• Title/Summary/Keyword: 질소산화물)

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A Study on Characteristics of Exhaust Gas Emissions of Water-Bunker Oil Mixed by Homogenizer (균질기에 의해 혼합된 물-벙커유의 배기가스 배출 특성에 관한 연구)

  • Choi, Jung-Sik;Han, Sang-Goo;Choi, Jae-Hyuk;Park, Sang-Kyun;Park, Ro-Seong;Kim, Dae-Hun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.5
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    • pp.518-524
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    • 2013
  • In this study, we conducted a study on characteristics of exhaust gas emissions from boiler when water-bunker oil mixed by homogenizer was burned in boiler. The results showed that NOx concentration and CO concentration of the homogenized bunker oil was decreased by 19% and 54% compared to pure bunker oil pretreatment was not being performed. And, in the case of water-bunker A oil, the NOx concentration was decreased with increasing water mixing ratio in bunker A oil. In particular, the NOx concentration in exhaust gas of 20 %water-80 %bunker A oil decrease by 45 % compared with pure bunker-A. However, the CO concentration in exhaust gas of 20 %water-80 %bunker A oil shows irregular changes. This means that the mixing of water more than a certain amount can cause a decrease in combustion performance. From this result, it can be found that critical mixing ratio of water in bunker A oil for normal combustion is 15% in this study. Deposition amount of soot that is collected in the vicinity of the chimney was decreased with increasing water mixing ratio.

Combustion of Diesel Particulate Matters under Mixed Catalyst System of Fuel-Borne Catalyst and Perovskite: Influence of Composition of Perovskite (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn) on Combustion Activity (Fuel-Borne Catalyst와 Perovskite로 구성된 복합촉매 시스템에 의한 디젤 탄소입자상 물질의 연소반응: 반응성능과 Perovskite 촉매조성 (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn)의 상관관계)

  • Lee, Dae-Won;Sung, Ju Young;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.281-290
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    • 2018
  • As the internal combustion engine vehicles of high fuel efficiency and low emission are demanded, it becomes important to procure technologies for improving low-temperature performance of automotive catalyst systems. In this study, we showed that the combustion rate of diesel particulate matter is greatly enhanced at low temperature by applying fuel-borne catalyst and perovskite catalyst concurrently. It was tried to examine the correlation between elemental composition of perovskite catalyst and combustion activity of mixed catalyst system. To achieve this goal, we applied temperature-programmed oxidation technique in testing the combustion behavior of perovskite-mixed particulate matter bed which contained the element of fuel-borne catalyst or not. We tried to explain the synergetic action of two catalyst components by comparing the trends of concentrations of carbon dioxide and nitrogen oxide in temperature-programmed oxidation results.

Experimental Study on Characteristics of NOX Reduction with Urea-Selective Catalytic Reduction System in Diesel Passenger Vehicle (승용 디젤차량에서 Urea-SCR 시스템의 NOX 저감 특성에 관한 실험적 연구)

  • Park, Seungwon;Lee, Seangwock;Cho, Yongseok;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.269-275
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    • 2017
  • $NO_X$ reducing technique such as LNT, LNC, and selective catalytic reduction (SCR) have been developed and applied, especially on heavy-duty vehicles. However, it is expected that $NO_X$ reduction techniques will also be applied to diesel passenger vehicles. The urea-SCR system is receiving attention as the most effective $NO_X$ reduction technology without a fuel penalty. Thus, many advanced countries are developing this technology. The urea-SCR system sprays an aqueous urea solution that separates $NO_X$ into $N_2$ and $H_2O$, which are harmless and emitted into the atmosphere. The urea injected in front of the SCR catalyst should be changed to 100% $NH_3$, which is required for $NO_X$ reduction in the SCR system to maximize the reduction efficiency. The purpose of this study was to determine the basic data for the urea-SCR system to maximize the $NO_X$ reduction efficiency by understanding the $NO_X$ reduction characteristics in a real passenger vehicle to comply with the post EURO-6 emission regulation.

Recovery of the Vanadium and Tungsten from Spent SCR Catalyst Leach Solutions by Hydrometallurgical Methods (SCR 폐촉매 침출액으로부터 습식제련법에 의한 바나듐, 텅스텐의 회수)

  • Choi, In-Hyeok;Moon, Gyeonghye;Jeon, Jong-Hyuk;Lee, Jin-Young;Jyothi, Rajesh Kumar
    • Resources Recycling
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    • v.29 no.2
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    • pp.62-68
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    • 2020
  • In new millennium, wide-reaching demands for selective catalytic reduction (SCR) catalyst have been increased gradually in new millennium. SCR catalyst can prevent the NOx emission to protect the environment. In SCR catalyst the main composition of the catalyst is typically TiO2 (70~80%), WO3 (7~10%), V2O5 (~1%) and others. When the SCR catalysts are used up and disposed to landfills, it is problematic that those should exist in the landfill site permanently due to their extremely low degradability. A new advanced technology needs to be developed primarily to protect environment and then recover the valuable metals. Hydrometallurgical techniques such as leaching and liquid-liquid extraction was designed and developed for the spent SCR catalyst processing. In a first stage, V and W selectively leached from spent SCR catalyst, then both the metals were processed by liquid-liquid extraction process. Various commercial extractants such as D2EHPA, PC 88A, TBP, Cyanex 272, Aliquat 336 were tested for selective extraction of title metals. Scrubbing and stripping studies were tested and optimized for vanadium and tungsten extraction and possible separation. 3rd phase studies were optimized by using iso-decanol reagent.

Manufacture and Characteristics of Concrete Sidewalk Blocks Using Photocatalyst Agent (광촉매제를 사용한 콘크리트 보도블록의 제조 및 특성)

  • Jung, Yong-Wook;Chang, Chun-Ho;Kim, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.423-430
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    • 2019
  • In this study, the flexural strength, absorption rate, methylene blue photo catalyst decomposition performance and anti-fouling performance were evaluated according to the photo catalyst mixing rate and block surface wash status by applying photo catalyst to the surface layer of concrete sidewalk block. The results showed that the flexural strength of the block that mixed photo catalyst only in the surface layer of the concrete block was 5.32MPa of the general block (SNW) of 5% photo catalyst, compared to 5.46MPa of the non-mixed concrete block of the reference concrete block. Surface washing block (SW) 5.26MPa, 10% photo catalyst general block (SNW) 5.26MPa, and 5.15MPa surface washing block (SW). It has been shown that the presence of surface washing and the mixing rate of photo catalyst in the concrete block have no effect on the flexural strength. Moreover, the photoreaction performance of concrete sidewalk blocks showed that the methylene blue removal rate of specimens with 5% TiO2 was 34.2%, the methylene blue removal rate of specimens with 10% TiO2 was 37.1%, and the removal rate of the methylene blue of specimens with 5% TiO2 was about 37.9% and 10% mixed specimens with TiO2 was about 37.6%.

Investigation of Tar/soot Yield of Bituminous and Low Rank Coal Blends (발전용 역청탄과 저열량탄 혼소시 Tar/Soot의 배출 특성 연구)

  • Lee, Byung Hwa;Kim, Jin Ho;Kim, Gyu Bo;Kim, Seng Mo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.42-48
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    • 2014
  • Soot and tar which were derived from combustion or pyrolysis processes in Puverized Coal(PC) furnace or boiler have been significantly dealing in a radiative heat transfer and an additional source of NOx. Furthermore, the increasing for the use of a coal with low caloric value gives rise to a lot of tar-soot yield and LOI in a recycled ash for using cement materials. So, the ash with higher tar-soot yield and LOI can not recycle due to decreased strength of concrete. In this study, tar-soot yields and flame structures were investigated using the LFR for a blending combustion with bituminous coal and sub-bituminous coal. Also, The investigation were conducted as each single coals and blending ratio. The coals are used in a doestic power plant. In the experimental results, sub-bituminous coal with high volatile contents shows longer soot cloud length than bituminous coal, but overall flame length was shorter than bituminous coal. Tar-soot yields of sub-bituminous coal is lower than those of bituminous coal. Combustion characteristics are different between single coal and blended coal. Therefore, finding an optimal coal blending ratio according to coal rank effects on tar-soot yields.

A Study on the Combustion Flow Characteristic and NOx Reduction of the Exhaust Gas Recurculation Burner using Coanda Nozzles (코안다 노즐을 이용한 배기가스 재순환 버너의 연소 유동 특성 및 NOx 저감에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.21 no.3
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    • pp.53-60
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    • 2017
  • Various researches have been conducted for the reduction of NOx at the combustion furnace and exhaust gas recirculation method is commonly used technology for NOx reduction. The present research adopted coanda nozzles at the outside pipes of furnace to entrain the exhaust gas for the exhaust gas recirculation and the mixed gas was ejected to the tangential direction to cause the swirl flow in the furnace. The combustion flow characteristics in the exhaust gas recirculation burner with coanda nozzle has been elucidated by analyzing the swirl flow streamlines, temepraure and reaction rate distribution in the furnace. The exhaust gas entrained flow rate has been investigated by changing the excess air factor and coanda nozzle gap and the exhaust gas entrained flow rate increased with the increase of excess air factor and it decreased with the increase of coanda nozzle gap. The mean temperature at the exit plane of exhaust gas decreased with the excess air factor and it was little affected by the increase of coanda nozzle gap. The NOx mass fraction at the exhaust gas exit plane remarkably decreased with the excess air factor and it was also little affected by the increase of coanda nozzle gap.

Development and Application of an Evaluation Method for a Freight Vehicle Route Management System (화물자동차 통행관리제도의 평가방법 개발 및 적용 (서울지역을 대상으로))

  • Kim, Yu-Chan;Park, Dong-Joo
    • Journal of Korean Society of Transportation
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    • v.26 no.4
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    • pp.17-28
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    • 2008
  • Favorable policies for freight vehicles (i.e., trucks), such as exclusive "Truck-ways," have been proposed, and at the same time restricted policies for freight vehicles have been suggested because transportation of goods by truck aggravates traffic congestion and environmental conditions in urban areas. This study discusses the limitations of assessment processes for freight vehicle route management systems which have been carried out from limited perspectives such as physical distribution efficiency and traffic circulation. The objective of this study is to propose an assessment method of truck route management systems in urban areas which includes more varied criteria. This research modified the two existing assessment indices of physical distribution efficiency and traffic circulation. In addition two new assessment indexes are proposed: (i) exposure indices for population directly influenced by nitrous oxide, a representative pollutant, and (ii) a friction index between trips for attending elementary school and freight vehicle trips. It was found that from the perspective of physical distribution efficiency and traffic circulation, the "before" alternative is better than "after". However, from the aspect of traffic safety and environmental impacts the "after" alternative is better than "before". It is expected that the proposed evaluation method in this study would be useful when identifying reasonable policies for truck route management in urban areas.

The Realization on GAS Sensor Module for Inteligent Wireless Communication (지능형 무선통신용 가스 센서 모듈 구현)

  • Kim, Hyo-Chan;Weon, Young-Su;Cho, Hyung-Rae
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.11 no.6
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    • pp.123-132
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    • 2012
  • Gas sensors has been used very differently that depending on following purposes; Automotive (exhaust gas, fuel mixture gas, oxygen, particulates), agriculture / food industry (fresh, stored, CO2, humidity, NH3, nitrogen oxide gas, organic gas, toxic gas emitted from pesticides and insecticides), industrial / medical (chemical gas, hydrogen, oxygen and toxic gases), military (chemical weapon), environmental measurements (CO and other air pollution consisting of sulfur and nitrogen gas), residential (LNG, LPG, butane, indoor air, humidity). The types of industrial toxic substances are known about 700 species and many of these exist in gaseous form under normal conditions. he multi-gas detection sensors will be developed for casualties that detect the most important and find easy three kinds of gases in marine plant; carbon dioxide(CO2), carbon(CO), ammonia(NH3). Package block consists of gas sensing device minor ingredient, rf front end, zigbee chip. Develope interworking technology between the sensor and zigbee chip inside a package. Conduct a performance test through test jig about prototype zigbee sensor module with rf output power and unwanted emission test. This research task available early address when poisonous gas leaked from large industrial site and contribution for workers' safety at the enclosed space.

An appropriateness review on the road tunnel ventilation standards by pollutants site measurement and case study (오염물질 현장측정 및 사례조사를 통한 도로터널 환기기준의 적정성에 관한 연구)

  • Kim, Hyo-Gyu;Baek, Doo-San;Yoo, Ji-Oh
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.3
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    • pp.323-335
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    • 2020
  • In this study, a series of site measurement of particulate and gases pollutants at five tunnels were carried out along with case studies to review the suitability of the current road tunnel ventilation design standards. Previous studies by other researchers have shown that the ratios of the level of measurement to the standard were 27.9%, 1.6% and 3.4% for TSP, CO and NOx, respectively. Those measured in this site study shows even lower ratios; the ratios were 2.6%, 0.8% and 0.3%, for TSP, CO and NOx, respectively. The particle size analysis of TSP for the five tunnels shows that PM10 including tire wear and re-suspended road dust exceeded 20.4%. This implies that non-exhaust particulate matter must be taken into account, since the current design standards for the particulate matter (visibility) include only the engine emission. Based on the recent research results, for vehicle emission rate and slope-speed correction factors, revision of ventilation design standards for pollutants is required. WRA (PIARC) also emphasizes the necessity of the ventilation design standards for pollutants. In addition, enactment of a new road tunnel ventilation system operation standard or guideline is strongly recommended when considering the low operating rate of the ventilation system with jet-fans.