• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.11
• /
• pp.597-606
• /
• 2015

This work investigates the carbonation of KOH-dissolved methanol and ethanol solution systems carried out for $CO_2$ fixation. Potassium methyl carbonate (PMC) and potassium ethyl carbonate (PEC) were synthesized during the reaction in each solution as the solid powder, and they were characterized in detail. The amount of $CO_2$ chemically absorbed to produce the PMC and PEC precipitates were calculated to be 97.90% and 99.58% of their theoretical values, respectively. In addition, a substantial amount of $CO_2$ was physically absorbed in the solution during the carbonation. PMC precipitates were consisted of the pure PMC and $KHCO_3$ with the weight ratio of 5:5, respectively. PEC precipitates were also mixture of the pure PEC and $KHCO_3$ with the weight ratio of 8:2, respectively. When these two precipitates were dissolved in excess water, methanol and ethanol were regenerated remaining solid $KHCO_3$ in the solutions. Therefore, the process has the potential to be one of the efficient options of CCS and CCU technologies.

• Korean Chemical Engineering Research
• /
• v.47 no.6
• /
• pp.727-733
• /
• 2009

Effects of $Ca(OH)_2$ concentration(0.16~0.64 wt%), total volumetric flow rate(3~6 L/min) and $CO_2$ volume fraction(0.3~0.6) on morphology of the precipitated $CaCO_3$ and the mean particle size of the precipitated $CaCO_3$ were investigated in the slurry bubble column reactor. Experiments were carried out in acrylic reactor($0.11m-ID{\times}1.0m-high$) with a internal tube($0.04m-ID{\times}1.0m-high$). The calibration curve on the mass ratio of $CaCO_3$ to $Ca(OH)_2$ was obtained by FT-IR for the conversion of $Ca(OH)_2$ with the reaction time. The reaction rate of $Ca(OH)_2$ increased with increasing the volumetric flow rate of $CO_2$. From SEM images, the crystal size of $CaCO_3$ increased with increasing the reaction rate in the saturated concentration of $Ca(OH)_2$ (0.16 wt%). In addition, the crystal size of precipitated $CaCO_3$ decreased with increasing the concentration of $Ca(OH)_2$, but the mean particle size of precipitated $CaCO_3$ increased with increasing the concentration of $Ca(OH)_2$.

• 한국전기화학회:학술대회논문집
• /
• 2001.06a
• /
• pp.243-248
• /
• 2001

• 한국전기화학회:학술대회논문집
• /
• 2004.04a
• /
• pp.4-4
• /
• 2004

• Korean Chemical Engineering Research
• /
• v.46 no.6
• /
• pp.1148-1152
• /
• 2008

Molten carbonate oxidation (MCO) is one of the promising alternative technologies for the treatment of the chlorinated organic compounds because it is capable of trapping chlorine during a destruction of them. In this study, destructions of chlorinated organic compounds ($C_6H_5Cl$, $C_2HCl_3$ and $CCl_4$) and an insulated oil containing PCBs were performed by using the two stage molten carbonate oxidation system. MCO reactor temperature largely affected the destruction of the chlorinated organic compounds. Destruction of the chlorinated organics very efficient in the primary MCO reactor however a significant amount of CO was emitted from the MCO system. This CO emission was gradually decreased by an increase in the primary reactor temperature and oxidizing air feed rate. The HCl emission from the MCO system was below 7 ppm regardless of tested conditions. The chlorine collection efficiencies were in the range of 99.95-99.99%. The destruction of PCBs in the insulated oil was efficient at a temperature above $900^{\circ}C$ and overall destruction efficiency of them was determined as over 99.9999%.

• Journal of the Korea Institute of Building Construction
• /
• v.15 no.1
• /
• pp.9-16
• /
• 2015

The goal of this research was evaluating and suggesting the solution of preventing carbonation of concrete replaced high-volume of slag. The concrete mixtures were prepared with high-volume slag and recycled aggregate, and the concrete samples were evaluated the carbonation depth with various surface treatment methods. For various surface treatment methods and surface protecting sheets, bonding strength and carbonation depth were measured. Basically, from the results, the carbonation of concrete was completely prevented with any type of surface treatment method and surface protecting sheet as far as the surface treatment materials were remained. Therefore, in this research, it was known and suggested that the easiness of handling and sufficient bonding performance was much important than the quality of surface protecting sheets.

• Resources Recycling
• /
• v.30 no.5
• /
• pp.49-56
• /
• 2021

In this study, using strontium sulfate (SrSO₄) recovered from magnetite ore in Hongcheon, the Black Ash process was used to produce strontium carbonate (SrCO₃). In the carbothermic reaction step, SrSO₄ was reacted with carbon (C) at 1273 K under Ar gas atmosphere using a gas-tight quartz reactor to produce strontium sulfide (SrS). Afterward, water leaching of the residues produced from the carbothermic reaction at 353 K and carbonation of the leaching solution using sodium carbonate (Na₂CO₃) at 298 K were conducted to produce SrCO₃. The results of this study demonstrate the feasibility of the production of SrCO₃ via the Black Ash process using domestic magnetite ore containing strontium (Sr).

• Applied Chemistry for Engineering
• /
• v.19 no.2
• /
• pp.209-213
• /
• 2008

The fixed bed gasification reactor with 1 m hight and 10.2 cm diameter was utilized for the hydrogen production from biomass wastes. Lauan sawdust was used for non-catalytic and catalytic gasification reaction as a sample in the fixed bed reactor. The fixed bed temperature and catalyst are the major variables affecting the process operation. Thus, the effect of fixed bed temperature and the catalysts on gas composition were studied at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. The yield of hydrogen was increased at higher temperature in the fixed bed reaction. Fractions of hydrogen, carbon monoxide and methane gas in the product gas increased when sodium carbonate ($Na_2CO_3$) and potassium carbonate ($K_2CO_3$) catalysts were used. Furthermore, sodium carbonate catalyst was more effective to obtain higher hydrogen yield compared to potassium carbonate catalyst.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.23 no.6
• /
• pp.53-60
• /
• 2019

The purpose of this study is to evaluate the degree of improvement in strengths by mixing blast-furnace slag and fly ash in polymer cement mortar(PCM). The test specimens are prepared with EVA polymer dispersion, two types of Admixtures (blast-furnace slag and fly ash), five kinds of polymer-cement ratios (0, 5, 10, 15 and 20%), and six kinds of admixtures (0, 3, 5, 10, 15 and 20%). Plain cement mortar is also made for comparison. From the test results, the flowing of PCM is greatly improved with the mixing of the admixtures, and strengths of PCM compared to ordinary cement mortar are also improved due to a decrease in water cement ratio. In addition, the strength characteristics of PCM by admixtures are greatly improved in flexural strength with fly ash compared to other strengths. It is apparent that the optimum mix proportions with polymer-cement ratio of 10% or more, admixture contents 5 to 10% of flay ash for flexural strength improvement of EVA-cement mortar are recommended in this study.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.4
• /
• pp.259-266
• /
• 2018

In the work, the carbonation behavior and strength characteristics in cold-joint concrete are evaluated for OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag)concrete considering three levels of curing age (28, 91 and 365 days). The compressive strength in GGBFS concrete is level of 86% of OPC concrete at the 91 days of curing period, but is level of 107% at 365 curing days due to hydration reaction. Carbonation velocities in both OPC and GGBFS concrete significantly decease after 91 curing days. The effect of cold joint on carbonation is evaluated to be small in GGBFS concrete. The increasing ratios of carbonation velocity in cold joint are 1.06 and 1.33 for 28-day and 365-day curing condition, respectively. However they decreases to 1.08 and 1.04 for GGBFS concrete for the same curing conditions.