• Title/Summary/Keyword: 초기농도

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Laboratory Study on the Settling Properties of Silty Mud (실트질 점토의 심강(沈降) 특성(特性)에 관한 연구)

  • Kim, Cha Kyum;Lee, Jong Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.3
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    • pp.85-93
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    • 1991
  • To investigate the effect of the initial sediment concentration ($C_o$) and bed shear stress (${\tau}_b$) on the settling properties of silty mud, deposition experiments were conducted in a recirculating flume using silty mud sediment taken from the Youngkwang coast which is located in the eastern Yellow Sea. The relative concentration, $C/C_o$ (C=depth averaged concentration), and the relative equilibrium concentration, $C_{eq}/C_o$ ($C_{eq}$=depth averaged concentration in the equilibrium state), have been found to depend much more strongly on the bed shear stress than initial concentration, and to increase with increasing bed shear stress. The minimum value. ${\tau}_{bmin}$, and maximum value. ${\tau}_{bmax}$, of critical bed shear stress for deposition of the Youngkwang sediment were deduced to be $0.017N/m^2$ and $1.25N/m^2$, respectively, and these values depend strongly on the properties of sediment (grain size and mineralogy). Formulas for the relative concentration and apparent median settling velocity in the range of ${\tau}_b{\geq}{\tau}_{bmin}$ were deduced. The apparent median settling velocity was found to depend much more strongly on the bed shear stress than the initial concentration and to decrease exponentially with increasing bed shear stress.

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Effect of Environmental Factors on By-products Production in Ethanol Fermentation (에탄올 발효에서 부산물 생성에 미치는 환경인자의 영향)

  • 김진현;유영제
    • KSBB Journal
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    • v.8 no.5
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    • pp.446-451
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    • 1993
  • In ethanol fermentation, by-products such as glycerol, acetic acid and lactic acid are produced along with ethanol. The effects of culture conditions on cell growth ethanol production and by-products biosynthesis were investigated in ethanol fermentation using S. cerevisiae. With increasing aeration rate or yeast extract concentration, ethanol and by-products biosynthesis decreased while final cell mass increased. With increasing glucose concentration or decreasing temperature, final cell mass, ethanol and by-products concentrations all increased. The optimal pH for the cell growth, ethanol and by-products productions was found to be pH 4.5. By-products biosynthesis was found, in general, to proceed with the ethanol biosynthesis. The results can be applied for the optimization of ethanol fermentation and for the recovery and purification of ethanol from the culture broth.

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Effect of Ruthenium Red and Ryanodine on Calcium Ion Metabolism in Oocyte and Early Embryo of Mouse (생쥐의 난자와 초기배아의 칼슘이온 대사에 미치는 Ruthenium Red와 Ryanodine의 영향)

  • Lee Joon Yeong;Hong Soon Cap;Kim Tae Sik;Min Byeong Yeol;Kim Haekwon;Yoon Yong-Dal
    • Development and Reproduction
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    • v.7 no.2
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    • pp.95-103
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    • 2003
  • Intracellular calcium is an important physiological factor in most cells, and ruthenium red and ryanodine play an important role as calcium modulators. Ruthenium red inhibits calcium-induced calcium release(CICR) from the intracellular calcium store. Ryanodine activates calcium release through ryanodine channel. The present experiment was performed to investigate the effects of two modulators on calcium ion metabolism and to determine their dose-dependency in oocyte and early embryo of mouse. Intracellular calcium ion concentration was measured in realtime by using confocal laser scanning microscope(CLSM) after loading of Fluo-3/AM in mouse oocytes and early embryos. Ruthenium red decreased intracellular calcium ion concentration in oocytes and early embryos at its high concentration(30, 300 $\mu$M). Ryanodine increased intracellular calcium ion concentration in oocytes and early embryos in low concentration(0.01 $\mu$M) but decreased that at higher concentrations(1, 10 $\mu$M). These results indicate that two modulators affected calcium ion metabolism in oocyte and early embryo of mouse, and their dose-dependency was different from somatic cell including myocytes.

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Biodegradation Kinetics of Benzene by Pseudomonas aeruginosa

  • 박춘하;김동주
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.235-238
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    • 2001
  • Monod kinetics에 관련된 주요 생분해 파라미터를 도출하기 위하여 microcosm 규모의 배치실험에서 BTEX 화합물에 대해 분해능이 우수한 Pseudomonas aeruginosa을 이용해 다양한 농도의 벤젠에 대한 분해기작을 고찰하였다. 벤젠의 생분해율(D)과 Maximumspecific growth rate ($\mu$$_{max}$)는 기질의 농도가 증가할수록 높아지다가 최고점에 도달 후에 점차적으로 감소하였으며 이것은 어느 한계점 이상의 벤젠 농도가 미생물의 생분해에 방해 요소로 작용한다는 것을 나타낸다. 그러나 미생물에 의한 벤젠 분해의 상관관계를 나타내는 yield coefficient(Y)는 벤젠의 초기 농도가 낮을수록 높은 값을 나타내었다. Microbial decay constant( b)와 half-saturation constant(K$_{c}$)는 각각 0.21~0.48day$^{-1}$와 218mg/$\ell$로서 문헌값 보다 높은 수치를 나타내었다. 실험으로부터 결정된 생분해 파라미터들은 초기 벤젠 농도에 따라 큰 차이를 보이므로 생분해 모델링에 사용할 파라미터는 기질농도에 따라 적절하게 선택되어야 한다고 사료된다.

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Determination of Optimized Operational Parameters for Photocatalytic Oxidation Reactors Using Factorial Design (요인분석법을 이용한 광촉매 산화반응조의 최적 운영인자 도출)

  • Hur, Joon-Moo;Cheon, Seung-Yul;Rhee, In-Hyoung;Kim, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.23 no.2
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    • pp.85-91
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    • 2004
  • The objective of this study is to determine the optimum conditions of operational parameters using factorial design for phenol degradation in photocatalytic oxidation reactors. Factorial design is widely used to select the dominant factors and their ranges in experiments involving several factors where it is necessary to study the effect of factors on a response. The effects of initial concentration of phenol, intensity of UV light and surface area of catalyst on phenol degradation were investigated. Two levels were considered in this study so that the experiment was a $2^3$ factorial design with three replicates. The experimental results show that an increase in initial concentration of phenol from 5 to 50 mg/L intensity of UV light from 5,000 to $20,000\;{\mu}W/cm^2$, and surface area of catalyst from 740 to $2,105\;cm^2$ enhanced the phenol degradation rate by an average of 1.86, 1.79, and 2.10 mg/L hr, respectively. Interaction effects do not appear to be as large on the phenol degradation rate as the main effects of single factors. The optimum working condition for photocatalytic oxidation reactors, despite the higher three factors the better removal rate, is the highest surface area or catalyst.

The Effects of high Energy(1.5MeV) B+ ion Implantation and Initial Oxygen Concentration Upon Deep Level in CZ Silicon Wafer (고 에너지 (1.5 MeV) Boron 이온 주입과 초기 산소농도 조건이 깊은 준위에 미치는 영향에 관한 연구)

  • Song, Yeong-Min;Mun, Yeong-Hui;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.55-60
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    • 2001
  • The effect of high energy B ion implantation and initial oxygen concentration upon defect formation and gettering of metallic impurities in Czochralski silicon wafer has been studied by applying DLTS( Deep Level Transient Spectroscopy), SIMS(Secondary ton Mass Spectroscopy), BMD (Bulk Micro-Defect) analysis and TEM(Transmission Electron Microscopy). DLTS results show the signal of the deep levels not only in as-implanted samples but also in low and high temperature annealed samples. Vacancy-related deep levels in as- implanted samples were changed to metallic impurities-related deep levels with increase of annealing temperature. In the case of high temperature anneal, by showing the lower deep level concentration with increase of initial oxygen concentration, high initial oxygen concentration seems to be more effective compared with the lower initial oxygen one.

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Analysis of Characteristics of Cohesive Sediment Settling (점착성 퇴적물의 침전 특성 분석)

  • Kim, Jong-Woo;Yoon, Sei-Eui;Lee, Jong-Tae
    • Journal of Korea Water Resources Association
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    • v.38 no.2
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    • pp.133-142
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    • 2005
  • The settling concentration of fine suspended solid particles(alumina(Al$_2$O$_3$) and quartz(SiO$_2$)) is investigated with the physico-chemical effects(initial concentration, pH and NaCl). Laboratory tests have confirmed the significant influence of increasing initial concentration and salinity which can lead to flocculation due to the intermolecular attraction. Furthermore, the influence of the pH value on the concentration-time corves of alumina has been on firmed. Besides a numerical model to predict the behaviour of cohesive deposit under still water is analyzed by solving the unsteady one-dimensional diffusion-advection equation with a explicit, implicit, Crank-Nicolson and finite difference scheme. The model predicts the existence of an equilibrium concentration. Application of the model with implicit centered difference to data from settling experiments shows a similar distribution.

Dechlorination of Atrazine in Sediment Using Zero Valent Iron (영가철($Fe^0$)을 이용한 퇴적물내 Atrazine의 탈염소화)

  • Kim, Geon-Ha;Jeong, Woo-Hyeok;Choe, Seung-Hee
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.33-40
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    • 2006
  • Residual pesticides discharged from diffuse sources at agricultural area in association with suspended solid will be settled at downstream, and may degrade surface water quality. This research studied dechlorination kinetic of atrazine, one of triazine-category herbicide, using zero-valent iron (ZVI) in sediment. It can be observed from the experiments that buffer capacity of sediment helped pH maintained beutral, resulted in continuous dechlorination. Sediments were spiked with atrazine at 10, 30, and 50 mg atrazine/L of total sediment for batch experiments. Dechlorination constants were $1.38x10^{-1}/d$ for the initial concentration of 10 mg/L, $1.29x10^{-l}/d$ for 30 mg/L, and $7.43x10^{-2}/d$ for 50 mg/L while dechlorination constants of initial concentration of 50 mg/L without ZVI adding were estimated as $3.05x10^{-2}/d. Half lifes atrazine by ZVI were estimated as 5.03 d fur 10 mg/L, 5.38 d for 30 mg/L, and 9.33 d for 50 mg/L, respectively.

Fe$^{\circ}$/$H_2$$O_2$시스템을 이용한 고농도 유류오염 미세토양의 화학적 산화처리

  • 장윤영;지원현;김지형;황경엽
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.34-37
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    • 2001
  • 폐수처리분야에 널리 사용되어 온 펜톤산화반응을 응용한 Fe$^{\circ}$/$H_2O$$_2$시스템을 이용하여 고농도 유류오염 미세호양(100$\mu\textrm{m}$이하)의 화학적 산화처리 실험을 수행하였다. 반응은 100$m\ell$, 삼각프라스크에 오염토양(5g)과 반응시약을 주입한 후 자석교반기를 이용하여 회분 식으로 진행하였으며 일정 시간(0, 1, 2, 4, 8, 24hr)별로 TPH를 측정하였다. 그리고 각 조건별 시간에 따른 반응특성을 살펴보았다. 일반적으로 알려진 펜톤산화반응의 수요 반응조건인 초기 pH /$H_2O$$_2$ 및 Fe$^{\circ}$의 주입농도, 그리고 초기 디젤오염농도의 조건을 변화하며 각 조건별 처리효과를 알아보았다. 본 연구결과에서 최적 pH조건은 3인 것으로 나타났으며, 분말철(Fe$^{\circ}$)과 $H_2O$$_2$의 주입농도를 증가함에 따라 오염토양의 TPH 제거효율도 비례적으로 향상되었다. 초기오염농도에 따른 최종 처리효율은 큰 차이가 없었으나. 고농도 오염일수록 제거된 디젤의 총량은 크게 나타나. 본 논문에서 제시한 방법이 고농도 오염토양일수록 더 큰 효과를 얻을 수 있음을 보여주었다. 대부분의 반응이 반응개시 후 약 8시간 이내에 이루어졌는데, 반응에 수반되는 pH 상승과 그에 따른 반응성의 저감효과를 일정 pH 조절에 의해 감소시킴으로써 반응성의 향상을 좀 더 높일 수 있을 것으로 판단된다. 결론적으로, Fe$^{\circ}$/$H_2O$$_2$시스템을 이용한 화학적 산화처리방법은 경제성과 처리성능에서 고농도 유류오염 미세토양의 효율적인 처리방안으로서 향후 적용 가능성이 높을 것으로 기대된다.

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