• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.20 no.1
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• pp.30-36
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• 1984

It is well known that the application of linear elastic fracture mechanics is inadequate to solve the large deformation fracture failures which occurr in ductile manner because of the large scale yielding due to the severe stress concentration in the region adjacent to the crack tip. The authors have been evolved a fracture model, the crack plane equilibrium model, for this kinds of elastic-plastic fracture problems in the previous report. In this report, the crack plane equilibrium model was compared with the Irwin's plastic zone corrected linear elastic fracture mechanics through theoretical comparisons and experimental results to examine the validity of the crack plane equilibrium model as an available tool for nonlinear fracture analysis. Through this study, the main results were reached as follows; Irwin's plastic zone corrected linear elastic fracture mechanics could be applicable only for small scale yielding problems as expected while the crack plane equilibrium model valid as a fracture model for large deformation fracture failure. However, the followings should be considered for the more precise evaluations of CPE model; 1) It is necessary to test more specimens which contain small cracks in the range of 2a/W<0.1. 2) It is important to detect the crack initiation point during the fracture test for determining an accurate fracture load. 3) Effects of specimen thickness in the fracture process zone should be examined.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.16 no.8
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• pp.1747-1752
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• 2012

The SiOC film of carbon centered system was prepared using bistrimethylsilylmethane (BTMSM) and oxygen mixed precursor by the chemical vapor deposition. The dielectric constant is measured by MIS(metal/insulator/Si) structure, but it could decrease the reliability because the uniformity is not assured. To research the dielectric constant of SiOC film, the range of low polarization was researched in SiOC film using the optical analysis and hardness, and then calculated the dielectric constant of SiOC film with amorphous structure of high degree. After annealing, the dielectric constant of SiOC film was decreased owing to the lowering of polarization, and FTIR spectra of the main bond was shifted to higher wave number. The main bond of 950~1200 cm-1 was composed of the Si-C and Si-O bonds. The intensity increases in Si-O bond infers the bonding strength became stronger than that of deposited film. Annealed SiOC film showed 2.06 in dielectric constant.

• Journal of Environmental Science International
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• v.5 no.5
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• pp.569-577
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• 1996

pure compound chloromethanes; methyl chloride, methylene chloride, chloroform and The carbon tetrachloride were used as a model of chlorocarbon system with Cl/H ratio to investigate thermal stability and hydrodechlorination process of carbon tetrachloride under excess hydrogen atmosphere. The parent thermal stability on basis of temperature required for 99% destruction at 1 second no was evaluated as $875^{\circ}C$ for $CH_3Cl$, $780^{\circ}C$ for $CH_2Cl_2$, $675^{\circ}C$ for $CHCl_3$ and $635^{\circ}C$ for $CCl_4$. Chloroform was thermally less stable than $CCl_4$ at fairly low temperatures $(<570^{\circ}C).$ The lion of $CCl_4$ became more sensitive to increasing temperature, and $CCl_4$ was degraded CHCl3 at above $570^{\circ}C.$ The number and quantity of chlorinated products decreases with increasing temperature for the Product distribution of $CCl_4$ decomposition reaction system. Formation of non-chlorinated hydrocarbons such as $CH_4$, $C_2H_4$ and C_2H_6$ increased as the temperature rise and particularly small amount of methyl chloride was observed above $850^{\circ}C$ in $CC1_4$/$H_2$ reaction system. The less chlorinated products are more stable, with methyl chloride the most stable chlorocarbon in this reaction system.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.138-143
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• 2011

To investigate the electromagnetic interference shielding efficiency (EMI SE) property based on heat treatment effects of carbon fibers in various temperatures, the polyacrilonitrle-based carbon fibers were prepared by electrospinning method and treated at 1073, 1323, 1873 and 2573 K. The surface morphology of carbon fibers was investigated by using FE-SEM and the carbon crystallization was studied by Raman spectroscopy based on effects of reaction temperatures. The electrical conductivity was obtained by measuring the surface resistance with four probe method on carbon crystallization. The permittivity, permeability and EMI SE were investigated by using S-parameter in the range of 800~4500 MHz. In case of carbon fibers treated at 2573 K, the improved carbon crystallization was confirmed by Raman spectrum and the enhanced electrical conductivity showing 54.7 S/cm was also observed. The permittivity was dramatically improved by factor of 4 based on effect of high reaction temperature. Eventually, the highly improved EMI SE value was obtained showing around 41.7 dB.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.309-314
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• 2022

Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

• The Journal of the Korea Contents Association
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• v.14 no.2
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• pp.482-493
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• 2014

Many kinds of carbon emission monitoring systems or integrated systems have been developed so far. However, despite of the development of related techniques, they tend to be lack of statistic processing functions for feedback and policy-making data for users. In this study, a new CEMS (Carbon Emission Monitoring System) has been suggested and implemented in Sejong City, Korea. This system adapted automatic remote reading system from the site management agency as data hub to collect the electricity, gas and water usage of each household. The CEMS is consisted of 6 parts; carbon emission measurement, carbon emission standard setup and management, statistic analysis and the incentives. CEMS is distinguished with other systems for its UIs for users and the administrators. Also, data sharing with urban information system(UIS) of local government to produce information for users and policy-makers. This system makes it possible to investigate the change of energy consumption patterns, especially depending on the family structure and the housing characteristics. Furthermore, analyzing their correlation with carbon emission, it is expected to provide basic data used to establish urban environmental policies.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.4
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• pp.477-486
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• 1986

본 연구에서는 SM20C를 모재로 하여 입경의 크기가 다른 3종의 복합조직강을 제작 동일한 분위기에서 저 및 고사이클 전영역에 걸쳐 피로특성을 검토하고져 한다. 제일보는 그 중 저사이클특성에 대한 보고이다. 일반적으로 저사이클 피로현상은 재 료가 탄소성 상태하에서 전위, 미소크랙, 보이드(void) 등의 인자가 복합적으로 작용 하여 발생함으로 변형률속도, 제어파형, 온도, 시험방법 및 분위기에 따라 많은 영향 을 받는다. 따라서 본 연구에서는 두가지 실험방법을 사용, 응력-변형율거동을 검토 복합조직강의 피로특성과 입경크기가 피로거동 및 강도에 미치는 영향을 비교 고찰하 였다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.5
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• pp.564-571
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• 1985

The estimation of fracture toughness in inhomogeneous material is still insufficient because it is difficult to get information of fracture initiation at the crack tip. Therefore, martensite-ferrite dual phase steel was prepared for a model material and micro-fracture behavior was investigated in the region of pre-fatigue crack in order to understand the characteristic of fracture resistance in inhomogeneous materials. In the case of severely inhomogeneous state, micro-fracture appearance is not distributed homogenously so that the estimation of fracture toughness is hardly possible. On the other hand when the grain size is refined or the strength of martensite is lowered, micro-fracture appearance is distributed homogenously and fracture toughness remarkably increases.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.55.1-55.1
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• 2010

차세대 디스플레이용 전극 재료는 투명하면서도 낮은 저항값을 가져야 하는 투명 전극 재료로 금속, 금속산화물, 전도성 고분자, 탄소재료 등을 들 수 있다. 금속재료는 전도도는 우수하지만, 낮은 투과도로 투명전극 재료로 적절하지 않고, 대표적인 금속산화물 재료인 indium tin oxide (ITO)의 경우, 우수한 투과성과 낮은 면저항을 기반으로 차세대 디스플레이용 전극으로 현재 사용되고 있다. 하지만 ITO 박막은 휘거나 접을 때 기계적 안정성이 취약한 문제점을 나타내고 있다. 이러한 문제점을 극복하기 위해 전도성과 탄성계수가 높고, 저온에서 대면적 공정이 가능한 CNT을 투명 박막 전극 연구가 활발히 진행되고 있다. 하지만 투명전극 제조시, 탄소 나노튜브 간의 van der waals 인력에 의한 응집 현상으로 인한 분산의 불안정성과 분산제 사용으로 인하여 탄소 나노튜브 박막전극의 전기적, 광학적 특성이 저하를 야기한다. 이에 본 실험에서는 아크 방전 공정으로 합성한 SWCNT 분산액을 사용하여 spray coating 방법으로 glass 위에 박막을 형성하였다. SWCNT 투명 박막 전극 위에 DC sputtering을 이용하여 얇은Ni를 도포한 후, $450{\sim}500^{\circ}C$, ethylene gas 분위기의 thermal CVD방법으로 Carbon NanoFibers (CNFs)를 생성시킴과 동시에 분산제를 burning out하였다. CNF 성장 전후의 투명 박막의 전기적 특성은 four point probe를 이용하여 면저항과 UV-vis 장비를 이용하여 가시광선 영역에서의 광학적 투과도를 측정 비교하였다.

• Tunnel and Underground Space
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• v.19 no.6
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• pp.498-506
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• 2009

The stability assessment of a concrete liner of a compressed air storage tunnel should be performed by an approach which is different from that commonly used for the liners of road tunnels, since the liner is exposed to high air pressure. In this study, the stability analysis method for the liner of compressed air storage tunnel is proposed based on the elastic and elasto-plastic solutions of the thick-walled cylinder problem. In case of elastic analysis, the yield initiation condition at the inner boundary is considered as the failure condition of the liner, while the condition which results in the extension of yielding zone to a certain depth is taken as a failure indicator of the liner in the elasto-plastic analysis taking Mohr-Coulomb criterion. The application of the proposed method revealed that the influence of the relative magnitude of boundary loads on the stability of liner is considerable. In particular, noting that the estimation of the outer boundary load may be relatively difficult, it is thought that the precise prediction of outer boundary load is very important in the analysis. Accordingly, the emphasis is put on the selection of the liner installation time, which may govern the magnitude of outer boundary load.