• Korean Journal of Plant Resources
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• v.27 no.1
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• pp.60-71
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• 2014

This study was conducted to identify the potential of rape stalk as a raw material for biorefinery process of rape flower. At first, rape stalk (RS) was immersed in distilled water (DW), acetic acid (AA), oxalic acid (OA), sulfuric acid (SA) and sodium hydroxide (SH) solutions, and the content of reducing sugars liberated from immersed RS was analyzed. Glucose, xylose, arabinose and sucrose were detected varying with the immersion type. In particular, 1% AA-immersion of RS for 72 hr was the most effective conditions to liberate glucose from RS. Secondly, the RS residues were used for elementary analysis and fabrication of fuel pellets. In addition to the solution type, concentration of immersion solutions (0%, 1%, 2%) and immersion time (24, 72, 120 hr) were used as experimental factors. The contents of nitrogen, sulfur and chlorine reduced effectively through the immersion of RS in DW, AA and OA solutions. For properties of RS-based pellets, bulk density and higher heating value of RS-based pellets greatly increased with the immersion of RS, and the qualities were much higher than those of the A-grade pellet of the EN standards. Ash content decreased remarkably through the immersion of RS, and was satisfied with the A-grade pellet standard. Durability was negatively affected by the immersion of RS, and did not reached to B-grade of the EN standard. In conclusion, acid immersion of RS can be a pretreatment method for the production of fuel pellet and bioethanol, but use of the immersed RS for the production of high-quality pellets might be restricted due to low durability of immersed-RS pellets. Therefore, further studies, such as investigation of detailed immersion conditions, fabrication of mixed pellets with wooden materials and addition of binders, are needed to resolve the problems.

• Korean Journal of Food Science and Technology
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• v.24 no.5
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• pp.511-514
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• 1992

The effects of soaking conditions (time and temperature) of rice on the water absorption behaviors and the consequent textural properties after cooking were investigated. Water absorption during soaking was completed in 30 min at $23^{\circ}C$, while the hydration continued up to 60 min at $4^{\circ}C$. The hardness (H) of the cooked rice decreased, while the stickiness (S) and S/H ratio increased with increased soaking time. Soaking at $23^{\circ}C$ gave higher values of S and S/H of cooked rice than soaking at $4^{\circ}C$. Soaking for $10{\sim}40\;min$ at $4^{\circ}C$ or for $10{\sim}20\;min$ at $23^{\circ}C$ resulted the value of S/H between 0.15 and 0.20, which had been found at acceptable textural parameters of the cooked rice.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.1
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• pp.53-60
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• 2024

Compressive strength in concrete has many affecting parameters and varies with exposure conditions. Although the concrete has same mix proportions, its properties are different with exposure conditions, and sea-environment can be classified into three groups such as tidal, atmospheric, and sea submerged region particularly. In this study, compressive strength was evaluated on 7-year-cured concrete and the results from previous equations (KDS, ACI, CEB, and JSCE) were compared with them. Furthermore the strength and carbonation progress were evaluated on concrete cured for 7 years exposed to three different sea environment. Three levels of w/c (water to cement) ratio (0.37, 0.42, and 0.47) and three different exposure conditions (tidal, atmospheric, and submerged) were considered. The results from wet-cured condition are all higher than those from the previously proposed equations, and the results from different sea exposure conditions (tidal, atmospheric, and submerged region) were lower than those from wet-cured condition. A reduction of strength was evaluated with increasing w/c ratio and the minimum strength was evaluated in the sea-submerged conditions. Several experimental constants applicable to the previous equations were obtained from regression analysis since the strength change with w/c ratios were not considered in those equations. Regarding carbonation depth with different exposure conditions, higher carbonation depth clearly was observed with increasing w/c ratios, and evaluated in the order of atmospheric, submerged, and tidal region. Considerable carbonation depth was observed in submerged and tidal region due to sulfate ion and dissloved carbon dioxide as well.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.299-306
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• 2017

In this research, it was examined chloride ion penetration resistance of slag-replaced concrete and cementless slag concrete considering marine environmental exposure conditions of splash zone, tidal zone and immersion zone. In the design strength of grade 24 MPa, the specimens were tested to determine their compressive strength, scanning electron microscopy images and chloride migration coefficient. Further, chloride ion penetration depth and carbonation depth of specimens exposed to marine environment were measured. Experimental results confirm that chloride migration coefficient of specimens tended to decrease with increasing the replacement ratio of ground granulated blast-furnace slag in accelerated laboratory test. In addition, the specimens exposed to the tidal zone were found to be the greatest chloride ion penetration depth compared to splash zone and immersion zone. On the other hand, the chloride ion penetration depth of the specimens exposed to splash zone tended to increase with increasing the replacement ratio of ground granulated blast-furnace slag in contrast with the results for the tidal zone and immersion zone.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.80-86
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• 2024

This study was conducted to evaluate the potential of rape stalk (RAS) as a raw material for the production of solid bio-fuels. RAS was immersed in an aqueous solution with acetic acid concentration of 1 percent, The content of reducing sugars separated from the RAS was analyzed. Glucose showed the highest content followed by xylose, galactose, arabinose and mannose. The immersed and non-immersed RAS were used for producing pellets with a pilot-scaled flat-die pellet mill. Bulk density and calorific values of the pellets improved with the use of the immersed RAS and the addition of wood particles. The values exceeded the minimum requirements for the A-grade of non-woody pellets (≧600 kg/m³ & ≧ 14.5 MJ/kg) designated by the ISO. Ash content of the pellets reduced with the immersion of RAS and the value satisfied the A-grade level (≦6.0%) of the ISO standard. The durability of the immersed RAS-based pellets was much higher than that of non-immersed IRS-based pellets, and the values were increased with the addition of wood particles. However, the durability did not meet the acceptance level for the B-grade of non-woody pellets (≧96.0%) designated by the ISO. These results suggested that the addition of binders in the production of non-woody pellets using an RAS immersed in acetic acid-based aqueous solution is required for the commercialization of the pellets.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.119-126
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• 2019

In case of RC(Reinforced Concrete) structures which are constructed in coastal areas, chloride ions in sea water corrode the steel rebar in concrete. Especially in coastal areas, RC structures are affected by not only immersion of sea water, but also tidal of sea water and airborne chloride ions. In this study, marine environment exposure tests are conducted, considering 3 types of exposure environments(immersion zone, tidal zone, splash zone) and the exposure periods of 180 days, 365 days, and 730 days. Also, the concrete mixtures for this study are established, considering 3 levels of W/B(Water to Binder) ratio(0.37, 0.42, 0.47) and 2 levels of substitution rate of Fly ash(0 %, 30 %). In all exposure environments, Fly ash concrete has lower apparent chloride diffusion coefficients than OPC concrete. It is thought that fly ash's pozzolan reaction improves chloride resistance of concrete. Fly ash concrete has up to 63.5 % of decreasing rate in 180 days of exposure and up to 55.8 % of decreasing rate in 730 days of exposure, based on diffusion coefficients of OPC concrete. As a result of evaluation about effects of exposure environments, apparent chloride diffusion coefficients of fly ash concrete are evaluated in order of tidal zone, immersion zone, and splash zone. In tidal zone, It is thought that repeated cycles of wetting and drying of sea water cause the diffusion of chloride ions rapidly.

• Journal of the Korean Wood Science and Technology
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• v.37 no.4
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• pp.381-387
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• 2009

Enhancing enzymatic saccharification of corn stover by aqueous ammonia soaking pretreatment was investigated on chemical compositional changes and enzymatic hydrolysis characteristics. At three different levels of aqueous ammonia soaking temperature and time ($140^{\circ}C$-1 h, $90^{\circ}C$-16 h and $50^{\circ}C$-6 days), higher temperature and shorter treatment time led to more xylan and lignin removal based on overall composition analysis and carbohydrate compositional analysis. More xylan and lignin removal in higher temperature treatment led to higher enzymatic saccharification of cellulose and xylan to monosaccharide by commercial cellulase mixtures (Celluclast 1.5L and Novozym 342 from Novozyme, Denmark).

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.2
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• pp.18-27
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• 2022

In this study, the time-dependent chloride ingress behavior in GGBFS concrete was evaluated considering marine exposure conditions and the properties of concrete mixtures. The concrete mixture for this study had 3 levels of water to binder ratio and the substitution rate of GGBFS, and outdoor exposure tests were performed considering submerged area, tidal area, and splash area. According to the evaluation results of diffusion coefficient considering properties of concrete mixtures, as the substitution rate of GGBFS increased, the decreasing rate of the diffusion coefficient decreased based on exposure periods of 730 days(2 years). As the evaluation result of the diffusion behavior according to the marine exposure conditions, the diffusion coefficient was evaluated in the order of submerged area, tidal area, and splash area. In tidal area, a relatively high diffusion coefficient was evaluated due to the repetition of wet and dry seawater. In this study, the effects of GGBFS substitution rate on the decreasing behavior of apparent chloride diffusion coefficient was analyzed in consideration of exposure conditions and periods. Linear regression analysis was performed with apparent chloride diffusion coefficient as output value and GGBFS substitution rate as input value. After 730 days of exposure, the effect of GGBFS on diffusion coefficient was significantly reduced. Even for OPC concrete, after 730 days, the diffusion coefficient was as low as that of GGBFS concrete, so the gradient of the regression equation decreased significantly. It is thought that improved durability performance for chloride ingress can be secured before 730 days through the use of GGBFS.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.60-61
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• 2013

For reinforced concrete structures located in a sea environment, the Impressed Current Cathodic Protection (ICCP) is mostly used as a signature method to prevent steel corrosion. For this research, specimens to which the ICCP is applied were manufactured under the assumption of two following cases the specimens are exposed to various salt damage environments (submerged zone, tidal zone), and deteriorative factors (crack) occur in concrete. For the specimens manufactured, an enhancement experiment for deterioration was conducted through regular cycle change under the temperature between 15 ~ 70℃ with 70 ~ 90% humidity. Afterwards, the method effect was verified through a half-cell method and application of the ICCP derived from salt damage environments was investigated.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4542-4551
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• 2013

Recently, much attention has focused on the study of eco-friendly concrete using recycled by-products for protecting marine ecosystem and durability of concrete exposed to marine condition. This study evaluated the durabilities of 4 different type of concrete mixtures(Control, Marine, Porous, New slag) with the seawater resistance by marine environment exposure experiment and freeze-thaw resistance, resistance to chloride ion penetration considering severe deterioration environment. In this study, we conducted seawater resistance using compressive strength according to the age(7/28/56 days) of specimen and curing conditions(standard(fresh water), tidal, immersion, artificial seawater). The results show that compressive strength of concrete exposed to marine environment exposure condition was lower than those of the standard curing condition. Also, compressive strength of New slag using eco-friendly materials for protecting marine ecosystem was lower than those of other concretes, there is need to improve the performance of New slag. The results for freeze-thaw resistance showed that all mixtures have excellent, but the Porous and New slag were lower than others. Also, the more improved resistance to chloride ion penetration than those of the Marine was measured in the New slag regardless of curing condition.