• Analytical Science and Technology
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• v.31 no.6
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• pp.225-231
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• 2018

Benzoic acid, methyl paraben, and butyl paraben are preservatives that have been used in pharmaceutical, cosmetic, and food products. However, as their toxicities for human have been reported, many nations and organizations including Korea have established a regulation limit for thier usage of these preservatives in food products. The present study developed the isotope dilution liquid chromatography mass spectrometry method for accurate determination of three target preseratives in soysauce. In this study, the isotope dilution liquid chromatography mass spectrometry method was developed for accurate determination of three target preservatives in soy sauce. LC separation was optimized considering the pKa of benzoic acid which is lower than those of methyl and butyl parabens. A C18 column was used with 5 mM ammonium acetate and methanol as mobile phases. Mass spectrometry was operated in negative mode and selected reaction monitoring mode (SRM). Soy sauce sample was cleaned-up with C18 SPE cartridge for removing matrix inferences and color material. Optimized conditions and the method were validated with soy sauce reference materials for the analysis of food preservatives from Health Science Authority in Singapore. The measured values of benzoic acid, methyl and butyl paraben agreed well with reference values within their uncertainties.

• Journal of Conservation Science
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• v.28 no.1
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• pp.63-73
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• 2012

In this study, the 89 components of the gases emitted from grave goods at Sim Seol(1570-1630) tomb identified and quantitatively analyzed using a thermal desorption system integrated with gas chromatography-mass spectrometer. The concentration of major components show the levels of alpha-pinene 4,113ppbv, beta-pinene 2,510ppbv and limonene 2,424ppbv, that of the others orderly show p-menth-2-ene, acetone, isolongifolene and isoborneol. The functional groups of high concentration level cover 65% of terpenes and 25.8% of alcohols. The expected odor intensity orderly show 35.1% of terpenes, 33.4% of aldehydes and 8.8% of alcohols. Terpenes have generally effect of a perfume, antifungal and antimicrobial activity, and could come out of the pine(Pinus densiflora) coffin, aldehydes and alcohols could be come out of both the Sim Seol mirra and Pinus densiflora for a long time. The analyses of gases emitted from a excavated properties or a tomb are assessed that it can pc001 provide a scientific basis on a counterplan against harmful gases, a method of conservation treatments and a evaluation of effectiveness in conservation of cultural properties in a tomb.

• Journal of Conservation Science
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• v.32 no.4
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• pp.449-457
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• 2016

A stoneware bottle was recovered from the Incheon Yeongheungdo Shipwreck in 2013. Primary observations showed that this object had a sealed opening and was covered with a foreign material. After it was cleaned via mechanical and chemical methods, wave patterns were observed on the outer surface of the bottle and a yellowish-brown transparent material was found within. In this paper, the process of conserving the stoneware bottle and the analysis conducted on the unknown material found within is explained. The conservation process included steps such as cleaning, desalination and restoration. After of the missing area located at the rim, the original shape of the bottle was made clear. In addition, the unknown inner material was analyzed using FT-IR and GC-MS. Results showed that the material is similar to golden lacquer. It is speculated that the Yeongheungdo Ship had wrecked during the Unified Silla period while carrying a bottle loaded with golden lacquer.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.7 no.4
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• pp.313-320
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• 1995

A numerical analysis on the wave deformation in the shallow water region is performed for the case of two intersecting wave trains of the same frequency on uniformly sloping beaches. This model is based on the consideration of wave energy balance and wave action conservation, and iteratively solved the set of conservation equations of both mass and horizontal momentum. Using the computed results, the wave deformations in accordance with the variation of the parameters luck as incident wave angie and wave height in deep water which influences the variation of wave hight and mean water level under the intersecting wave trains in the shallow water region. are considered.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.63-63
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• 2017

우리나라에서 홍수기에는 하천에 부유사를 포함한 수체가 침강되어 하층 밀도류 형태로 전파된다. 온도로 성층화가 심하게 되지 않은 댐의 경우 하층 밀도류로 댐체까지 전파되고, 유출되어 하류로 흘러가거나 차단되어 담수된다. 침사용 저수지는 하류에 있는 저수지에 유사 전파를 막기 위해 건설된 댐으로, 이를 잘 관리하기 위해서는 밀도류의 차단에 대한 연구가 필수적이다. 따라서 본 연구의 목적은 층적분 모형을 사용하여 밀도류의 전파와 이에 따른 저수지의 유사 차단 현상을 모의하는 것이다. 이를 위하여 1차원 수치모형을 제시하였으며 실내실험 자료에 적용하여 밀도류의 전파 및 차단 양상을 분석하였다. 모의 결과 소류사는 대부분 상류단에서 퇴적되고, 부유사가 밀도류에 포함되어 하류단까지 전파되고, 차단되는 것을 확인하였다. 또한, 질량보존과 운동량 보존에 의해 저수지 전체에서 밀도류 두께가 증가되며 담수되는 현상을 확인하였다. 담수된 밀도류의 포집효율에 영향을 미치는 인자를 분석하고, 포집효율에 대한 각 입자의 민감도 분석을 수행하였다.

• Journal of the Korean Chemical Society
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• v.64 no.5
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• pp.304-317
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• 2020

This study was conducted on four 11^th grade students at a high school in a small town to determine the effectiveness of responsive teaching. The three phases of the responsive teaching method proposed in the previous study were subdivided into six stages; Step 1 is elicitation of students' thoughts related to macroscopic world, Step 2 is drawing of students' early thoughts related to microscopic world, Step 3 is disciplinary connections with ideas of the particle, Step 4 is to clarify the learner's thoughts on the particle by the teacher's involvement, Step 5 is deepening students' thoughts, and Step 6 is expanding ideas. In Step 4, students came to the recognition that the cause of mass was atoms and that the cause of volume was molecules. In Step 5, students led to a shift in thinking that could ignore the volume of the molecules themselves through the properties of protons and neutrons that affect mass from a particle perspective. In the Step 6 of expanding ideas, students explained molecular motion by the concept of material point which ignores the volume of particles. This steps gave students perspectives on the relationship between the mass and volume of particles required by Avogadro's law. The students recognized that some systems could be studied only indirectly because they were too small, too large, too fast, or too slow to observe directly.

• Water for future
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• v.37 no.3
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• pp.44-49
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• 2004

지표 수문학(surface hydrology)은 강수에 의한 수자원의 발생, 육지나 하천, 그리고 해양에서 발생하는 증발이나 유출 등에 의한 수자원의 손실과 저수지나 댐에서 수위 상승, 토양수분이나 적설의 증가, 그리고 지하수면의 상승 등에 의한 저류량의 증가 등을 종합적으로 설명하는 과학이다. 수자원의 발생이나 손실, 그리고 저류량의 증가를 설명하기 위해서는 질량보존의 법칙과 같은 단순한 물수지 방정식을 이용한다. 그러나, 지표면에서 발생되는 증발이나 식물에 의해서 발생되는 증산 등과 같은 증발산 작용은 에너지를 수반하기 때문에 수문학적인 수지를 규명하기 위해서는 물수지와 에너지수지를 동시에 이용해야 한다.(중략)

• Proceedings of the Korea Society for Simulation Conference
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• 1998.10a
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• pp.95-99
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• 1998

한전 전력연구원은 발전소의 복잡한 계통을 효과적으로 시뮬레이션하는 GUI(Graphical User Interface)에 기반을 둔 시뮬레이션 툴(PowerSim)을 독자적으로 개발하였다. 본 논문에서는 열교환기, 펌프, 밸브, 탱크등의 구성요소에 적합한 열수력 모델을 개발하고, 이 모델을 ORCAD로부터 생성된 Netlist의 연결정보에 맞게 연결하여 발전계통을 시뮬레이션하는 과정을 서술하였다. 또한, 발전계통의 열수력현상을 지배하는 질량, 운동량, 에너지 보존 방정식을 실시간에서 풀 수 있는 알고리즘을 제시하였다.

• Journal of Conservation Science
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• v.31 no.3
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• pp.299-308
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• 2015

Aim of this study is to identify dyestuff of the Dallryeong(official's robe in Joseon Dynasty, 16th century) excavated from Yuryang-dong, Cheonan, in 1996. For this purpose, extracted dyestuffs from Dallryeong fabric and from natural dyestuffs for red color(safflower, Sapanwood, Madder) which are presumed to have been used in the Dallryeong, are analyzed and compared by high performance liquid chromatography(HPLC). As a result, HPLC chromatogram of extracts of the Dallryeong's dyestuff and safflower are showed a peak at 17.5 minutes. The UV/Vis spectra of the samples are showed the maximum absorption wavelength at 519nm. This result is identical with the analysis of the previous studies on red dyestuff of safflower. In addition, the analysis of Mass Spectrometry(MS) showed the identical result of the peak with m/z 910. Following these results, excavated pink Dallryeong were considered to have been dyed with safflower.

• Journal of the Korean Chemical Society
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• v.57 no.4
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• pp.507-514
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• 2013

In this study, the characteristics of visually impaired elementary students' conceptions on dissolution were investigated. The semi-structured interviews about phenomenon of dissolution, uniformity of solution, conservation of mass on dissolving and volume change during dissolving were conducted with 4 fifth-grade elementary students with visual impairments (three were blind, and one had low-vision). Interviews were recorded and the data were analyzed after transcription. As a result, students with visual impairments knew well about the phenomenon of dissolution, uniformity of solution, and conservation of mass on dissolving, while they couldn't explain volume change during dissolving. Although students with visual impairments were found to have similar level of understanding with students without visual impairments, they had sounder understanding about uniformity of solution. However, students with visual impairments had superficial understanding based on phenomenal experiences. Some of students with visual impairments tried to give micro-level explanation. Based on these results, educational implications were discussed.