• Plant Journal
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• v.9 no.2
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• pp.42-45
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• 2013

The worldwide issue of greenhouse gas reduction has recently drawn great attention to carbon capture and storage(CCS). In this study, we developed a 10,000 ton/year pilot injection plant for geological storage of carbon dioxide. Major components of the pilot plant include a pressure pump, a booster pump, and an inline heater to bring liquid carbon dioxide into its supercritical state. The test results show that the pilot plant readily achieves the injection pressure and temperature, showing satisfactory control performance. The overall power consumption is 2,000 ~ 2,500 W, more than 75% of which consumed by the pressure pump. This study will facilitate varied research on greenhouse gas reduction as the only domestically developed system for geological injection.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.1
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• pp.131-139
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• 1999

Experimental investigations on flame spread in droplet arrays have been conducted under supercritical ambient pressures of fuel droplet. Flame spread rates are measured for n-Decane droplet of diameters of 0.75 and 1.0mm, using high speed images of OH chemiluminescence up to 3.0MPa. The pattern of flame spread is categorized into two: a continuous mode and an intermittent one. There exists a limit droplet spacing, above which flame spread does not occur. Flame spread rate with the decrease of droplet spacing increases and then decreases after takin& a maximum. It is also seen that there exists a limit ambient pressure, above which flame spread does not occur. Flame spread rate decreases monotonically with the increase of ambient pressure. Exceptionally, In the case of a small droplet spacing, flame spread with the increase of ambient pressure is extended to supercritical pressures of fuel droplet. This is caused by enhanced vaporization with the increase of ambient pressure. Consequently, in flame spread with droplet droplet spacing, the relative position of flame to droplet spacing plays an important role. The monotonic decrease with ambient pressure is mainly related to the reduction of flame radius in subcritical pressures and the extension to supercritical pressures of flame spread is caused by the reduction of ignition time of unburnt droplet due to the enhanced vaporization at supercritical pressures.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.2
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• pp.259-266
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• 2010

The heat flowrate and pressure dorp of $CO_2$ in a multi-tube-in-tube helical coil type gas cooler were predicted using LMTD method and compared with the experimental data. The mass flowrate of $CO_2$ and coolant were varied from 0.06 to 0.075 [kg/s], and the cooling pressure of gas cooler were from 8 to 10 [MPa], respectively. The LMTD method is used to predict the heat flowrate and pressure drop of supercritical $CO_2$ during in-tube cooling. The equations used by LMTD method were Gnielinski correlation for $CO_2$ and Dittus-Boelter correlation for coolant, respectively. The equation used to predict the pressure drop of $CO_2$ and coolant is Blasius correlation. In comparison of heat flowrate and pressure drop of $CO_2$ measured by experiment to that predicted by LMTD method, the experimental heat flowrate and pressure drop of $CO_2$ in the multi-tube-in-tube helical coil type gas cooler shows a relatively good agreement with that predicted by LMTD method.

• Korean Journal of Pharmacognosy
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• v.30 no.1
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• pp.59-64
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• 1999

Supercritical fluid extraction (SFE) technique was applied to extract cytotoxic substances from five medicinal plants including Angelica gigas, Angelica acutiloba, Aralia cordata, Spirodela polyrhiza, Bupleurum falcatum, and Acanthopanax sessiliflorus. The cytotoxicities against P388, A549, and HL-60 cell lines were determined for the supercritical carbon dioxide extracts of five plant materials employed and were compared with those of the conventional organic solvent extracts such as n-hexane, $CHCl_{3}$, and MeOH to evaluate the SFE as an alternative method to conventional organic solvent extraction. In most cases, the SFE extracts of plant materials showed enhanced cytotoxicities when compared with those of other organic solvent extracts. In addition, the optimum temperature and pressure of SFE for extraction of the cytotoxic substances were largely affected by both the plant species and the cell lines tested. These results suggested that SFE could be an alternative to the conventional organic solvent method for the selective extraction of cytotoxic compounds from plants.

• Journal of Power System Engineering
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• v.18 no.5
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• pp.42-47
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• 2014

In this paper, the cycle performance analysis for the COP of supercritical heat pump using various refrigerants is presented to offer the basic design data for the operating parameters of the system. The working fluids are R134a, R22, R32, R290, R600, R600a, R1270 and R744. The operating parameters considered in this study include superheating degree of evaporator, temperature of gas cooler inlet and outlet, compressor efficiency and evaporating temperature in the supercritical heat pump system. The main results were summarized as follows : Superheating degree, temperature of gas cooler inlet and outlet, compressor efficiency and evaporating temperature of supercritical heat pump system have an effect on the COP of this system. With a thorough grasp of these effect, it is necessary to design the supercritical heat pump using R134a. And, in comparison of COP of supercritical heat pump using various refrigerants, R32 and R600 is the highest, and R744 is the lowest among other refrigerants. From these results, it is confirmed that the COP of supercritical heat pump using R744 is higher than that using freon refrigerants such as R32 and R134a.

• KSBB Journal
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• v.25 no.1
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• pp.1-10
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• 2010

Biodiesel is a type of biofuel obtained from bioresources and able to use in diesel vehicles as an alternative/additive to petro diesel. In recent biodiesel research, there are three main issues which include high quality biodiesel, low cost feed stock and a highly efficient biodiesel production process. The sustainable production and use of biodiesel are attracting much attention in the renewable energy field. In this paper, we review some of the literatures related to environmental and economic evaluation for biodiesel production and analysis the issues including life cycle assessment (LCA), global warming potential (GWP), energy consumption, biodiesel production cost, production technologies and feedstock.

• KSBB Journal
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• v.22 no.3
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• pp.174-178
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• 2007

The aim of this study was to identifyisothiocyanates (ITCs) from wasabi (Wasabi japonica Matsum) using supercritical carbon dioxide ($SCO_2$) and to compare the composition in the extracts between $SCO_2$ and organic solvents extraction. A semi-continuous high pressure apparatus was used to extract wasabi (roots, stems and leaves) at following conditions pressure 80$\sim$120 bar, temperature $40\sim50^{\circ}C$. Ether, ethanol, chloroform and dichloromethane were used as organic solvents. The ITCs extracted by means of both separation technologies were analyzed by a gas chromatography system. As the results of study, AITC and ITCs were highly extracted at 40$^{\circ}C$ and 80 bar. To extract AITC from wasabi, $SCO_2$ extraction is more effective than organic solvents extraction, resulted in thermal degeneration and remaining of organic solvents.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.23 no.5
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• pp.385-393
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• 2013

In this paper, the mechanism identification and the avoidance measures on the phenomena of transient acoustic vibration amplified at the water-supply piping system to regulate the steam temperature of the boiler reheater in 500MW class supercritical power plant are presented. The pressure pulsation waves induced by the impeller passing of two feed-water pumps with five blades are coincident with the local acoustic modes of boiler reheater water-supply piping system. There are the phenomena amplified at the peaks of 5X, 10X, 15X and 20X in spectrums of piping vibration, sound pressure, and the feed-water's pressure pulsation waves. The shut-off device is installed in the piping system for the interception of pressure pulsation waves transmitted from two feed-water pumps and the modified design change of the piping layout is applied for the acoustic resonance avoidance. The acoustic natural frequencies are separated from the harmonics of pressure pulsation waves induced by the pump impellers passing through the design change of the span length. The acoustic vibration is gone by resonance avoidance measures. As a result, more than 20 dBA reduction is achieved from 100 dBA to 80 dBA.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.763-767
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• 2010

High-pressure phase behavior for the binary mixture of 1-propanol with supercritical $CO_2$ has been measured by means of a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The equilibrium loci of the pressure - composition and pressure - temperature were obtained for the binary mixture of 1-propanol + $CO_2$ system at 305.15 K, 313.15 K, 323.15 K and 333.15 K, and from 2 MPa to 11 MPa. The critical temperature of the mixture increased with the temperature. The pressure-composition line for the binary mixture of $CO_2$-1-propanol system showed a typical type-II phase behavior. The experimental P-x envelopes were correlated by using the Peng-Robinson equation of state in a satisfactory manner to obtain the parameters with $k_{ij}=0.116$ and ${\eta}_{ij}=-0.065$.