• Proceedings of the KIEE Conference
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• 2005.07b
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• pp.1285-1287
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• 2005

고온초전도 선재 중에서 YBCO 박막을 금속테이프에 증착하여 제조되는 coated conductor는 높은 자기장에서도 임계전류밀도의 감소가 크지 않아 고자장용 초전도 자석을 제조하는데 많이 활용될 것으로 기대되고 있다. coated conductor를 고자장용 초전도 자석제작에 활용하기 위해서는 긴 길이의 도체를 제조하는 것과 함께, 도체의 접합기술이 필요하다. 이는 초전도 자석을 영구전류모드로 운전하기 위해서는 도체의 접촉저항이 충분히 적어야 하기 때문이다. 그러나 박막형 coated conductor는 아직 긴 길이의 선재제조기술이 확립되어 있지 않고, 또 박막형 coated conductor의 형태와 사용되는 제조기술이 본질적으로 초전도 접합을 형성시키기에 매우 어려워서 아직 까지 초전도 접합에 대한 연구결과가 발표되지 않고 있으며, 접합 특성을 측정하는 기술도 개발되지 않았다. 본 연구에서는 coated conductor의 접합특성을 측정하기 위한 기본적인 시험방법을 제안하고, 전도성 금속접합재를 이용한 접합시료를 제작하여 그 특성을 평가한 결과를 발표한다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05a
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• pp.30-33
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• 2003

YBCO coated conductor, also called the 2nd generation high temperature superconducting wire, consists of oxide multi-layer hetero-epitaxial thin films. Pulsed laser deposition (PLD) is one of many film deposition methods used to make coated conductor, and is the one known to be the best to make superconducting layer so far. As a part of the effort to make long length coated conductor, the optimum deposition condition of YBCO film on single crystal substrate (SrTiO3) was investigated using PLD. Substrate temperature, oxygen partial pressure, and laser fluence were varied to find the best combination to grow high quality YBCO film.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.268-269
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• 2005

YBCO 박막형 초전도체(coated conductor) 제조를 위해서는 여러 층의 완충층이 필요하다. 현재 일반적인 완충층의 구조는 seed layer로써 $Y_2O_3$, diffusion barrier로 YSZ, capping layer로 $CeO_2$가 사용되고 있다. 특히, capping layer로 $CeO_2$는 YBCO와 lattice mismatch가 매우 우수한 산화물로 이용되고 있다 본 연구에서는 $CeO_2$ capping layer가 증착 방법에 따라 그 위에 증착되어지는 초전도층의 특성에 어떤 영향을 미치는지 연구하였다. $CeO_2$를 thermal evaporation과 PLD (pulsed laser deposition) 증착 방법으로 증착 한 후 그 위에 PLD 방법으로 YBCO를 증착하여 coated conductor의 성능을 평가하였다.

• Progress in Superconductivity and Cryogenics
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• v.12 no.3
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• pp.7-11
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• 2010

For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. In this work, we investigated electric characteristic of YBCO films on $SrTiO_3$ (100) substrates whose surfaces were modified by the introduction of Au nanoparticles (AuNPs). Au nanoparticles were uniformly dispersed on STO substrates with one of typical solution techniques, self assembled monolayer. After heating the STO substrates with Au nanoparticles, the size of Au nanoparticles was around 29~32 nm in height and 41~49 nm in diameter. XRD diffraction patterns taken on the YBCO film with Au nanoparticles show the c-axis orientation. The measured $T_c$ of YBCO /AuNPs films was around 89K and the $J_c$ was 0.75 MA/$cm^2$ at 65 K and 1 T.

• Progress in Superconductivity and Cryogenics
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• v.6 no.1
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• pp.12-17
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• 2004

High critical current density. $J_c$ over $1MA/cm^2$ at 77 K in a self field was successfully achieved from the YBCO film prepared on (100) $SrTiO_3$ single-crystal substrates by the TFA-MOD process. Unlike a normal TFA-MOD process, we prepared the TFA precursor solution by dissolving YBCO powder into the trifluoroacetic acid. A significant amount of the second phases, including $BaF_2$, was observed in the films fired at $700-725^{\circ}C$ for 2 h under $P(O_2)=10^{-3}$ atm and $P(H_2O)=4.2%$, most probably due to an insufficient reaction time, and hence $T_c$ was greatly degraded. However the films fired at $750-800^{\circ}C$ for 2 h were composed of strongly c-axis oriented YBCO grams without any second phases. and exhibited the $T_c$ values of 89.5 ~ 91 K with a sharp transition. With increasing the firing temperature from 750 to $800^{\circ}C$ average grain size of YBCO was increased and grain connectivity was enhanced. The highest $J_c$ value of $1.1MA/cm^2$ was obtained from the YBCO film fired at $800^{\circ}C$.

• Progress in Superconductivity
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• v.5 no.1
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• pp.80-83
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• 2003

Superconducting YBCO thin films are fabricated on single-crystalline substrates by Metallo-organic Depostion process employing Trifluoroacetic acid as a chelating agent (MOD-TFA). (100)-oriented single crystalline LaAlO$_3$ substrates were employed to grow superconducting film with high crystallinity. The fully processed YBCO thin films were characterized with XRD, SEM, EDS, etc. The microstructures of YBCO thin films show labyrinth-like patterns. The origin of this microstructure was delineated by compositional inhomogeneity during the MOD process and it was shown that the microstructure may be modified by additives. In this work, effects of additives on the microstructures and electrical properties of YBCO thin films have been investigated.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2002.02a
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• pp.138-140
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• 2002

We fabricated textured Ni substrate for YBCO coated film and evaluated the degree of texture in terms of rolling condition and annealing time. The substrate was compacted from pure Ni powder and reduced the thickness to 100 $\mu$m by rolling followed by heat treatment. As decreasing the thickness of substrate, it was observed that the non-uniform deformation such as ‘wave edge’ or ‘wave buckle’ developed locally on it, causing reduced texture. On the other hand, uniformly deformed substrate showed better cube texture indicating the FWHM of in-plane and out-of-plane of about $11^{\circ}$ ~ $14^{\circ}$. In addition, annealing at $1000^{\circ}C$ for 1~ 8 hr did not make a remarkable difference on the texture.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.4
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• pp.391-397
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• 2006

We present investigations of a hybrid type superconducting fault current limiter (SFCL), which consists of transformers and resistive superconducting elements. The secondary windings of the transformer were separated into several electrically isolated circuits and linked inductively with each other by mutual flux, each of which has a superconducting current limiting element of $YBa_2Cu_3O_7$ (YBCO) stripes as a current limiting element. Simple connection in series of the SFCL elements tends to produce ill-timed quenching because of power dissipation unbalance between SFCL elements. Both electrical isolation and mutual flux linkage of the elements provides a solution to power dissipation unbalance, inducing simultaneous quench and current redistribution of the YBCO films. This design enables to increase the voltage rating of SFCL with given YBCO stripes.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2001.02a
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• pp.92-94
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• 2001

We investigated quench recovery characteristics of Au/YBCO thin film meander lines. YB$a_{2}$$Cu_{3}$ $O_{7}$films were coated in-situ with a gold layer and patterned into 2 mm wide meander lines by photolithography. The limiters were tested with simulated fault currents at various source voltages. Resistance decreased first slowly and then rapidly to zero. Resistance vs. time curves for different source voltages fell on top of each other when translated horizontally. The slowly varying portion of data fell on straight lines of a slope on a semi-log scale at all source voltages. A heat balance equation reflecting heat loss from meander lines to surroundings explains these results quantitatively.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 1999.02a
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• pp.26-29
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• 1999

Superconducting $YBa_{2}$$Cu_{3}$ $O_{7-x}$(YBCO) thin films were deposited on MgO(100) substrates using a hollow cathode discharge sputtering system. Influence of the sputtering conditions such as substrate temperature and discharge sputtering gas pressure on electrical and structural properties were investigated. It was found that YBCO thin films with zero resistance temperature higher than 85 K were obtained to the pressure 200 mToorr(Ar/O2=0.9), substrate temperature of $760^{\circ}C$, and target-substrate distance of 10 mm during film deposition. Homogeneous large area YBCO films with 2 inch diameter were also sucessfully fabricated by this method.