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A Study for Kinetics and Oxidation Reaction of Substituted Benzyl Alcohols Using (C10H8N2H)2Cr2O7 ((C10H8N2H)2Cr2O7를 이용한 치환 벤질 알코올류의 산화반응과 반응속도에 관한 연구)

  • Park, Young Cho;Kim, Young Sik;Kim, Soo Jong
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.597-600
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    • 2017
  • $(C_{10}H_8N_2H)_2Cr_2O_7$ was synthesized by reacting 4,4'-bipyridine and chromium (VI) trioxide. The structure of the product was characterized with FT-IR (infrared spectroscopy) and elemental analysis. The oxidation of benzyl alcohol using $(C_{10}H_8N_2H)_2Cr_2O_7$ in various solvents showed that the reactivity increased with the increase of the solvent dielectric constant, in the order of DMF (N,N'-dimethylformamide) > acetone > chloroform > cyclohexane. In the presence of DMF, an acidic catalyst such as $H_2SO_4$ $(C_{10}H_8N_2H)_2Cr_2O_7$ oxidized benzyl alcohol (H) and its derivatives ($p-OCH_3$, $m-CH_3$, $m-OCH_3$, m-Cl, $m-NO_2$). Electron donating substituents accelerated the reaction rate, whereas electron acceptor groups retarded the reaction rate. Hammett reaction constant (${\rho}$) was -0.70 (308 K). The observed experimental data were used to rationalize the hydride ion transfer in the rate determining step.

Antioxidative Effects of Soybean Extracts by using Various Solvents (다양한 용매를 이용한 대두 추출물의 항산화효과)

  • Kim, Jee-Young;Maeng, Young-Sun;Lee, Ki-Young
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.635-639
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    • 1995
  • The effective extraction of antioxidative substances from soybean was investigated by using various solvents, such as water, ethanol, methanol, acetone, chloroform, benzene, ethyl acetate, ether, dichloromethane, and hexane. Extraction was performed by cold method at $30^{\circ}C$ and by reflux method at $85^{\circ}C$. The antioxidative effect of the extracts was determined by peroxide value during the oxidation of soybean oil containing the extracts at $105^{\circ}C$ for 10 hours, and also by TBARS(thiobarbituric acid reactive substances) formed during the peroxidation of egg lecithin liposomes. The antioxidant activity of the extracts from raw soybean was higher than that from defatted soybean. The antioxidant activity of the extracts by reflux method was higher than that by cold method. The methanol extract from defatted and roasted soybean(DRS) showed the highest antioxidative effect against oxidation of soybean oil, while the water extract from DRS in egg lecithin liposomes. In the peroxidation of egg lecithin liposomes, the antioxidative effect of polar solvents extracts were higher than those by nonpolar solvents extracts.

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Antioxidant Activity of Various Solvent Extracts Obtained from A Maillard-type Browning Reaction Mixture (각종용매(各種溶媒)로부터 추출(抽出)한 Maillard형(型) 갈색화반응(褐色化反應) 생성물(生成物)의 산화억제작용(酸化抑制作用))

  • Won, Jong-Tai;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.12 no.4
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    • pp.235-241
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    • 1980
  • Equal portions of a Maillard-type browning mixture (0.2 M glucose+0.2 M glycine), heated at $100^{\circ}C$ for 12 hr, were extracted with the same amounts of eight solvents, respectively. The extracts were then dissolved in equal amounts of an edible soybean oil, and the resulting substrates and a portion of the soybean oil (Control) were stored in an incubator kept at $45.0{\pm}1.0^{\circ}C$ for three weeks. Peroxide values and TBA values of Control and the substrates were determined regularly during the storage period. The POVs of Control and the substrates containing acetone, benzene, chloroform, ethanol, diethyl ether, methanol, methylene chloride, and petroleum ether extracts after 12 days of storage were respectively $60.0{\pm}3.6$, $31.9{\pm}0.9$, $37.6{\pm}2.2$, $48.1{\pm}1.1$, $11.9{\pm}1.3$, $4.85{\pm}0.4$, $11.5{\pm}1.0$, $45.3{\pm}0.3$, and $43.3{\pm}4.2\;m.\;mole/kg\;oil$. The TBA values after 16 days of storage were respectively $0.28{\pm}0.02$, $0.20{\pm}0.01$, $0.21{\pm}0.01$, $0.26{\pm}0.03$, $0.16{\pm}0.02$, $0.28{\pm}0.02$, $0.17{\pm}0.01$, $0.33{\pm}0.05$, and $0.31{\pm}0.02$. The induction periods (arbitrarily taken as the time in hours for a substrate to reach a peroxide value of 30 m. mole/kg oil) of Control and the substrates were respectively 193, 280, 252, 220, 478, 229, 455, 217, and 214 hr. The antioxidant activity of each extract estimated on the basis of the length of the induction periods was, in decreasing order, as follows; ethanol>methanol>acetone>benzene>diethyl ether>chloroform, pertroleum ether, methylene chloride.

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Numerical Study of Settlement Reduction Ratio for the Bottom Ash Mixture Compaction Pile (수치해석적 방법에 의한 저회혼합다짐말뚝의 침하저감비에 관한 연구)

  • Chu, Ickchan;Kim, Gooyoung;Do, Jongnam;Cho, Hyunsoo;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.3
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    • pp.53-58
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    • 2012
  • In general, sand compaction pile(SCP) method and gravel compaction pile(GCP) method have been mainly used to reinforce soft soils such as soft clay or loose sandy ground. But the sand compaction pile method has problems such as lack of sand supply and destroying the nature while collecting sand, the gravel compaction pile method has a problem such as decreased permeability of the drainage material due to clogging. Recently, the study to replace sand with bottom ash which has similar engineering properties with sand is in active. As a fundamental research on bottom ash mixture compaction pile utilizing bottom ash, its behavioral characteristics depending on granular materials and replacement ratio has been simulated numerically. In particular, Settlement Reduction Ratio(SRR) according to the distance from the center of pile was calculated. The main findings were as follows. Change values of Mixture Compaction Pile's SRR according to granular materials showed similar patterns and stiffness of the composite soil is increased depending on the replacement ratio so SRR showed decreased patterns. Especially, when the replacement ratio is in 20~40%, it increase significantly. When the replacement ratio is over 40%, it increase slowly. When considering the economics, 30~40% replacement ratio is appropriate.

Phospholipids Isolation from Squid Viscera Residues After Supercritical Carbon Dioxide Extraction (오징어 내장의 초임계 이산화탄소 추출 잔류물로부터 인지질의 분리)

  • U, Pyoung-Ook;Chun, Byung-Soo
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.741-746
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    • 2010
  • Phospholipids were recovered from squid viscera residues by ethanol extraction after supercritical carbon dioxide($SCO_2$) extraction and from squid viscera was not processed $SCO_2$ by various organic solvent extraction. $SCO_2$ extraction were performed at $45^{\circ}C$ and 20 MPa for removal of non polar lipid molecules from freeze dried squid viscera sample. Phospholipids were extracted from freeze dried squid viscera sample by chloroform, hexane, methanol, and ethanol and from $SCO_2$extracted squid viscera sample by ethanol. The pH was fixed at 5.7 for all phospholipids extraction conditions. Phospholipid classes were analyzed by HPLC equipped with evaporative light scattering detector (ELSD). Phosphatidyl choline(PC) extracted by ethanol from $SCO_2$ extracted residues was higher than that of extracted by ethanol from squid viscera. But phosphatidyl ethanolamine(PE) and phosphatidic acid(PA) were extracted higher percentage in raw squid viscera. The fatty acid compositions in phospholipids extract by ethanol extract from $SCO_2$ extracted residues were analyzed by gas chromatography(GC). Docosahexanoic acid(DHA) was found in highest percentage in phospholipid extract.

Effect of Chlorella Culture Solution Using Anaerobic digestate on Seed Germination in Perennial Ryegrass (혐기소화액을 배지로 이용한 클로렐라 배양액 처리가 페레니얼라이그라스 종자 발아에 미치는 영향)

  • Byeon, Ji-Eun;Lee, Jin Woong;Choi, Min Soo;Ryoo, Jong-Won
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.38 no.1
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    • pp.7-15
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    • 2018
  • This experiments were conducted to evaluate the influence of Chlorella culture solution using anaerobic digestate as medium on seed germination of perennial ryegrass seeds. Four treatments were compared: control with distilled water, anaerobic digestate, Chlorella culture solution and Chlorella culture filtrate. The germination percentage of perennial ryegrass seeds was highest in the Chlorella culture solution treatment. Days required for 50, 70% seed germination were faster at 1.7 day in Chlorella culture solution compared to control. Root length of perennial ryegrass seeds was longer by 1~2cm in the Chlorella culture solution compared with control. The relative root length was by 40% longer in the Chlorella culture solution treatment compared to control. The germination index (GI) of perennial ryegrass seeds was higher by 180~202% in the Chlorella culture solution treatment compared to control. The decay rate was low as 50.0% in Chlorella culture solution, but decay rate of perennial ryegrass seeds showed 86.7~83.3% in control plot and in anaerobic digestate, respectively. Chlorella culture solution have shown stimulatory effects in germination and development of root. Overall, Chlorella culture solution could be useful to apply for promotion of germination and root elongation of seeds.

Copolymerization of Ethylene and Cycloolefin with Metallocene Catalyst : III. Effect of ${\alpha}$-Olefin Addition (메탈로센 촉매를 이용한 에틸렌과 시클로올레핀의 공중합 : III. ${\alpha}$-올레핀 첨가의 영향)

  • Lee, Dong-Ho;Lee, Jo-Hoon;Kim, Hyun-Joon;Kim, Woo-Sik;Min, Kyung-Eun;Park, Lee-Soon;Seo, Kwan-Ho;Kang, Inn-Kyu
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.468-475
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    • 2001
  • For copolymerization of ethylene and norbornene initiated by various metallocene catalysts such as $rac-Et(Ind)_2ZrCl_2,\;rac-Me_2Si(Ind)_2ZrCl_2,\;rac-Me_2Si(Cp)_2ZrCl_2,\;and\;(n-BuCp)_2ZrCl_2$ with modified methylaluminoxane(MMAO) cocatalyst, the ${\alpha}$-olefins such as 1-hexene(H), 1-octene and 1-decene were added as a 3rd monomer. In this situation, the effects of the polymerization condition, the catalyst structure as well as the structure and the amount of added ${\alpha}$-olefin on the catalyst activity as well as the properties and structure of polymer were examined. As results, it was found that the catalyst activity and thermal property of polymer depended on not only catalyst structure but also ${\alpha}$-olefin structure. For $rac-Et(Ind)_2ZrCl_2/MMAO$ catalyst system, it was possible to get high activity and controllable $T_g$ of polymer. Among ${\alpha}$-olefins, H as a 3rd monomer exhibited the maximum enhancement in catalyst activity.

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Effect of fresh chlorella powder on improving qualities and storage condition of organic soybean tofu (클로렐라 생균 분말이 유기농 두부의 품질과 저장성 향상에 미치는 영향)

  • Kim, Min-Jeong;Shim, Chang-Ki;Kim, Yong-Ki;Hong, Sung-Jun;Park, Jong-Ho;Han, Eun-Jung;Kim, Seok-Cheol
    • Food Science and Preservation
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    • v.23 no.6
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    • pp.832-838
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    • 2016
  • The purpose of this study was to investigate the effect of a fresh chlorella powder on yield, quality and self-life of organic soybean tofu. After added with a fresh chlorella powder, yields, physical properties, color, shelf-life and sensory properties of the organic soybean tofu added with chlorella powder was compared to the properties of soybean tofu. The yield of soybean tofu increased with the addition of more than 1% chlorella powder. Hardness of the organic soybean tofu with chlorella significantly increased compared to that of the soybean tofu. However, Hunter's color values of L, a, and b decreased by increases in the chlorella powder concentration. Total microbial population of the soybean tofu was higher than that of the organic soybean tofu with chlorella. However, pH of chlorella tofu decreased during storage period at $4^{\circ}C$. After 7 days storage at $4^{\circ}C$, the total microbial population decreased significantly with the addition of 2% chlorella powder. The L and a value of chlorella tofu was increased. On the other hand, the b value of chlorella tofu was decreased during storage. The results revealed that a fresh chlorella powder was a useful material to improve yield, quality and storage condition of the organic soybean tofu.

Functional evaluation of marine micro-algae Amphidinium carterae extract (해양 미세조류 Amphidinium carterae 추출물의 기능성 평가)

  • Kim, Hae-Mi;Oh, Hyeonhwa;Jeong, Jong Hoon;Lee, Sang-Cheon;Moon, Hye-Jung;Jeong, Yong-Seob
    • Food Science and Preservation
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    • v.24 no.5
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    • pp.673-679
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    • 2017
  • In this study, the antimicrobial, antioxidant activities and ${\alpha}$-glucosidase inhibitory activities of Amphidinium carterae ethanol extract (AE) was evaluated for using as a functional food ingredient. Chlorella ethanol extract (CE) was used to the comparison as a control. Anticancer activities of the AE and CE were analyzed by HepG2 and HT-29 human cancer cell. The AE showed antimicrobial activities for all tested bacterial strains. Whereas, CE showed antimicrobial activities for several tested bacterial strains only. The CE showed higher total phenolics contents, DPPH and ABTS radical-scavenging activities (47.36 mg/g, 22.42% and 28.58%, respectively) than those of AE (8.88 mg/g, 20.16% and 17.69%, respectively). AE showed anti-diabetic effect on ${\alpha}$-glucosidase inhibitory activity with dose-dependantly manner. The cell viability of AE ($125{\mu}g/mL$) on HepG2 and HT-29 human cancer cells were 38.12% and 11.27%, respectively. It was demonstrated that ethanol was efficient solvent for extracting functional components from A. carterae. These results indicated that AE can be described as a good candidate for using as a functional food ingredient.

Evaluation of Antioxidant Capacity and Antimutagen Activity of Bulbil Extracts of the Dioscorea japonica Decaisne and Dioscorea batatas Decaisne (단마와 장마 영여자의 항산화능 및 항돌연변이 활성 검정)

  • Park, Jeong-Seob;Lee, Jung-Ho;Bang, Keuk-Soo
    • Korean Journal of Plant Resources
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    • v.25 no.2
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    • pp.200-208
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    • 2012
  • The bulbil of the $Dioscorea$ $species$ is produced, the amount of which is 2,000 tons annually, but it has been discarded without specific use. In this study the antioxidant and antimutagenicity of bulbil of the $Dioscorea$, which compared to bulbil of Danma($Dioscorea$ $japonica$ Decaisne) and Jangma($Dioscorea$ $batatas$ Decaisne), a major domestic cultivation species. The study was done by extracting bulbil of the Dioscorea methanol and the methanol extracts was re-extracted with chloroform, ethyl acetate, $n$-butanol and water. In methanol extract of Danma and Jangma, polyphenolic compounds contained 2.2 and 3.9 mg/g extract, respectively. The ethyl acetate fraction of Danma and Jangma had higher polyphenolic contents of 33.9 and 39.1 mg/g, whereas water fractions were much lower at 2.4 and 5.8 mg/g. Determination of antioxidant activity showed that the ethylacetate fraction strong DPPH radical scavenging activity and ABTS radical scavenging activity. The inhibitory effects of methanol extracts and chloroform, ethylacetate, $n$-butanol, water fraction from bulbil of Danma and Jangma on the mutagenicity in 1-NP, $AFB_1$, Trp-P-1 were investigated using $S.$ $typhimurium$ TA98. Danma and Jangma cultivars decreased the reverse mutation induced by 1-NP, $AFB_1$, Trp-P-1 in $S.$ $typhimurium$ TA98. The fraction of chloroform and ethylacetate showed strong inhibitory effects, in a dose dependant manner against the mutagenicities induced by 1-NP, $AFB_1$, Trp-P-1 in $S.$ $typhimurium$ TA98.