• Applied Chemistry for Engineering
• /
• v.27 no.5
• /
• pp.472-477
• /
• 2016

We studied the effects of anodic oxidation treatments of carbon fibers on interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites with various current densities. The surface of treated carbon fibers was characterized by atomic force microscope (AFM), field emission-scanning electron microscope (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The interlaminar shear strength (ILSS) of the composites was determined by a short beam shear test. This result showed that both the roughness and oxygen group of the carbon fibers surface increased in proportion to the current density. After anodic-oxidation-treated, the ILSS also increased as a function of the current density. In addition, the proportional relationship between ILSS and phenolic hydroxyl group was confirmed. The ILSS of the CF-2.0 sample increased by 4% compared to that of the CF-AS sample, because the anodic oxidation treatment increased the oxygen group and roughness on the carbon fibers surface, which leading to the improvement of the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites. Among these, the phenolic hydroxyl group which has the proportional relationship with ILSS is found to be the most important factor for improving the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites.

• Proceedings of the Korean Society of Fisheries Technology Conference
• /
• 2003.10a
• /
• pp.39-42
• /
• 2003

최근에 널리 쓰이고 있는 섬유강화 복합재료는 플라스틱 재료가 갖고 있는 가공성의 장점을 충분히 발휘한 재료로서 모재인 수지와 강화재인 강화섬유로 구성되며 사용된 섬유의 종류에 따라 유리섬유강화플라스틱(GFRP : glass fiber reinforced plastic)과 탄소섬유강화플라스틱(CFRP : carbon fiber reinforced plastic)으로 구분된다. 이 두 복합재료가 건설, 선박, 자동차 그리고 우주항공분야에 이르기까지 거의 모든 산업에서 다양하게 이용되고 있다. (중략)

• Journal of the Korean Society for Railway
• /
• v.11 no.4
• /
• pp.357-363
• /
• 2008

This study investigates the durability of carbon/epoxy composites for use on train car bodies under a salt water spray environment. Salt water solution with 5% NaCl, similar to natural salt water, was used for the salt water environmental tests. The specimens were obtained from a composite panel consisting of an epoxy matrix reinforced with T700 carbon fabric. The specimens were exposed to the salt water environment for up to 12 months. Mechanical tests were performed to obtain tensile properties, flexural properties, and shear properties. Dynamic mechanical analysis was used to measure such thermal properties as storage modulus, loss modulus, and tan $\delta$. Also FT/IR tests were conducted to investigate changes in chemical structure with exposure. The results revealed that fiber-dominated mechanical properties were not affected much by exposure time, but matrix-dominated mechanical properties decreased with increasing exposure time. Storage modulus was not very sensitive to exposure time, but glass transition temperature was affected, slightly decreasing with increasing exposure time. Although the peak intensity of FT/IR curves was affected slightly by exposure time, the peak shape and peak location of FT/IR curves were not noticeably changed. Carbon/epoxy composites used for this study were relatively stable to the salt water environment.

• Composites Research
• /
• v.33 no.6
• /
• pp.341-345
• /
• 2020

We propose a measurement method for evaluating constituent contents of carbon fiber/epoxy composites through a thermogravimetric analyzer (TGA). The sample used in the test was taken from a strand specimen made of carbon fiber/epoxy tow prepreg, and the change in weight of the sample over time was measured in real time. Using a field emission scanning electron microscope (FE-SEM), we examine the thermal damage condition of the carbon fiber depending on whether resin was removed or not. We find that it was possible to test even a small amount of sample when using TGA vis-à-vis using a conventional muffle furnace. In addition, TGA enables the temperature and exposure time to be controlled, allowing the constituent contents of composite materials to be efficiently and quantitatively evaluated.

• Polymer(Korea)
• /
• v.24 no.2
• /
• pp.237-244
• /
• 2000

Phenolic resin used as a precursor of carbonized matrix for carbon-carbon composites was modified by addition of molybdenum disilicide (MoSi$_2$) in various concentrations of 0, 4, 12 and 20% by weight to improve the anti-oxidation properties of the composites. The green body was manufactured by a prepreg method and was submitted to carbonization up to 110$0^{\circ}C$. In this work, the oxidation behavior of carbon-carbon composites with MoSi$_2$ as an oxidation inhibitor was investigated at the temperature range of 600-100$0^{\circ}C$ in an air environment. The carbon-carbon composites with MoSi$_2$ showed a significantly improved oxidation resistance due to both the reduction of the porosity formation and the formation of mobile diffusion barrier for oxygen when compared to those without MoSi$_2$. Carbon active sites should be blocked, decreasing the oxidation rate of carbon. This is probably due to the effect of the inherent MoSi$_2$ properties, resulted from a formation of the protective layer against oxygen attack in the composites studied.

• Composites Research
• /
• v.16 no.3
• /
• pp.41-48
• /
• 2003

In this work, the effect of molybdenum disilicide(MoSi$_2$) content on the impact properties of carbon-carbon composites(C/C composites) was investigated in the presence of MoSi$_2$. The content of MoSi$_2$ was varied in 0, 4, 12 and 20 wt% on the basis of resin matrix for anti-oxidation properties of the composites under high temperature. As a result, the composites made with MoSi$_2$ resulted in an increase of interfacial adhesion between fibers and matrix, which could improve the impact properties of the composites. Especially, 12 wt% Mosi$_2$ composites showed the highest impact properties in the present system. This was probably due to the existence of brittle-to-ductile transition(BDT) properties of MoSi$_2$ in the vicinity of 90$0^{\circ}C$, resulting from increasing the interfacial adhesion force among fibers, filler, and matrix in the composites.

• Composites Research
• /
• v.35 no.4
• /
• pp.242-247
• /
• 2022

This study has a different direction from the existing technology of applying recycled carbon fiber obtained by recycling waste CFRP to CFRP again. A study was conducted to utilize recycled carbon fiber as a raw material for manufacturing a carbon/carbon (C/C) composite material comprising carbon as a matrix. First, it was attempted to recycle a commonly used epoxy resin composite material through a thermal decomposition process. By applying the newly proposed oxidation-inert atmosphere conversion technology to the pyrolysis process, the residual carbon rate of 1~2% was improved to 19%. Through this, the possibility of manufacturing C/C composite materials utilizing epoxy resin was confirmed. However, in the case of carbon obtained by the oxidation-inert atmosphere controlled pyrolysis process, the degree of oxygen bonding is high, so further improvement studies are needed. In addition, short-fiber C/C composite material specimens were prepared through the crushing and disintegrating processes after thermal decomposition of waste CFRP, and the optimum process conditions were derived through the evaluation of mechanical properties.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.16 no.6
• /
• pp.81-86
• /
• 2017

The high-pressure resin transfer molding (HP-RTM) process has a very effective for the mass production of carbon fiber reinforced plastic (CFRP) for light weight in the automotive industry. In developing robust equipment, new process and fast cure matrix systems reduces significantly the cycle time less than 5 minutes in recent years. This paper describes the cavity pressure, temperature and molding characteristics of the HP-RTM process. The HP-RTM mold was equipped with two cavity pressure sensors and three temperature sensors. The cavity pressure characteristics of the HP-RTM injection, pressurization, and curing processes were studied. This experiment was conducted with selected process parameters such as mold cap size, maximum press force, and injection volume. Consequently, this monitoring method provides correlations between the selected process parameters and final forming characteristics in this work.

• Composites Research
• /
• v.37 no.2
• /
• pp.68-75
• /
• 2024

Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

• Polymer(Korea)
• /
• v.26 no.6
• /
• pp.718-727
• /
• 2002

In this work, an Ar+ beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method h single fiber pull-out test was executed to investigate the basic characteristics of the single Carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy as a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.