• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.4
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• pp.179-185
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• 2005

Polycyclic aromatic hydrocarbons (PAHs) are a kind of toxic environmental pollutants and has been accumulated usually in marine sediments. Due to their potential hazardous to human, removal of PAHs from environments has been great concern. In the present study, the effect of microbial inoculation and the supplementation of mixed form cyclodextrin (M-CD) was assessed in the pre-sterilized or nonsterilized microcosms for optimizing operational conditions for ex situ bioremediation of sediments contaminated by PAHs. Activity of electron transport system (ETSA) was increased by the addition of M-CD regardless of inoculation of microorganisms in microcosms without sterilization. The degradation rate of PAHs in sterilized microcosms was app. 9-20% by the inoculation of single strain and 24-37% by the inoculation of microbial consortium supplemented with 1% M-CD, respectively. The degradation was not observed in microcosms without sterilization under the same conditions. The proportion of inoculated microorganisms also decreased in nonsterilized microcosms. Signals of inoculated bacteria were decreased to detection limit after 2 days in the microcosms without M-CD. In conclusion, microbial inoculation with appropriate carbon sources and removal of natural flora and grazers are required for the efficient ex situ bioremediation of sediments contaminated by PAHs in bioslurry reactor.

• Economic and Environmental Geology
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• v.36 no.3
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• pp.149-157
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• 2003

Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

• Microbiology and Biotechnology Letters
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• v.37 no.4
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• pp.333-339
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• 2009

Using a novel pine needle agar, fifteen bacterial species were isolated from pine litter. These bacteria were able to degrade aromatic hydrocarbons derived from lignin and utilize the ortho-cleavage of the $\beta$-ketoadipate pathway to degrade protocatechuate or catechol. A different utilization array of aromatic hydrocarbons by these bacteria was also determined. This study provides the information on bacterial species living in pine litter and suggests that these bacteria have metabolic abilities to utilize aromatic hydrocarbons derived from lignin biodegradation.

• Journal of Wetlands Research
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• v.15 no.4
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• pp.441-451
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• 2013

Samples for estimating concentrations of polycyclic aromatic hydrocargons(PAHs), total petroleum hydrocarbons(TPHs), and benzene-toluene-ethylbenzene-xylene(BTEX) were collected at the tidal flat sediments of 8 coastal sites in Incheon, at seventy-two sampling stations for the surface sediment and twenty-four stations for the sediment core, twice in the spring and fall in 2011. This study was performed to evaluate the distributions of seasonal and spatial concentrations of PAHs, TPHs, and BTEX in the tidal flat sediments. The source origin of PAHs were carried out. The total average concentration of PAHs in the tidal flat sediment was $95.62{\mu}g/kg$. The characteristic of PAHs concentration distributions was observed that the average concentration in the autumn was lower than that in the spring, and higher concentration in the sediment core than the surface sediment, and greater vertical concentration at the top rather than the bottom in the sediment core. The total average concentration of TPHs at all sampling sites was in the value of 46 mg/kg. The characteristic of the TPHs concentration distribution was observed that the average concentration in the fall was much higher than that in the spring, and higher concentration in the surface sediment than the sediment core. The possible source of PAHs inputs were mainly derived from both pyrogenic and petrogenic origin at the surface sediment at Janghwari site and the sediment cores of both Sorae and Okyeon sites, while the rest sites of study areas originated with pyrogenic combustion.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.190-195
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• 2002

The intermittent high vibration has been occurred one or two times a day for a 500MW large steam turbine during 5 months. This abnormal vibration was caused by the rubbing between the rotor and the carbide accumulated on the seal tooth of oil deflector. It was found that the accumulated carbide was insulation material installed on the HIP casing from the examination of the chemical composition. Also, this paper presents the mechanism of the intermittent high vibration and the proper method to eliminate this vibration problem. This result would be good practice to find the solution of similar high vibration in the steam turbines for power plant as well as industrial rotating machineries.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.11
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• pp.897-903
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• 2002

The periodic high vibration has been occurred one or two times a day for a 500 MW large steam turbine during 5 months. This abnormal vibration was caused by the rubbing between the rotor and the carbide accumulated on the seal tooth of oil deflector. It was found that the accumulated carbide was insulation material installed on the HIP casing from the examination of the chemical composition. Also, this paper presents the mechanism of the periodic high vibration and the proper method to eliminate this vibration problem. This result would be good practice to find the solution of similar high vibration in the steam turbines for power plant as well as industrial rotating machineries.

• The Korean Journal of Petroleum Geology
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• v.7 no.1_2 s.8
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• pp.35-40
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• 1999

Chemical and isotopic compositions of hydrocarbon gases were analyBed to characterize the properties of the shallow gases distributed in the southeastern part of the Ulleung Basin, offshore Korea. Sediments from the core were also analyzed to determine the characteristics and relationship to shallow gases. Hydrocarbon gases in the sediments consisted of methane (697.9-6054.4 ppm), ethane, propane, butane and hexane. The total carbon content of the sediments ranges from 1.84fe to $5.11{\%}$ and the total organic carbon content ranges from $0.29{\%} \;to\; 2.65{\%}$. High C/N ratio (>10) indicates that input of terrestrial organic matter was prevalent at the time of deposition. The methane content and stable isotopic data indicate that hydrocarbon gases from the sediments are identified to be thermogenic gas and mixture of both biogenic and thermal gases. Based on the Rock-Eval and carbon isotopic data, the level of thermal maturity of organic matter in the sediments $(Tmax<425^{\circ}C)$ is lower than that of gas. It suggests that thermal gases in the sediments migrated from the deeper sediments than the penetrated depth.

• Economic and Environmental Geology
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• v.48 no.4
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• pp.301-312
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• 2015

A commercial gas field was found in the southwestern continental shelf of the Ulleung Basin, East Sea in the late 1990s. To develop additional gas field, an exploration well was drilled through the coarse infill of submarine canyon near the gas field, but it was uneconomic to develop hydrocarbons. Using newly acquired deep seismic reflection and previous well data, we have identified additional geological structure which has hydrocarbon potentials below submarine canyons in the southwestern margin of the basin. Based on the interpretation of the deep seismic reflection and well data, the sequences of the study area can be classified into the syn-rift megasequence(MS1), post-rift megasequence(MS2), syn-compressional megasequence(MS3), and post-compressional megasequence(MS4) in relation to the tectonic events. MS1, deposited simultaneously with the basin formation before the middle Miocene, is characterized by chaotic seismic facies with low- to moderate-amplitude and low frequency reflections. MS2 comprises laterally continuous, low- to moderate-amplitude reflections, showing progradational stacking patterns due to high rates of sediment supply during basin expansion in the middle Miocene. MS3 is mainly composed of continuous reflections with high amplitude and moderate- to high-frequency which are interpreted as coarse-grained sediments. The coarse-grained sediments of MS3 sequence is widely truncated by several submarine canyons which filled with fine-grained sediment of MS4 to form a stratigraphic trap of hydrocarbon. Therefore, the reservoir and seal of the hydrocarbon trap in the study area are coarse-grained sediment of MS3 and submarine canyon filled with fine-grained sediment of MS4, respectively. A flat-spot seismic anomaly, which may indicate the presence of hydrocarbon, is observed within the stratigraphic trap.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2002.05b
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• pp.314-316
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• 2002

• The Korean Journal of Petroleum Geology
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• v.6 no.1_2 s.7
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• pp.25-36
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• 1998

Organic geochemical analyses were carried out in order to characterize organic matter (OM) in the sediments recovered from Korea/japan Joint Development Zone (JDZ V-1, V-3, VII-1 and VII-2) which is located in the northern end of the East China Sea Shelf Basin. Late Miocene sediments from the JDZ V-1 and V-3 wells generally contain less than $0.5\%$ of total organic carbon (TOC). However, early Miocene and Oligocene sediments show TOC values of $0.6-0.8\%$. Middle to late Miocene sediments are rich in TOC up to $20\%$ from JDZ VII-1 and JDZ VII-2 wells. The reason for this rich TOC might be attributed to the presence of coaly shales. Kerogens in the Tertiary sediments from the JDZ series wells are mainly composed of terrestrially derived woody organic matter. Elemental analyses indicate that OM from these wells can be compared to type III. Low hydrocarbon potential and hydrogen index reflect the type of OM. According to the biomarker analyses, the input of the terrestrial OM is prevalent. Oxidizing condition is also indicated by Pristane/Phytane ratio. Samples from the JDZ V-1 and V-3 wells obtain maturities equivalent to the oil generation zone around total depth, and organic matter below 3600 m from JDZ VII-1 and VII-2 wells reached dry gas generation stage. Oligocene sediments below 3500 m in the JDZ VII-1 and JDZ VII-2 wells may have generated limited amount of hydrocarbons, showing a progressive decrease in hydrogen index with depth, due to thermal degradation with increased burial. Gas shows and finely disseminated gilsonite may indicate the generation and migration of the hydrocarbons.