• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 가을 학술논문 발표대회
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• pp.73-74
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• 2022

The corrosion inhibitive effect of a new hydrazone-based heterocyclic compound for steel in simulated concrete pore solution with 3.5 wt.% sodium chloride was investigated by experimental and computational techniques. Electrochemical studies, up to 30 days of immersion, and surface analysis (X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscope (SEM)) were performed to assess the corrosion protection abilities of investigated compound for steel rebar. Results showed that adding the organic compound to the chloride contaminated concrete pore solution decreased the corrosion rate of the steel rebar thanks to the effective adsorption of inhibitor molecules. After 30 days of immersion of steel rebar in inhibited chloride contaminated synthetic concrete pore solution, the inhibition efficiency exceeded 80% at low concentration of 1 mmol/L. Computational studies by Density Functional based Tight Binding (DFTB) method revealed the formation of covalent bonds between the hydrazone molecule and the iron surface.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.119-120
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• 2023

Corrosion of the steel rebar in coastal environment caused huge economical loss of the globe. Therefore, coating on the steel rebar being used to mitigate the corrosion. In the present study, we have applied epoxy coating on arc thermal sprayed Al coating (a dual metal/polymeric coating) vis-à-vis compared with as coated one (Al coating). The corrosion studies were performed in simulated concrete pore solution with 3.5 wt. % NaCl solution. The morphology of the dual epoxy/Al coating is smooth while Al coating shows rankle and defects. Due to defects, Al coating is susceptible to corrosion while dual epoxy/Al coating has performed excellent compared to as coated one at extended period of immersion.

• 한국건축시공학회지
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• 제15권6호
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• pp.561-567
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• 2015

본 연구는 순환골재의 품질을 개선시키기 위해 pH 10.2의 알칼리성을 띄고 있는 입경 5nm~60nm 정도의 40% 콜로이달 실리카 수용액을 사용하고, 4가지 표면처리방법을 적용하여 순환골재의 품질 향상 시험을 하였다. 순환골재의 품질시험은 비중, 흡수율, 기공률, 계면특성, 그리고 압축 및 인장시험을 하였다. 100kpa의 일정 압력하에서 콜로이달 실리카 수용액이 표면에 도포되고 $60^{\circ}C$에서 건조됨으로써 콜로이달 실리카 용액이 순환골재의 시멘트 모르타르의 표면을 일정한 두께로 효과적으로 코팅되었다. 4가지 표면처리 방법 중 Method C에 의한 표면처리방법이 순환골재의 품질을 효과적으로 개선시켰으며, 그로인해 순환골재콘크리트의 압축강도 및 인장강도 향상에 영향을 미친 것으로 판단된다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.59-60
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• 2023

The corrosion of steel rebar embedded in the coastal areas is corroding once the chloride ions ingress through the pores of the concrete. Therefore, in the present study, a 100 ㎛ thick Al and Zn coating was deposited by an arc thermal spray process onto the steel. The corrosion studies of these deposited coatings were assessed in 3.5 wt.% NaCl contaminated concrete pore (CP) solution with immersion periods. The results show that the Al coating is more corrosion resistance compared to the Zn coating attributed to the formation of gibbsite (γ-Al(OH)₃) whereas Zn coating exhibits Zn(OH)₂ onto the coating surface as passive layer. The Zn(OH)₂ is readily soluble in an alkaline solution. Alternatively, γ-Al(OH)₃ on the Al coating surface is less solubility in the alkaline pH, which further provides barrier protection against corrosion.