• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.1
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• pp.18-24
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• 2016

Mineral carbonation is a technology for permanently storing carbon dioxide by reacting with metal oxides containing calcium and magnesium. In this study, we used sea water and alkaline industrial by-product such as paper sludge ash (PSA) for the storage of carbon dioxide through direct carbonation. We found the optimum conditions of both sea water content (mixing ratio of sea water and PSA) and reaction time required in the direct carbonation through various experiments using sea water and PSA. In addition, we compared the amounts of carbon dioxide storage with the cases when sea water and ultra-pure water were separately used as solvents in the direct carbonation with PSA. The amount of carbon dioxide storage was calculated by using both solid weight increase through the carbonation reaction and the contents of carbonate salts from thermal gravimetric analysis. PSA particle used in this study contained 67.2% of calcium. The optimum sea water content and reaction time in the carbonation reaction using sea water and PSA were 5 mL/g and 2 hours, respectively, under the conditions of 0.05 L/min flow rate of carbon dioxide injected at $25^{\circ}C$ and 1 atm. The amounts of carbon dioxide stored when sea water and ultra-pure water were separately used as solvents in the direct carbonation with PSA were 113 and $101kg\;CO_2/(ton\;PSA)$, respectively. The solid obtained through the carbonation reaction using sea water and PSA was composed of mainly calcium carbonate in the form of calcite and a small amount of magnesium carbonate. The solid obtained by using ultra-pure water, also, was found to be carbonate salt in the form of calcite.

• Resources Recycling
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• v.29 no.6
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• pp.27-34
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• 2020

In order to remove sulfate(SO42-) and purify the Li2CO3, dissolution and recrystallization of crude Li2CO3 using distilled water and HCl solution was performed. When Li2CO3 was dissolved using distilled water, the amount of dissolved Li2CO3(wt.%) increased as the solution temperature decrease and showed about 1.50 wt.% at 2.5℃. In addition, when Na2CO3 was added and the Li2CO3 solution was recrystallized, the recrystallization(%) increased with increasing temperature, resulting in a 49.00 % at 95 ℃. On the other hand, when Li2CO3 was dissolved using HCl solution, there was no effect of reaction temperature. As the concentration of HCl solution increased, the amount of dissolved Li2CO3(wt.%) increased, indicating 7.10 wt.% in 2.0 M HCl solution. When the LiCl solution was recrystallized by adding Na2CO3, it exhibited a recrystallization(%) of 86.10 % at a reaction temperature of 70 ℃, and showed a sulfate ion removal(%) of 96.50 % or more. Finally, more than 99.10 % of Na and more than 99.90 % of sulfate were removed from the recrystallized Li2CO3 powder through water washing, and purified Li2CO3 with a purity of 99.10 % could be recovered.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2011.04a
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• pp.400-403
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• 2011

본 논문에서는 시차열중량분석법과 X-선 회절분석법을 이용한 원전콘크리트의 탄산화에 의한 열화도 평가를 진행하였으며 두 가지 정성적 분석방법을 이용한 반정량적 평가 방법을 개발하였다. 원자력발전소 건설에 사용된 동일한 콘크리트 배합을 사용한 시편을 촉진 탄산화 시험장치에 28, 56, 91, 180, 365일 기간에 걸쳐 노출시켜 탄산화를 진행하였으며 노출된 시편은 시차열중량분석법, X-선 회절분석법을 이용하여 탄산화에 따라 발생된 열화생성물의 양을 정성적으로 분석하였다. 그 결과, 탄산화로 인해 발생되는 Calcite의 양이 노출기간에 따라 점차적으로 증가되는 것이 확인되었으며, Calcite의 생성을 위해 이산화탄소와 반응하는 Portlandite의 양이 점차적으로 감소되는 것이 확인되었다. 본 논문에서는 위의 언급된 두 방법의 관계성을 통해 열화도 평가를 진행하였다.

• Journal of Nutrition and Health
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• v.48 no.6
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• pp.488-495
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• 2015

Purpose: This study was conducted to evaluate nutrition intake and diet quality according to carbonated drink consumption in male adolescents (middle-school students = 480, high-school students = 417). Methods: We analyzed data from the combined 2007~2009 KNHANES (Korean National Health and Nutrition Examination Survey). Subjects were divided into two groups, the LCDI (low carbonated drink intake (< 1 time/week), n = 362) group and the HCDI (high carbonated drink intake (${\geq}1$ time/week), n = 535) group, according to carbonated beverage consumption. Nutrient and food group intake, NAR (nutrient adequacy ratio), and MAR (mean adequacy ratio) were analyzed using data from the 24-recall method. Results: Intake of plant protein, vitamin C, plant calcium, phosphorous, and potassium was significantly lower in the HCDI group, compared with the LCDI group. Percent of RNI (recommended nutrient intake) of vitamin C and phosphorous was significantly lower in the HCDI group, compared with the LCDI group. Percentage of subjects who consumed under EAR (estimated average requirement) of protein and vitamin C was significantly higher in the HCDI group, compared with the LCDI group. The NAR of phosphorous was significantly lower in the HCDI group, compared with the LCDI group. Food intakes from potato and starches, pulses and vegetables were significantly lower in the HCDI group, compared with the LCDI group. Conclusion: Consumption of carbonated drinks decreased the diet quality, including calcium, potassium, protein, and vitamin C. Therefore, nutrition education relating to consumption of carbonated drinks is required for male adolescents in order to maintain healthy dietary habits.

• Journal of the Korea Concrete Institute
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• v.21 no.3
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• pp.255-264
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• 2009

Permeability coefficient of concrete is a substaintial key parameter for understanding the durability performance of concrete and its microstructural densification. Many researches for the issue have been accomplished, however, it is very rare to deal with the theoretical study on permeability coefficient in connection with carbonation of concrete and the the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. The purpose of this study is to establish a fundamental approach to compute the permeability coefficeint of (non)carbonated concrete. When simulating a microstructural characteristics as a starting point for deriving a model for the permeability coefficient by the numerical simulation program for cementitious materials, HYMOSTRUC, a more realistic formulation can be achieved. For several compositions of cement pastes, the permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. Emphasis was on the microstructural changes and its effective change of the permeability coefficient of carbonated concrete. For carbonated concrete, reduced porosity was calculated and this was used for calculating the permeability coefficeint. The computational result was compared with experimental outcome.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.151-156
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• 2013

Crystallization of $CaCO_3$ is practiced on a polymethylsiloxane (PDMS) - based microfluidic system. Liquid- liquid reaction was investigated by mixing calcium chloride ($CaCl_2$) and sodium carbonate ($Na_2CO_3$) solution to crystallize $CaCO_3$. Aspartic acid (Asp) was added to investigate the morphology change such as vaterite and calcite. Suitable ratio of $Na_2CO_3$ and $CaCl_2$ was searched for initial seed formation. Christmas tree model was used as microfluidic device to form concentration gradient of $Na_2CO_3$ and $CaCl_2$. After observing microfluidic channel by using optical microscope, we found that seeds of $CaCO_3$ were formed under the condition that the ratio of $Na_2CO_3$ and $CaCl_2$ was 2:1. Morphology of crystals were also observed as $CaCO_3$ crystals grow. When Asp was added, vaterite crystal was more frequently found in two morphologies (vaterite and calcite) and seed formation and crystal growth were inhibited.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.5
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• pp.81-88
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• 2007

Among deteriorations of concrete due to environmental exposure, carbonation problems of concrete structures have increased in urban and underground structures. But conventional carbonation-prediction equations that were proposed by foreign references, can not be applied directly to the prediction of carbonation for domestic concrete structures. The purpose of this study is to propose a prediction equation of carbonation depth by considering domestic exposure conditions of concrete structures. For the derivation of the equation, conventional carbonation-prediction equations are analyzed. Through considering the relationship between results of prediction equation and those of various domestic field survey data, the so-called correction factors for different domestic exposure condition of concrete structures are derived. Finally, a carbonation-prediction equation of concrete structures under domestic exposure conditions is proposed with consideration for concrete strength in core and correction factors.

• Journal of the Korea Convergence Society
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• v.13 no.4
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• pp.271-278
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• 2022

Carbonated drinks are a kind of drink that is popular in our daily lives and are sold mainly among young people. There are many brands of carbonated drinks currently on sale, and most of them emphasize the distinction of texture, and brand images and packages have further commercialized package design as a whole. It is necessary to increase the emotional experience of soda package design, which can increase the added value of the brand. Sensibility is the most common psychological experience in humans and is the subjective experience and feeling of things. By combining the emotional experience with the package design of carbonated drinks, it provides more emotional user experience while purchasing carbonated drinks, realizing diversification of product package designs and satisfying consumers' emotional needs. This paper first examines the package design of carbonated drinks, I hope it will be an implication if you increase the emotional experience of soda package design.

• Economic and Environmental Geology
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• v.56 no.3
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• pp.217-227
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• 2023

Crystalline calcium carbonate (CaCO₃) occurs in various geological and aqueous environments as calcite, aragonite, and vaterite. These minerals also have practical applications in engineered settings. Synthetic methods of calcium carbonate have been developed for scientific research and technical applications. For example, these methods have become widely adopted for studying the formation of CaCO₃ minerals and (geo-)chemical processes involving these minerals in natural and engineered systems. Furthermore, these methods have the potential to be applied in various technical and biomedical fields. Water-based synthesis is particularly important for simulating the formation of calcium carbonate minerals in natural aqueous environments. This review paper describes the procedures and experimental conditions for water-based synthetic methods of each calcium carbonate polymorph, compares the morphological and structural features of the resulting crystals, and analyzes the crystallization mechanisms.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.4A
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• pp.343-352
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• 2010

Recently, many researchers have been carried out to estimate more controlled service life and long-term performance of carbonated concrete structures. Durability analysis and design based on probability have been induced to new concrete structures for design. This paper provides a carbonation prediction model based on the Fick's 1st law of diffusion using statistic data of carbonated concrete structures and the probabilistic analysis of the durability performance has been carried out by using a Bayes' theorem. The influence of concerned design parameters such as $CO_2$ diffusion coefficient, atmospheric $CO_2$ concentration, absorption quantity of $CO_2$ and the degree of hydration was investigated. Using a monitoring data, this model which was based on probabilistic approach was predicted a carbonation depth and a remaining service life at a variety of environmental concrete structures. Form the result, the application method using a realistic carbonation prediction model can be to estimate erosion-open-time, controlled durability and to determine a making decision for suitable repair and maintenance of carbonated concrete structures.