• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.578-584
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• 2021

This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)₂ consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.3
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• pp.1040-1046
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• 2010

The main disadvantage of rapid setting concrete is the occurrence of cracking because of fast hydration reaction due to high thermal expansion and shrinkage. However, if the fly ash is used in concrete, it is possible to prevent cracking since the hydration heat can be decreased. Although Very-Early Strength-Latex Modified Concrete(VES-LMC) is an excellent material, occurrence of cracking has been reported because of high hydration heat. In the present study, new method which can apply the fly ash to the VES-LMC was developed. Research for the new method to improve the safety for the cracking was conducted. Safety was confirmed by reducing the shrinkage and hydration heat in the condition of overcoming the low early-age strength. Detailed conclusions are follows. Early-age compressive strength was decreased a little with increase of UFFA content. However, 28-d compressive strength was statistically insignificant regardless of UFFA contents. If the UFFA is replaced 15% to 20% of unit cement weight in concrete, maximum shrinkage can be reduced up to 43% to 47%. Usage of UFFA in VES-LMC guarantees the safety for cracking since it is very effective to control of early-age shrinkage.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.349-356
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• 2016

This report presents the results of an investigation on the early strength development of pastes high volume slag cement (HVSC) activated with different concentration of sodium carbonate ($Na_2CO_3$). The ordinary Portland cement (OPC) was replaced by ground granulated blast furnace slag (GGBFS) from 50% to 90% by mass, the dry powders were blended before the paste mixing. The $Na_2CO_3$ was added at 0, 2, 4, 6, 8 and 10% by total binder (OPC+GGBFS) weight. A constant water-to-binder ratio (w/b)=0.45 was used for all mixtures. The research carried out the compressive strength, ultrasonic pulse velocity (UPV), water absorption and X-ray diffraction (XRD) analysis at early ages(1 and 3 days). The incase of mixtures, V5 (50% OPC + 50% GGBFS), V6 (40% OPC + 60% GGBFS) and V7 (30% OPC + 70% GGBFS) specimens with 6% $Na_2CO_3$, V8 (20% OPC + 80% GGBFS) and V9 (10% OPC + 90% GGBFS) specimens with 10% $Na_2CO_3$ showed the maximum strength development. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of specimens indicated that the hydration products formed in samples were CSH and calcite phases.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.188-193
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• 2015

Blast Furnace Slag is good for enhancing the qualities of concrete such as reducing hydration heat increasing fluidity, long-term strength and durability, but it has some problems: construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, an aqueous alkali solution for alkali activated reaction was obtained by the electrolysis using concentrated water discharged from seawater desalination process. Prepared aqueous alkali solution was applied to produce mortars using blast furnace slag. The results can be summarized as follows : For the mortar, compressive strength was decreased below 2% of NaOH and increased below 6% of NaOH. And compressive strength was increased gradually with increasing NaOCl contents. However, NaCl contents of mortars caused a decrease of 28days strength above early strength.

• Applied Chemistry for Engineering
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• v.8 no.5
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• pp.822-829
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• 1997

When $Al_2(SO_4)_3$ as an accelerator was added to $\beta$-hemihydrate gypsum, the setting time, mobility and compressive strength properties of $\beta$-hemihydrate gypsum were examined with the adding of two types grounded gypsum crushed by ball mill. By 15wt% adding of 7% $Al_2(SO_4)_3$ dilute solution, the setting time of $\beta$-hemihydrate gypsum was sharply accelerated than that of non-added $\beta$-hemihydrate gypsum. When ground phospho gypsum(PG) and chemical gypsum(CG) were added to $\beta$-hemihydrate gypsum, the initial and final setting time of $\beta$-hemihydrate gypsum were accelerated markedly with the increasing of grinding time and added amount of ground phospho gypsum. Especially, this trend largely presented when ground phospho gypsum was added to $\beta$-hemihydrate gypsum. The compressive strength of $\beta$-hemihydrate gypsum added by ground phospho and chemical gypsum was largely increased at initial curing time such as 1, 3 days. Particularly, the compressive strength of $\beta$-hemihydrate gypsum added by ground phospho gypsum was increased by 15~20% than that of ground chemical gypsum.

• International Journal of Highway Engineering
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• v.12 no.3
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• pp.113-119
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• 2010

This study presents experimental findings on the performance of cement concrete pavement incorporating mineral admixtures such as ground granulated blastfurnace slag and silica fume. Flexural strength, compressive strength, charge passed, diffusion coefficient of chloride ions and initial surface absorption of cement concrete pavement incorporating mineral admixtures were periodically measured and the corresponding results were compared to those of plain concrete pavement. As a result, strength behaviors of concrete pavement were dependent on the types of mineral admixtures. However, it was true that incorporation of silica fume had a beneficial effect on compressive strength development. Furthermore, the application of mineral admixtures led to a lower diffusion coefficient of chloride ions compared to plain concrete pavement. Based on the experimental results, the present study would be helpful to design high-performance cement concrete pavement.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.629-632
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• 2008

As concrete is a material which is subject to wide quality fluctuations by temperature, grip of seasonal feature and maintenance of ambient temperature and humidity to secure the quality required after casting concrete are able to keep away from harmful effects. In case of summer, a high temperature has caused rapid hydration reaction of cement in early age, which has caused to decrease strength by autogenous shrinkage. Therefore we need to consider a countermeasure for decrease in the hydration heat of hot-weather concrete, according to minimize water and cement content and use mineral admixtures In this experimental research, the compressive strength development for replacement ratio of mineral admixtures, curing temperature and methods of concrete was investigated to confirm the effects of mixture design and curing condition on compressive strength of concrete.

• Journal of the Korea Institute of Building Construction
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• v.12 no.3
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• pp.315-322
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• 2012

The effect of ground granulated blast-furnace slag(GGBS) and alkali activator compressive strength, resistance of chloride attack and freezing-thawing is assessed to develop high volume slag concrete, the replacement rate of GGBS of which is more than 80 percent. result, as the replacement rate of GGBS increases, the compressive strength development properties of concrete in early and long term age decreased and resistance chloride attack and freezing-thawing is increased. The early strength development property, however, is extremely advanced by addition of the alkali activator, which is also found to improve resistance chloride attack and freezing-thawing.

• Journal of the Korea Institute of Building Construction
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• v.12 no.4
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• pp.393-400
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• 2012

The effect of ground granulated blast-furnace slag (GGBS) and alkaline activator on the properties of setting, compressive strength, drying shrinkage and resistance of carbonation was assessed to develop high volume slag concrete, the GGBS replacement rate of which was more than 80 percent. The changes in the concrete as the replacement rate of GGBS increases were as follows. Initial and final setting time was delayed by two and a half hours, and the compressive strength development properties of concrete in early and long term age were decreased. Drying shrinkage was satisfactory as below $6{\times}10^{-4}$ in every mixture, and yet showed a tangible trend by replacement rate. Carbonation was materially increased. Setting time and early strength development property, however, were extremely advanced by the addition of the alkaline activator. While drying shrinkage was improved by the alkaline activator, resistance to carbonation was not.

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.3
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• pp.292-303
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• 2002

This paper presents experimental results for early-age properties of concrete such as the setting time and strength, evaluated via the ultrasonic pulse velocity (UPV). Developing and using an automatically-recording monitoring system, the UPV's of mortar and concrete with various water to binder ratios (W/B) were measured during the first 24 hours. In addition, probe penetration and compression tests were conducted to measure the setting time and compressive strength, respectively. It was observed that the UPV's of mortar with high W/B remained constant during the first 6.5 hours and then abruptly began to increase at constant rates. On the other hand, the UPV of mortar with low W/B increased relatively slowly and gradually due to the setting retardation caused by the use of high range water reducing agent (HRWR). It was found that setting of concrete occurs when the UPV reaches a certain value. Moreover, it was concluded that the estimation formulas should incorporate the effects of W/B to more accurately estimate the early-age strength of concrete from the UPV.