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Synthesis and Electrochemical Characteristics of Carbon added Li3V2(PO4)3 (탄소첨가한 Li3V2(PO4)3의 합성 및 전기화학적 특성)

  • Jo, Yeong-Im;Na, Byung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.15 no.2
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    • pp.101-108
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    • 2012
  • The purpose of this study was to improve the conductivity of $Li_3V_2(PO_4){_3}$ by adding carbon source so that the discharge rate and cyclic properties were improved. Glucose and CNT were added to $Li_3V_2(PO_4){_3}$ and the structure and electrochemical properties were studied. $Li_3V_2(PO_4){_3}$, $Li_3V_2(PO_4){_3}$/C and $Li_3V_2(PO_4){_3}$/CNT were synthesised by solid state reaction using hydrogen reduction method at 600, 700, 800, $900^{\circ}C$. The cathode materials were assembled to coin cell type 2032 with Lithium metal as a counter electrode. The coin cell was galvanostatically evaluated in the voltage range of 3.0~4.8 V.

Video Image Analysis in Accordance with Power Density of Arcing for Current Collection System in Electric Railway (전기철도 집전장치의 아크량에 따른 비디오 이미지 분석)

  • Park, Young;Lee, Kiwon;Park, Chulmin;Kim, Jae-Kwang;Jeon, Ahram;Kwon, Sam-Young;Cho, Yong Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.9
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    • pp.1343-1347
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    • 2013
  • This paper presents an analysis methods for current collection quality in catenary system by means of video image based monitoring system. Arcing is the sparking at the interface point between pantograph and contact wire when the electric trains have traction current values at speed. Percentage of arcing at maximum line speed is measurable parameters for compliance with the requirements on dynamic behaviour of the interface between pantograph and contact wire in accordance with requirement of IEC and EN standards. The arc detector and video is installed on a train aim at the trailing contact strip according to the travel direction. The arc detector presented and measured verity of value such as the duration and power density of each arc and the video image is measured a image when the arc is occurred in pantograph. In this paper we analysis of video image in accordance with power density of arcing from arc detector and compared with video image and power density of arcing so as to produce quality of arcing from image.

Characterization of Working Electrode Using by Hydrothermal and Electrophoretic Deposition for Dye Sensitized Solar Cells

  • Gong, Jae-Seok;Choe, Yun-Su;Park, Min-Ho;Jeong, Su-Chang;Choe, Hyeon-Gwang;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.308-308
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    • 2013
  • 본 연구에 염료감응형 태양전지(Dye Sensitized Solar Cells; DSSCs)의 광전변환효율을 높이기 위해 작업전극에 새로운 구조의 광투과층 및 산란층을 도입하였다. DSSCs 작업전극의 빛을 투과시키는 투과층에 크기가 10 nm 이하의 nanoparticle $TiO_2$를 적용하고, 투과된 빛이 산란되어 많은 전자가 여기 될 수 있도록 기존의 큰 입자 사이즈였던 산란층을 이용하는 대신 $TiO_2$ nanorod 및 nanotube 형태의 구조를 도입하여 기존의 작업전극과 비교하였다. 산란층에서 방향성을 가지는 rutile 상의 $TiO_2$는 저온에서 안정적인 anatase 상의 $TiO_2$보다 화학적으로 안정하며, 높은 산란율을 가지고, 광에 의해 여기된 전자를 직접적으로 집전전극에 전달해 줌으로서 소자의 효율을 증가시킨다고 보고되고 있다. Rutile 상의 $TiO_2$ 층 제작 시 수열합성법을 이용하면 nanorod 모양의 $TiO_2$층을 형성할 수 있고, 이와 같은 방법으로 성장시킨 산란층에 전기영동법의 식각 효과를 사용하면 nanotube 모양의 $TiO_2$층을 성장시킬 수 있어 산란효과의 극대화 및 전극의 표면적을 넓히는 장점이 있다. 각각의 방법을 이용하여 만든 구조 위에 입자 크기 10 nm의 $TiO_2$를 Dr blade 방법으로 도포하여 double layer (산란층+흡수층)로 구성된 작업 전극을 이용한 DSSCs를 제작한 후 I-V curve와 EIS (Electrochemical Impedance Spectroscopy)를 측정하여 효율 및 전기화학적 특성을 분석하였다.

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STUDY ON THE PREVENTION METHOD FOR HEAT ACCUMULATION FOR PERSONAL RAPID TRANSIT (PRT) VEHICLE UNDER BODY (PRT 차량하부 열부하 저감방안 도출 연구)

  • Kwon, S.B.;Song, J.H.;Kang, S.W.;Jeong, R.G.;Kim, H.B.;Lee, C.H.;Seo, D.K.
    • Journal of computational fluids engineering
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    • v.18 no.1
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    • pp.58-62
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    • 2013
  • Personal Rapid Transit (PRT) is the emerging personal transport vehicle operating on the loop automatically. The PRT system utilize the electrical power from super capacity or battery, it is important to manage the power or energy. In this regards, the management of high temperature occurred by the operation of system is significantly important to prevent from serious damage of component. In this study, we studied the adequate shape of underbody which can reduce the heat accumulation by pickup coil and condenser using natural air cooling. We suggested the additional air pathway, air inlet and flow separator to decrease the temperature of the heat source components. It was found that suggested system can decrease the temperature of PRT under body by 16% during the static mode and by 10% during the running mode at 30km/h. It is expected that the findings of this study will feed into final design of newly built Korean PRT vehicle.

Specific Capacitance Characteristics of Electric Double Layer Capacitors with Phenol Based Activated Carbon Fiber Electrodes and Aqueous Electrolytes (페놀계 활성탄소섬유 전극과 수용성 전해질을 사용하는 전기이중층 캐패시터의 비축전용량 특성)

  • Kim, Jong Huy;An, Kay Hyeok;Shin, Kyung Hee;Ryoo, Min Woong;Kim, Dong Kuk
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.814-821
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    • 1999
  • The specific capacitance characteristics of the electric double layer capacitors(ELDC) which were made of phenol based activated carbon fiber(ACF) electrodes. Also the effect of aqueous electrolytes on the cell performance has been investigated with respect to different specific surface areas of electrodes and different kinds of aqueous electrolytes. It has been shown that larger surface area and pore size, higher conductivity of electrodes, and higher ion mobility of electrolytes have better specific capacitances. It has been found that heat treatment at $1200^{\circ}C$ and $CO_2$ post-activation at $900^{\circ}C$ of the electrode are effective to improve the specific capacitance over 145F/g and 165F/g, respectively. The EDLC showed high efficiency and long cycle life over 30000 cycles.

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A Study on the Geometry Change for the Increased Contact Wire Tension in the Pre-sagged Existing Catenary (사전 이도가 주어진 기설 전차선로에서 전차선 장력을 증가시켰을 때 전차선 기하학적 형상 변화 연구)

  • An, Seung-Hwa;Kim, Yoon-Ho
    • Journal of the Korean Society for Railway
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    • v.15 no.5
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    • pp.447-453
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    • 2012
  • It is studied that the structure of the contact plane geometry of the contact wire would be changed when the contact wire tension is increased in the existing overhead contact lines for the purpose of improving the operation speed temporarily. In this paper, the dropper length formula which could be well applied to the pre-sagged catenary is reviewed first. Second, the changing amount of the pre-sag if the contact wire tension change from 20kN to 23kN or from 20kN to 25kN for the Gyeongbu HSL(high speed line) 49.5m catenary is evaluated by using of the self-written program in accordance with the dropper length formula. Moreover, the increasing tension and measuring the pre-sag change experiment in the Gyeongbu 2 HSL was conducted. The calculated data are compared with the measured data. As a result, it is found that the geometry change is very little and will not make the current collection performance deteriorated.

Development of a Pulley-type Tensioning Device (도르래식 장력조정장치 개발)

  • Lee, Ki-Won;Cho, Yong-Hyeon;Park, Young
    • Journal of the Korean Society for Railway
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    • v.12 no.5
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    • pp.663-669
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    • 2009
  • In the electrical railway, the increase of tensions in an overhead contact lines is essential to speed-up of train, because current collection quality largely depends on the ratio of a wave propagation speed to a train speed. For Kyungbu high-speed line, a pulley-type tensioning device is required to have a tension variation of maximum 3%. Therefore we developed a pulley-type tensioning device in order to meet tension variation requirement of the high-speed tensioning device. To verify the performance of the developed device, a performance test, overload test and failure test were carried out according to the factory test procedure of the Kyung-Bu High-speed line. Furthermore, we also performed reliability performance through not only a fatigue test in a factory, but also on-line verification test in Chungbuk line for over 1 year. These tests verified that the tensioning device had applicability to a main line.

Substrate Effect on the Electrochemical Properties of $LiCoO_2$ Thin-Film Cathode for Li Microbattery (리튬 미소전지용 $LiCoO_2$ 박막양극의 전기화학적 특성에 미치는 기판의 영향)

  • Lee Jong-Ki;Lee Seung-Joo;Baik Hong-Koo;Lee Sung-Man
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.157-161
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    • 2000
  • In order to investigate the substrate effect on the electrochemical properties of thin-film electrode, $LiCoO_2$ was deposited onto the alumina, chemically etched-Si and flat-Si substrates. After annealing at $800^{\circ}C$ in $O_2$ for 30min, the film deposited on the alumina consisted of large particles with several cracks, whereas the film deposited on the flat-Si substrate was composed of very small and uniform particles. The films deposited on the flat-Si showed improved electrochemical properties such as peak potential divergence and rate-capability, over those deposited on the alumina and chemically etched-Si substrate, which can be attributed to the differences of the particle size surface morphology, and the electrical resistance of the current collector.

Electrochemical Characteristics of Assembled-Graphite/DSA Electrode for Redox Flow Battery (Redox Flow Battery용 일체화된 흑연/DSA 전극의 전기화학적 특성)

  • Kim, Hyung-Sun
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.123-127
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    • 2010
  • An assembled-graphite/DSA(Dimensionally Stable Anode) was prepared using graphite powder to increase durability and energy efficiency of redox flow battery and investigated its electrochemical properties in vanadium-based electrolyte. The cyclic voltammetry (CV) was carried out in the voltage range of -0.7V and 1.6V vs. SCE at 5 mV/sec scan rate to analyze vanadium redox reaction. From the CV results, the assembled-graphite/DSA electrode showed a fast couple reaction and good reversibility in 2M $VOSO_4$ + 2.5 M $H_2SO_4$ electrolyte. Therefore, it has been expected that this electrode increases power density as well as energy density of redox flow battery.

On the Implementation of an Advanced Judgement Algorithm for Contact Loss of Catenary System (전차선의 집전상태 판단 알고리즘 구현)

  • Park, Young;Jung, Ho-Sung;Yun, Il-Kwon;Kim, Wonha
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.6
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    • pp.850-854
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    • 2014
  • Analyzing dynamic performance between pantograph and contact wire depends on mechanical and electrical conditions such as contact force, currents, aerodynamics of pantograph and tension of overhead contact wire. For the characteristic of dynamic performance between pantograph and overhead contact wire, various evaluation systems are used to measuring of the interaction of the contact line and the pantograph. Among the various methods, the contact force and percentage of arcing are intended to prove the safety and the quality of the current collection system on the train. However, these methods are only capable of measuring on the train which are installed measurement systems. Therefore in this paper, a track-side monitoring system was implemented to measure electrical characteristics from active overhead contact wire systems in order to constantly estimate current collection performance of railway operation. In addition, a method to analyze loss of contact phenomena was proposed. According to simulation results, the proposed system was capable of measuring abnormal electrical behavior of pantograph and contact wires on the track-side. The advantage of the proposed system is possible to detect loss of contact or any other electrical abnormalities of all types of trains within sections from sub to sub without the need to install any on-board equipment on trains.