• Elastomers and Composites
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• v.35 no.2
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• pp.122-131
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• 2000

In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy ($G_T$) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (Ea) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon flacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

• Elastomers and Composites
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• v.38 no.3
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• pp.273-280
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• 2003

Elastic responses on both pure natural rubber melts with different molecular weights and the rubber compounds mixed with various types of carbon blacks were investigated in this study. Furthermore, the degree of bound rubber was measured for various carbon blacks with different sizes and structures in order to study the interaction between the rubber and carbon blacks, and to study the correlation between the interaction and the elastic responses. As a loading amount of carbon black increased, the degree of bound rubber became higher, particularly far carbon-black particles with smaller sizes and higher structures. The elastic responses of the rubber melt filled with carbon black remarkably improved, as compared with those of unfilled rubber melt, specially in carbon black showing higher contents of bound rubber. Stress relaxation was more delayed and recovery behavior became more elastic, as the molecular weight of the rubber melt increased and the size of carbon-black particles was decreased. Permanent set became higher, as the molecular weight of the rubber melts decreased and the size of carbon-black particles increased.

• Journal of Navigation and Port Research
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• v.47 no.3
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• pp.134-146
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• 2023

The issue of 'carbon reduction' can be said to be one of the most important issues worldwide. For efficient carbon reduction, it is necessary to consider ways to increase absorption and reduce emissions. Accordingly, much attention has been paid to increasing carbon absorption using blue carbon biomass. Blue carbon biomass refers to an ecosystem related to blue carbon, which has a higher carbon absorption rate than inland ecosystems and a longer collection period. It is very efficient in reducing carbon. Therefore, in this study, a current status survey was conducted on domestic and foreign policies, studies, and plans related to the preservation of blue carbon biomass habitats. Basic research was conducted to prepare plans for future preservation of blue carbon biomass habitats suitable for the domestic environment.

• Journal of the Korean Ceramic Society
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• v.38 no.8
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• pp.755-760
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• 2001

본 연구에서는 카본전극의 표면개질에 따른 리튬이온 전지의 전지특성 변화에 대해서 연구하였다. 즉, mesocarbon microbeads(MCMB) 카본에 에폭시 수지(resin)를 코팅시킴으로서 카본전극 표면에 개질시켰으며, 이에 따른 전극의 전기화학적 특성을 고찰하였다. 에폭시 수지에 의한 카본의 표면코팅은 30%의 H$_2$SO$_4$용액에서 2시간 동안 refluxing한 MCMB를 에폭시 수지를 용해시킨 THF(tetrahydrofuran) 용액에 넣어 혼합함으로써 MCMB 표면에 에폭시 수지가 코팅되도록 하였다. 이렇게 에폭시 수지가 코팅된 MCMB를 약 1000-130$0^{\circ}C$로 열처리하여 고분해능 투과전자현미경으로 관찰한 결과, 코팅층은 비정질 카본 구조를 갖게됨을 알 수 있었다. 또한, 에폭시 수지에 의하여 코팅된 MCMB는 코팅되지 않은 MCMB보다 더 높은 BET 비표면적을 나타내었다. Li/MCMB 전지 cell을 만들어 충방전시험을 수행한 결과, 에폭시 수지에 의하여 코팅된 MCMB로 만든 전극이 더 우수한 충방전 용량과 싸이클 특성을 나타내었다. 에폭시 수지 코팅으로 전극 표면을 개질시킴으로서 전지특성이 개선된 원인에 관하여 에폭시 코팅의 결정구조와 전극계면에서의 부동태 피막(passivation film) 형성과 연계하여 논의하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.109-112
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• 2007

유동층 반응기를 이용한 프로판의 촉매 분해는 $CO_2$를 방출하지 않고 수소를 생성하는 새로운 방식이다. 카본블랙을 이용한 프로판 분해는 메탄보다 상대적으로 분해가 잘되며, 같은 온도에서 전환률이 높기 때문에 수소 생성량이 더 많다. 촉매로 사용된 카본블랙은 반응 중 생성되는 탄소의 침적에도 불구하고 8시간 이상 촉매의 활성이 유지되어 전환율이 일정하게 유지되었다. 프로판 촉매 분해 실험은 상압에서 600 ${\sim}$ $800^{\circ}C$ 온도 변화 실험을 수행하였고, 가스 유속 변화는 2.0 ${\sim}$ $4.0U_mf$에서 실험 조건 변화에 따른 실험을 하였다. 온도, 유속 변화에 따른 생성 가스의 몰분율과 프로판 전환율을 분석하였다. 프로판 분해에 의해 생성된 기체는 수소뿐만 아니라 메탄, 에틸렌, 에탄, 프로필렌과 분해되지 않은 프로판이 배출되었다. 수소를 제외한 여타 가스들은 고온에서 실험을 할수록 몰비가 줄어들었다. 고온에서 프로판의 전환율과 수소 수득률이 증가하였다. 프로판 분해 실험 전후의 카본블랙 표면의 변화는 FE-TEM으로 관측하였다.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2003.11a
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• pp.157-160
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• 2003

mesocarbon microbeads (MCMB) 카본 분말에 제2상 첨가물로서 소량의 주석산화물$(SnO_2)$을 균일하게 분산 첨가시킴으로서 리튬이차전지의 부극재료로 사용되는 카본 분말의 전지 성능을 개선하였다. 주석산화물 첨가 방법는 전하적정법을 사용하여 Sn을 MCMB 분말에 삽입시키고, 다시 삽입된 Sn이 산화되도록 대기 중에서 $250^{\circ}C$로 1시간동안 후열처리를 하였다. 주석산화물이 첨가된 MCMB 카본분말로 Li/MCMB 전지 cell을 만들어 충방전시험을 수행한 결과, raw MCMB로 만든 전극보다 더 우수한 충방전 용량과 싸이클 특성을 나타내었다. 즉, 주석산화물 삽입에 의해 표면개질된 MCMB 카본 분말은 기존의 MCMB에 비해 높은 초기 방전용량과 충전용량을 나타내었고, 또한 높은 가역 특성과 좋은 cycleability를 보였다. 삽입된 $SnO_2$의 양이 증가할수록 높은 가역용량을 나타내었고 비가역용량 역시 높은 값을 나타내었다.

• Composites Research
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• v.16 no.2
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• pp.48-53
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• 2003

This paper presents a study on the permittivities of the I-glass fabric/epoxy composite laminates containing carbon black dispersions at microwave frequency. Measurements were performed at the frequency band of 5 GHz∼18 GHz. The results showed that the complex permittivities of the composites depend strongly on the natures and concentrations of the carbon black dispersion. A new scheme is proposed to obtain a mixing law for the estimation of the complex permittivities of the composite laminates as a function of concentration of carbon black. Simultaneously, the complex permittivity of carbon black itself was also calculated by the scheme. The experimental values of the complex permittivities of the composites were compared to those calculated.

• Analytical Science and Technology
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• v.20 no.4
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• pp.296-301
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• 2007

Carbon nanofibers (CNFs) are non-microporous materials with a high surface area ($100{\sim}200m^2/g$) and high purity. Therefore, the material has a high potential for use as catalyst support. Activated carbon fibers (ACFs) are of increasing concern with regard to the levels of toxic air pollutants emitted from high-technology industry. Rayon-based CNFs and ACFs was subjected to thermal oxidation under a wide variety of temperature and air conditions to modify the surface properties. Rayon-based CNFs and ACFs were prepared by using thermal chemistry. CNFs were synthesized at temperatures above $600^{\circ}C$ in an air atmosphere and grew with increased temperature and air conditions. After heating at $800^{\circ}C$ for 72 hr, carbonized rayon with ACFs had $2,662m^2/g$ (BET) of surface area and $1.41cm^3/g$ of pore volume. The resulting ACFs had a 99% surface area in which pore size was 10 nm or less, and a 60 % surface area in which pore size was 2 nm or less.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.6
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• pp.309-313
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• 2013

Silicon carbide (SiC) has recently drawn an enormous industrial interest because of its useful mechanical properties such as thermal resistance, abrasion resistance and thermal conductivity at high temperature. Especially, high purity SiC is applicable to the fields of power semiconductor and lighting emitting diode (LED). In this work, high purity carbon powders as raw material for high purity SiC were prepared by a RF induction thermal plasma. Dodecane ($C_{12}H_{26}$) as hydrocarbon liquid precursor has been utilized for synthesis of high purity carbon powders. It is found that the filtercollected carbon powders showed smaller particle size (10~20 nm) and low crystallinity compared to the reactor-collected carbon powders. The purities of reactor-collected and filter-collected carbon powders were 99.9997 % (5N7) and 99.9993 % (5N3), respectively. In addition, the impurities of carbon powders synthesized by RF induction thermal plasma were mainly originated from the surrounding environment.

• Journal of the Microelectronics and Packaging Society
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• v.22 no.4
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• pp.47-56
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• 2015

In this paper, the Thermal behavior and reliability characteristics of carbon CCL (Copper Claded Layer), which can be used as the core of HDI (High Density Interconnection) PCB (Printed Circuit Board) are evaluated through experiments and numerical analysis using CAE (Computer Aided Engineering) software. For the characterization of the carbon CCL, it is compared with the conventional FR-4 core and Heavy Cu core. From research results, the deformation amount of the flexure strength of PCB is the highest with pitch grade carbon and thermal behavior of PCB is lowest as temperature increases. In addition, TC (Thermal Cycling), LLTS (Liquid-to-Liquid Thermal Shock) and Humidity tests have been applied in the PCB with carbon core and the reliability of PCB with carbon core is confirmed through reliability tests. Also, possibility of uneven surface of the via hole and wear of the drill bit due to the carbon fibers are analyzed. surface of the via hole is uniform, the surface of the drill bit is smooth. Therefore, it is proved that the carbon CCL has the drilling workability of the same level as conventional core material.