• Title/Summary/Keyword: 탄소미립자

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On the two phase detonation in carbon laden oxygen : taking into account of inner particle temperature distribution (입자온도 분포를 고려한 탄소입자와 산소에서의 이상폭발현상에 관한 연구)

  • 승성표;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.5
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    • pp.1104-1112
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    • 1988
  • In this study the structure of a two phase detonation has been numerically investigated through the assumption of a steady and one-dimensional flow in the suspension of carbon particles and pure oxygen. The bow shock formation in front of carbon particles has been taken into consideration when the relative velocity of gas flow with respect to the particle exceeds the local speed of sound. But its effect was found to be very limited to the induction zone only. Furthermore the interior particle temperature distribution has been considered in this work. It was found that the inner temperature gradient was very steep in the region of high relative velocity. On the while the temperature distribution inside the particle was almost uniform in the region of low relative velocity. Overall, the effect of the interior particle temperature distribution has been significant in the two phase detonation.

The Origin and Characteristics of Sedimentary Organic Matter on Sindu-ri Tidal Flat, Korea (신두리 갯벌 퇴적 유기물의 기원과 특성)

  • Shin, Woo Seok
    • Journal of Wetlands Research
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    • v.22 no.2
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    • pp.59-65
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    • 2020
  • The purpose of this study is to determine the origin of organic matter on sediment at Sindu-ri tidal flat. Grain size, organic matter, C/N ratio and the 13C and δ15N ratio were measured at three stations (Stn. A, B, C) of the tidal flat. As a result, the spatial variation in sediment properties showed that organic matter was related positively to the sediment mud content. Organic matters originating from marine particulate organic matter (marine POM) and fish farm particulate organic matter (fish farm POM) showed sedimentation of organic matters at Stn. A, sandy tidal flat, though terrestial plant (TP) and benthic microalgae (BMA) did at Stn.C, muddy tidal flat. Meanwhile, Stn. B, the intermediate property of Stn. A and C, was affected by marine POM and BMA. Furthermore, it was revealed that the amount and origin of organic matters in the sediments depended on spatial variation, and the factors were different from the stations. Particularly, at the Stn. C, the sediment showed high concentration of TOC in terrestrial organic matter and smaller size particles (< 63 ㎛). These facts suggest the many small size particles and organic matter will affect the sediment environmental condition in the Stn. C.

Effect of Agitation Speed and Air Rate on Separation Efficiency in Fly Ash Flotation (플라이애시 부유선별 과정에서 교반속도와 공기주입량 변화에 따른 영향 연구)

  • Kim, Min Sik;Kang, Heon Chan
    • Resources Recycling
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    • v.27 no.1
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    • pp.45-54
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    • 2018
  • This study aimed to investigate the effects of mechanical factors such as agitation speed and air rate in fly ash flotation. Specifically, we used thermal power plant fly ash with unburned carbon content of 3.4 to 3.7%. The effect of pH, agitation speed, collector dosage, and frother dosage - the key factors of froth flotation - showed unburned carbon recovery and unburned carbon content of 63% and 34%, respectively, when the dosage of safflower oil used as collector was 800 g/ton, pH was 7, agitation speed was 1,200 rpm, and frother dosage was 400 g/ton. The SEM/EDS analysis of fly ash in that case indicated that the spherical fly ash particles lowered the unburned carbon content as they floated with the air bubbles without being dissolved in the unburned carbon or settled in the ore solution. The other experiment of changing the mechanical factors such as agitation speed and air rate resulted in unburned carbon recovery and unburned carbon content of 74% and 67%, respectively, at air rate of 8 L/min and agitation speed of 900 rpm. The recovery and unburned carbon content increased as the low agitation speed and additional air injection decreased the strength of the eddy current in the ore solution and consequently prevented the floating of fine fly ash particles with unburned carbon. In addition, the recovery rate and unburned carbon increased further to 80% and 70%, respectively, showing the best performance when the agitation speed and air rate were lowered to 800 rpm and 6 L/min, respectively.

Numerical Study on the Effect of Changes of Geometric Shape of Diesel Particulate Filter on Light-Off Characteristics and Transient Thermal Behavior during Regeneration (디젤입자상물질필터의 기하학적 형상변화가 재생과정 중 활성화 특성 및 비정상 온도거동에 미치는 영향에 관한 수치적 연구)

  • Jeong, Soo-Jin;Lee, Sang-Jin;Kim, Woo-Seung;Lee, Chun-Beom
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.4
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    • pp.68-76
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    • 2006
  • The minimization of maximum DPF wall temperature and the fast Light-off during regeneration are the targets for the high durability of the DPF system and the high efficiency of regeneration. In order to predict transient thermal response of DPF, one-channel numerical modeling has been adopted. The effect of the ratio of length to diameter(L/D), cell density, the amount of soot loading on temporal thermal response and regeneration characteristics has been numerically investigated under two different running conditions: city driving mode and high speed mode. The results indicate that the maximum wall temperature of DPF increase with increasing 'L/D' in 'High speed mode'. For 'City driving mode', the maximum wall temperature decreases with increasing 'L/D' in the range of $'L/D{\geq}0.6'$. The maximum temperature decreases with increasing cell density because heat conduction and heat capacity are increased. It is also found that the effect of amount of soot loading on light-off time is negligible.

Flotation for Improving Grade of Domestic Fine Coal (국내산(國內産) 미립(微粒) 석탄(石炭)의 품위향상(品位向上)을 위한 부유선별(浮遊選別) 연구(硏究))

  • Han, Oh-Hyung;Kim, Min-Gyu;Kim, Byoung-Gon
    • Resources Recycling
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    • v.22 no.6
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    • pp.64-72
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    • 2013
  • The purpose of this study is to confirm the possibility of obtaining high grade coal from 57.39% of fixed carbon fine coal. Also, the mineralogical, physical/chemical and liberation characteristics are to be identified to decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and CPT column flotation proper for the processing of fine particles were used with the variation in kinds and quantity of frother, collector and depressant. Also air flow rate and feeding rates were examined. As a result of batch flotation using 20% of pulp density DMU 101 collector(100 mL/ton), AF65 frother(300 mL/ton), sodium metaphosphate depressant (1 kg/ton), 67.57% of ash rejection and 70.90% of combustible recovery were obtained. The result of CPT column flotation was 85.59% of ash rejection and 88.97% of combustible recovery under the conditions of 5% of pulp density, DMU-101 collector (100 mL/ton), AF65 frother(10 L/ton), SMP depressant(1 kg/ton), wash water(100 mL/min.) and air flow rate(1,200 mL/min.).

Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo Type Surfactants(Parts 1)-Dispersion of Phthalocyanine or Carbon Black- (올리고머형 음이온성 계면활성제 수용액에서 안료의 분산성(제1보) - Phthalocyanine이나 Carbon Black의 분산 -)

  • Lee, H.W.;Yun, Y.K.;Park, H.Ch.;Nam, K.D.
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.1-5
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    • 1998
  • The dispersing behaviors of oligomer-type anionic surfactants, cooligomers of diethyl maleate(CmD-Na) or maleic anhydride (CmM-Na) and $C_4{\sim}C_{16}$ alkyl vinylether, which have a different alkyl chain length of the hydrophobic group or degree of polymerization, were studied on the aqueous suspension of ${\alpha}-$ and ${\beta}-$ copper phthalocyanine and carbon black particles. In case of the side alkyl chain length of $C_4{\sim}C_{10}$ of CmD-Na, the dispersing actions were good in the concentration range of 0.01 to 0.1%. Especially, side alkyl groups played an important role in the orientation adsorption on the surface of pigment particles, and oligomers having smaller degrees of polymerization were more effective in the dispersing action, but did not affect the dispersability of carbon black.

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Inorganic-organic nano-hybrid; Preparation of Nano-sized TiO$_2$ Paste Trapped OMC Nano-emulsion and it's Application for Cosmetics (OMC Nano-emulsion을 포집하고 있는 Nano-TiO$_2$-Paste의 합성과 화장품의 응용)

  • Byung Gyu, Park;Jong Heon, Kim;Jin Hee, Im;Kyoung Chul, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.181-187
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    • 2004
  • Preparations of mesoporous materials using various templates and their applicability have been intensively investigated for many years. We studied on synthesizing mesoporous Ti02 with pores in which sensitive compounds having weak physico-chemical properties such as thermal or UV irradiation and low solubility in solvent are trapped. Prior to trapping OMC in the pores of mesoporous titania, OMC was nano-emulsified in O/W system using Lecithin. Thereafter the OMC was trapped in the pores of mesoporous titania using sol-gel method. Main focus of this work is to prepare OMC-trapped mesoporous titania and to trace the stability and solubility of nano-emulsified OMC in the pores of mesoporous titania, and compared with that of mesoporous silica. OMC-trapped mesoporous Inorganic-Organic hybrid titania showed higher factors in sun protecting and a skin penetration phenomenon was reduced.

The Extraction of Manganese from the Medium-Low Carbon Ferromanganese Dust with Nitric Acid (질산에 의한 중.저탄소페로망간제조분진에 함유된 망간의 침출)

  • 이계승;한기천;송영준;신강호;조동성
    • Resources Recycling
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    • v.9 no.1
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    • pp.21-26
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    • 2000
  • Extraction of manganese was investigated with nitric acid from the dust which was generated in the AOD process producing a medium-low carbon ferromanganese from a high carbon ferromanganese. Content of manganese oxide in the dust was about 90%, and phase of it was confirmed as $Mn_3O_4$, The $Mn_3O_4$ particles was agglomerated as spherical shape, and had a lot of pore and crack inside. Maximum recovery of Mn from the sample in the leaching step was about 67% and residue was the amorphous $MnO_2$. The extraction of Mn increased with increasing temperature, but decreased in proportion to concentration of nitric acid. The extraction rate was in good agreement with the pore diffusion model.

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Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(Parts 2) - Dispersion of Red Iron Oxide or Titanium Dioxide - (올리고머형 음이온성 계면활성제 수용액에서 안료의 분산안정성(제2보) - 산화철이나 산화티티늄의 분산 -)

  • Lee, Hyang Woo;Lee, Jin Hee;Park, Heung Joe;Nam, Ki Dae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.1-5
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    • 1999
  • The dispersing performance of oligomer-type anionic surfactants ($C_mD-Na$), cooligomers of diethylester maleate and alkylvinylether of different alkyl chain lengths or polymerization degree were studied on the aqueous suspension of iron dxide or titanium dioxide particles which are hydrophilic pigments. The dispersion behavior of oligomer-type surfactants for these dispersoids, although anion charges on the surface of pigments particles showed different dispersing properties, was dependent upon the side alkyl chain length. Oligomer-type surfactants having more than $C_8$ side alkyl chain exhibited large dispersing action for relatively hydrophobic ${\alpha}-Fe_2O_3$ and Anatase $TiO_2$ in the concentration range of more than 0.1% oligomer-type surfactant solutions.

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Electrochemical Properties of Using MnO2-HCS Composite for Supercapacitor (MnO2-HCS 복합체를 이용한 슈퍼커패시터의 전기화학적 특성)

  • Jin, En Mei;Jeong, Sang Mun
    • Clean Technology
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    • v.24 no.3
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    • pp.183-189
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    • 2018
  • Hollow carbon spheres (HCS) and carbon spheres (CS) were prepared by a hydrothermal reaction and they were introduced as a substrate for the deposition of $MnO_2$ nanoparticles. The $MnO_2$ nanoparticles were deposited on the carbon surface by a chemical redox deposition method. After deposition, the $MnO_2$ nanoparticles were uniformally distributed on the carbon surface in a slit-shape, and sparse $MnO_2$ slits appeared on the HCS surface. The $MnO_2-HCS$ showed an initial specific capacitance of $164.1F\;g^{-1}$ at scan rate of $20mv\;s^{-1}$, and after 1,000 cycles, the specific capacitance was maintained to $141.3F\;g^{-1}$. The capacity retention of $MnO_2-HCS$ and $MnO_2-CS$ were calculated to 86% and 78% in the cycle performance test up to 1,000 cycles, respectively. $MnO_2-HCS$ showed a good cycle stability due to the mesoporous hollow structure which can cause a faster diffusion of the electrolyte and can easily adsorb and desorb $Na^+$ ions on the surface of the electrode.