친화적인 지류라 할 수 있다. 그러나, 국산 골판지 고지( Korean O Old Corrugated Container)의 경우 골판지 고지 이외에 각종 인쇄고지와 기타 산업용지가 혼합된 최하급지로서, 고지 재생 시 여러 가지 많은 제한요소를 지니고 있다. 국산 골판지 고지는 거듭된 재생처리로 인하여 미세분의 함량이 전체 지료의 절반에 달할 만큼 많으며, 아울러 섬유가 각질화됨에 따라 재생처리가 거듭될수록 그러한 미세분의 형성이 더욱 조장 되고 있다. 일반적으로 크기 75µm 이하의 무기질 및 단섬유를 일걷는 미세분은 골판지 원지 의 초지시 습지필의 탈수를 저해하여 생산성을 저하시키는 요인이 되어 왔다. 이러한 문제 를 해결하기 위해 선진국에서는 골판지 고지를 스크린 또는 클리너 둥으로 정선 처리하여 장단섬유를 분급한 다음, 장섬유분을 선택적으로 고해하여 종이의 강도를 향상시키는 기술 이 개발되어 적용돼 왔으나, 이러한 기술은 우리 나라와 같이 장섬유 보다 미세분 함량이 많은 저급의 골판지 고지를 주원료로 삼는 골판지 원지의 강도 개선에 큰 효과를 거둘 수 없는 기술이라고 판단된다. 이는 기존의 섬유 분급 처리는 고급 고지의 경우에는 효과적이 나 저급의 혼합고지를 100% 재활용하여 구성되는 국산 골판지의 생산 시에 적용하기에는 5 50-60%에 이르는 미세분이 포함되어 분리의 대상이 섬유장이 다른 펼프 섬유라기 보다는 미세섬유를 펄프섬유로부터 분리하는 것이 필요하기 때문이다. 이러한 문제점을 극복하기 위해서는 기포의 수력학적 포집작용을 이용하여 고농도의 미세분을 선택적으로 분급시키는 부상부 유 분급처리방법을 적용하였다. 이 방법은 미세분의 농축을 위한 부가적인 처리가 필요치 않으며, 분급에 천공을 이용하지 않기 때문에 분급처리 시 천공의 plugging 문제가 발생되 지 않는다는 장점도 가지고 있다. 미세분 분급을 위한 최적의 부상부유 조건은 장섬유의 응 집을 촉진하면서 미세분은 그러한 응집체에 포함되지 않은 상태로 자유로이 부상하여 걷혀 지는 경우이다. 응집거동을 조절하기 위한 시도로서 부상부유 처리시 유량을 달리한 실험결 과에 의하면 유량이 낮을수록 장섬유 손실이 줄고 미세분이 선택적으로 포집되나 전체 부상 부유 리젝트의 양이 줄어드는 문제점이 있었다. 이에 본 실험에서는 장섬유의 응집에 영향 하는 또 다른 인자로서 지료의 농도를 증가시키면서, 미세분의 부상부유를 촉진시키도록 유 량을 증가시키는 조건으로 부상부유 처리에 의한 미세분 분급효율을 증가시키고자 하였다.

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Preparation and Keeping Quality of Intermediate Moisture Food from Oyster and Sea Mussel (굴, 홍합의 중간수분 식품제조 및 저장 안정성에 관한 연구)

  • Jo, Kil-Suk;Kim, Hyun-Ku;Kang, Tong-Sam;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.363-370
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    • 1988
  • An attempt was made in this study to investigate the possibility of processing oyster and sea mussel into an intermediate moisture food. To obtain a palatable and instant product, shucked samples were heated in soy sauce for 5 min., heated in seasoning solution for 10 min., and then dried by the method of hot-air blowing for 4-6 hours at $40^{\circ}C$. Optimum seasoning solutions consisted of 2% monosodium glutamate, 3.5% sodium chloride, 15% sorbitol, 2% propylene glycol, 5% glycine and 0.02% rosemary oleoresin in 72.48% water. Judging from water activity, thiobarbituric acid, viable cell count, volatile basic nitrogen, surface color and sensory evaluation, vacuum-packaging method in nylon/PE $(20{\mu}m/40{\mu}m)$ or polyester/viniliden chloride/polypropylene $(12{\mu}m/15{\mu}m/50{\mu}m)$ film bag did hardly damage to the quality of intermediate moisture products, but air-packaging method in polyethylene(0.06m/m) bag did considerable damage to the quality during storage for 60 days in an incubator with 49-51% relative humidity at $30^{\circ}C$.

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Effects of Sewage Treatment on Characteristics of Sludge as a Composting Material (하수처리가 퇴비화를 위한 하수 슬러지 특성에 미치는 영향)

  • Kim, Jae-Koo;Kim, Jong-Soo
    • Applied Biological Chemistry
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    • v.41 no.2
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    • pp.181-186
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    • 1998
  • The effects of sewage treatment on characteristics of sludge as a composting material were investigated for a year during the initial operation at the full-scale Chunan sewage treatment plant. Due to the shortage of design capacity of belt press, a sludge dewatering unit, non-volatile solids were recirculating and concentrating in the treatment plant, resulting in an increase of MLSS and a decrease in F/M ratio at the activated sludge system. Special attention is required for long term operations since the increase of non-volatile solids in the plant would deteriorates the treatment efficiency. The sewage sludge of the Chunan sewage treatment plant showed 79.5% of water content, 11.6% of organic content, and C/N ratio of 6.1, and contained As 1.8 mg/kg, Cd 27 mg/kg, Hg <0.1 mg/kg, Pb 54 mg/kg, T-Cr 370 mg/kg, and Cu 1,100mg/kg of heavy metals. In order to be used as raw material for optimum composting, the sewage sludge requires bulking agents for moistrure/porosity control and a carbon source for adjusting C/N ratio. However, the sewage sludge is not adequate as a soil conditioner after composing due to a high content of heavy metals. If the sewage sludge has to he used as a soil conditioner after composting, it as required to identify and remove tire industrial wastewater portions in tire influent of the plant since heavy metals in the influent were mostly concentrated in dewatered sludge.

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Studies on the Application Rate of Cattle Slurry and Urea N on Productivity of Silage Corn and Leaching of Nitrogen in Lysimeter (액상발효우분(Cattle Slurry) 및 요소의 N 시용수준이 옥수수의 생산성과 N의 용탈에 관한 연구)

  • 육완방;최기춘
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.22 no.1
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    • pp.37-44
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    • 2002
  • This study was conducted to investigate the effects of the application rate of cattle slury and urea N on productivity of corn and environmental pollution in com cultivation soil. The experiment was conformed in lysimeter which was constructed with 0.33m diameter and 1m height. This study was arranged in split plot design. Main plots were the application rate of mineral fertilizer, as urea, such as 0, 100 and 200kgN/ha and subplots were the application rate of cattle slurry, such as 0, 200 and 400kgN/ha. The results obtained were summarized as follows. 1. Dry matter yields of corn increased as the application rate of cattle slurry and urea increased. 2. Total nitrogen content of whole corn was increased as the application rate of cattle slurry and urea increased 3. The average nitrate content in leaching water by application rate of the slurry and urea N was 7.78$\mu\textrm{g}$/$m\ell$(ranged from 6.27 to 9.02$\mu\textrm{g}$/$m\ell$). Nitrate content was hardly influenced by application rates of the slurry and urea. However, nitrate content rises in proportion to a rise in precipitation.

Economic Assesment of Phosphorus Control System for Reject Water using a Integral Type Slow Mixing/Sedimentation Tank and Fiber Filter (일체형 완속교반침전조와 섬유여과기를 이용한 반류수 인 제어시스템의 경제성 연구)

  • Kim, Mi-Ran;Kim, Jeong-Sook;Jang, Jeong-Gook
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.822-829
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    • 2017
  • As a method to reduce the total phosphorus in sewage treatment plant, we applied the integral type slow mixing/sedimentation fiber filtration system to compare the control methods for the sewage effluent and the reject water. It was analyzed that about 92.4 kg T-P/day should be removed in order to satisfy the final concentration of phosphorus of 0.2 mg T-P/L, which is reinforced effluent standard. Therefore the total phosphorus removal efficiency should be 96% for sewage effluent and 69.2% for reject water (dehydrated filtrate) respectively. The system operation cost to achieve the target of total phosphorus removal efficiency was assessed. It has been found that the treatment cost of the reject water containing high concentration of phosphorus with a low flow rate is reduced to about 1/2.4 of the coagulant cost and about 1/120 of the electricity cost, compared to that of the sewage effluent treatment. Also the economics of the integral type slow mixing/sedimentation fiber filtration system and the general coagulation and sedimentation system were compared. It was evaluated that the development system was more economical because the installation area of the integral type slow mixing/sedimentation fiber filtration system was about 1/7 smaller than that of the general coagulation and sedimentation system, and the annual operation cost including the required amount of coagulant and electricity cost of the development system was lowered about 1/1.7 than that of the general system.

Experimental Study of Desalting Methods Using Ethyl Alcohol for Archaeological Cast Iron Objects (에틸알코올 용매를 이용한 주조철제유물의 탈염 실험 연구)

  • Lee, Hye Youn;Cho, Ju Hye
    • Journal of Conservation Science
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    • v.31 no.2
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    • pp.95-104
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    • 2015
  • Excavated archaeological cast iron objects in improper storage are quickly corroded and disintegrated into block and powder finally. Hence desalination treatment which is a way of removing internal corrosive factors, especially chloride ion, is an important process. But desalination is often omitted or objects are dehydrated by alcohol because the destruction of objects could occur during desalting. Although current desalting methods mostly use an aqueous alkali solution, $OH^-$ ions of water could accelerate corrosion and broaden internal cracks cause of high surface tension. Therefore this study experimented desalting using ethyl alcohol, which is low surface tension, to investigate an effect of desalination. As a result, desalting using ethyl alcohol showed the similar or more effective results of desalting using water. In addition, as aspects of desalting safety, ethyl alcohol desalting method was smaller destruction of objects and extraction of Fe from the objects than the aqueous alkali solution. However, this study explored the possibility of desalting methods using organic solvent in fieldwork, so the results would provide basic date for making the safe and effective desalting method for archaeological cast iron objects through further experiments.

Effect of Processing Methods on Phisico-Chemical Properties of Instant Rice (제법(製法)에따른 즉석미반(米飯)의 이화학적(理化學的) 성상(性狀))

  • Kim, Dong Woo;Cho, Kwang Yun;Bae, Jung Surl
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.12 no.3
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    • pp.230-235
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    • 1983
  • Physicochemical properties of instant rice prepared by hot-air drying, alcohol dehydration and freeze-hot air drying were studied. Freeze-hot air drying rice showed the fastest rehydration rate as well as the most desirable textural characteristics. Sensory evaluation suggested that the freeze-hot air drying rice also had more desirable taste, flavor and texture. However, color was more desirable in alcohol dehydrated rice.

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Removal of PVC from Mixed Plastic Waste by Combination of Air Classification and Centrifugal Process (풍력(風力) 및 습식비중(濕式比重) 선별(選別)에 의한 혼합(混合)폐플라스틱 종말품(終末品)으로부터 PVC 제거(除去)에 관한 연구(硏究))

  • Choi, Woo-Zin;Yoo, Jae-Myung
    • Resources Recycling
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    • v.16 no.5
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    • pp.71-76
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    • 2007
  • The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

Removal of Dissolved Organic Matter by Ozone-biological Activated Carbon process (오존처리와 생물활성탄 공정에 의한 상수원수 중의 용존유기물 제거)

  • 이상훈;문순식;신종철;최광근;심상준;박대원;이진원
    • KSBB Journal
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    • v.18 no.3
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    • pp.211-216
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    • 2003
  • The removal yield of dissolved organic matter in drinking water by biological activated carbon (BAC) process was investigated. The tested processes wer raw water-AC process (BAC1), raw water-ozonation-BAC process (BAC2), and raw water-ozonation-coagulation/sedimentation-BAC process (BAC3). The amounts of organic matter was measured as dissolved organic carbon (DOC), ulta-violet radiation at 254 nm wavelength ($UV_{254}$), total nitrogen (T-N), ammonia nitrogen (NH_3$-N), and total phosphate (T-P). As a results, 30.7% DOC was removed by BAC2 process, which showed higher removal efficiency than BAC1 or BAC3 processes. The removal yield of $UV_{254}$ in BAC1, BAC2, and BAC3 processes were observed as 45.3%, 44.6%, 58.4%, respectively. And the removal yield of ammonia nitrogen were 66%, 81%, 29% in each BAC processes. The optimal empty bed contact time (EBCT) of BAC processes was estimated as 10 minute. This study has shown that BAC process combined with ozone treatment was efficient for removing dissolved organic matter in water.