• Title/Summary/Keyword: 탄소성 영역

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Hydrochemistry and Origin of Noble Gases and $CO_2$ Gas Within Carbonated Mineral Waters in the Kyeoungbuk-Kangwon Province, Korea (경북-강원일대 탄산약수의 수질화학과 탄산 및 영족기체 기원)

  • Jeong, Chan-Ho;Yoo, Sang-Woo;Kim, Kyu-Han;Nagao, Keisuke
    • The Journal of Engineering Geology
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    • v.21 no.1
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    • pp.65-77
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    • 2011
  • Hydrochemical and carbon isotopic (${\delta}^{13}C_{DIC}$) analyses of 11 water samples, and noble gas isotopic analyses of 8 water samples collected in the Kyeoungbuk and Kangwon areas of Korea were performed to determine their hydrochemical characteristics and to interpret the source of noble gases and $CO_2$ gas in the water. The carbonated mineral waters are weakly acidic (PH = 5.59-6.04), and electrical conductivity ranges from 302 to $864\;{\mu}S/cm$. The chemical composition of all the water samples is Ca-$HCO_3$ type. The high contents of Fe and Mn exceed the safe limits for drinking water. The ${\delta}^{13}C_{DIC}$ values of the samples range from -5.30‰ to -2.84‰, indicating that the carbon is supplied mainly from a deep-seated source and to a lesser degree from an inorganic carbonate source. The $^3He/^4He$ ratios of the samples range from $1.51{\times}10^{-6}$ to $6.45{\times}10^{-6}$. The samples plot into three groups on a $^3He/^4He$ versus $^4He/^{20}Ne$ diagram: the deep-seated field (e.g., a mantle source), the atmospheric field, and the air-mantle mixing field. A wide range of $^4He/^{20}Ne$ ratios is observed ($0.036{\times}10^{-6}$ to $1.76{\times}10^{-6}$), indicating that while radiogenic $^4He$ is dominant in these water samples, mantle-origin He is also present. The supply of $CO_2$ gas and noble gases from a deep-seated source to carbonated waters is inferred to be controlled by geological structures such as faults and geological boundaries.

Modeling the Fate and Transport of Arsenic in Wetland Sediments (습지 퇴적물에서 비소의 성상과 이동 모의에 관한 수학적 모형)

  • Park, Seok-Soon;Wang, Soo-Kyun
    • Korean Journal of Ecology and Environment
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    • v.36 no.4 s.105
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    • pp.434-446
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    • 2003
  • The fate and transport of many trace metals, metalloids, and radionuclides in porous media is closely linked to the biogeochemical reactions that occur as a result of organic carbon being sequentially degraded by different microorganisms using a series of terminal electron acceptors. The spatial distribution of these biogeochemical reactions is affected by processes that are often unique and/or characteristic to a specific environment. Generic model formulations have been developed and applied to simulate the fate and transport of arsenic in two hydrologic settings, permanently flooded freshwater sediments, namely non-vegetated wetland sediments and vegetated wetland sediments. The key physical processes that have been considered are sedimentation, effects of roots on biogeochemistry, advective transport, and differences in mixing processes. Steady-state formulations were applied to the sedimentary environments. Results of numerical simulations show that these physical processes significantly affect the chemical profiles of different electron acceptors, their reduced species, and arsenate as well as arsenite that will result from the degradation of an organic carbon source in the sediments. Even though specific biological transformations are allowed to proceed only in zones where they are thermodynamically favorable, the results show that mixing as well as abiotic reactions can make the profiles of individual electron acceptors overlap and/or appear to reverse their expected order.

Flexural Strength of HSB Steel Girders Due to Inelastic Lateral-Torsional Buckling - Sections with Slender Web (HSB 강거더의 비탄성 횡비틂좌굴에 의한 휨강도 - 세장 복부판 단면)

  • Cho, Eun-Young;Shin, Dong-Ku
    • Journal of Korean Society of Steel Construction
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    • v.24 no.2
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    • pp.217-231
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    • 2012
  • The flexural behavior of HSB I-girder with a non-slender web attributed to inelastic lateral-torsional buckling under uniform bending was investigated using nonlinear finite element analysis of ABAQUS. The girder was assumed to have a compact or noncompact web in order to prevent premature bend-buckling of the web. The unbraced length of the girder was selected so that inelastic lateral-torsional buckling governs the ultimate flexural strength. The compression flange was also assumed to be either compact or noncompact to prevent local buckling of the elastic flange. Both homogeneous sections fabricated from HSB600 or HSB800 steel and hybrid sections with HSB800 flanges and SM570-TMC web were considered. In the FE analysis, the flanges and web of I-girder were modeled as thin shell elements. Initial imperfections and residual stresses were imposed on the FE model. An elasto-plastic strain hardening material was assumed for steel. After establishing the validity of the present FE analysis by comparing FE results with test results in existing literature, the effects of initial imperfection and residual stress on the inelastic lateral-torsional buckling behavior were analyzed. Finite element analysis results for 96 sections demonstrated that the current inelastic strength equations for the compression flange in AASHTO LTFD can be applied to predict the inelastic lateral torsional buckling strength of homogeneous and hybrid HSB I-girders with a non-slender web.

Hierarchical Finite-Element Modeling of SiCp/Al2124-T4 Composites with Dislocation Plasticity and Size-Dependent Failure (전위 소성과 크기 종속 파손을 고려한 SiCp/Al2124-T4 복합재의 계층적 유한요소 모델링)

  • Suh, Yeong-Sung;Kim, Yong-Bae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.2
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    • pp.187-194
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    • 2012
  • The strength of particle-reinforced metal matrix composites is, in general, known to be increased by the geometrically necessary dislocations punched around a particle that form during cooling after consolidation because of coefficient of thermal expansion (CTE) mismatch between the particle and the matrix. An additional strength increase may also be observed, since another type of geometrically necessary dislocation can be formed during extensive deformation as a result of the strain gradient plasticity due to the elastic-plastic mismatch between the particle and the matrix. In this paper, the magnitudes of these two types of dislocations are calculated based on the dislocation plasticity. The dislocations are then converted to the respective strengths and allocated hierarchically to the matrix around the particle in the axisymmetric finite-element unit cell model. The proposed method is shown to be very effective by performing finite-element strength analysis of $SiC_p$/Al2124-T4 composites that included ductile failure in the matrix and particlematrix decohesion. The predicted results for different particle sizes and volume fractions show that the length scale effect of the particle size obviously affects the strength and failure behavior of the particle-reinforced metal matrix composites.

Parametric Study of Dynamic Soil-pile-structure Interaction in Dry Sand by 3D Numerical Model (3차원 수치 모델을 이용한 건조사질토 지반-말뚝-구조물 동적 상호작용의 매개변수 연구)

  • Kwon, Sun-Yong;Yoo, Min-Taek
    • Journal of the Korean Geotechnical Society
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    • v.32 no.9
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    • pp.51-62
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    • 2016
  • Parametric studies for various site conditions by using 3d numerical model were carried out in order to estimate dynamic behavior of soil-pile-structure system in dry soil deposits. Proposed model was analyzed in time domain using FLAC3D which is commercial finite difference code to properly simulate nonlinear response of soil under strong earthquake. Mohr-Coulomb criterion was adopted as soil constitutive model. Soil nonlinearity was considered by adopting the hysteretic damping model, and an interface model which can simulate separation and slip between soil and pile was adopted. Simplified continuum modeling was used as boundary condition to reduce analysis time. Also, initial shear modulus and yield depth were appropriately determined for accurate simulation of system's nonlinear behavior. Parametric study was performed by varying weight of superstructure, pile length, pile head fixity, soil relative density with proposed numerical model. From the results of parametric study, it is identified that inertial force induced by superstructure is dominant on dynamic behavior of soil-pile-structure system and effect of kinematic force induced by soil movement was relatively small. Difference in dynamic behavior according to the pile length and pile head fixity was also numerically investigated.

Isolation of Mutant Strains from Keratinase Producing Bacillus subtilis SMMJ-2 and Comparision of Their Enzymatic Properties (Keratinase 생산균 Bacillus subtilis SMMJ-2의 변이주 분리와 효소학적 특성 비교)

  • Ko, Hee-Sun;Kim, Hyun-Soo
    • KSBB Journal
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    • v.25 no.5
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    • pp.429-436
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    • 2010
  • Keratinase is widely used in certain industrial applications. The present study sought to improve the culture conditions of Bacillus subtilis SMMJ-2 to facilitate mass production of keratinase. Strain SMMJ-2 was irradiated by ultraviolet light and the resulting isolates were tested for keratinase activity. Isolates displaying elevated keratinase activity were selected and used to determine the optimum temperature (24, 30, 37, 45, $55^{\circ}C$) for bacterial keratinase production during a 4 day incubation period. The highest enzyme activity (55 units/mL/min), from a Bacillus subtilis SMMJ-2 mutant (mutant No. 2) was demonstrated following incubation at $30^{\circ}C$. The effects of carbon and nitrogen sources on keratinase production were confirmed by measuring the enzyme activity from the culture broth of the mutant strain cultured in various media containing different carbon source and nitrogen sources during a 4 day period. The optimal medium composition for producing keratinase consisted of 1% glucose, 0.7% $K_2HPO_4$, 0.2% $K_2HPO_4$, and 1.2% soybean meal. Optimal initial pH and temperature for producing keratinase were 7.0 and $30^{\circ}C$, respectively. Keratinases produced by B. subtilis SMMJ-2 and the mutant No. 2 were purified from the culture broth which used soybean meal as a nitrogen source. Membrane ultrafiltration, DEAE-sephacel ion exchange and Sephadex G-100 gel chromatography were used to purify the enzymes. The purified keratinases from both B. subtilis SMMJ-2 and the mutant No. 2 showed single bands and their molecular weights were estimated as 28 kDa and 42 kDa, respectively on SDS-polyacrylamide gel electrophoresis.

Numerical Study of Combustion Characteristics by Pressure and Oxygen Concentration in Counter-Flow Diffusion Flame Model (대향류 확산 화염 모델에서의 압력 및 산소분율에 따른 연소 특성 변화에 관한 수치해석 연구)

  • Park, Jinje;Lee, Youngjae
    • Clean Technology
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    • v.27 no.1
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    • pp.93-103
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    • 2021
  • As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

Calibration of δ13C values of CO2 gas with different concentrations in the analysis with Laser Absorption Spectrometry (레이저흡광분석기(Laser Absorption Spectrometry)를 이용한 CO2가스의 탄소안정동위원소비 보정식 산출)

  • Jeong, Taeyang;Woo, Nam C.;Shin, Woo-Jin;Bong, Yeon-Sik;Choi, Seunghyun;Kim, Youn-Tae
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.537-544
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    • 2017
  • Stable carbon isotope ratio of carbon dioxide (${\delta}^{13}C_{CO2}$) is used as an important indicator in the researches for global climate change and carbon capture and sequestration technology. The ${\delta}^{13}C$ value has been usually analyzed with Isotope Ratio Mass Spectrometer (IRMS). Recently, the use of Laser Absorption Spectrometry (LAS) is increasing because of the cost efficiency and field applicability. The purpose of this study was to suggest practical procedures to prepare laboratory reference gases for ${\delta}^{13}C_{CO2}$ analysis using LAS. $CO_2$ gas was adjusted to have the concentrations within the analytical range. Then, the concentration of $CO_2$ was assessed in a lab approved by the Korea Laboratory Accreditation Scheme and the ${\delta}^{13}C_{CO2}$ value was measured by IRMS. When the instrument ran over 12 hours, the ${\delta}^{13}C$ values were drifted up to ${\pm}10$‰ if the concentration of $CO_2$ was shifted up to 1.0% of relative standard deviation. Therefore, periodical investigation of analytical suitability and correction should be conducted. Because ${\delta}^{13}C_{CO2}$ showed the dependency on $CO_2$ concentration, we suggested the equation for calibrating the concentration effect. After calibration, ${\delta}^{13}C_{CO2}$ was well matched with the result of IRMS within ${\pm}0.52$‰.

Cellulose degrading basidiomycetes yeast isolated from the gut of grasshopper in Korea (한국의 메뚜기의 장에서 분리된 Cellulose를 분해하는 담자균 효모)

  • Kim, Ju-Young;Jang, Jun Hwee;Park, Ji-Hyun;Jung, Hee-Young;Park, Jong-Seok;Cho, Sung-Jin;Lee, Hoon Bok;Limtong, Savitree;Subramani, Gayathri;Sung, Gi-Ho;Kim, Myung Kyum
    • Korean Journal of Microbiology
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    • v.54 no.4
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    • pp.362-368
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    • 2018
  • Grasshoppers play vital role in the digestion of photosynthetically fixed carbons. With the aid of intestinal microflora, the grasshopper can degrade leaves constituents such as cellulose and hemicellulose. The purpose of this study was to examine cellulolytic yeast isolates from the gut of grasshoppers collected in Gyeonggi Province, South Korea. Among the yeast isolates, ON2, ON17 (two strains), and ON6 (one strain) showed positive cellulolytic activity in the CMC-plate assay. The sequence analyses of D1/D2 domains of the large subunit rDNA gene and the internal transcribed spacer (ITS) regions revealed that the strains ON2 and ON17 were most closely related to Papiliotrema aspenensis CBS $13867^T$ (100%, sequence similarity in D1/D2 domains; 99.4% sequence similarity in ITS) and strain ON6 related to Saitozyma flava (100% in D1/D2 domains; 99.0% in ITS). All these three yeast strains are capable of degrading cellulose; therefore, the members of endosymbiotic yeasts may produce their own enzymes for carbohydrate degradation and convert mobilized sugar monomers to volatile fatty acids. Thus, the endosymbiotic yeast strains ON2, ON17 (represents the genus Papilioterma) and ON6 (Saitozyma) belonging to the family Tremellomycetes, are unreported strains in Korea.

Evaluating the Economic Feasibility of Green Construction Projects using FiT and CDM Support Mechanisms (녹색 건설 사업의 FiT 및 CDM 보조방안에 의한 수익성 향상 분석에 관한 연구)

  • Koo, Bonsang
    • Korean Journal of Construction Engineering and Management
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    • v.14 no.3
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    • pp.123-133
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    • 2013
  • Green infrastructure projects have the potential to reduce global warming and deliver sustainable energy solutions. Recently, the construction industry has been expanding their portfolios in New and Renewable (NRE) projects. However, the economic feasibility of NRE projects have not been validated and construction companies are not acquainted with their associated risks. This research performed a two-tiered feasibility study of the domestic projects registered for CDM in the UNFCCC. The first phase involved calculating the average IRR and NPV of the domestic CDM projects, which showed that their profitability to be very low. In the second phase, four NRE projects (Solar, Wind, Hydro, Landfill Gas) were selected and additional income generated from Feed-in-Tariff and CER sales were added to determine the improvements in the projects' IRR and NPV. Results indicate that Solar and Landfill Gas projects benefited the most from the two support mechanisms, while benefits to Wind and Hydro projects were minimal. While the Landfill Gas project had the highest IRR, the Wind project was the most investment attractive due to its NPV and minimal dependency on FiT and CER sales. Construction companies should enter into NRE projects with a long term view as related technologies mature.