• Clean Technology
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• v.17 no.1
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• pp.37-40
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• 2011

Some ionic liquids are suitable for catalysts and solvents which are applicable to $CO_2$ fixation reaction converting $CO_2$ to carbonate. Using the ionic liquids, the synthesis process will become greener and simpler because of easy catalyst recycling and unnecessary use of volatile and harmful organic solvents. In this work, the synthesis of propylene carbonate from propylene oxide using carbon dioxide and ionic liquids were measured at high pressures up to ~140 bar and at temperatures between $60^{\circ}C$ and $80^{\circ}C$. As a results, we found the optimum condition and obtained the maximum yield under that condition.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.1-9
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• 2017

The cryogenic nitrogen spray of a swirl injector has been numerically investigated using three dimensional LES turbulence model to analyze the dynamic characteristics under supercritical condition. To predict the precise nitrogen properties under supercritical condition, SRK equation of state, Chung's method for viscosity and thermal conductivity and Takahashi's correlation based on Fuller's theory for diffusion coefficient are implemented. The complex flow structures due to interaction between flow field and acoustic field are observed inside and outside the injector under supercritical condition. FFT, POD, and DMD techniques are employed to understand the coherent structures. By implementing the FFT, the dominant frequencies are identified inside and outside the injector. The coherent flow structures related to the dominant frequencies are visualized using the POD and DMD techniques. In addition, the DMD provides the damping coefficient which is related with the instability prediction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.1
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• pp.140-148
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• 1999

Experiments on flame spread in an one-dimensional droplet array up to supercritical pressures of fuel droplet have been conducted In normal gravity and microgravity. Evaporating process around unburnt droplet is observed through high-speed Schlieren and direct visualizations in detail, and flame spread rate is measured using high speed chemiluminescence images of OH radical. Flame spread behaviors are categorized into three: flame spread is continuous at low pressures and is regularly intermittent up to the critical pressure of fuel. flame spread is irregularly intermittent and zig-zag at supercritical pressures of fuel. At atmospheric pressure, the limit droplet spacing and the droplet spacing of maximum flame spread rate in microgravity are larger than those in normal gravity. In microgravity, the flame spread rate with the increase of ambient pressure decreases initially, takes a minimum, and then decreases after taking maximum. This is so because the flame spread time is determined by competing effects between the increased transfer time of thermal boundary layer due to reduced flame diameter and the reduced ignition delay time in terms of the increase of ambient pressure. Consequently, it is found that flame spread behaviors in microgravity are considerably different from those in normal gravity due to the absence of natural convection.

• KSBB Journal
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• v.15 no.1
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• pp.80-83
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• 2000

Polyacetylenes were extracted from Korean ginseng using supercritical $CO_2$ Yield of extraction of panaxydol and panaxynol was increased as the pressure of supercritical $CO_2$ increased at the range from 200 to 300 bar. The optimal yields of panaxydol and panaxynol was achieved at 65 and $55^{\circ}C$, respectively. Methanol was applied as a modifier. The highest yield of panaxydol and panaxynol were 0.230 and 0.054 mg/g-dry weight at modifier concentration of 10%(w/w), 300 bar, and $65^{\circ}C$. When these results were compared to that of methanol-extraction, the recoveries of panaxydol and panaxynol by supercritical $CO_2$ extraction in SFE were 37.8 and 55.1%, respectively.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.53-56
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• 2015

In this study, investigated the synthesis method of p-Phenylenediamine (PPD) by amination of p-Diiodobenzene (PDIB) under supercritical ammonia and CuI catalyst conditions. We examined the effects of various process variables (e.g., reaction temperature, pressure, amount of ammonia inserted, amount of catalyst inserted, and reaction time) on the production yield of PPD by analyzing the Gas Chromatography (GC). The experimental results demonstrated that PPD was not produced under non-catalyst conditions, and PPD production yield increased with increasing temperature, pressure, amount of catalyst inserted, and reaction time. However, for the reaction temperature case, it was found that $200^{\circ}C$ was the optimal temperature, because thermal degradation of PPD occurred above $250^{\circ}C$. In addition, we confirmed the structure of PPD and the bonding characteristics of the amine group via FT-IR and H-NMR analysis.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.3
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• pp.500-508
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• 2004

The heat transfer coefficients during gas cooling process of carbon dioxide in a horizontal tube were investigated. The experiments are conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater, and a gas cooler(test section). The water loop consists of a variable-speed pump, an isothermal tank, and a flow meter. The gas cooler is a counterflow heat exchanger by cooled water flowing in the annulus. The $CO_2$ flows in the horizontal stainless steel tube. which is 9.53mm in O.D. and 7.75mm in I.D. The gas cooler is 6 [m] in length. which is divided into 12 subsections, respectively. The experimental conditions considered in the study are following range of variables : refrigerant temperature is between 20 and $100^{\circ}C$. mass fluxes ranged from 200 to 400kg/($m^2$.s), average pressure varied from 7.5 to 10.0MPa. The main results were summarized as follows : The friction factors of $CO_2$ in the gas cooler show a relatively good agreement with those predicted by Blasius' correlation. The local heat transfer coefficient in the gas cooler has compared with most of correlations, which are the famous ones for forced convection heat transfer of turbulent flow. The results show that the local heat transfer coefficient of gas cooler agrees well with the correlation by Bringer-Smith except that at the region near pseudo critical temperature. while that at the near pseudo critical temperature is higher than the correlation.

• Tribology and Lubricants
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• v.34 no.2
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• pp.43-48
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• 2018

This paper presents the thermohydrodynamic analysis of tilting journal pad bearings supporting a power turbine rotor applied to a 250 kW super-critical $CO_2$ cycle. In the analysis, the generalized Reynolds equation and 3D energy equation are solved to predict oil film temperature and the 3D heat conduction equation is solved for pad temperature. The power turbine rotor is supported by two tilting pad bearings consisting of five pads with an oil supply block between the pads. Copper backing pads with higher thermal conductivity compared to steel backing pads are adopted to improve thermal management. The predicted maximum pad temperature is around $55^{\circ}C$ which is approximately $15^{\circ}C$ higher than oil supply temperature. In addition, the predicted minimum film thickness is 50 mm at a rotating speed of 5,000 rpm. These results indicate that there is no issue in the thermal behavior of the bearing. An operation test is performed with a power turbine module consisting of a power turbine, a reduction gear and a generator. Thermocouples are installed at the 75% position from the leading edge of the pad to monitor pad temperature. The power turbine uses compressed air at a temperature of $250^{\circ}C$ in its operation. The steady state pad temperatures measured in the test show good agreement with the predicted temperatures.

• Journal of the Korean Applied Science and Technology
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• v.35 no.2
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• pp.540-559
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• 2018

The utilization of sewage sludge for liquid biofuel production is considered as a approach for achieving better energy security, sustainable productivity and economical raw material. Thermochemical technologies of sewage sludge into energy and fuel has been considered as one of the most effective process. Generally, sewage sludge contains more than 80% of moisture, has high metal contents and 14 ~ 20 MJ/kg of calorific value. This paper reviews the technologies of converting sewage sludge to liquid biofuel via three main thermochemical conversion processes namely pyrolysis, transesterification and supercritical. The fuel properties of liquid fuels produced by different technologies from sewage sludge and definition in relevant laws for liquid biofuels in Korea are also discussed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.10
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• pp.779-786
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• 2015

The objective of this study is to propose a new channel shape that improves thermal-hydraulic performance. The existing Zigzag channel has high pressure loss due to flow separation and reverse flow. To improve this disadvantage, partial straight channel is inserted into bended points. Also, the effects of straight channel's length change on heat transfer and pressure loss are analyzed. Thermal-hydraulic performance of the new shape and existing Zigzag channel are quantitatively compared in terms of Goodness Factor. Mass flow rate was changed from $1.41{\times}10^{-4}$ to $2.48{\times}10^{-4}kg/s$. The average volume goodness factor of 1mm straight channel shape was increased by 25% compared to the Zigzag channel.

• KSBB Journal
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• v.23 no.2
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• pp.153-157
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• 2008

Maca (Lepidium meyenii) has been used as a food and medicine in Peru for thousands of years. More recently a wide array of commercial maca products have gained popularity as dietary supplements with claims of anabolic and aphrodisiac effects. Even though the biologically active principles of maca are not fully known, the lipidic extract of maca tubers containing macamides showed promising physiological activities. In this study, the lipidic extract were collected from maca tubers by using supercritical carbon dioxide ($SCO_2$). Substance estimated as macamide in the extract was isolated and purified by preparative HPLC with recycling system. Two of the purified substance was identified as N-benzyl-5-oxo-6E,8E-octadecadienamide and N-benzylhexadecan amide by LC/MS, $^1H$-NMR and $^{13}C$-NMR analyses.