• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.154.2-154.2
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• 2010

상대적으로 이산화탄소 배출량이 적으며, 기존의 천연가스를 대체할 수 있고, 21세기 신 에너지원으로 기대되고 있는 메탄 하이드레이트(Methane hydrate)는 태평양과 대서양의 대륙사면 및 대륙붕, 남극대륙의 주변해역 등지에서 자연적으로 발생한 메탄 하이드레이트의 분포가 확인되었으며, 그 매장량의 1조 탄소톤 이상으로 기존 화석연료의 매장량이 5천억 탄소톤, 대기중의 메탄가스가 3억 6천만 탄소톤임을 고려할 때 2배에 이르는 막대한 양이라고 보고하였다. 따라서 메탄 하이드레이트는 화석에너지를 대체할 수 있는 차세대 청정 에너지 또는 대체 에너지원으로서의 무한한 잠재력을 가지고 있어 새로운 에너지분야로 크게 주목을 받고 있다. 또한 하이드레이트는 $172m^3$의 메탄가스와 $0.8m^3$의 물로 분해된다. 만약, 특성을 역으로 이용하여 산업적으로 고체화 수송을 할 경우 화수송보다 18-24%의 비용절감이 이루어질 것으로 예상되어진다. 그러나 메탄 하이드레이트를 인공적으로 만들경우 물과 가스의 반응율이 낮아 하이드레이트 형성시간이 상당히 길고 가스 충진율도 낮다. 따라서 본 연구에서는 하이드레이트를 빨리 만들며 가스 충진율도 증가시키기 위하여 증류수와 다공성물질이며 나노세공(Nano pore)을 가지고 있는 제올라이트를 증류수에 첨가하고, 초음파 분산하여 만든 혼합유체를 메탄가스와 반응시켜 하이드레이트 형성 실험을 수행하여 비교 분석하였다. 그 결과 0.01 wt% 제올라이트 혼합유체에서 증류수보다 하이드레이트가 훨씬 빨리 생성되었으며, 메탄가스소모량은 ${\Delta}T_{subc}$=0.5K에서 약 4배 높음을 보였다.

• Journal of the Korean Professional Engineers Association
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• v.20 no.3
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• pp.5-14
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• 1987

연속체의 해석에 있어서, 특별한 경우를 제외하고는, 구조물의 개략적인 거동을 파악해야 될 경우가 종종 있다. 이러한 요구에 부응하기 위해서 강체요소법(Rigid Element Method)이라 불리우는 새로운 해석법이 개발되었다. 강체요소법은 원래 평정연구실에서 벽식프리캐스트 철근콘크리트 구조물의 탄소성해석을 하기 위해서 개발된 해석법에 착안하여, 내수벽과 같은 연속체에 적용함으로서 시작된 수치해석법이다. 그 후 저자들은 도통쉘, 구형쉘 혹은 이들이 조합된 쉘구조물에 적용할 수 있도록 개발 확장하였다. 강체요소법의 기본개념은 연속체의 분해된 각 요소를 강체(rigid body)라고 가정하고, 각 요소들은 요소의 강성으로 치환된 가상스프링으로 서로 연결되어 있다고 가정하여, 이 가상스프링의 거동을 평가함으로서 전체구조물의 거동을 파악하는 해석법이다. 이때 요소의 주변에 취해진 스프링은 해석을 단순화하기 위해서 축력, 면내전단력 및 면외전단력만을 전달한다고 가정하고, 요소의 강체변위(자유도)는 요소내의 임의의 한 점에서 취하며, 이 점에서의 강체변위(rigid displacements)는 요소의 주변에 취해진 스프링을 통하여 다른 요소로 전달된다. 상기와 같은 강체요소법의 개념을 연속체의 탄성 및 탄소성해석에 적용하면, 해석적 개념이 단순할 뿐만 아니라 구조물 전체의 자유도수를 대폭 줄여 컴퓨터 계산시간을 절약할 수 있는 잇점이 있고, 거시적인 모델(macroscopic modeling)과 미시적인 모델 (microscopic modeling)의 중간적인 성격을 가지기 때문에 구조물의 파괴상황에 대해서도 그 개략을 파악할 수 있다. 본 논문에서는 강체요소법을 보다 일반화된 해석법으로 개발, 확장하기 위해서 종전에 단층스프링시스템(single-layer spring system)으로 해석이 어려웠던 문제점들을 보완한 복층프링시스템(double-layer spring system)을 사용함으로서 휨, 비틀림의 효과를 파악할 수 있는 이론적 개념을 적용한 새로운 구요소, 원통요소 및 평면요소를 개발하고, 이러한 강체요소들의 적합매트릭스의 유도 및 해석저긴 방법을 정식화하였다. 또 휨, 비틀림 및 전단력의 효과를 고려한 사각형원통요소 및 능형원 통요소를 이용하여 원통쉘의 탄성 및 탄소성해석할 수 있는 프로그램을 개발하고, 이 프로그램으로 캔틸레버로된 연속형철근콘크리트 원통쉘의 탄성 및 탄소성해석에 적용하여 구조물의 거동에 관한 수치해석의 결과, 즉 내력의 분포, 균열의 진전, 파괴의 상황 및 변형의 상태 등을 파악해 보았다.

• The Korean Journal of Quaternary Research
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• v.15 no.2
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• pp.63-73
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• 2001

In total, 29 $^{14}C$ dates were obtained from Paleolithic sites in the Korean peninsula. If not the dates from the Sorori peat layers, the number will be less than 20. Low boundary of Upper Paleolithic could be estimated by some early of the dates from Blade stone industries. Couple of $^{14}C$ dates indicate that beginning of Upper Paleolithic industries could approach to 40 K BP, but it is premature to establish fine chronology of Upper Paleolithic. Some of the $^{14}C$ dates of microlithic industries probably represent too earlier age than generally thought. Tentatively, the beginning of microlithic industries may go back to an age of slightly older than 20 K BP, as indicated in Janghungri, Sokchangni, Noeundong etc. The obtained $^{14}C$ dates at present are very important for construction of Paleolithic chronology. but it is necessary to accumulate for more $^{14}C$ dates in future along with results from other dating techniques and to reconstruct site formation processes for obtaining objective age of stone industries.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.2
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• pp.75-83
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• 2009

In order to understand the impacts of the construction of artificial sea dikes on carbon cycle in Samangeum area being a closed environment after April, 2006, we had measured suspended particulate matters, particulate and dissolved organic carbon in the surface water of inner Saemangeum dike from 2003 to 2006. The significant inputs of suspended particulate matter and organic carbon were mainly occurred during the wet season which suggests that most organic matter loading is concentrated within a short period of time inside the dike. The concentrations of particulate matter and organic carbon have gradually increasing every year inside of dike from the Mangyeong river estuary to Saemangeum dike, which has been closed since 2003 after the construction of the 4th dike. The particulate organic carbon increased due to the phytoplankton blooms by eutrophication. If the large portion of particulate organic matter produced in the surface water sink to the bottom sediment, this will cause the anoxic condition in this closed environment.

• Korean Journal of Microbiology
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• v.53 no.1
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• pp.9-19
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• 2017

We studied soil composition, $N_2O$ production, a number of denitrifying bacteria, community structure and T-RFLP patterns of denitrifying bacteria dependent on agricultural methods with the change of seasons. Analyses of the soil chemical composition revealed that total carbon and total organic carbon contents were 1.57% and 1.28% in the organic farming soil, 1.52% and 1.24% in the emptiness farming soil, and 1.40% and 0.95% in traditional farming soil, respectively. So, the amount of organic carbon was relatively high in the environment friendly farming soils than traditional farming soils. In case of $N_2O$ production, the amount of $N_2O$ production was high in May and November soils, but the rate of $N_2O$ production was fast in August soil. The average number of denitrifying bacteria were $1.32{\times}10^4MPN{\cdot}g^{-1}$ in the organic farming soil, $1.17{\times}10^4MPN{\cdot}g^{-1}$ in the emptiness farming soil, and $6.29{\times}10^3MPN{\cdot}g^{-1}$ in the traditional farming soil. It was confirmed that the environment friendly farming soil have a larger number of denitrifying bacteria than the traditional farming soil. As a result of the phylogenetic analyses, it was confirmed that six clusters were included in organic farming soil among total 10 clusters. And the result of PCA profile distribution of T-RFLP pattern on agricultural methods, the range of distribution showed wide in the organic farming method, relatively narrow in the conventional farming method, and middle in the emptiness farming method. Therefore, we could concluded that the distribution and the community structure of denitrifying bacteria were changed according to the agricultural methods and seasons.

• Proceedings of the Korean Ceranic Society Conference
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• 2000.04a
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• pp.99.2-99.2
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• 2000

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.449-454
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• 2016

In this study, highly monodispersed porous carbon microcapsules with a hollow core were synthesized using polystyrene (PS) beads as a hard template. The surface of PS was first modified with polyvinylpyrollidone (PVP) for the easy attachment of inorganic silica sol. After coating the surface of PVP modified PS microspheres with SBA-16 sol, the carbon microcapsules with a hollow macroporous core were fabricated through reverse replication method by filling carbon sources in the mesopores of silica mold. The hollow carbons having a mesoporous shell structure and narrow particle size distribution could be obtained after the carbonization of carbon source and the dissolution of silica mold by HF solution. The mesoporous characteristics and electrochemical properties of hollow carbon microcapsules were characterized by XRD, SEM, TEM, $N_2$ adsorption/desorption analysis and cyclic voltammetry. They showed the high electric conductivity and capability for use as efficient electro-materials such as a supercapacitor.

• Journal of Korean Society for Geospatial Information Science
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• v.19 no.2
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• pp.49-54
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• 2011

Recently Korean government announced the vision for low-carbon green growth. Quantifying of the carbon storage, distribution, and change of urban trees is vital to understanding the role of vegetation in the urban environment. In the city planning the carbon storage estimation has become an important factor. In this paper, KOMPSAT-2 satellite imagery was used to develop a method to predict the urban forest carbon storage from the Normalized Difference Vegetation Index (NDVI) computed from a time sequence image data. The total carbon storage change by trees in the 6 administrative zonings of Jinju was estimated using the image data in 2007 and 2009. Therefore the paper presents a method based on the satellite images, which can estimate the spread of urban tree and carbon storage variation using KOMPSAT-2.

• Journal of the Korean Chemical Society
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• v.25 no.1
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• pp.21-25
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• 1981

A study was made of the influence of butyl alcohol on the distribution coefficients of barium and mercury ions between the ion exchange resin, Dowex 50w-x8, 200~400 mesh and solutions containing hydrochloric acid, butyl alcohol and water. The determination of the distribution coefficients of barium and mercury are made by using the batch method. The distribution coefficients of metal ions decrease generally as the number of branches of carbon in the molecule of butyl alcohol increase. It shows that solubility in water and stereo-isomerism of the butyl alcohol have influence upon the distribution coefficient of barium and mercury.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.8 no.3
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• pp.317-326
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• 2003

In order to improve our knowledge of the characteristics of organic compounds in coastal waters, water samples were collected from the Incheon coastal region, the Hyungsan River in Youngil Bay and the Busan coastal region. Also, mooring was carried out near the Kanghwa Island and Seo Island. In this study, the relationship between the total organic carbon (TOC) and salinity, chemical oxygen demand (COD) and salinity were evaluated and determined. Riverine end-member of TOC into the Korean coastal area and its COD estimated from these relationships were 5.32 mg C/l and 8.87 mg O$_2$/l, respectively. The oxidation efficiency of COD to TOC estimated using the high-temperature catalytic oxidation method was about 47％. The linear relationship between TOC and COD was derived as COD (mg O$_2$/l)=0.61${\times}$TOC (mg C/l) -0.03, (R$^2$=0.66). Therefore, it is possible to estimate total organic carbon using this equation from previously reported chemical oxygen demand.