• Title/Summary/Keyword: 침출수 유출

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Heavy matal removal in leaching water from the region buried tungsten tailing (중석광 폐재광미의 매립지에서 나오는 침출수 중의 중금속 제거)

  • Lee, Dong-Hoon;Oh, Sae-Gang;Choi, Choong-Lyeal;Park, Man;Choi, Jyung
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.218-222
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    • 2000
  • Wasted${\cdot}$rested mine areas give lots of effect on around-environmental changes after mining development. Leaching water at reclaimed land has been eluted from the solid components through physical, chemical, biological procedures by waters percolated through reclaimed site. The element analysis of waste tungsten ore tailing, leaching water analysis and removal of heavy metal by zeolite were performed to investigate the influent of acid rain on the released contents of H. M. The heavy metal contents in leaching water were determined to be As $1.21\;{\sim}\;1.54\;ppm$, Pb $0.11\;{\sim}\;0.15\;ppm$ and $SO_4\;^{2-}$ was $302\;{\sim}\;378ppm$. As deionized water and simulated acid rain (pH 3,4) were percolated through columns packed tungsten ore tailing, the amount of Mn, Na, Ca which were dissolved by pH4 solution was higher than those by distilled water. However, W and Mo were eluted easily by high pH solution. The change of heavy metal concentration by column experiment packed zeolite was effective a little because heavy metals were adsorved much more by zeolite.

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A Feasibility Study on GMC (Geo-Multicell-Composite) of the Leachate Collection System in Landfill (폐기물 매립시설의 배수층 및 보호층으로서의 Geo-Multicell-Composite(GMC)의 적합성에 관한 연구)

  • Jung, Sung-Hoon;Oh, Seungjin;Oh, Minah;Kim, Joonha;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.4
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    • pp.67-76
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    • 2013
  • Landfill require special care due to the dangers of nearby surface water and underground water pollution caused by leakage of leachate. The leachate does not leak due to the installation of the geomembrane but sharp wastes or landfill equipment can damage the geomembrane and therefore a means of protecting the geomembrane is required. In Korea, in accordance with the waste control act being modified in 1999, protecting the geosynthetics liner on top of the slope of landfill and installing a drainage layer to fluently drain leachate became mandatory, and technologies are being researched to both protect the geomembrane and quickly drain leachate simultaneously. Therefore, this research has its purpose in studying the drainage functions of leachate and protection functions of the geomembrane in order to examine the application possibilities of Geo-Multicell-Composite (GMC) as a Leachate Collection Removal and Protection System (LCRPs) at the slope on top of the geomembrane of landfill by observing methods of inserting filler with high-quality water permeability at the drainage net. GMC's horizontal permeability coefficient is $8.0{\times}10^{-4}m^2/s$ to legal standards satisfeid. Also crash gravel used as filler respected by vertical permeability is 5.0 cm/s, embroidering puncture strength 140.2 kgf. A result of storm drain using artificial rain in GMC model facility, maxinum flow rate of 1,120 L/hr even spray without surface runoff was about 92~97% penetration. Further study, instead of crash gravel used as a filler, such as using recycled aggregate utilization increases and the resulting construction cost is expected to savings.

Seasonal Variation and Natural Attenuation of Trace Elements in the Stream Water Affected by Mine Drainage from the Abandoned Indae Mine Areas (인대광산 지역 광산배수에 영향을 받은 하천에서 미량원소의 계절적인 수질변화와 자연저감)

  • Kang, Min-Ju;Lee, Pyeong-Koo;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.40 no.3 s.184
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    • pp.277-293
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    • 2007
  • Seasonal and spatial variations in the concentrations of trace elements, pH and Eh were found in a creek watershed affected by mine drainage and leachate from several waste rock dumps within the As-Pb-rich Indae mine site. Because of mining activity dating back to about 40 years ago and rupture of the waste rock dumps, this creek was heavily contaminated. Due to the influx of leachate and mine drainage, the water quality of upstream reach in this creek was characterized by largest seasonal and spatial variations in concentrations of Zn(up to $5.830 mg/{\ell}$), Cu(up to $1.333 mg/{\ell}$), Cd(up to $0.031 mg/{\ell}$) and $SO_4^{2-}$(up to $173 mg/{\ell}$), relatively acidic pH values (3.8-5.1) and highly oxidized condition. The most abundant metals in the leachate samples were in order of Zn($0.045-13.909 mg/{\ell}$), Fe($0.017-8.730mg/{\ell}$), Cu($0.010-4.154mg/{\ell}$) and Cd($n.d.-0.077mg/{\ell}$), with low pH(3.1-6.1), and high $SO_4^{2-}$(up to $310 mg/{\ell}$). The mine drainage also contained high concentrations of Zn, Cu, Cd and $SO_4^{2-}$ and remained constantly near-neutral pH values(6.5-7.0) in all the year. While the leachate and mine drainage might not affect short-term fluctuations in flow, it may significantly influence the concentrations of chemicals in the stream. The abundance and chemistry of Fe-(oxy)hydroxide within this creek indicated that the Fe-(oxy)hydroxide formation could be responsible for some removal of trace elements from the creek waters. Spatial and seasonal variations along down-stream reach of this creek were caused largely by the influx of water from uncontaminated tributaries. In addition, the trace metal concentrations in this creek have been decreased nearly down to the background level at a short distance from the discharge points without any artificial treatments after hydrologic mixing in a tributary. The nonconservative(i.e. precipitation, adsorption, oxidation, dissolution etc.) and conservative(hydrologic mixing) reactions constituted an efficient mechanism of natural attenuation which reduces considerably the transference of trace elements to rivers.

산성광산배수 평가 및 처리기술 분석

  • 최정찬
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.02a
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    • pp.29-48
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    • 2001
  • 일반적인 폐수처리 시 여러 광물들이 사용되는 데 예를 들면, 수산화칼슘 및 탄산나트륨은 중화제, 점토는 응집제, 알룸(alum) 및 염화철은 인 제거제로 사용되고 있다. 산성광산배수인 경우에는 알칼리성의 중화제로 석회 (CaO), 석회석 (CaCO$_3$), 가성소다 (NaOH), 탄산나트륨 (NaCO$_3$) 등이 사용된다. 그러나, 설비비 및 유지비가 많이 들어 몇 십년 동안 계속해서 침출되는 산성광산배수를 처리하기에는 문제가 있다. 산성광산배수 (Acid Mine Drainage, AMD)는 pH가 6.0 미만이고 총산도 (totalacidity)가 총알카리도 (total alkalinity)를 초과하는 물로서 노천광이 가행되었던 지역, 가행중이거나 휴광 또는 폐광된 광산에서 유출된다. 또한 도로사면 절개부나 지하철 터널에서도 황철석(pyrite)이나 백철석 (marcasite)을 함유하는 층이 공기 중에 노출되면 산성수가 침출되어 나오기도 한다. 산성광산배수에 의한 하천수의 오염이 매우 극심하여 때로는 미생물마저도 그 속에 살 수 없게 된다. 산성광산배수에 의해 오염된 하천수의 오염범위는 산성수의 양, 농도, 하천에 유입되는 산성수의 분포, 상류에서 흘러드는 오염되지 않은 물의 양, 지류에서 유입되는 물의 양에 따라 좌우된다. 산성광산배수 오염이 문제시되고 있는 나라는 미국을 포함하여 호주, 일본, 한국, 러시아, 남아연방 등이다. 산성광산배수는 환원환경에서 생성된 석탄층 및 접촉교대 또는 열수에 의해 생성된 금속광이 공기 및 물에 노출되어 생성되는 자연적인 현상이다. 그러나 국지적인 지역에서 인간이 이 광상들을 환경영향을 고려하지 않고 대규모로 개발할 때 인간 생활에 심각한 영향을 미치는 것이다. 광산산성배수를 처리하기 위해 상기와 같이 여러 기술이 도입 적용되었으며 일부 기술들은 현재도 사용되고 있다. 각 기술마다 일장일단이 있으므로 경비의 과다, 유지 및 관리에 대한 지속성 여부, 공간의 확보 여부, 지역적 특수성에 맞춰 가장 적합한 방법을 채택하여야 하며 꾸준히 채택한 기술의 개량 및 새로운 기술의 첨가가 요구되고 있다. 따라서, 산성광산배수 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 광산산성폐수가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.

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Hydrogeological characteristics of a seepage area of white leachate (백색침출수 용출지역의 수리지질학적 고찰)

  • Kim, Man-Il;Park, Young-Gyu;Kim, Eul-Young;Kim, Yang-Bin;Yong, Hwan-Ho;Ji, Won-Hyun
    • The Journal of Engineering Geology
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    • v.20 no.4
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    • pp.381-390
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    • 2010
  • This study assessed the hydrogeological characteristics of a seepage area of white leachate. The geological characteristics of the leachate were determined by a surface survey, and an electrical resistivity survey and borehole image processing system (BIPS) were applied to estimate the distribution of discontinuities, to assess the geological structure of the seepage areas. Fluctuations in groundwater level within boreholes were measured during periods of precipitation in the dry and wet seasons. The results show that electrical resistivity is lower in the seepage section than in non-seepage sections. The distribution of fracture zones and limestone cavities was inferred from the logging data and BIPS data. Variations in groundwater level and groundwater recharge, related to rainfall events, show the direct effect of rainfall events during the rainy season. We obtained a strong relationship between seepage amount and rainfall (correlation coefficients of 0.83-0.97).

Effect of the Addition of Granular Activated Carbon and Granular Sludge on the Performance of Upflow Anaerobic Sludge Blanket Reactors for Treating Leachate (상향류 혐기성 슬러지 블랭킷 반응조를 이용한 침출수 처리시 입상 활성탄 및 입상슬러지 첨가의 영향)

  • Lee, Chae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.91-97
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    • 2008
  • The objective of this research is to investigate the effect of the addition of granular activated carbon (GAC) and granular sludge on the performance of upflow anaerobic sludge blanket (UASB) reactors for treating leachate. For the control reactor, sludge obtained from an anaerobic digester was used as a seed material. On the other hand, GAC and granular sludge were incorporated with the seed sludge in the GAC reactor and the Granule reactor, respectively. The shortest acclimation period was observed in the Granule reactor. The GAC reactor also gave comparable performance to the Granule reactor at the beginning of operation. However, as the adsorptive capacity of GAC was exhausted, the effluent COD concentration increased gradually. Once the systems were stabilized, the GAC reactor showed slightly better results than the other two reactors in terms of chemical oxygen demand (COD) removal. COD removal in all reactors was more than 90% at hydraulic retention time of 1.0 day. Furthermore, GAC reactor showed little variation in COD removal rate and remained at 95% with organic loading rate (OLR) of 4.0 to $8.2kg\;COD/m^3.d$. Initial operating period was reduced by the addition of granular sludge, while the treatment efficiency was enhanced by the addition of GAC.

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The 3-D Simulation of Electrophoresis Method in Leachate System for Repairing of Leaks in Waste Landfill Geomembrane Liner (폐기물 매립지 차수층 누출시 전기영동 복원을 위한 침출수 환경에서의 3차원 형상 모사 연구)

  • Han, Sang-Jae;Kim, Jong-Yun;Kim, Byung-Il;Kim, Soo-Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.1C
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    • pp.17-25
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    • 2010
  • Electrophoresis may offer a new technique to repair in service leaking geomembrane liner of municipal solid waste (MSW) impoundment. The method involves introducing a suspended clay particles, which are charged negatively, into the leakage in geomembrane liners by electrokinetic phenomena and formation of clay cake around leakage for prevention of leachate outflows. Therefore, the 3-dimensional leakage simulation experiments are conducted to evaluate the field applicability of sealing leaks of waste impoundment. In addition, the adequateness of optimum influence factors deduced from 1-dimensional experiments is evaluated. After the test, the total size (width, length) of clay cake formation around leak is increased with enlargement of leakage diameter and distance decrease detween anode and cathode.

Future changes in runoff characteristics of an estuarine reservoir watershed using CMIP6 multi-GCMs (CMIP6 다중 GCMs을 적용한 담수호 유역의 미래 유출특성 변화)

  • Sinae Kim;Seokhyeon Kim;Hyunji Lee;Jihye Kwak;Jihye Kim;Moon-Seong Kang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.419-419
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    • 2023
  • 하천의 최종 유출부와 해양이 만나는 지점을 하구라고 하며, 우리나라는 주로 서해안 지역에 하구 방조제 건설에 따른 담수호가 조성되어 다양한 목적으로 수자원이 활용되고 있다. 이러한 하구 담수호는 바다로 유입되기 직전의 물을 저류시켜 수자원 확보에 긍정적이나, 일반적으로 유역의 최하류에 위치해 있어 오염물질 유입, 부영양화, 염분 침출로 인한 오염물질 용출 등에 취약하다. 따라서 담수호의 회복탄력성 향상과 지속가능한 수자원 관리를 위해서는 미래 기후변화에 따른 영향 분석이 필수적이다. 특히 기후변화는 거대규모의 홍수과 같은 자연재난, 농업가뭄 및 식생가뭄 등의 증가로 이어질 수 있으므로, 이에 효과적으로 대비하기 위해서는 미래 기후조건에 따른 하천의 미래 유출량 변화 예측이 수행되어야 한다. 본 연구에서는 불확실한 미래 수문변화를 예측하기 위해 CMIP6(Coupled Model Intercomparison Project Phase 6) GCMs(Global Climate Models)의 SSP(Shared Socioeconomic Pathways) 시나리오를 유역 유출모델에 적용하여 기후변화에 따른 미래 유출특성의 변화를 예측하였다. 충청남도 서산시에 위치한 간월호 유역을 대상유역으로 선정하고, HSPF(Hydrological Simulation Program-FORTRAN) 모형을 적용하여 상류유역의 과거 및 미래 장기유출량 모의를 수행하였다. 모의된 시나리오별 유출량을 기반으로 최빈유량곡선법을 적용하여 미래의 기준유량 발생시점 및 지속기간의 변화를 분석하였으며, CVDs(Center-of-volume dates)의 변화를 통해 기후변화에 따른 홍수기의 시기적 변화 양상을 파악하고자 하였다. 본 연구의 결과는 미래 유역 환경변화를 고려한 담수호의 수자원 보전관리계획 수립에 있어 기초자료로 활용될 수 있을 것으로 기대된다.

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Application of Molecular Biological Technique for Development of Stability Indicator in Uncontrolled Landfill (불량매립지 안정화 지표 개발을 위한 분자생물학적 기술의 적용)

  • Park, Hyun-A;Han, Ji-Sun;Kim, Chang-Gyun;Lee, Jin-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.128-136
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    • 2006
  • This study was conducted for developing the stability parameter in uncontrolled landfill by using a biomolecular investigation on the microbial community growing through leachate plume. Landfill J(which is in Cheonan) and landfill T(which is in Wonju) were chosen for this study among a total of 244 closed uncontrolled landfills. It addressed the genetic diversity of the microbial community in the leachate by 165 rDNA gene cloning using PCR and compared quantitative analysis of denitrifiers and methanotrophs with the conventional water quality parameters. From the BLAST search, genes of 47.6% in landfill J, and 32.5% in landfill T, respectively, showed more than 97% of the similarity where Proteobacteria phylum was most significantly observed. It showed that the numbers of denitrification genes, i.e. nirS gene and cnorB gene in the J site are 7 and 4 times higher than those in T site, which is well reflecting from a difference of site closure showing 7 and 13 years after being closed, respectively. In addition, the quantitative analysis on methane formation gene showed that J1 spot immediately bordering with the sources has the greatest number of methane formation bacteria, and it was decreased rapidly according to distribute toward the outer boundary of landfill. The comparative investigation between the number of genes, i.e. nirS gene, cnorB gene and MCR gene, md the conventional monitoring parameters, i.e. TOC, $NH_3-N,\;NO_3-N,\;NO_2-N,\;Cl^-$, alkalinity, addressed that more than 99% of the correlation was observed except for the $NO_3-N$. It was concluded that biomolecular investigation was well consistent with the conventional monitoring parameters to interpret their influences and stability made by leachate plume formed in downgradient around the uncontrolled sites.

Analysis on Contaminant Transport according to the Embedded Depth of Vertical Barrier of Offshore Landfill (해상 폐기물매립지 연직차수벽체 근입심도에 따른 오염물질 이동특성 분석)

  • Park, Haeyong;Oh, Myounghak;Kwon, Osoon
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.8
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    • pp.29-37
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    • 2016
  • In order to prevent leakage of contaminants in offshore landfill, vertical barrier should be installed. Vertical barrier should be installed at designed depth of seabed to prevent the horizontal transport of contaminant in the subsurface. In this study, the seepage and contaminant transport in the subsurface according to embedded depth of vertical barrier were analyzed by using 2-D finite element analysis program SEEP/W and 3-D finite difference analysis program Visual Modflow. Numerical modelling results show that seepage flux and contaminant transport in seabed was greatly reduced when vertical barrier was installed at certain depth of low permeable layer. Therefore, the determination of minimum embedded depth for preventing contaminant leakage is helpful to design the economical vertical barrier.