• Title/Summary/Keyword: 친환경 화학

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Effective Water Pollution Management using Reservoir Tank Automatic Classification (저수조 자동 분류를 이용한 효과적인 수질 오염 관리)

  • Chung, Kyung-Yong;Jun, In-Ja
    • The Journal of the Korea Contents Association
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    • v.9 no.8
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    • pp.1-8
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    • 2009
  • With the development of IT convergence technology and the construction of master plan for the four rivers restoration of the government, the importance of the eco-friendly water pollution management is being spotlighted. In this paper, we proposed the effective water pollution management using the reservoir tank automatic classification for improving the water quality and on-line managing efforts of ceo-friendly reservoir tanks. The proposed method defined the seven factors of water pollution evaluation and managed the water pollution according to hydrogen ion concentration(pH), chemical oxygen demand(COD), suspend solid(SS), dissolved oxygen(DO), count of coliform group(MPN), total phosphorus(T-P), and total nitrogen(T-N) using the sensors. We measured the values for the seven factors from the reservoir tank and normalized to ranging from 1 to 9. To evaluate the performance of the water pollution management using the reservoir tank automatic classification, we conducted F-measure so as to verify usefulness. This evaluation found that the difference of satisfaction by the traditional system was statistically meaningful.

The Evaluation of Korea's Competitiveness in Lubricants Industries Using Patent Index Analysis (특허 지표 분석을 통한 국내 윤활유 제조 기술 평가)

  • Kim, Chanjung;Kwon, Sunghoon;Kim, Jiyong
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.332-339
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    • 2016
  • We evaluate the technical competitiveness of Korea in lubricating oil industries by comparatively analyzing the patent activities. In achieving the goal, we collect and statistically analyze the historical patent data of lubricants production technologies. We here consider nine technology groups classified by their raw material types and process features of four countries such as USA, Japan, EU and Korea. We then evaluate Korea's competitiveness in lubricating oil industries using different patent index including patent family size, cites per patent, patent impact index and technology strength. Based on the evaluation results, we finally propose the practical strategies to improve Korea's competitiveness in lubricants industries.

Research Trend of Solid Electrolyte for Lithium Rechargeable Batteries (리튬 이차전지용 고체전해질 개발 동향)

  • Suh, Soon-Sung;Yi, Cheol-Woo;Kim, Keon
    • Journal of the Korean Electrochemical Society
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    • v.15 no.1
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    • pp.1-11
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    • 2012
  • Recently lithium ion secondary batteries (LIB) have rapidly developed because of their advantages such as high energy densities and capacities. Among them, an electrical vehicle which is the one of the environmental-friendly transportation facilities has been received a great attention, but, it is needed to overcome several obstacles of the LIB performances. LIB is practically adapted to Hybrid Electric Vehicle (HEV), but the issues for high capacities, long life time and safety should be solved. Moreover, LIBs still have some possibilities of explosion in the case of overheating of the used organic electrolyte and overcharging of the cell. Hence, it is urgently needed to replace the liquid electrolytes into the solid electrolytes due to the safety issues. Therefore, in this review, we summarized and discussed the research trends of the solid electrolyte to solve the concerns of safety and capacity of LIBs and published patents and articles.

Suppression of Citrus Canker by Pretreatment with Rhizobacterial Strains Showing Antibacterial Activity (항균활성 식물근권세균 전 처리에 의한 감귤 궤양병 억제)

  • Yang, Ji Seun;Kang, So Young;Jeun, Yong Chull
    • Research in Plant Disease
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    • v.20 no.2
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    • pp.101-106
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    • 2014
  • Citrus canker caused by Xanthomonas citri subsp. citri (Xcc) is one of the most important diseases on citrus. Although Satsuma mandarin cultivating mostly in Korea is moderately resistance to canker, occurrence of the disease were more frequently reported since last decade. Like other diseases in citrus, citrus canker was mainly protected by chemical fungicide in the field. Due to the side effect of the chemicals, alternative method of disease control is recently required. In this study four rhizobacterial strains TRH423-3, MRL408-3, THJ609-3 and TRH415-2 are selected by testing its antifungal activity against Xcc. Pre-inoculation with the selected rhizobacterial strains caused disease suppression on the citrus leaves after inoculation with the citrus canker pathogen. Similarly, in the field test symptoms of citrus canker were less developed in the citrus trees applied several times with the selected rhizobacterial strains compared with those of untreated trees. Therefore, it is suggested that the selected rhizobacterial strains may be valuable as an alternative method in the environment-friendly citrus farm.

A Study on the Reactivity, Performance of 4HBA Modified High Solid Acrylic Polyurethane Paint (4HBA 변성 하이솔리드 아크릴 우레탄 도료의 반응성 및 물성 연구)

  • Seo, Seok-Hwan;Suh, Cha-Soo;Park, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.52-61
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    • 2009
  • In this study, TAPEH (t-amyl peroxy 2-ethyl hexanoate) was selected for the reaction initiator which is a core factor for developing acrylic polyol binder. Tone M100 (caprolactone acrylate), 4HBA (4-hydroxy butyl acrylate), and 2HEMA (2-hydroxy ethyl methacrylate) were used for hydroxy-monomers. To check the applicability of raw materials mentioned above into the binders of 2 components acrylic polyurethane paint and reduce the VOC, the reactivity and film performance by different kinds of aliphatic polyisocyanate hardeners which are already generalized were reviewed. As the Tin-based catalyst has been regulated, the comparison test of reactivity and performance between the conventional catalyst and non-toxic metal catalyst recommended as the alternative was conducted as well. As a result, we were able to obtain the basic data which are necessary for applying 2 components high solid polyurethane paint and also reached a conclusion that it can be applied for developing new paints in terms of high performance, workability and environmental care.

R & D Trends on Direct Formic Acid Fuel Cells (직접 개미산 연료전지의 연구동향)

  • Kwon, Yongchai;Han, Jonghee;Kim, Jinsoo
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.583-591
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    • 2008
  • Recently, as a demand for the portable device is surged, there are needs to develop a new fuel cell system for replacing the conventionally used secondary battery. For this purpose, it becomes important to develop direct formic acid fuel cell (DFAFC) that uses formic acid as a fuel. The formic acid can offer typical advantages such as excellent non-toxicity of the level to be used as food additive, smaller crossover flux through electrolyte, and high reaction capability caused by high theoretical electromotive force (EMF). With the typical merits of formic acid, the efforts for optimizing reaction catalyst and cell design are being made to enhance performance and long term stability of DFAFC. As a result, to date, the DFAFC having the power density of more than $300mW/cm^2$ was developed. In this paper, basic performing theory and configuration of DFAFC are initially introduced and future opportunities of DFAFC including the development of catalyst for the anode electrode and electrolyte, and design for the optimization of cell structure are discussed.

Research on Characteristics of Multifunctional Soil Binder Based on Polyacrylamide (폴리아크릴아마이드를 기반으로 하는 다기능성 토양안정제의 특성에 관한 연구)

  • Kim, Jin Kyung;Kim, Dae Ho;Joo, Sang Hyun;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.155-161
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    • 2018
  • For the efficient recovering of collapsed sloped soil, using a soil binder that can support the soil strongly and help the growth of plants is very important. The soil binder should also have functions of recovering the soil ecologically as well as be environmental friendly materials. In this research, optimum values of the water content and permeability and direct shear strength were searched by adding the water absorbent and coagulant into the soil binder. The polyacrylamide (PAM) with various anionic strength, super absorbent polymer (SAP) and cellulose ether (CE) were used as a soil binder, water absorbent and coagulant, respectively. Effects of the soil binder on the characteristics of soil were observed by changing the mixing ratio of PAM, SAP and CE. Experimental results showed that the soil binder increased the direct shear strength tens of times and the water content around two times, whereas decreased the water permeability. Also, the addition of CE to increase the coagulation of SAP increased more of the direct shear strength and water content.

Partial premixed combustion modeling of diffusion flame burner for SiO2 deposition as optical fiber cladding (광섬유 클래딩용 SiO2 증착을 위한 확산 화염 버너의 부분 예혼합 연소 모델링)

  • Park, Hyung-Bin;Han, Yoonsoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.365-371
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    • 2019
  • In this study, the flame temperature distribution of the diffusion flame burner for SiO2 deposition was analyzed by the computational fluid analysis. This corresponds to the previous step for simulating the SiO2 preform deposition process for manufacturing optical fibers using environmentally friendly raw materials. In order to model premixed combustion, heat flow, convection, and chemical reactions were considered, and Reynolds-averaged Navier-Stokes equations and k-ω models were used. As a result, the temperature distribution of the flame showed a tendency to increase the distance from the nozzle surface to the maximum temperature when the flow rate of the auxiliary oxygen increased. In addition, it was confirmed that the temperature distribution due to incomplete combustion was large in the combustion reaction with a large equivalence ratio of the mixed gas.

Deicing Performance of Environment-friendly Deicing Agents (친환경 제설제인 CMO의 성능평가 분석)

  • Lee, Seung-Woo;Woo, Chang-Wan;Kim, Jong-Oh;Park, Hee-Mun
    • International Journal of Highway Engineering
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    • v.7 no.3 s.25
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    • pp.53-62
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    • 2005
  • Efficient snow-removing work is one of important processes of winter road management. Calcium chloride has been used as a typical deicing agent in Korea. It presents superial performance as snow deicing agents, however it has been known to give serious environmental problem and to deteriorate durability of concrete structure in road by corrosion. The environment-friendly road deicing agents made from the waste material which is liquid phase organic matter that is Ca Mg and reactant of organic acid (nitric acid and propionic acid) have been introduced by number of researchers. They indicated the calcium magnesium salt of organic acids have advantage over the calcium choride in terms of lower production unit cost by resources recycling and can solve environmental problem and durability deterioration of structures. In this study, the deicing performance of calcium magnesium salt of organic acids(CMO) is investigated based on the series of experiments including the test for heat of dissolution, freezing point, ice melting test and ice penetration test.

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$TiO_2$ 기반 가시광 응답형 광촉매의 수소 생산

  • Choe, Jin-Yeong;Park, Won-Ung;Jeon, Jun-Hong;Mun, Seon-U;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.394-394
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    • 2011
  • 급속한 산업의 발달은 심각한 환경오염 및 에너지 문제를 가져왔다. 이를 해결하기 위하여 무한한 에너지원인 태양에너지를 원천으로 하는 친환경 정화소재로서의 광촉매(photocatalyst)를 통하여 인류의 에너지를 확보하는 것에 대한 관심이 급격하게 증가하고 있는 추세이다. 현재 광촉매로 가장 많이 사용되는 $TiO_2$의 경우 뛰어난 광활성과 저렴한 가격, 광 안정성, 화학적 안정성을 가짐에도 불구하고, 3.2 eV라는 상대적으로 넓은 band gap을 가지기 때문에 약 386 nm보다 짧은 파장을 갖는 자외선만 흡수할 수 있다. 이로 인한 가시광 응답성의 부재를 해결하기 위해 수십년간 많은 연구가 진행되어 왔다. 따라서 본 연구에서는 ICP assisted pulsed DC reactive magnetron sputtering을 이용하여 $TiO_2$를 기반으로 하면서 가시광영역의 빛을 흡수하여 높은 효율을 얻을 수 있도록 Nitrogen doping, Low band gap semi-conductor sensitization 등의 방법을 사용하여 광촉매를 제작하였다. 시료의 chemical state와 crystallinity를 확인하기 위하여 X-ray photoelectron spectroscopy와 X-ray diffraction method를 이용하여 분석을 수행하였으며, 이러한 공정을 통해 제작된 $TiO_2$기반 광촉매의 가시광 응답성을 확인하기 위하여 UV/Vis 스펙트럼을 측정하였다. 또한 물 분해 장치(water splitting device)를 제작하여 수소와 산소 생성시 흐르는 전류를 측정하여 광특성을 평가하였다.

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