• Title/Summary/Keyword: 탄소전극

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The development of complex electrode for fuel cell using CNT (CNT를 이용한 PEMFC 연료전지용 복합전극 개발)

  • Ok, Jinhee;Altalsukh, Dorjgotov;Rhee, Junki;Park, Sangsun;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.135.2-135.2
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    • 2010
  • Carbon nanotube(CNT) has been spotlighted as a promising candidate for catalyst support material for PEMFC (proton exchange membrane fuel cell). The considerable properties of CNT include high surface area, outstanding thermal, electrical conductivity and mechanical stability. In this study, to fully utilize the properties of CNTs, we prepared directly oriented CNT on carbon paper as a catalyst support in the cathode electrode. The CNT layer was prepared by a chemical vapor deposition(CVD) process. And the Pt particles were deposited on the CNT oriented carbon paper by impregnation and eletro-deposition method. The potential advantages of directly oriented CNT on carbon paper can include improved thermal and charge transfer through direct contact between the electrolyte and the electrode and enhanced exposure of Pt catalyst sites during the reaction.

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Differential Pulse Voltammetry of Lead(II) ton at Nation- EDTA-Glycerol Modified Glassy Carbon Electrodes (Nation-EDTA Glycerol이 수식된 유리탄소전극에서 납(II) 이온의 펄스차이전압전류법)

  • 박상희;박찬주;박은희;고영춘;정근호
    • Journal of Environmental Health Sciences
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    • v.28 no.5
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    • pp.53-58
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    • 2002
  • A method for the determination of lead(II) ion using a nafion-EDTA(ethylene diamine tetraacetic acid)-glycerol modified glassy carbon electrode was proposed. Lead(II) ion is accumulated at the electrode by complexation and electrostatic attraction with nafion-EDTA-glycerol and detected at -0.560$\pm$0.015V (vs. Ag/AgCl) by differential pulse voltammetry. For the determination of lead(II) ion, a standard calibration curve if obtained from 10$^{-9}$ M lead(II) ion to 10$^{-7}$ M, and the detection limit(3s) is as low as 5.0$\times$10$^{-10}$ M.

Capacitance Property for a Carbon-nanofiber/Cobalt Oxide Composite Electrode (탄소나노섬유/코발트산화물 복합전극의 케폐시턴스 특성)

  • Yoon, Yu-Il;Ko, Jang-Myoun
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.482-485
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    • 2008
  • Composite electrode consisting of carbon nanofiber (CNF) and cobalt oxide was prepared for supercapacitor electrode, and its electrochemical property was investigated by means of cyclic voltammetry. Cyclic voltammetric results for the composite electrode showed it had specific capacitance value of 420 F/g at 5 mV/s, which was higher than capacitance value of 180 F/g for the bare CNF. It is concluded that the capacitive property of CNF can be improved by coating cobalt oxide on it to increase the surface area of cobalt oxide.

CoMn Oxide/Carbon-nanofiber Composite Electrodes for Supercapacitors (코발트망간 산화물/탄소나노섬유 복합전극의 수퍼케폐시터 특성)

  • Kim, Yong-Il;Yoon, Yu-Il;Ko, Jang-Myoun
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.493-496
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    • 2008
  • Composite electrodes consisting of $CoMnO_2$ and carbon nanofibers(vapor grown carbon nanofiber, VGCF) with high electrical conducivity($CoMnO_2$/VGCF) were prepared on a porous nickel foam substrate as a current collector and their supercapacitive properties were investigated using cyclic voltammetry in 1 M KOH aqueous solution. The $CoMnO_2$/VGCF electrode exhibited high specific capacitance value of 630 F/g at 5 mV/s and excellent capacitance retention of 95% after $10^4$ cycles, indicating that the used VGCF played the important roles in reducing the interfacial resistance in the composite electrode to improve supercapacitive performance.

Voltammetric Determination of Ag(I) ion using Carbon Paste Electrode Modified with $Ph_2O_2S_3$ ($Ph_2O_2S_3$로 변성된 탄소반죽전극에 의한 Ag(I) 이온의 전압-전류법적 정량)

  • Lee, Ihn Chong
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.171-175
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    • 1999
  • Carbon paste electrodes, modified with podands containing more than two sulfur atoms, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $1.0{\times}10^{-6}$ to $9.0{\times}10^{-5}M$, and detection limit was $5.0{\times}10^{-7}M$.

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Determination of the Length of Coaxial Type Carbon Grounding Electrode to Minimize the Fluctuation of Grounding Impedance (접지임피던스의 변동이 최소가 되는 동축형 탄소접지전극의 길이의 산정)

  • Lee, Kang-Soo;Kim, Jong-Ho;Lee, Bock-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.12
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    • pp.164-170
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    • 2010
  • For the surge currents like lightning or ground fault currents containing high frequency components which cause the electromagnetic interferences for the electronic devices and communication equipment, the grounding impedances give the significantly composite characteristics which are dependent on the frequency of surge currents. In this paper, the analytical model and method for determining the optimal length of the newly developed coaxial type carbon ground electrode which has a little fluctuation in grounding impedance with frequency. The length of minimizing the fluctuation of grounding impedance by changing frequency from 100[Hz] to 1[MHz] was determined, and the validity of this proposed method was confirmed by comparing with the simulated and measured data.

Effects of anode and current collector materials on the power density of solid oxide electrolyte direct carbon fuel cell (고체산화물 전해질 직접탄소 연료전지의 전극 및 집전부 재질이 출력밀도에 미치는 영향)

  • Hwang, J.Y.;Yoon, J.E.;Kang, K.;Kim, J.H.;Lee, B.J.
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.392-394
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    • 2009
  • Direct Carbon Fuel Cells (DCFCs) generates electricity directly converting the chemical energy in coal. In the present study, effects of anode and current collector materials on the power density of DCFC are investigated experimentally. The adopted DCFC system is combined type of solid oxide fuel cells (SOFC) and molten carbonate fuel cells (MCFC) with the use of a liquid-molten salt anode and a solid oxide electrolyte, proposed by SRI. Power densities of 25 mm button cells with various combination of anode materials and current collector materials are measured.

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Voltammetric Determination of Ag(I) ion with Carbon Paste Electrode Modified with Macrocyclic Ligand Containing Oxygen and Nitrogen as Ligating Atoms (주게원자로 산소와 질소를 포함하는 거대고리 리간드로 변성된 탄소반죽전극에 의한 Ag(I) 이온의 전압-전류법적 정량)

  • Lee, Ihn Chong
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.91-95
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    • 2002
  • Carbon paste electrodes, modified with 5,6,14,15-dibenzo-1,4-dioxa-8,12-diazacyclopentadeca-5,14-diene containing different ligating atoms of oxygen and nitrogen, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $3.0{\times}10^{-6}M$ to $8.0{\times}10^{-5}M$, and detection limit was $8.5{\times}10^{-7}M$.

Effects by Changing Binder Contents in The Carbon Counter Electrode for Dye-sensitized Solar Cells (염료감응형 태양전지의 탄소대항전극 제조시 바인더에 따른 영향)

  • Kim, Seong-Jun;Kwon, Jung-Youl;Lee, Hyeon-Seok;Park, Jung-Cheul;Lee, Heon-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.114-115
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    • 2006
  • In the present study we investigated effects by changing binder contents m the carbon counter electrode for dye-sensitized solar cells. Binder contents changed for 6 wt%, 7 wt%, 8 wt% before making carbon electrode. In the result of the measurement the specific resistance for 6 wt% was lowest among others And the surface of the carbon electrode which was measured by SEM was best m the 6 wt"%. The electrode properties be showing in an experiment were due to increment of surface roughness that appeared the carbon electrode, which decreased internal surface area.

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Electrical discharge properties in vacuum by carbon nanotube electrodes (탄소나노튜브 전극에 의한 진공 방전 특성의 평가)

  • Kim, Hyun-Jin;Lee, Sang-Hoon;Kim, Seong-Jeen
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.60-63
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    • 2004
  • Recently, carbon nanotubes(CNTs) have been demonstrated to possess remarkable mechanical and electronic properties, in particular, for field emission applications. Its high aspect ratio and extremely small diameter, hollowness, together with high mechanical strength and high chemical stability, are advantages for use in field emitter. In this paper, we demonstrate electrical discharge properties from carbon nanotube cathode electrodes to use as an emitter electrode of vacuum gauges. Vertically aligned $2{\times}2mm^2$ CNT arrays on the silicon substrate were synthesized by the thermal CVD method on Fe catalytic metal, and a glass patterning by the sand blast method and the silicon/glass anodic bonding processes were applied to make samples with 2 electrodes. The field emission was examined under the vacuum range of $10^{-3}$ Torr.

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