• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.901-908
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• 2018

Graphite is used as a sample anode active material. However, since the maximum theoretical capacity is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of a high capacity lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is higher than that of graphite. However, it is not suitable for direct application to the anode active material because it has a volume expansion of 400%. In order to minimize the decrease of the discharge capacity due to the volume expansion, the Si was pulverized by the dry method to reduce the mechanical stress and the volume change of the reaction phase, and the change of the volume was suppressed by coating the carbon layers to the particle size controlled Si particles. And carbon fiber is grown like a thread on the particle surface to control secondary volume expansion and improve electrical conductivity. The physical and chemical properties of the materials were measured by XRD, SEM and TEM, and their electrochemical properties were evaluated. In this study, we have investigated the synthesis method that can be used as anode active material by improving cycle characteristics of Si.

• Korean Journal of Ecology and Environment
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• v.52 no.3
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• pp.192-201
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• 2019

While a fairly large amount of organic matter is produced daily via phytoplankton photosynthesis in Lake Paldang, South Korea, knowledge of the role of algal-derived organic matter (OM) as a refractory OM source is not adequate. To understand the contribution of algal-derived OM to the refractory pool, biodegradation experiment and $KMnO_4$ oxidation experiment were conducted for 60 days using $^{13}C$ and $^{15}N$ labeled natural phytoplankton assemblage. The assemblage was collected from Lake Paldang on May 20, 2010. The photosynthetically produced total organic carbon ($TO^{13}C$), particulate organic carbon ($PO^{13}C$), and particulate nitrogen ($P^{15}N$) remained at 26%, 20%, and 17% of the initial concentrations, respectively, in the form of non-biodegradable organic matter. In addition, 12% and 38% of $PO^{13}C$ remained after $KMnO_4$ treatment on Day 0 and 60, respectively. These results indicate that photosynthetic products could be an important source of refractory organic matter after microbial degradation. Moreover, the microbially transformed algal-derived OM could contribute to the oxidation rate of the chemical oxygen demand.

• Resources Recycling
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• v.31 no.4
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• pp.19-25
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• 2022

In this study, tungsten carbide (WC) powder was prepared using a novel recycling process for hard metal sludge that does not use ammonium paratungstate. Instead of ammonia, acid was used to remove the sodium and crystallized tungstate, resulting in the formation of tungstic acid (H₂WO₄). The WC powder was successfully synthesized by the carbothermal reduction of tungstic acid through H₂O decomposition, reduction of WO₃ to W, and formation of WC. The carbon content and holding time at the carbothermal reduction temperature were optimized to remove free carbon from the WC powder. As a result, most of the free carbon in the WC powder prepared from sludge was removed, and the content of free carbon in the synthesized WC powder was lower than that in commercial WC powder. Moreover, the crystallite size of WC prepared from H₂WO₄ was much smaller than that of commercial micron-sized WC powder produced from APT. The small crystallite size of WC induces grain growth during the sintering of the WC-Co composite; thus, a WC-Co composite with large WC grains was fabricated using the WC powder prepared from H₂WO₄. The large WC grains affected the mechanical properties of the WC-Co composite. Further, due to the large grain size, the WC-Co composite fabricated from H₂WO₄ exhibited a higher toughness than that of the WC-Co composite prepared from commercial WC powder.

• 전자공학회논문지 IE
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• v.43 no.4
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• pp.122-127
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• 2006

A series of conductive filler were prepared with electroless plating method. Base conductive materials of the filler were nickel and copper. The cores were prepared with Nylon 6 and rayon in different aspect ratio. Also, various complexes were made with ABS resin and conductive filler with different filler feed ratio. The conductivity of the filler was measured with conductivity analyzer and the size distributions of fillers was measured with laser particle size analyzer. Electromagnetic wave shielding efficiency of each complex film was measured with flange circular coaxial transmission line sample holder within the 1MHz$\sim$1GHz bandwidth range. From this study, the conductivity of filers surpass that of other carbon films. It is available that the filler made of fibrous materials can be applied in plastic molding industry of electric appliances as a EMI filler.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.27 no.1
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• pp.1-7
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• 2015

A boiling heat transfer system is used in a variety of industrial processes and applications, such as refrigeration, power generation, heat exchangers, cooling of high-power electronics components, and cooling of nuclear reactors. The critical heat flux (CHF) is the thermal limit during a boiling heat transfer phase change; at the CHF point, the heat transfer is maximized, followed by a drastic degradation beyond the CHF point. Therefore, Enhancement of CHF is essential for economy and safety of heat transfer system. In this study, the CHF and heat transfer coefficient under the pool-boiling state were tested using multi-wall carbon nanotubes (MWCNTs) CM-95 and CM-100. These two types of multi-wall carbon nanotubes have different sizes but the same thermal conductivity. The results showed that the highest CHF increased for both MWCNTs CM-95 and CM-100 at the volume fraction of 0.001%, and that the CHF-increase ratio for MWCNT CM-100 nanofluid with long particles was higher than that for MWCNT CM-95 nanofluid with short particles. Also, at the volume fraction of 0.001%, the MWCNT CM-100 nanofluid indicated a 5.5% higher CHF-increase ratio as well as an approximately 23.87% higher heat-transfer coefficient increase ratio compared with the MWCNT CM-95 nanofluid.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.4
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• pp.11-20
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• 2015

In the present work, a basic study on the in-situ biogenic methane generation from low grade coal bed was conducted. Lignite from Indonesia was used as a sample feedstock. A series of BMP (Biochemical Methane Potential) tests were carried out under the different experimental conditions. Although nutrients and anaerobic digester sludge were added to the coal, the produced amount of methane was limited. Both temperature control and particle size reduction showed little effect on the increase of methane potential. When rice straw was added to lignite as an external carbon source, methane yield of 94.4~110.4 mL/g VS was obtained after 60 days of BMP test. The calorific value of lignite after BMP test decreased (4.5~12.1 %) as increasing the content of rice straw (12.5~50 wt % of lignite), implying that anaerobic digestion of rice straw led to partial degradation of lignite. Therefore, rice straw could be used as an external carbon source for the start-up of in-situ biogas generation from low grade coal bed.

• Korean Journal of Remote Sensing
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• v.29 no.2
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• pp.243-251
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• 2013

The optical properties of long-range transported Asian dust were studied by the satellite observations and Sun/sky radiometer measurements from the Aerosol Robotic Network(AERONET) in Northeast Asia. The movement of Asian dust from source regions to downwind areas was tracked by the Ozone Monitoring Instrument(OMI) derived aerosol product imagery. The optical properties of Asian dust were classified for geographical locations, which are source regions such as deserts area in Dunhuang and Inner Mongolia, downwind areas such as Yulin and Beijing, and long-range transported regions such as Korea(Anmyon and Gosan) and Japan(Noto). In general, relatively higher aerosol mass loadings with larger aerosol particles at desert regions were found. Aerosol Optical Depth(AOD) decreased significantly in downwind areas and long-range transported areas, which was accompanied by increased Angstrom exponents. This indicates the effects of aerosol mixing with various pollutants during transport of Asian dust plume on aerosol optical properties. Moreover, relatively high Single-Scattering Albedo(SSA) at 440 nm values ranging from 0.90 - 0.96 and increasing tendency of SSA with wavelength were observed at source region. The spectral dependence of SSA decreased during long-range transport.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.5
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• pp.493-505
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• 2020

Food web structures in the lower trophic levels of the seas around the Korean peninsula were investigated in August 2019 using stable isotopes. There were variable ratios of the carbon (-26.18 ~ -20.61 ‰) and nitrogen stable (5.36 ~ 15.20 ‰) isotopes in the particulate organic matter (POM). Most of the organisms ingested micro-POM as a major food source, but this varied spatially. The chaetognaths (3.40 ± 0.61) occupied the highest trophic level. The isotope mixing model showed that the proportions (13 ~ 51 %) of some organisms (i.e., copepods and euphausiids) reflected the relative contributions as major food sources for chaetognaths at each site.

• Polymer(Korea)
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• v.36 no.3
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• pp.364-371
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• 2012

Polystyrene/single-walled carbon nanotube (PS/SWCNT) nanocomposites were prepared by latex technology and the effect of surfactant (SDS) on nanotube dispersion, rheological and electrical properties was investigated. The nanocomposites were prepared through freeze-drying after mixing PS particles and aqueous SWCNT/SDS suspension. As the SDS content increased, the storage modulus and complex viscosity of the nanocomposites were increased due to enhanced dispersion of nanotubes, but if the content excessively increased, the modulus and viscosity began to decrease due to low molecular weight of SDS. The electrical conductivity sharply increased with the addition of SDS, and then did not show significant changes. This result is speculated to be the competition between the increased dispersion of nanotubes and the deterioration of electrical conductivity by SDS adsorption. An optimal ratio of SDS to SWCNT for improving electrical conductivity and end-use properties was 2. With this ratio, the electrical percolation threshold of SWCNT was less than 1 wt%.

• Journal of the Korean GEO-environmental Society
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• v.16 no.10
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• pp.5-14
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• 2015

Suction affects the unsaturated soil as the negative pore pressure, and leads to increases of the yield stress and the plastic shear stiffness of the soil skeleton due to the growth in interparticle stress. Hence, in this study, in order to account for these effects of suction under the dynamic loading condition such as the earthquake, the element simulation of the cyclic triaxial test using induced stress-strain relation based on cyclic elasto-plastic constitutive model extended for unsaturated soil considering the $1^{st}$ and the $2^{nd}$ yield functions was conducted. Through the stress path, stress-strain relation and relation between volumetric strain and axial strain, it was seen in all the cases that the simulation results demonstrated a good agreement with the experimental results. It is expected that the results of this study possibly contribute to the accuracy improvement on the prediction of unsaturated soil behavior under the dynamic loading condition.